DK2949813T3 - Fremgangsmåde til fremstilling af et overflade-modificeret materiale - Google Patents

Fremgangsmåde til fremstilling af et overflade-modificeret materiale Download PDF

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DK2949813T3
DK2949813T3 DK14169922.3T DK14169922T DK2949813T3 DK 2949813 T3 DK2949813 T3 DK 2949813T3 DK 14169922 T DK14169922 T DK 14169922T DK 2949813 T3 DK2949813 T3 DK 2949813T3
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Denmark
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acid
succinic anhydride
alkaline earth
coating
ester
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DK14169922.3T
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English (en)
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Roger Bollström
Joachim Schoelkopf
Patrick Arthur Charles Gane
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Omya Int Ag
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01L—CHEMICAL OR PHYSICAL LABORATORY APPARATUS FOR GENERAL USE
    • B01L3/00—Containers or dishes for laboratory use, e.g. laboratory glassware; Droppers
    • B01L3/50—Containers for the purpose of retaining a material to be analysed, e.g. test tubes
    • B01L3/502—Containers for the purpose of retaining a material to be analysed, e.g. test tubes with fluid transport, e.g. in multi-compartment structures
    • B01L3/5027—Containers for the purpose of retaining a material to be analysed, e.g. test tubes with fluid transport, e.g. in multi-compartment structures by integrated microfluidic structures, i.e. dimensions of channels and chambers are such that surface tension forces are important, e.g. lab-on-a-chip
    • B01L3/502707—Containers for the purpose of retaining a material to be analysed, e.g. test tubes with fluid transport, e.g. in multi-compartment structures by integrated microfluidic structures, i.e. dimensions of channels and chambers are such that surface tension forces are important, e.g. lab-on-a-chip characterised by the manufacture of the container or its components
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F11/00—Compounds of calcium, strontium, or barium
    • C01F11/18—Carbonates
    • C01F11/185—After-treatment, e.g. grinding, purification, conversion of crystal morphology
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01L—CHEMICAL OR PHYSICAL LABORATORY APPARATUS FOR GENERAL USE
    • B01L3/00—Containers or dishes for laboratory use, e.g. laboratory glassware; Droppers
    • B01L3/50—Containers for the purpose of retaining a material to be analysed, e.g. test tubes
    • B01L3/508—Containers for the purpose of retaining a material to be analysed, e.g. test tubes rigid containers not provided for above
    • B01L3/5085—Containers for the purpose of retaining a material to be analysed, e.g. test tubes rigid containers not provided for above for multiple samples, e.g. microtitration plates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M3/00—Printing processes to produce particular kinds of printed work, e.g. patterns
    • B41M3/14—Security printing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5218—Macromolecular coatings characterised by inorganic additives, e.g. pigments, clays
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C09D11/108—Hydrocarbon resins
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/30—Inkjet printing inks
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
    • C09D125/02—Homopolymers or copolymers of hydrocarbons
    • C09D125/04—Homopolymers or copolymers of styrene
    • C09D125/06—Polystyrene
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
    • C09D125/02—Homopolymers or copolymers of hydrocarbons
    • C09D125/04—Homopolymers or copolymers of styrene
    • C09D125/08—Copolymers of styrene
    • C09D125/14—Copolymers of styrene with unsaturated esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C09D5/1681—Antifouling coatings characterised by surface structure, e.g. for roughness effect giving superhydrophobic coatings or Lotus effect
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/38—Coatings with pigments characterised by the pigments
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/66—Coatings characterised by a special visual effect, e.g. patterned, textured
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/72—Coated paper characterised by the paper substrate
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01L—CHEMICAL OR PHYSICAL LABORATORY APPARATUS FOR GENERAL USE
    • B01L2200/00—Solutions for specific problems relating to chemical or physical laboratory apparatus
    • B01L2200/12—Specific details about manufacturing devices
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01L—CHEMICAL OR PHYSICAL LABORATORY APPARATUS FOR GENERAL USE
    • B01L2300/00—Additional constructional details
    • B01L2300/08—Geometry, shape and general structure
    • B01L2300/0809—Geometry, shape and general structure rectangular shaped
    • B01L2300/0829—Multi-well plates; Microtitration plates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01L—CHEMICAL OR PHYSICAL LABORATORY APPARATUS FOR GENERAL USE
    • B01L2300/00—Additional constructional details
    • B01L2300/12—Specific details about materials
    • B01L2300/126—Paper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01L—CHEMICAL OR PHYSICAL LABORATORY APPARATUS FOR GENERAL USE
    • B01L2300/00—Additional constructional details
    • B01L2300/16—Surface properties and coatings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01L—CHEMICAL OR PHYSICAL LABORATORY APPARATUS FOR GENERAL USE
    • B01L2300/00—Additional constructional details
    • B01L2300/16—Surface properties and coatings
    • B01L2300/161—Control and use of surface tension forces, e.g. hydrophobic, hydrophilic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01L—CHEMICAL OR PHYSICAL LABORATORY APPARATUS FOR GENERAL USE
    • B01L2300/00—Additional constructional details
    • B01L2300/16—Surface properties and coatings
    • B01L2300/161—Control and use of surface tension forces, e.g. hydrophobic, hydrophilic
    • B01L2300/165—Specific details about hydrophobic, oleophobic surfaces
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/0011—Pre-treatment or treatment during printing of the recording material, e.g. heating, irradiating
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C08K2003/265—Calcium, strontium or barium carbonate

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
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  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
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  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Hematology (AREA)
  • Analytical Chemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Clinical Laboratory Science (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Geology (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Paints Or Removers (AREA)
  • Paper (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Surface Treatment Of Glass (AREA)
  • ing And Chemical Polishing (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Claims (17)

1. Fremgangsmåde til fremstilling af et overflade-modificeret materiale, omfattende følgende trin: a) at tilvejebringe et substrat, hvor substratet omfatter på mindst en side et coatinglag omfattende en saltdannende alkali- eller jordalkaliforbindelse, og b) at påføre en flydende behandlingssammensætning omfattende en syre på mindst et område af coatinglaget for at danne mindst et overflademodificeret område på og/eller inden i coatinglaget.
2. Fremgangsmåde ifølge krav 1, hvor substratet fra trin a) fremstilles ved i) at tilvejebringe et substrat, ii) at påføre en coatingsammensætning omfattende en saltdannende alkalieller jordalkaliforbindelse på mindst en side af substratet for at danne et coatinglag, og iii) at tørre coatinglaget.
3. Fremgangsmåde ifølge et hvilket som helst af de foregående krav, hvor substratet er valgt fra gruppen omfattende papir, karton, massivpap, plastic, cellofan, tekstil, træ, metal, glas, micablad, nitrocellulose, eller beton, fortrinsvis papir, karton, massivpap, eller plastic.
4. Fremgangsmåde ifølge et hvilket som helst af de foregående krav, hvor den saltdannende alkali- eller jordalkaliforbindelse er et alkali- eller jordalkalioxid, et alkali- eller jordalkalihydroxid, et alkali- eller jordalkalialkoxid, et alkali- eller jordalkalimethylcarbonat, et alkali- eller jordalkalihydroxycarbonat, et alkali- eller jordalkalibicarbonat, et alkali eller jordalkalicarbonat, eller en blanding deraf, fortrinsvis er den saltdannende alkali- eller jordalkaliforbindelse et alkali- eller jordalkalicarbonat der fortrinsvis er valgt fra lithiumcarbonat, natriumcarbonat, kaliumcarbonat, magnesiumcarbonat, calciummagnesiumcarbonat, calciumcarbonat, eller blandinger deraf, mere fortrinsvis er den saltdannende alkali- eller jordalkaliforbindelse calciumcarbonat, og mest fortrinsvis er den saltdannende alkali- eller jordalkaliforbindelse et formalet calciumcarbonat, et præcipiteret calciumcarbonat og/eller et overfladebehandlet calciumcarbonat.
5. Fremgangsmåde ifølge et hvilket som helst af de foregående krav, hvor den saltdannende alkali- eller jordalkaliforbindelse er i form af partikler med en vægtgennemsnitlig partikelstørrelse dso fra 15 nm til 200 pm, fortrinsvis fra 20 nm til 100 pm, mere fortrinsvis fra 50 nm til 50 pm, og mest fortrinsvis fra 100 nm til 2 pm.
6. Fremgangsmåde ifølge et hvilket som helst af de foregående krav, hvor coatinglaget endvidere omfatter et bindemiddel, fortrinsvis i en mængde fra 1 til 50 vægtprocent, baseret på den samlede vægt af den saltdannende alkali- eller jordalkaliforbindelse, fortrinsvis fra 3 til 30 vægtprocent, og mere fortrinsvis fra 5 til 15 vægtprocent.
7. Fremgangsmåde ifølge et hvilket som helst af de foregående krav, hvor syren er valgt fra gruppen bestående af saltsyre, svovlsyre, svovlsyrling, fosforsyre, citronsyre, oxalsyre, eddikesyre, myresyre, sulfaminsyre, vinsyre, fytinsyre, borsyre, ravsyre, suberinsyre, benzoesyre, og blandinger deraf, fortrinsvis er syren valgt fra gruppen bestående af saltsyre, svovlsyre, svovlsyrling, fosforsyre, oxalsyre, borsyre, suberinsyre, ravsyre, sulfaminsyre, vinsyre, eller blandinger deraf, mere fortrinsvis er syren valgt fra gruppen bestående af svovlsyre, fosforsyre, borsyre, suberinsyre, sulfaminsyre, vinsyre, eller blandinger deraf, og mest fortrinsvis er syren fosforsyre.
8. Fremgangsmåde ifølge et hvilket som helst af de foregående krav, hvor den flydende behandlingssammensætning endvidere omfatter en trykfarve, en pigmenteret trykfarve, et farvestof, en farve, metalioner, overgangsmetalioner, et overfladeaktivt stof, et opløsningsmiddel, et biocid, en korrosionsinhibitor, et farmaceutisk middel, et hydrofobiseringsmiddel, en voks, et salt, en polymer, en smeltelim, og/eller en polymeriseringssammensætning.
9. Fremgangsmåde ifølge et hvilket som helst af de foregående krav, hvor den flydende behandlingssammensætning omfatter syren i en mængde fra 0,1 til 100 vægtprocent, baseret på den samlede vægt af den flydende sammensætning, fortrinsvis i en mængde fra 1 til 80 vægtprocent, mere fortrinsvis i en mængde fra 2 til 50 vægtprocent, og mest fortrinsvis i en mængde fra 5 til 30 vægtprocent.
10. Fremgangsmåde ifølge et hvilket som helst af de foregående krav, hvor den flydende behandlingssammensætning påføres med sprøjtecoating, inkjettryk, offsettryk, flexotryk, filmtryk, udtegning, kontaktprægning, rotogravuretryk, spincoating, omvendt gravurecoating, spaltecoating, tæppecoating, slide bed coating, filmpresse, afmålt filmpresse, klingecoating, børstecoating og/eller en stift, fortrinsvis med inkjettryk eller sprøjtecoating.
11. Fremgangsmåde ifølge et hvilket som helst af de foregående krav, hvor den flydende behandlingssammensætning kontinuerligt påføres hele coatinglaget.
12. Fremgangsmåde ifølge et hvilket som helst af kravene 1 til 10, hvor den flydende behandlingssammensætning påføres coatinglaget i form af et forvalgt mønster, fortrinsvis i form af kanaler, barrierer, arrays, endimensionale stregkoder, todimensionale stregkoder, tredimensionale stregkoder, sikkerhedsmærker, tal, bogstaver, billeder eller designs.
13. Fremgangsmåde ifølge et hvilket som helst af de foregående krav, hvor fremgangsmåden endvidere omfatter et trin c) til at påføre et beskyttelseslag over det mindst ene overflade-modificerede område.
14. Fremgangsmåde ifølge et hvilket som helst af de foregående krav, hvor det mindst ene overflade-modificerede område opnået i trin b) vaskes eller skylles.
15. Overflade-modificeret materiale opnåelig med en fremgangsmåde ifølge et hvilket som helst af kravene 1 til 14.
16. Overflade-modificeret materiale ifølge krav 15, hvor det overflademodificerede materiale er et bioassayværktøj, en mikrofluidindretning, en indretning med et laboratorie på en chip, et papir-baseret analyse- og/eller diagnoseværktøj, en separationsplatform, et printmedie, et indpakningsmateriale, en vægmaling, en stregkode eller en datalagring.
17. Anvendelse af et overflade-modificeret materiale ifølge krav 15 eller 16 i trykapplikationer, i analyseapplikationer, i diagnoseapplikationer, i bioassays, i kemiske anvendelser, i elektriske anvendelser, i sikkerhedsindretninger, i synlige eller skjulte sikkerhedselementer, i mærkebeskyttelse, i mikroskrift, i mikrobilleder, i dekorative, kunstneriske, eller visuelle applikation, eller i indpakningsapplikationer.
DK14169922.3T 2014-05-26 2014-05-26 Fremgangsmåde til fremstilling af et overflade-modificeret materiale DK2949813T3 (da)

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US (1) US20170065974A1 (da)
EP (2) EP2949813B1 (da)
JP (2) JP2017522173A (da)
KR (2) KR102169594B1 (da)
CN (1) CN106458625B (da)
AR (1) AR100559A1 (da)
AU (1) AU2015266194B2 (da)
CA (1) CA2947664C (da)
CL (1) CL2016002996A1 (da)
DK (1) DK2949813T3 (da)
ES (1) ES2626081T3 (da)
HR (1) HRP20170647T1 (da)
HU (1) HUE032687T2 (da)
LT (1) LT2949813T (da)
MX (1) MX355857B (da)
MY (1) MY174610A (da)
PL (1) PL2949813T3 (da)
PT (1) PT2949813T (da)
RS (1) RS55895B1 (da)
RU (1) RU2663163C2 (da)
SG (1) SG11201608903PA (da)
SI (1) SI2949813T1 (da)
TW (1) TWI625304B (da)
UY (1) UY36135A (da)
WO (1) WO2015181056A1 (da)

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BR112018002238A2 (pt) 2015-08-06 2018-11-06 Lia Diagnostics, Inc. ensaios dispersíveis em água
PL3156369T3 (pl) 2015-10-16 2019-01-31 Omya International Ag PCC o dużej zawartości części stałych z dodatkiem kopolimerowym
EP3173247A1 (en) * 2015-11-24 2017-05-31 Omya International AG Printed watermark
EP3173522A1 (en) * 2015-11-24 2017-05-31 Omya International AG Method of tagging a substrate
EP3429962A4 (en) * 2016-03-15 2019-11-13 Imerys Carbonates USA, Inc. MINERALS WITH CHANGED SURFACE PROPERTIES
KR102213567B1 (ko) * 2016-07-15 2021-02-05 리아 다이아그노스틱스, 인크. 일시적으로 소수성인 매트릭스 물질의 처리, 물질, 키트 및 방법
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