DK2882826T3 - Katalytisk pyrolysefremgangsmåde - Google Patents

Katalytisk pyrolysefremgangsmåde Download PDF

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Publication number
DK2882826T3
DK2882826T3 DK13750287.8T DK13750287T DK2882826T3 DK 2882826 T3 DK2882826 T3 DK 2882826T3 DK 13750287 T DK13750287 T DK 13750287T DK 2882826 T3 DK2882826 T3 DK 2882826T3
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pyrolysis
weight
catalyst
reactor
added
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DK13750287.8T
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Milena Vasic
Martinus Henricus Pronk
Duren Ruben Van
Melle Koch
Den Oetelaar Leonardus Cornelis Albertus Van
Der Beek David Van
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Albemarle Europe Sprl
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B49/00—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated
    • C10B49/16—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with moving solid heat-carriers in divided form
    • C10B49/20—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with moving solid heat-carriers in divided form in dispersed form
    • C10B49/22—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with moving solid heat-carriers in divided form in dispersed form according to the "fluidised bed" technique
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B57/00—Other carbonising or coking processes; Features of destructive distillation processes in general
    • C10B57/04—Other carbonising or coking processes; Features of destructive distillation processes in general using charges of special composition
    • C10B57/06—Other carbonising or coking processes; Features of destructive distillation processes in general using charges of special composition containing additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • C10B53/02—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10C—WORKING-UP PITCH, ASPHALT, BITUMEN, TAR; PYROLIGNEOUS ACID
    • C10C5/00—Production of pyroligneous acid distillation of wood, dry distillation of organic waste
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/08—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal with moving catalysts
    • C10G1/086—Characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1011—Biomass
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2200/00—Components of fuel compositions
    • C10L2200/04—Organic compounds
    • C10L2200/0461—Fractions defined by their origin
    • C10L2200/0469—Renewables or materials of biological origin
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/02—Combustion or pyrolysis
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Claims (10)

1. Pyrolysefremgangsmåde til fremstilling af delvist kondensable dampprodukter fra et partikelformigt eller underopdelt biomasse-materiale, som er ubehandlet, hvis der ses bort fra eventuel tørring og/eller størrelsesreduktion, hvilken fremgangsmåde omfatter: A) at pyrolysere biomasse-materialet ved en eller flere temperaturer på 500°C og derover i en reaktor indeholdende (i) en katalysator, som er et rehydreret kalcineret calciumholdigt lagdelt dihydroxid bestående af partikler med en gennemsnitlig partikelstørrelse på 40 til 400 mikrometer, når den tilsættes reaktoren, hvilken katalysator eventuelt er i en præ-agglomereret strømningsdygtig eller fluidiserbar formet form, og (ii) et partikelformigt fluidiserbart varmeoverføringsmedium, fortrinsvis sand, til dannelse af pyrolyseprodukter; og B) at kondensere og isolere et flydende pyrolyseolieprodukt fra pyrolyseprodukterne og opsamle og isolere ikke-kondenserbare gasser adskilt fra det flydende pyrolyseolieprodukt.
2. Pyrolysefremgangsmåde ifølge krav 1, hvor katalysatoren indeholder 0,1 til 20 vægt% calcium, når den tilsættes til reaktoren, og hvor indholdet af reaktoren er og forbliver frit for særskilt tilføjede metalforbindelser bortset fra (a) divalent og trivalent metalindhold i det lagdelte dihydroxid i katalysatoren og (b) det tilsatte calciumindhold i katalysatoren.
3. Fremgangsmåde ifølge et hvilket som helst af kravene 1-2, hvor pyrolysen er en hurtig py ro lyse.
4. Fremgangsmåde ifølge et hvilket som helst af kravene 1-3, hvor biomassematerialet er en biomasse indeholdende lignocellulose.
5. Fremgangsmåde ifølge et hvilket som helst af kravene 1-4, hvor det flydende pyrolyseolieprodukt har et totalt syretal målt i milligram KOH/gram flydende produkt, som er lavere end et totalt syretal målt på samme måde for et flydende pyrolyseolieprodukt opnået ved pyrolyse under de samme betingelser bortset fra, at der anvendes sand alene (100 vægtdele) eller en kombination af et lagdelt dihydroxid (25 vægtdele) og sand (75 vægtdele) i stedet for katalysatoren (25 vægtdele) og sand (75 vægtdele).
6. Fremgangsmåde ifølge et hvilket som helst af kravene 1 til 4, hvor en vægtprocent af oxygen, som bestemt ved den generelle testprocedure for pyrolyse, fjernes fra det tilførte biomasse-materiale
og som beregnet ifølge formlen hvor: Ofjemet er vægt% ilt fjernet (vægt% baseret på oxygen i det tilførte biomasse-materiale) Mo : molmassen af O = 15,999 (g/mol) Xco : udbyttet af CO (vægt% af tilsat biomasse-materiale) Mco : molmassen af CO = 28,01 (g/mol)
Xco2 : udbyttet af CO2 (vægt% af tilsat biomasse-materiale) MCo2 : molmassen af CO2 = 44,01 (g/mol) XH2o : udbyttet af H20 (vægt% af tilsat biomasse-materiale) MH2o : molmassen af H20 = 18,02 (g/mol) Omsat : iltindhold i det tilsatte biomassemateriale (vægt%), er højere end vægtprocenten af oxygen, bestemt på samme måde, fjernet fra biomassemateriale pyroliseret under de samme betingelser bortset fra, at der anvendes sand alene (100 vægtdele) eller en kombination af et lagdelt dihydroxid (25 vægtdele) og sand (75 vægtdele) i stedet for den rehydrerede kalcinerede calciumholdige lagdelte dihydroxidkatalysator (25 vægtdele) og sand (75 vægtdele).
7. Pyrolysefremgangsmåde ifølge krav 1, som er en hurtig pyrolyseproces, hvor reaktoren er en fluidiseret leje-reaktor; og hvor pyrolyseprodukterne fjernes kontinuerligt.
8. Fremgangsmåde ifølge krav 1, hvor katalysatoren var i en præ-agglomereret, flydende formet form, når den tilsættes reaktoren.
9. Fremgangsmåde ifølge et hvilket som helst af kravene 1 eller 2, hvor katalysatoren har en lagdelt dihydroxidbestanddel, som omfatter, i det væsentlige består af eller består af et lagdelt magnesium/aluminium-dihydroxid, når den tilsættes reaktoren.
10. Fremgangsmåde ifølge krav 9, hvor det lagdelte magnesium/aluminium-dihydroxid haret molforhold mellem MgO og AI2O3 på 2:1 til 8:1.
DK13750287.8T 2012-08-08 2013-08-07 Katalytisk pyrolysefremgangsmåde DK2882826T3 (da)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201261681072P 2012-08-08 2012-08-08
PCT/EP2013/066533 WO2014023759A1 (en) 2012-08-08 2013-08-07 Catalytic pyrolysis process and pyrolysis products so formed

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US (1) US20150203761A1 (da)
EP (1) EP2882826B1 (da)
JP (1) JP6342394B2 (da)
CN (1) CN104662130B (da)
BR (1) BR112015002751B1 (da)
CA (1) CA2878709A1 (da)
DK (1) DK2882826T3 (da)
ES (1) ES2715320T3 (da)
HU (1) HUE042245T2 (da)
IN (1) IN2015DN00285A (da)
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WO (1) WO2014023759A1 (da)

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CN106047385A (zh) * 2016-07-20 2016-10-26 昆明理工大学 添加聚磷酸铵微胶囊和硼酸的生物质热解工艺
CN108865402A (zh) * 2018-06-08 2018-11-23 安徽省宝天农贸有限公司 一种菜籽油的制备方法
CN108841442A (zh) * 2018-06-08 2018-11-20 安徽省宝天农贸有限公司 一种高品质芝麻油的制备方法
CN109762583B (zh) * 2019-01-22 2020-02-21 广西壮族自治区林业科学研究院 一种生物质热解制备气、液、炭产品的方法
CN110129086B (zh) * 2019-03-13 2021-07-13 盐城工业职业技术学院 一种催化裂解植物沥青制备生物航煤的方法
KR102337176B1 (ko) * 2019-06-11 2021-12-10 한국에너지기술연구원 연속식 공정으로 업그레이딩된 열분해유의 대량생산 방법 및 연속식 공정 장치
CN113311093A (zh) * 2021-06-23 2021-08-27 海南大学 防火封堵材料实验室热解及烟气收集装置与分析方法
CN115029148B (zh) * 2022-06-09 2023-06-06 武汉轻工大学 一种生物质和聚烯烃塑料催化热解联产高品质生物油和介孔生物炭的方法

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CA2564729C (en) 2004-04-26 2014-04-15 Albemarle Netherlands B.V. Process for the preparation of an additive-containing anionic clay
MX2008014179A (es) * 2006-05-05 2009-02-04 Bioecon Int Holding Nv Proceso mejorado para convertir material portador de energia basado en carbono.
BRPI0714324A2 (pt) * 2006-07-17 2013-03-26 Bioecon Int Holding Nv processos para a conversço tÉrmica de uma biomassa particulada fina, e para a preparaÇço de um biolÍquido a partir de um material de biomassa sàlida
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JP2015524507A (ja) 2015-08-24
ES2715320T3 (es) 2019-06-03
WO2014023759A1 (en) 2014-02-13
EP2882826A1 (en) 2015-06-17
BR112015002751A2 (pt) 2018-04-10
US20150203761A1 (en) 2015-07-23
JP6342394B2 (ja) 2018-06-13
CN104662130A (zh) 2015-05-27
IN2015DN00285A (da) 2015-06-12
PL2882826T3 (pl) 2019-07-31
HUE042245T2 (hu) 2019-06-28
CA2878709A1 (en) 2014-02-13
EP2882826B1 (en) 2018-12-12
BR112015002751B1 (pt) 2020-04-14
CN104662130B (zh) 2017-10-03

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