DK2595722T3 - A method of stabilizing beverages gærfermenterede - Google Patents
A method of stabilizing beverages gærfermenterede Download PDFInfo
- Publication number
- DK2595722T3 DK2595722T3 DK11738064.2T DK11738064T DK2595722T3 DK 2595722 T3 DK2595722 T3 DK 2595722T3 DK 11738064 T DK11738064 T DK 11738064T DK 2595722 T3 DK2595722 T3 DK 2595722T3
- Authority
- DK
- Denmark
- Prior art keywords
- pvpp
- particles
- yeast
- filter
- fermented liquid
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 65
- 235000013361 beverage Nutrition 0.000 title description 2
- 230000000087 stabilizing effect Effects 0.000 title 1
- 229920000523 polyvinylpolypyrrolidone Polymers 0.000 claims description 243
- 239000001253 polyvinylpolypyrrolidone Substances 0.000 claims description 243
- 235000013809 polyvinylpolypyrrolidone Nutrition 0.000 claims description 243
- 239000002245 particle Substances 0.000 claims description 136
- 239000007788 liquid Substances 0.000 claims description 96
- 240000004808 Saccharomyces cerevisiae Species 0.000 claims description 76
- 239000012465 retentate Substances 0.000 claims description 59
- 239000002002 slurry Substances 0.000 claims description 51
- 238000000926 separation method Methods 0.000 claims description 49
- 150000008442 polyphenolic compounds Chemical class 0.000 claims description 46
- 235000013824 polyphenols Nutrition 0.000 claims description 46
- 102000004169 proteins and genes Human genes 0.000 claims description 39
- 108090000623 proteins and genes Proteins 0.000 claims description 39
- 238000001914 filtration Methods 0.000 claims description 38
- 239000003518 caustics Substances 0.000 claims description 36
- 238000004062 sedimentation Methods 0.000 claims description 21
- 239000000706 filtrate Substances 0.000 claims description 19
- 238000005374 membrane filtration Methods 0.000 claims description 16
- 239000011148 porous material Substances 0.000 claims description 13
- 238000000855 fermentation Methods 0.000 claims description 10
- 230000004151 fermentation Effects 0.000 claims description 10
- 230000008569 process Effects 0.000 claims description 10
- 235000019985 fermented beverage Nutrition 0.000 claims description 9
- 239000012528 membrane Substances 0.000 claims description 9
- 230000001172 regenerating effect Effects 0.000 claims description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 5
- 238000007670 refining Methods 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 3
- 238000004064 recycling Methods 0.000 claims description 3
- 238000007599 discharging Methods 0.000 claims 2
- 238000004519 manufacturing process Methods 0.000 claims 1
- 238000010186 staining Methods 0.000 claims 1
- 235000013405 beer Nutrition 0.000 description 22
- 238000011069 regeneration method Methods 0.000 description 22
- 230000008929 regeneration Effects 0.000 description 20
- 238000005188 flotation Methods 0.000 description 12
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 238000005406 washing Methods 0.000 description 8
- 239000002671 adjuvant Substances 0.000 description 7
- 230000008901 benefit Effects 0.000 description 7
- 239000002253 acid Substances 0.000 description 6
- 238000001179 sorption measurement Methods 0.000 description 6
- 238000011144 upstream manufacturing Methods 0.000 description 6
- 210000005253 yeast cell Anatomy 0.000 description 6
- 239000000463 material Substances 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 238000005119 centrifugation Methods 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 230000006641 stabilisation Effects 0.000 description 4
- 239000003381 stabilizer Substances 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 102000004190 Enzymes Human genes 0.000 description 3
- 108090000790 Enzymes Proteins 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 238000003795 desorption Methods 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 238000009434 installation Methods 0.000 description 3
- 230000003134 recirculating effect Effects 0.000 description 3
- 230000003019 stabilising effect Effects 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 235000018553 tannin Nutrition 0.000 description 3
- 239000002699 waste material Substances 0.000 description 3
- PFTAWBLQPZVEMU-DZGCQCFKSA-N (+)-catechin Chemical compound C1([C@H]2OC3=CC(O)=CC(O)=C3C[C@@H]2O)=CC=C(O)C(O)=C1 PFTAWBLQPZVEMU-DZGCQCFKSA-N 0.000 description 2
- 239000004959 Rilsan Substances 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 238000010923 batch production Methods 0.000 description 2
- ADRVNXBAWSRFAJ-UHFFFAOYSA-N catechin Natural products OC1Cc2cc(O)cc(O)c2OC1c3ccc(O)c(O)c3 ADRVNXBAWSRFAJ-UHFFFAOYSA-N 0.000 description 2
- 235000005487 catechin Nutrition 0.000 description 2
- 229950001002 cianidanol Drugs 0.000 description 2
- 238000010924 continuous production Methods 0.000 description 2
- 239000012065 filter cake Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000006194 liquid suspension Substances 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 101800000263 Acidic protein Proteins 0.000 description 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 1
- GXCLVBGFBYZDAG-UHFFFAOYSA-N N-[2-(1H-indol-3-yl)ethyl]-N-methylprop-2-en-1-amine Chemical compound CN(CCC1=CNC2=C1C=CC=C2)CC=C GXCLVBGFBYZDAG-UHFFFAOYSA-N 0.000 description 1
- 229920000571 Nylon 11 Polymers 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000005352 clarification Methods 0.000 description 1
- 229920006037 cross link polymer Polymers 0.000 description 1
- 239000008232 de-aerated water Substances 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 230000002255 enzymatic effect Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 125000004387 flavanoid group Chemical group 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000002934 lysing effect Effects 0.000 description 1
- 238000005360 mashing Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 239000010451 perlite Substances 0.000 description 1
- 235000019362 perlite Nutrition 0.000 description 1
- 235000015047 pilsener Nutrition 0.000 description 1
- 229920000191 poly(N-vinyl pyrrolidone) Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000024042 response to gravity Effects 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 235000019640 taste Nutrition 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 235000015041 whisky Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12H—PASTEURISATION, STERILISATION, PRESERVATION, PURIFICATION, CLARIFICATION OR AGEING OF ALCOHOLIC BEVERAGES; METHODS FOR ALTERING THE ALCOHOL CONTENT OF FERMENTED SOLUTIONS OR ALCOHOLIC BEVERAGES
- C12H1/00—Pasteurisation, sterilisation, preservation, purification, clarification, or ageing of alcoholic beverages
- C12H1/02—Pasteurisation, sterilisation, preservation, purification, clarification, or ageing of alcoholic beverages combined with removal of precipitate or added materials, e.g. adsorption material
- C12H1/04—Pasteurisation, sterilisation, preservation, purification, clarification, or ageing of alcoholic beverages combined with removal of precipitate or added materials, e.g. adsorption material with the aid of ion-exchange material or inert clarification material, e.g. adsorption material
- C12H1/0416—Pasteurisation, sterilisation, preservation, purification, clarification, or ageing of alcoholic beverages combined with removal of precipitate or added materials, e.g. adsorption material with the aid of ion-exchange material or inert clarification material, e.g. adsorption material with the aid of organic added material
- C12H1/0424—Pasteurisation, sterilisation, preservation, purification, clarification, or ageing of alcoholic beverages combined with removal of precipitate or added materials, e.g. adsorption material with the aid of ion-exchange material or inert clarification material, e.g. adsorption material with the aid of organic added material with the aid of a polymer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D15/00—Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D41/00—Regeneration of the filtering material or filter elements outside the filter for liquid or gaseous fluids
- B01D41/02—Regeneration of the filtering material or filter elements outside the filter for liquid or gaseous fluids of loose filtering material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
- B01J20/26—Synthetic macromolecular compounds
- B01J20/261—Synthetic macromolecular compounds obtained by reactions only involving carbon to carbon unsaturated bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
- B01J20/26—Synthetic macromolecular compounds
- B01J20/265—Synthetic macromolecular compounds modified or post-treated polymers
- B01J20/267—Cross-linked polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/34—Regenerating or reactivating
- B01J20/3425—Regenerating or reactivating of sorbents or filter aids comprising organic materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/34—Regenerating or reactivating
- B01J20/345—Regenerating or reactivating using a particular desorbing compound or mixture
- B01J20/3475—Regenerating or reactivating using a particular desorbing compound or mixture in the liquid phase
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Analytical Chemistry (AREA)
- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- Genetics & Genomics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- Bioinformatics & Cheminformatics (AREA)
- Food Science & Technology (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Distillation Of Fermentation Liquor, Processing Of Alcohols, Vinegar And Beer (AREA)
- Micro-Organisms Or Cultivation Processes Thereof (AREA)
- Non-Alcoholic Beverages (AREA)
- Processing Of Solid Wastes (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP10170389 | 2010-07-22 | ||
| PCT/NL2011/050523 WO2012011807A1 (en) | 2010-07-22 | 2011-07-18 | A method of stabilising yeast fermented beverages |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DK2595722T3 true DK2595722T3 (en) | 2015-01-12 |
Family
ID=43306289
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DK11738064.2T DK2595722T3 (en) | 2010-07-22 | 2011-07-18 | A method of stabilizing beverages gærfermenterede |
Country Status (17)
| Country | Link |
|---|---|
| US (1) | US9481859B2 (enExample) |
| EP (1) | EP2595722B1 (enExample) |
| JP (1) | JP5774697B2 (enExample) |
| CN (1) | CN103096992B (enExample) |
| AR (1) | AR082289A1 (enExample) |
| BR (1) | BR112013001470B1 (enExample) |
| CA (1) | CA2806012C (enExample) |
| CO (1) | CO6690742A2 (enExample) |
| DK (1) | DK2595722T3 (enExample) |
| EA (1) | EA025808B1 (enExample) |
| ES (1) | ES2529374T3 (enExample) |
| MX (1) | MX338079B (enExample) |
| PL (1) | PL2595722T3 (enExample) |
| PT (1) | PT2595722E (enExample) |
| UA (1) | UA107384C2 (enExample) |
| WO (1) | WO2012011807A1 (enExample) |
| ZA (1) | ZA201300585B (enExample) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2015080657A1 (en) * | 2013-11-28 | 2015-06-04 | Ge Healthcare Bio-Sciences Ab | Stabilization of fermented beverages |
| MX2021000864A (es) | 2018-07-27 | 2021-03-26 | Arc Medical Devices Inc | Fucanos altos en sulfato para el tratamiento de adhesiones fibrosas. |
| US12186334B2 (en) | 2018-07-27 | 2025-01-07 | ARC Medical Inc. | High-molecular-weight fucans for treating fibrous adhesions and other diseases and conditions |
| AU2020230466B2 (en) * | 2019-03-05 | 2021-05-13 | Arc Medical Devices Inc. | Systems and methods for tangential flow filtration of viscous compositions |
| JP7499126B2 (ja) * | 2020-09-10 | 2024-06-13 | リファインホールディングス株式会社 | 炭素質材料分散体からの異物除去方法 |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE58908717D1 (de) * | 1988-07-15 | 1995-01-19 | Filtrox Werk Ag | Filtrationsverfahren, Verwendung von Stabilisierungsmitteln, Anlage für ein Filtrationsverfahren und Verfahren zum Betreiben der Anlage. |
| US5262053A (en) * | 1988-07-15 | 1993-11-16 | Filtrox-Werk Ag | Filtration process, use of stabilizers installation for a filtration process, and procedure for operating said installation |
| EP0551245B1 (de) | 1992-03-06 | 1996-09-11 | Filtrox-Werk AG | Verfahren zur Filtration verschmutzter Lauge und Anlage zur Durchführung des Verfahrens |
| US5801051A (en) | 1994-02-10 | 1998-09-01 | Filtrox-Werk Ag | Method and apparatus for cleaning a filter aid |
| GB2288608A (en) | 1994-04-14 | 1995-10-25 | Isp Investments Inc | Beverage stabilisation |
| FR2733922B1 (fr) * | 1995-05-12 | 1997-07-25 | Interbrew Sa | Nouveaux adjuvants de filtration, nouveaux supports de filtration, procede de filtration les utilisant et procede de regeneration desdits adjuvants |
| US20030054077A1 (en) * | 1995-12-28 | 2003-03-20 | Kirin Beer Kabushiki Kaisha | Clarification of beer fermentation |
| JPH09173045A (ja) * | 1995-12-28 | 1997-07-08 | Kirin Brewery Co Ltd | ビール用清澄剤およびビールの清澄化方法 |
| JPH10263374A (ja) * | 1997-03-24 | 1998-10-06 | Mitsui Chem Inc | 発酵飲料濾過用フィルター |
| DE19739734C2 (de) | 1997-09-11 | 2001-06-07 | Hrch Huppmann Gmbh | Läuteranlage mit Abscheidevorrichtung |
| WO1999016531A1 (en) | 1997-09-30 | 1999-04-08 | Anheuser Busch | Regeneration of filter media |
| AU3176399A (en) * | 1998-03-16 | 1999-10-11 | Environment Products Limited | Improved method and apparatus for processing a preparation |
| DE69928921T2 (de) | 1998-05-15 | 2006-07-27 | Isp Investments Inc., Wilmington | Vormischungszusammensetzung zur bierklärung |
| AUPQ528900A0 (en) * | 2000-01-28 | 2000-02-17 | D'Arenberg Osborn, Chester | A treatment process for removal of chloranisole compounds |
| US20030044498A1 (en) * | 2001-06-14 | 2003-03-06 | Isp Investments Inc. | Colloidal stabilization of beer |
| US7581543B2 (en) | 2004-04-14 | 2009-09-01 | Philip Morris Usa Inc. | Reduction of phenolic compound precursors in tobacco |
| BRPI0712711B1 (pt) * | 2006-05-19 | 2017-12-26 | Heineken Supply Chain B. V. | Method for producing a translucent drink fermented by yeast |
| MX2009002964A (es) | 2006-09-29 | 2009-04-01 | Basf Se | Metodo para regenerar un agente de filtracion auxiliar. |
| ATE438706T1 (de) | 2007-03-30 | 2009-08-15 | Krones Ag | Verfahren zum filtern von bier |
| WO2010052130A2 (de) | 2008-11-07 | 2010-05-14 | Basf Se | Verfahren zur auftrennung von filterhilfsmittelpartikeln für die anschwemmfiltration |
-
2011
- 2011-07-18 WO PCT/NL2011/050523 patent/WO2012011807A1/en not_active Ceased
- 2011-07-18 JP JP2013520683A patent/JP5774697B2/ja active Active
- 2011-07-18 PT PT11738064T patent/PT2595722E/pt unknown
- 2011-07-18 DK DK11738064.2T patent/DK2595722T3/en active
- 2011-07-18 MX MX2013000816A patent/MX338079B/es active IP Right Grant
- 2011-07-18 BR BR112013001470-9A patent/BR112013001470B1/pt active IP Right Grant
- 2011-07-18 PL PL11738064T patent/PL2595722T3/pl unknown
- 2011-07-18 CN CN201180040693.1A patent/CN103096992B/zh active Active
- 2011-07-18 EP EP11738064.2A patent/EP2595722B1/en active Active
- 2011-07-18 CA CA2806012A patent/CA2806012C/en active Active
- 2011-07-18 US US13/811,229 patent/US9481859B2/en active Active
- 2011-07-18 EA EA201390151A patent/EA025808B1/ru not_active IP Right Cessation
- 2011-07-18 ES ES11738064.2T patent/ES2529374T3/es active Active
- 2011-07-18 UA UAA201300743A patent/UA107384C2/uk unknown
- 2011-07-19 AR ARP110102609A patent/AR082289A1/es active IP Right Grant
-
2013
- 2013-01-22 ZA ZA2013/00585A patent/ZA201300585B/en unknown
- 2013-01-22 CO CO13011184A patent/CO6690742A2/es active IP Right Grant
Also Published As
| Publication number | Publication date |
|---|---|
| MX338079B (es) | 2016-04-01 |
| CN103096992B (zh) | 2016-07-13 |
| JP2013532474A (ja) | 2013-08-19 |
| EA201390151A1 (ru) | 2013-05-30 |
| AR082289A1 (es) | 2012-11-28 |
| EP2595722A1 (en) | 2013-05-29 |
| PL2595722T3 (pl) | 2015-04-30 |
| BR112013001470A2 (pt) | 2016-05-31 |
| ES2529374T3 (es) | 2015-02-19 |
| WO2012011807A1 (en) | 2012-01-26 |
| US9481859B2 (en) | 2016-11-01 |
| JP5774697B2 (ja) | 2015-09-09 |
| PT2595722E (pt) | 2015-03-02 |
| UA107384C2 (uk) | 2014-12-25 |
| CN103096992A (zh) | 2013-05-08 |
| BR112013001470B1 (pt) | 2020-11-10 |
| EA025808B1 (ru) | 2017-01-30 |
| MX2013000816A (es) | 2013-02-27 |
| CA2806012C (en) | 2018-07-17 |
| ZA201300585B (en) | 2013-09-25 |
| EP2595722B1 (en) | 2014-12-03 |
| CA2806012A1 (en) | 2012-01-26 |
| US20130183403A1 (en) | 2013-07-18 |
| CO6690742A2 (es) | 2013-06-17 |
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