DK2496624T3 - Fremgangsmåde til fremstilling af et polyurethanskum ved hjælp af et over- eller nærkritisk drivmiddel - Google Patents
Fremgangsmåde til fremstilling af et polyurethanskum ved hjælp af et over- eller nærkritisk drivmiddelInfo
- Publication number
- DK2496624T3 DK2496624T3 DK10775804.7T DK10775804T DK2496624T3 DK 2496624 T3 DK2496624 T3 DK 2496624T3 DK 10775804 T DK10775804 T DK 10775804T DK 2496624 T3 DK2496624 T3 DK 2496624T3
- Authority
- DK
- Denmark
- Prior art keywords
- narcritical
- polyurethan
- food
- fuel
- procedure
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/14—Manufacture of cellular products
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/34—Auxiliary operations
- B29C44/3469—Cell or pore nucleation
- B29C44/348—Cell or pore nucleation by regulating the temperature and/or the pressure, e.g. suppression of foaming until the pressure is rapidly decreased
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/34—Auxiliary operations
- B29C44/60—Measuring, controlling or regulating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6633—Compounds of group C08G18/42
- C08G18/6637—Compounds of group C08G18/42 with compounds of group C08G18/32 or polyamines of C08G18/38
- C08G18/664—Compounds of group C08G18/42 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
- C08G18/6644—Compounds of group C08G18/42 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203 having at least three hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G81/00—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/02—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by the reacting monomers or modifying agents during the preparation or modification of macromolecules
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/122—Hydrogen, oxygen, CO2, nitrogen or noble gases
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/141—Hydrocarbons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/04—Condition, form or state of moulded material or of the material to be shaped cellular or porous
- B29K2105/041—Microporous
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0025—Foam properties rigid
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0041—Foam properties having specified density
- C08G2110/005—< 50kg/m3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/08—Supercritical fluid
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Polyurethanes Or Polyureas (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102009053218A DE102009053218A1 (de) | 2009-11-06 | 2009-11-06 | Verfahren zur Herstellung eines Polyurethanschaums mittels über- oder nahekritischen Treibmittels |
PCT/EP2010/066744 WO2011054873A2 (de) | 2009-11-06 | 2010-11-03 | Verfahren zur herstellung eines polyurethanschaums mittels über- oder nahekritischen treibmittels |
Publications (1)
Publication Number | Publication Date |
---|---|
DK2496624T3 true DK2496624T3 (da) | 2014-11-03 |
Family
ID=43970450
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DK10775804.7T DK2496624T3 (da) | 2009-11-06 | 2010-11-03 | Fremgangsmåde til fremstilling af et polyurethanskum ved hjælp af et over- eller nærkritisk drivmiddel |
Country Status (14)
Country | Link |
---|---|
US (1) | US9139683B2 (da) |
EP (1) | EP2496624B1 (da) |
JP (1) | JP5629778B2 (da) |
KR (1) | KR101761953B1 (da) |
CN (1) | CN102712737B (da) |
BR (1) | BR112012010624A2 (da) |
CA (1) | CA2779979C (da) |
DE (1) | DE102009053218A1 (da) |
DK (1) | DK2496624T3 (da) |
ES (1) | ES2523996T3 (da) |
MX (1) | MX349772B (da) |
PL (1) | PL2496624T3 (da) |
RU (1) | RU2541573C9 (da) |
WO (1) | WO2011054873A2 (da) |
Families Citing this family (32)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ES2561254T3 (es) * | 2010-05-21 | 2016-02-25 | Basf Se | Espumas poliméricas nanoporosas |
EP2610310A4 (en) * | 2010-08-23 | 2014-10-15 | Nitto Denko Corp | EMULSION WATER / OIL, MOUSSE AND FUNCTIONAL FOAM |
DE102010060390A1 (de) * | 2010-11-05 | 2012-05-10 | Bayer Materialscience Aktiengesellschaft | Emulsionsförmige Reaktionsmischung und Verfahren zur Herstellung von Polyurethanschäumen aus einer solchen Reaktionsmischung |
DE102010060386A1 (de) * | 2010-11-05 | 2012-05-10 | Bayer Materialscience Aktiengesellschaft | Verfahren zur Herstellung eines geschäumten Materials, hierbei eingesetzte emulsionsförmige Zusammensetzung und hieraus erhältliches geschäumtes Material |
CN104619736B (zh) * | 2012-07-31 | 2017-08-18 | 科思创德国股份有限公司 | 使用乳化发泡剂制备聚氨酯泡沫的方法 |
US10414921B1 (en) | 2013-09-04 | 2019-09-17 | Virfex, LLC | Polyurethane foam based ballistic armor |
JP2016537466A (ja) * | 2013-11-08 | 2016-12-01 | コベストロ、ドイチュラント、アクチエンゲゼルシャフトCovestro Deutschland Ag | ポリウレタン発泡体およびその製造方法 |
DE102013223391A1 (de) | 2013-11-15 | 2015-05-21 | Universität Zu Köln | Herstellung von porösen Materialien durch Expansion von Polymergelen |
US10626290B2 (en) * | 2013-12-16 | 2020-04-21 | Ppg Industries Ohio, Inc. | Method of extending pot life of coating compositions |
RU2648065C2 (ru) * | 2014-01-23 | 2018-03-22 | ДАУ ГЛОБАЛ ТЕКНОЛОДЖИЗ ЭлЭлСи | Жесткий пенополиуретан, имеющий ячейки малого размера |
US10322534B2 (en) | 2014-05-28 | 2019-06-18 | Dow Global Technologies Llc | Mold process for making nanofoam |
US10308782B2 (en) | 2014-08-15 | 2019-06-04 | Dow Global Technologies Llc | Polydimethylsiloxane grafted polyethylene foam |
CN104388073B (zh) * | 2014-11-27 | 2017-07-28 | 中国石油化工股份有限公司 | 超临界二氧化碳固体增稠剂及其制备方法和用途 |
CN105070819B (zh) * | 2015-06-30 | 2017-12-08 | 厦门大学 | 一种调控氧化物材料热导率的方法 |
EP3420008A1 (en) | 2016-02-26 | 2019-01-02 | Solvay SA | Process for the preparation of a polyurethane foam |
US10577801B2 (en) * | 2016-07-15 | 2020-03-03 | Firestone Building Products Company, Llc | Silicone membranes |
WO2018019907A1 (de) | 2016-07-29 | 2018-02-01 | Covestro Deutschland Ag | System und verfahren zur herstellung eines geschäumten polymers |
WO2018018571A1 (en) * | 2016-07-29 | 2018-02-01 | Dow Global Technologies Llc | Insulative apparatus |
CN108219097A (zh) * | 2016-12-14 | 2018-06-29 | 上海东大化学有限公司 | 一种单组份聚氨酯发泡胶及其制备方法 |
EP3372625A1 (de) * | 2017-03-07 | 2018-09-12 | Covestro Deutschland AG | Polyurethanschaum und verfahren zu seiner herstellung |
WO2019043043A1 (en) | 2017-08-29 | 2019-03-07 | Solvay Sa | PROCESS FOR THE PREPARATION OF POLYURETHANE FOAM |
WO2019063562A1 (en) | 2017-09-27 | 2019-04-04 | Solvay Sa | PROCESS FOR THE PREPARATION OF POLYURETHANE FOAM |
KR101902441B1 (ko) * | 2017-11-28 | 2018-10-01 | 주식회사 지아이테크 | 배치형 발포 공정을 이용한 다경도 다탄성 폴리우레탄 폼 제조 방법 |
EP3560970A1 (de) | 2018-04-25 | 2019-10-30 | Covestro Deutschland AG | Offenzelliger polyurethanhartschaum und dessen verwendung |
EP3564283A1 (de) | 2018-04-30 | 2019-11-06 | Covestro Deutschland AG | Verfahren zur herstellung von geschlossenzelligem polyurethanschaum |
DE102019200446A1 (de) | 2019-01-16 | 2020-07-16 | Evonik Operations Gmbh | Poly-OH-funktionelle Trisiloxane, deren Herstellung sowie deren Verwendung zur Herstellung von Polyurethanschäumen |
FR3095207B1 (fr) * | 2019-04-16 | 2021-04-23 | Commissariat Energie Atomique | Procédé de fonctionnalisation de surface en milieu fluide supercritique |
CN110409553B (zh) * | 2019-08-06 | 2021-06-15 | 长江水利委员会长江科学院 | 一种高寒高海拔地区太阳能光伏供水系统 |
EP3789417A1 (de) | 2019-09-06 | 2021-03-10 | Covestro Deutschland AG | Polyurethan-basierter isolationskörper und verfahren zu seiner herstellung |
EP3838545A1 (de) | 2019-12-17 | 2021-06-23 | Covestro Deutschland AG | Polyolmischungen und deren verwendung in der herstellung feinzelliger polyurethanschäume |
KR102397310B1 (ko) * | 2020-04-08 | 2022-05-12 | 에이치디씨현대이피 주식회사 | 용매를 사용하지 않는 고발포 폴리우레탄 폼 제조방법 및 이 제조방법에 의해 제조된 폴리우레탄 폼 |
CN112795174A (zh) * | 2020-12-31 | 2021-05-14 | 平湖华申汽车内饰件有限公司 | 一种汽车内饰聚氨酯自动发泡一体化工艺 |
Family Cites Families (20)
Publication number | Priority date | Publication date | Assignee | Title |
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US4604090A (en) | 1983-11-22 | 1986-08-05 | Consolidated Controls Corporation | Compact implantable medication infusion device |
CA1337750C (en) * | 1987-11-24 | 1995-12-19 | John L. Fulton | Supercritical fluid reverse micelle separation |
US4906672A (en) | 1988-07-29 | 1990-03-06 | Pmc, Inc. | Blowing agents for polyurethane foam |
EP0811032B1 (en) | 1995-12-22 | 2003-03-19 | Crompton Corporation | Production of polyurethan foams using enol-ether capped polyether polysiloxan copolymers |
TW568921B (en) * | 1998-08-07 | 2004-01-01 | Huntsman Int Llc | Process for preparing a moulded flexible polyurethane foam |
CN1321800C (zh) * | 1999-12-24 | 2007-06-20 | 亨茨曼国际有限公司 | 气助注塑 |
DE10030384A1 (de) * | 2000-06-21 | 2002-01-03 | Hennecke Gmbh | Verfahren zur Herstellung von Blockschaum |
US6294107B1 (en) | 2000-07-26 | 2001-09-25 | Basf Corporation | Alkylene oxide modified silicone glycol compatibilizing agents for stable polyester polyol compositions |
US6491846B1 (en) | 2001-06-21 | 2002-12-10 | Bayer Antwerpen, N.V. | Process for the in-situ production of polyol blends, the in-situ produced polyol blends, and their use in the production of viscoelastic foam |
JP4154654B2 (ja) * | 2002-09-13 | 2008-09-24 | アキレス株式会社 | 硬質ポリウレタンフォームの製造方法 |
DE10260815B4 (de) | 2002-12-23 | 2008-07-03 | Universität Zu Köln | Aufgeschäumtes Material und Herstellverfahren für das aufgeschäumte Material |
JP4217895B2 (ja) * | 2003-12-01 | 2009-02-04 | 株式会社ブリヂストン | ポリウレタン発泡成形体の製造方法 |
US7183330B2 (en) | 2003-12-15 | 2007-02-27 | Air Products And Chemicals, Inc. | Silicone surfactants for rigid polyurethane foam made with hydrocarbon blowing agents |
JP5266756B2 (ja) * | 2005-04-21 | 2013-08-21 | 旭硝子株式会社 | 低反発性軟質ポリウレタンフォームおよびその製造方法 |
DE102005025970A1 (de) | 2005-06-03 | 2006-12-07 | Basf Ag | Poröse Polyisocyanat-Polyadditionsprodukte |
DE602006019497D1 (de) | 2006-02-15 | 2011-02-17 | Stepan Co | Verträglichmachende tenside für polyurethanpolyole und harze |
US20070238798A1 (en) * | 2006-04-05 | 2007-10-11 | Mcdaniel Kenneth G | Flexible polyurethane foams made from vegetable oil alkoxylated via DMC-catalysis |
US20090062414A1 (en) * | 2007-08-28 | 2009-03-05 | David Picheng Huang | System and method for producing damping polyurethane CMP pads |
US20090099273A1 (en) * | 2007-10-12 | 2009-04-16 | Williams David J | Non-silicone surfactants for polyurethane or polyisocyanurate foam containing halogenated olefins as blowing agents |
JP5388471B2 (ja) * | 2008-04-07 | 2014-01-15 | 株式会社イノアックコーポレーション | 金属粉末を含有するポリウレタン発泡体 |
-
2009
- 2009-11-06 DE DE102009053218A patent/DE102009053218A1/de not_active Ceased
-
2010
- 2010-11-03 PL PL10775804T patent/PL2496624T3/pl unknown
- 2010-11-03 MX MX2012005242A patent/MX349772B/es active IP Right Grant
- 2010-11-03 EP EP10775804.7A patent/EP2496624B1/de active Active
- 2010-11-03 RU RU2012123133/04A patent/RU2541573C9/ru active
- 2010-11-03 CN CN201080061627.8A patent/CN102712737B/zh active Active
- 2010-11-03 ES ES10775804.7T patent/ES2523996T3/es active Active
- 2010-11-03 US US13/505,769 patent/US9139683B2/en not_active Expired - Fee Related
- 2010-11-03 CA CA2779979A patent/CA2779979C/en not_active Expired - Fee Related
- 2010-11-03 KR KR1020127014600A patent/KR101761953B1/ko active IP Right Grant
- 2010-11-03 DK DK10775804.7T patent/DK2496624T3/da active
- 2010-11-03 WO PCT/EP2010/066744 patent/WO2011054873A2/de active Application Filing
- 2010-11-03 BR BR112012010624A patent/BR112012010624A2/pt not_active Application Discontinuation
- 2010-11-03 JP JP2012537389A patent/JP5629778B2/ja not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
JP2013510209A (ja) | 2013-03-21 |
EP2496624A2 (de) | 2012-09-12 |
BR112012010624A2 (pt) | 2016-03-29 |
RU2541573C2 (ru) | 2015-02-20 |
JP5629778B2 (ja) | 2014-11-26 |
KR20120094009A (ko) | 2012-08-23 |
PL2496624T3 (pl) | 2015-01-30 |
RU2541573C9 (ru) | 2015-11-10 |
EP2496624B1 (de) | 2014-09-17 |
CN102712737B (zh) | 2014-07-09 |
US9139683B2 (en) | 2015-09-22 |
ES2523996T3 (es) | 2014-12-03 |
DE102009053218A1 (de) | 2011-07-14 |
WO2011054873A2 (de) | 2011-05-12 |
CN102712737A (zh) | 2012-10-03 |
MX349772B (es) | 2017-08-10 |
KR101761953B1 (ko) | 2017-07-26 |
WO2011054873A3 (de) | 2011-11-24 |
CA2779979C (en) | 2017-10-24 |
RU2012123133A (ru) | 2013-12-20 |
US20120245243A1 (en) | 2012-09-27 |
MX2012005242A (es) | 2012-06-13 |
CA2779979A1 (en) | 2011-05-12 |
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