DK2493938T3 - POLYETHYLEN MANUFACTURED WITH CHILDREN LATE TRANSITION METAL CATALYST SYSTEMS - Google Patents
POLYETHYLEN MANUFACTURED WITH CHILDREN LATE TRANSITION METAL CATALYST SYSTEMS Download PDFInfo
- Publication number
- DK2493938T3 DK2493938T3 DK10778604.8T DK10778604T DK2493938T3 DK 2493938 T3 DK2493938 T3 DK 2493938T3 DK 10778604 T DK10778604 T DK 10778604T DK 2493938 T3 DK2493938 T3 DK 2493938T3
- Authority
- DK
- Denmark
- Prior art keywords
- polyethylene
- transition metal
- late transition
- silica
- metal catalyst
- Prior art date
Links
- -1 POLYETHYLEN Polymers 0.000 title claims description 27
- 239000003054 catalyst Substances 0.000 title claims description 25
- 229920000573 polyethylene Polymers 0.000 title claims description 23
- 229910052723 transition metal Inorganic materials 0.000 title claims description 8
- 150000003624 transition metals Chemical class 0.000 title claims description 8
- 101100020619 Arabidopsis thaliana LATE gene Proteins 0.000 title claims 2
- 239000004698 Polyethylene Substances 0.000 claims description 23
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 20
- 230000004913 activation Effects 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 13
- 230000003213 activating effect Effects 0.000 claims description 12
- 239000000377 silicon dioxide Substances 0.000 claims description 10
- 229910052782 aluminium Inorganic materials 0.000 claims description 8
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 7
- 239000005977 Ethylene Substances 0.000 claims description 7
- 239000002516 radical scavenger Substances 0.000 claims description 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 claims description 6
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 claims description 5
- 230000008569 process Effects 0.000 claims description 5
- 229910021585 Nickel(II) bromide Inorganic materials 0.000 claims description 4
- IPLJNQFXJUCRNH-UHFFFAOYSA-L nickel(2+);dibromide Chemical compound [Ni+2].[Br-].[Br-] IPLJNQFXJUCRNH-UHFFFAOYSA-L 0.000 claims description 4
- 239000000178 monomer Substances 0.000 claims description 2
- 238000006116 polymerization reaction Methods 0.000 claims 3
- 229920000642 polymer Polymers 0.000 description 17
- 238000005259 measurement Methods 0.000 description 14
- 238000001542 size-exclusion chromatography Methods 0.000 description 11
- 239000011148 porous material Substances 0.000 description 10
- 238000005227 gel permeation chromatography Methods 0.000 description 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Natural products CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 8
- 230000000694 effects Effects 0.000 description 8
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 8
- 239000002904 solvent Substances 0.000 description 7
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 6
- CPOFMOWDMVWCLF-UHFFFAOYSA-N methyl(oxo)alumane Chemical group C[Al]=O CPOFMOWDMVWCLF-UHFFFAOYSA-N 0.000 description 6
- PBKONEOXTCPAFI-UHFFFAOYSA-N 1,2,4-trichlorobenzene Chemical compound ClC1=CC=C(Cl)C(Cl)=C1 PBKONEOXTCPAFI-UHFFFAOYSA-N 0.000 description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 5
- 150000001335 aliphatic alkanes Chemical class 0.000 description 5
- 239000004411 aluminium Substances 0.000 description 5
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 4
- FFUAGWLWBBFQJT-UHFFFAOYSA-N hexamethyldisilazane Chemical compound C[Si](C)(C)N[Si](C)(C)C FFUAGWLWBBFQJT-UHFFFAOYSA-N 0.000 description 4
- 239000001282 iso-butane Substances 0.000 description 4
- 239000003446 ligand Substances 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 229910000071 diazene Inorganic materials 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 238000001228 spectrum Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000012190 activator Substances 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- 150000003623 transition metal compounds Chemical class 0.000 description 2
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 2
- RELMFMZEBKVZJC-UHFFFAOYSA-N 1,2,3-trichlorobenzene Chemical compound ClC1=CC=CC(Cl)=C1Cl RELMFMZEBKVZJC-UHFFFAOYSA-N 0.000 description 1
- 238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical group [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- NHTMVDHEPJAVLT-UHFFFAOYSA-N Isooctane Chemical compound CC(C)CC(C)(C)C NHTMVDHEPJAVLT-UHFFFAOYSA-N 0.000 description 1
- 238000005481 NMR spectroscopy Methods 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000002156 adsorbate Substances 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- UHOVQNZJYSORNB-MZWXYZOWSA-N benzene-d6 Chemical compound [2H]C1=C([2H])C([2H])=C([2H])C([2H])=C1[2H] UHOVQNZJYSORNB-MZWXYZOWSA-N 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 238000010516 chain-walking reaction Methods 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- RAABOESOVLLHRU-UHFFFAOYSA-N diazene Chemical compound N=N RAABOESOVLLHRU-UHFFFAOYSA-N 0.000 description 1
- JVSWJIKNEAIKJW-UHFFFAOYSA-N dimethyl-hexane Natural products CCCCCC(C)C JVSWJIKNEAIKJW-UHFFFAOYSA-N 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000001595 flow curve Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 1
- UQEAIHBTYFGYIE-UHFFFAOYSA-N hexamethyldisiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)C UQEAIHBTYFGYIE-UHFFFAOYSA-N 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 230000003534 oscillatory effect Effects 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- KDLHZDBZIXYQEI-UHFFFAOYSA-N palladium Substances [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 1
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 230000008707 rearrangement Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000000974 shear rheometry Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/02—Carriers therefor
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/70—Iron group metals, platinum group metals or compounds thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP09174498A EP2316864A1 (en) | 2009-10-29 | 2009-10-29 | Polyethylene prepared with supported late transition metal catalyst system. |
| PCT/EP2010/066320 WO2011051371A1 (en) | 2009-10-29 | 2010-10-28 | Polyethylene prepared with supported late transition metal catalyst systems |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DK2493938T3 true DK2493938T3 (en) | 2019-04-01 |
Family
ID=41818604
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DK10778604.8T DK2493938T3 (en) | 2009-10-29 | 2010-10-28 | POLYETHYLEN MANUFACTURED WITH CHILDREN LATE TRANSITION METAL CATALYST SYSTEMS |
Country Status (11)
| Country | Link |
|---|---|
| US (2) | US8822612B2 (OSRAM) |
| EP (2) | EP2316864A1 (OSRAM) |
| KR (1) | KR101472643B1 (OSRAM) |
| CN (1) | CN102597019A (OSRAM) |
| BR (1) | BR112012010048A2 (OSRAM) |
| DK (1) | DK2493938T3 (OSRAM) |
| EA (1) | EA201270593A1 (OSRAM) |
| ES (1) | ES2715080T3 (OSRAM) |
| IN (1) | IN2012DN01557A (OSRAM) |
| MX (1) | MX2012004950A (OSRAM) |
| WO (1) | WO2011051371A1 (OSRAM) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109153750B (zh) * | 2016-05-20 | 2022-04-26 | 切弗朗菲利浦化学公司 | 制备低密度聚乙烯的低压方法 |
| KR101958015B1 (ko) | 2016-11-08 | 2019-07-04 | 주식회사 엘지화학 | 에틸렌/알파-올레핀 공중합체 |
| CN107118288B (zh) * | 2017-05-25 | 2019-10-18 | 江苏奥克化学有限公司 | 一种负载型后过渡金属催化剂及其制备方法 |
| US11376575B2 (en) * | 2018-09-17 | 2022-07-05 | Chevron Phillips Chemical Company Lp | Modified supported chromium catalysts and ethylene-based polymers produced therefrom |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5700895A (en) * | 1993-08-23 | 1997-12-23 | Sumitomo Chemical Company, Limited | Ethylene-α-olefin copolymer and molded article thereof |
| US5880241A (en) | 1995-01-24 | 1999-03-09 | E. I. Du Pont De Nemours And Company | Olefin polymers |
| EP1348723A3 (en) | 1995-01-24 | 2004-09-29 | E.I. Du Pont De Nemours And Company | Alpha-olefins and olefin polymers and processes for their preparation |
| JPH08306233A (ja) * | 1995-05-08 | 1996-11-22 | Fujikura Ltd | 電力ケーブル用絶縁体組成物 |
| IL129929A0 (en) | 1996-12-17 | 2000-02-29 | Du Pont | Polymerization of ethylene with specific iron or cobalt complexes novel pyridinebis (imines) and novel complexes of pyridinebis(imines) with iron and cobalt |
| US5865677A (en) | 1997-01-03 | 1999-02-02 | Tiger Electronics, Ltd. | Hand-held electronic game |
| CA2282415A1 (en) | 1997-02-25 | 1998-08-27 | Christopher Moore Killian | Polymers containing functionalized olefin monomers |
| US6103658A (en) * | 1997-03-10 | 2000-08-15 | Eastman Chemical Company | Olefin polymerization catalysts containing group 8-10 transition metals, processes employing such catalysts and polymers obtained therefrom |
| US6822062B2 (en) * | 1997-03-10 | 2004-11-23 | Eastman Chemical Company | Supported group 8-10 transition metal olefin polymerization catalysts |
| CA2210131C (en) * | 1997-07-09 | 2005-08-02 | Douglas W. Stephan | Supported phosphinimine-cp catalysts |
| US6255414B1 (en) * | 1998-09-01 | 2001-07-03 | E. I. Du Pont De Nemours And Company | Polymerization of olefins |
| JP2000080125A (ja) * | 1998-09-08 | 2000-03-21 | Idemitsu Petrochem Co Ltd | エチレン単独重合体及びそれを成形してなる成形体 |
| CA2341526A1 (en) * | 1998-10-14 | 2000-04-20 | Mark F. Teasley | Polymerization of olefins |
| US6531424B2 (en) * | 1999-12-17 | 2003-03-11 | E. I. Du Pont De Nemours And Company | Polymerization of olefins |
| JP2004527594A (ja) * | 2001-01-12 | 2004-09-09 | アトフイナ・リサーチ・ソシエテ・アノニム | メタロセンフィルム樹脂 |
| EP1674523A1 (en) * | 2004-12-22 | 2006-06-28 | Total Petrochemicals Research Feluy | Caps and closures |
| BRPI0608063A2 (pt) | 2005-03-04 | 2009-11-03 | Du Pont | processo para a formação de um precursor de polimerização de olefina suportado e produto do mesmo |
| JP2007177183A (ja) * | 2005-12-28 | 2007-07-12 | Nippon Polyethylene Kk | 電線・ケーブル被覆用樹脂材料及びそれを用いた被覆電線・ケーブル |
| JP5414971B2 (ja) * | 2005-12-28 | 2014-02-12 | 日本ポリエチレン株式会社 | エチレン系樹脂組成物によるフィルム |
| EP1972642A1 (en) | 2007-03-19 | 2008-09-24 | Total Petrochemicals Research Feluy | Homo-or co-polymers of ethylene with combination of processability and toughness properties |
| JP5407299B2 (ja) * | 2007-11-30 | 2014-02-05 | 住友化学株式会社 | エチレン−α−オレフィン共重合体および成形体 |
| JP5807325B2 (ja) * | 2009-09-30 | 2015-11-10 | 住友化学株式会社 | 遷移金属錯体、該遷移金属錯体の製造方法、三量化用触媒、１−ヘキセンの製造方法、エチレン系重合体の製造方法、置換シクロペンタジエン化合物、及び、該置換シクロペンタジエン化合物の製造方法 |
-
2009
- 2009-10-29 EP EP09174498A patent/EP2316864A1/en not_active Withdrawn
-
2010
- 2010-10-28 KR KR1020127009942A patent/KR101472643B1/ko not_active Expired - Fee Related
- 2010-10-28 CN CN2010800490091A patent/CN102597019A/zh active Pending
- 2010-10-28 DK DK10778604.8T patent/DK2493938T3/en active
- 2010-10-28 MX MX2012004950A patent/MX2012004950A/es not_active Application Discontinuation
- 2010-10-28 EP EP10778604.8A patent/EP2493938B1/en not_active Not-in-force
- 2010-10-28 EA EA201270593A patent/EA201270593A1/ru unknown
- 2010-10-28 IN IN1557DEN2012 patent/IN2012DN01557A/en unknown
- 2010-10-28 WO PCT/EP2010/066320 patent/WO2011051371A1/en not_active Ceased
- 2010-10-28 BR BR112012010048A patent/BR112012010048A2/pt not_active IP Right Cessation
- 2010-10-28 US US13/502,158 patent/US8822612B2/en not_active Expired - Fee Related
- 2010-10-28 ES ES10778604T patent/ES2715080T3/es active Active
-
2014
- 2014-07-07 US US14/324,402 patent/US9181366B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| IN2012DN01557A (OSRAM) | 2015-06-05 |
| US20120277388A1 (en) | 2012-11-01 |
| US20140323675A1 (en) | 2014-10-30 |
| ES2715080T3 (es) | 2019-05-31 |
| EP2493938B1 (en) | 2018-12-12 |
| BR112012010048A2 (pt) | 2016-05-24 |
| KR101472643B1 (ko) | 2014-12-15 |
| US9181366B2 (en) | 2015-11-10 |
| US8822612B2 (en) | 2014-09-02 |
| EP2493938A1 (en) | 2012-09-05 |
| EA201270593A1 (ru) | 2012-09-28 |
| KR20120068925A (ko) | 2012-06-27 |
| MX2012004950A (es) | 2012-06-12 |
| WO2011051371A1 (en) | 2011-05-05 |
| EP2316864A1 (en) | 2011-05-04 |
| CN102597019A (zh) | 2012-07-18 |
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