DK2474357T3 - Fremgangsmåde til fremstilling af en zeolitkatalysator til hydrogenkrakning indeholdende to adskilte hydrogenerende funktioner - Google Patents

Fremgangsmåde til fremstilling af en zeolitkatalysator til hydrogenkrakning indeholdende to adskilte hydrogenerende funktioner Download PDF

Info

Publication number
DK2474357T3
DK2474357T3 DK11290585.6T DK11290585T DK2474357T3 DK 2474357 T3 DK2474357 T3 DK 2474357T3 DK 11290585 T DK11290585 T DK 11290585T DK 2474357 T3 DK2474357 T3 DK 2474357T3
Authority
DK
Denmark
Prior art keywords
zeolite
catalyst
weight
nickel
comprised
Prior art date
Application number
DK11290585.6T
Other languages
English (en)
Inventor
Jeremy Francis
Laurent Simon
Emmanuelle Guillon
Nicolas Bats
Avelino Corma
Christophe Pichon
Original Assignee
Ifp Energies Now
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ifp Energies Now filed Critical Ifp Energies Now
Application granted granted Critical
Publication of DK2474357T3 publication Critical patent/DK2474357T3/da

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/10—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing iron group metals, noble metals or copper
    • B01J29/14—Iron group metals or copper
    • B01J29/146—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/064—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/16—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J29/166—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391—Physical properties of the active metal ingredient
    • B01J35/394—Metal dispersion value, e.g. percentage or fraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B01J35/69—Pore distribution bimodal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0205—Impregnation in several steps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/20—Sulfiding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J6/00—Heat treatments such as Calcining; Fusing ; Pyrolysis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J6/00—Heat treatments such as Calcining; Fusing ; Pyrolysis
    • B01J6/001—Calcining
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/12—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
    • C10G47/12—Inorganic carriers
    • C10G47/16—Crystalline alumino-silicate carriers
    • C10G47/20—Crystalline alumino-silicate carriers the catalyst containing other metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
    • C10G49/02—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 characterised by the catalyst used
    • C10G49/08—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
    • C10G65/12—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including cracking steps and other hydrotreatment steps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/14—After treatment, characterised by the effect to be obtained to alter the inside of the molecular sieve channels
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/16—After treatment, characterised by the effect to be obtained to increase the Si/Al ratio; Dealumination
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/20—After treatment, characterised by the effect to be obtained to introduce other elements in the catalyst composition comprising the molecular sieve, but not specially in or on the molecular sieve itself
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/36—Steaming
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/37—Acid treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/38—Base treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/30—Physical properties of feedstocks or products
    • C10G2300/301—Boiling range
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4018—Spatial velocity, e.g. LHSV, WHSV

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Dispersion Chemistry (AREA)

Claims (6)

1. Fremgangsmåde til fremstilling af en katalysator, der omfatter mindst et hydro-dehydrogenerende grundstof valgt fra gruppen dannet af grundstofferne fra gruppe VIB og ikke-ædelmetaller fra gruppe VIII i det periodiske system taget alene eller i blanding, og en bærer, som omfatter aluminiumoxid og mindst en dealuminiseret USY-zeolit, hvilken fremgangsmåde omfatter følgende trin: b) afsætning af grundstoffet nikkel på den dealuminiserede zeolit i en mængde på mellem 0,8 og 3 vægt-% i forhold til den samlede masse af zeolitten, hvilken dealuminiserede USY-zeolit har et samlet atomforhold af silicium i forhold til aluminium på mellem 2,5 og 10, en vægtandel af aluminiumatomer uden for gitteret på over 20 % i forhold til den samlede masse af aluminium, der er til stede i zeolitten, et mesoporøst volumen målt ved nitrogen-porøsimetri på over 0,07 ml.g-1, et mikroporøst volumen målt ved nitrogen-porøsimetri på over 0,20 ml.g-1 og en gitterparameter ao af enhedsmasken på over 24,28 Å, idet vægtandelen af aluminiumatomer uden for gitteret bestemmes ud fra en RMN-MAS-analyse af 27Al-f aststof på et Bruker-spektrometer af typen Avance 400 MHz ved hjælp af en 4 mm-sonde; c) formgivning af blandingen af den dealuminiserede zeolit, der omfatter nikkel, som er opnået i udgangen af trin b) , med aluminiumoxidet for at opnå bæreren; d) indførelse af mindst et hydro-dehydrogenerende grundstof ved imprægnering af bæreren med en forbindelse af grundstoffet, e) tørring og kalcinering af det opnåede slutprodukt, idet den opnåede katalysator har en hydrogenerende aktiv fase, der er afsat på USY-zeolitten i trin b), og som udelukkende er udgjort af nikkel.
2. Fremstillingsfremgangsmåde ifølge krav 1, hvor grundstoffet nikkel er afsat på den dealuminiserede USY-zeolit enten ved en tør imprægneringsteknik eller ved en kationbytningsteknik.
3. Fremstillingsfremgangsmåde ifølge et af kravene 1 til 2, hvor trin b) efterfølges af en tørring og/eller en kalcinering eller af en kalcinering uden forudgående tørring.
4. Fremstillingsfremgangsmåde ifølge krav 3, hvor tørringen udføres ved en temperatur på mellem 60 og 250 °C, og kalcineringen ved en temperatur på fra 250 til 800 °C i et tidsrum på mellem 30 minutter og 6 timer.
5. Fremstillingsfremgangsmåde ifølge et af kravene 1 til 4, hvor der i trin b) afsættes en mængde af grundstoffet nikkel på den dealuminiserede zeolit på mellem 1,2 og 3 vægt-% i forhold til den samlede masse af zeolitten.
6. Fremstillingsfremgangsmåde ifølge et af kravene 1 til 5, hvor indholdet af metal fra gruppe VIB i procentdel af oxid af grundstoffet ligger på mellem 5 og 40 vægt-% i forhold til den samlede masse af katalysatoren, og indholdet af ikke-ædelmetal fra gruppe VIII i procentdel af oxid af grundstoffet ligger på mellem 0,5 og 10 vægt-% i forhold til den samlede masse af katalysatoren, idet indholdet af grundstoffet nikkel, der er afsat på den dealuminiserede USY-zeolit, ikke er medregnet i indholdet af ikke-ædelmetal af gruppe VIII.
DK11290585.6T 2011-01-07 2011-12-20 Fremgangsmåde til fremstilling af en zeolitkatalysator til hydrogenkrakning indeholdende to adskilte hydrogenerende funktioner DK2474357T3 (da)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1100043A FR2970259B1 (fr) 2011-01-07 2011-01-07 Procede d'hydrocraquage utilisant un catalyseur zeolithique contenant deux fonctions hydrogenantes distinctes.

Publications (1)

Publication Number Publication Date
DK2474357T3 true DK2474357T3 (da) 2019-01-07

Family

ID=44342980

Family Applications (1)

Application Number Title Priority Date Filing Date
DK11290585.6T DK2474357T3 (da) 2011-01-07 2011-12-20 Fremgangsmåde til fremstilling af en zeolitkatalysator til hydrogenkrakning indeholdende to adskilte hydrogenerende funktioner

Country Status (7)

Country Link
US (1) US9914113B2 (da)
EP (1) EP2474357B1 (da)
JP (1) JP5830383B2 (da)
KR (1) KR101908733B1 (da)
BR (1) BR102012000290B1 (da)
DK (1) DK2474357T3 (da)
FR (1) FR2970259B1 (da)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5940935B2 (ja) 2012-08-17 2016-06-29 日揮触媒化成株式会社 炭化水素接触分解用触媒
CN104640632A (zh) 2012-09-17 2015-05-20 国际壳牌研究有限公司 制备加氢裂化催化剂的方法
DE102014205783A1 (de) * 2014-03-27 2015-10-01 Johnson Matthey Public Limited Company Katalysator sowie Verfahren zum Herstellen eines Katalysator
FR3022472B1 (fr) * 2014-06-18 2020-01-24 Arkema France Procede d'activation de catalyseurs d'hydrocraquage
US10213772B2 (en) 2015-04-10 2019-02-26 Chevron U.S.A. Inc. Middle distillate hydrocracking catalyst containing zeolite USY with enhanced acid sites
US10407311B2 (en) * 2017-05-17 2019-09-10 Saudi Arabian Oil Company Zeolites, the production thereof, and their uses for upgrading heavy oils
CN109867292A (zh) * 2017-12-04 2019-06-11 中国石油天然气股份有限公司 一种具有介孔结构的usy分子筛及其制备方法
CN109876860B (zh) * 2019-03-14 2021-09-14 吉林大学 一种双亲性催化剂ts-1@aof的制备方法
CN111822056B (zh) * 2019-04-19 2023-01-10 中国石油化工股份有限公司 高酸量硅铝材料及其制备方法
US11148124B2 (en) * 2019-12-04 2021-10-19 Saudi Arabian Oil Company Hierarchical zeolite Y and nano-sized zeolite beta composite
EP4247551A1 (en) * 2020-11-17 2023-09-27 Regents of the University of Minnesota Dehydration of lactic acid and related compounds in solid acids via multifunctional flexible modifiers
CN116060081B (zh) * 2021-10-31 2024-10-01 中国石油化工股份有限公司 一种捕硅催化剂及其制备方法
CN116282066A (zh) * 2022-12-22 2023-06-23 复榆(张家港)新材料科技有限公司 一种再生的酸性母液制多级孔高硅fau沸石的方法

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3536605A (en) * 1968-09-27 1970-10-27 Chevron Res Hydrotreating catalyst comprising an ultra-stable crystalline zeolitic molecular sieve component,and methods for making and using said catalyst
US3875081A (en) * 1969-10-24 1975-04-01 Union Oil Co Hydrocarbon conversion catalyst
DE3818294A1 (de) * 1987-06-11 1988-12-22 Leuna Werke Veb Katalysator zur herstellung von pyrolyserohstoff aus vakuumdestillaten
US5401704A (en) 1990-10-23 1995-03-28 Mobil Oil Corporation Hydrocracking catalyst and process using small crystal size zeolite Y
TW358120B (en) * 1994-08-24 1999-05-11 Shell Int Research Hydrocarbon conversion catalysts
FR2769856B1 (fr) * 1997-10-20 1999-12-03 Inst Francais Du Petrole Catalyseur et procede d'hydrocraquage de coupes hydrocarbonees
ES2207134T3 (es) 1998-05-06 2004-05-16 Institut Francais Du Petrole Catalizador a base de zeolita beta y de elemento promotor y procedimiento de hidrocraqueo.
JP2000265176A (ja) * 1999-03-18 2000-09-26 Idemitsu Kosan Co Ltd 軽油留分の水素化脱硫方法
JP4624610B2 (ja) * 2001-08-02 2011-02-02 日揮触媒化成株式会社 水素化処理触媒の製造方法
US7192900B2 (en) 2002-11-27 2007-03-20 Shell Oil Company Hydrocracking catalyst
FR2869894B1 (fr) 2004-05-10 2007-02-23 Inst Francais Du Petrole Methode de synthese de metalloaluminosilicate cristallise par synthese directe
JP4535929B2 (ja) * 2005-04-28 2010-09-01 財団法人石油産業活性化センター 炭化水素油の接触分解用触媒及び接触分解方法
FR2888584B1 (fr) 2005-07-18 2010-12-10 Inst Francais Du Petrole Procede de production de distillats moyens par hydroisomerisation et hydrocraquage de charges issues du procede fischer-tropsch utilisant un lit de garde multifonctionnel
US7510645B2 (en) * 2005-11-04 2009-03-31 Uop Llc Hydrocracking catalyst containing beta and Y zeolites, and process for its use to produce naphtha
US7704475B2 (en) * 2005-12-14 2010-04-27 Basf Catalysts Llc Zeolite catalyst with improved NOx reduction in SCR
FR2952379B1 (fr) * 2009-11-10 2012-05-11 Inst Francais Du Petrole Procede d'hydrocraquage mettant en oeuvre une zeolithe modifiee par un traitement basique
FR2952378B1 (fr) * 2009-11-10 2012-04-20 Inst Francais Du Petrole Procede d'hydrotraitement et d'hydroisomerisation de charges issues de source renouvelable mettant en oeuvre une zeolithe modifiee par un traitement basique

Also Published As

Publication number Publication date
US20120205286A1 (en) 2012-08-16
JP2012143751A (ja) 2012-08-02
EP2474357B1 (fr) 2018-09-05
JP5830383B2 (ja) 2015-12-09
US9914113B2 (en) 2018-03-13
EP2474357A1 (fr) 2012-07-11
BR102012000290A2 (pt) 2014-01-07
FR2970259B1 (fr) 2014-07-18
FR2970259A1 (fr) 2012-07-13
KR101908733B1 (ko) 2018-10-16
KR20120080550A (ko) 2012-07-17
BR102012000290B1 (pt) 2019-12-10

Similar Documents

Publication Publication Date Title
DK2474357T3 (da) Fremgangsmåde til fremstilling af en zeolitkatalysator til hydrogenkrakning indeholdende to adskilte hydrogenerende funktioner
JP5873627B2 (ja) 塩基処理により改変されたゼオライトを用いる水素化分解方法
JP5577339B2 (ja) Ｉｚｍ−２ゼオライトベース触媒及び炭化水素原料の水素化転化／水素化分解法
JP5022903B2 (ja) アルミノシリケートドープ触媒および炭化水素供給材料処理の改良法
JP5292301B2 (ja) 階層的多孔度を有する含ケイ素材料をベースとする触媒および炭化水素仕込原料の水素化分解／水素化転化および水素化処理のための方法
JP5860900B2 (ja) メソ構造化酸化物マトリクス中に捕捉されたヘテロポリアニオンをベースとする球状材料、および精製方法における触媒としてのその使用
JP6236399B2 (ja) 少なくとも１種のゼオライトｎｕ−８６、少なくとも１種のゼオライトｕｓｙ、及び多孔質鉱物マトリクスを含む触媒、並びに該触媒を用いる、炭化水素供給原料の水素化転化法
US9925533B2 (en) Method of preparing a catalyst usable in hydroconversion comprising at least one zeolite NU-86
US8647499B2 (en) Hydrocracking method using a modified zeolite
JP4644763B2 (ja) 水素化分解に有用なケイ素含有ｙ型ゼオライトベース触媒
JP4780537B2 (ja) 部分非晶質ゼオライトｙおよび第ｖｂ族元素を含む触媒、並びに炭化水素石油仕込原料の水素化転換および水素化精製におけるその使用
JP6009196B2 (ja) 潤滑油用基油の製造方法
CN118317833A (zh) 用于石脑油生产的以严格大于12的Y/β比包含沸石Y和沸石β的加氢裂化催化剂
CN118317832A (zh) 用于生产石脑油的以5至12的Y/β比包含具有严格大于24.50埃的晶格参数的Y沸石和β沸石的加氢裂化催化剂
CN118785971A (zh) 包含基于二氧化硅-氧化铝基质和沸石的载体的催化剂、其制备和烃原料的加氢裂化方法