DK170456B1 - Fremgangsmåde til fremstilling af faste, fytoaktive midler - Google Patents
Fremgangsmåde til fremstilling af faste, fytoaktive midler Download PDFInfo
- Publication number
 - DK170456B1 DK170456B1 DK419287A DK419287A DK170456B1 DK 170456 B1 DK170456 B1 DK 170456B1 DK 419287 A DK419287 A DK 419287A DK 419287 A DK419287 A DK 419287A DK 170456 B1 DK170456 B1 DK 170456B1
 - Authority
 - DK
 - Denmark
 - Prior art keywords
 - phosphonomethyl
 - surfactant
 - process according
 - solid
 - agent
 - Prior art date
 
Links
- 239000007787 solid Substances 0.000 title claims description 40
 - 238000000034 method Methods 0.000 title claims description 24
 - 238000002360 preparation method Methods 0.000 title claims description 7
 - 239000004094 surface-active agent Substances 0.000 claims description 60
 - 239000003795 chemical substances by application Substances 0.000 claims description 32
 - 239000000203 mixture Substances 0.000 claims description 21
 - -1 amine salt Chemical class 0.000 claims description 20
 - 150000001875 compounds Chemical class 0.000 claims description 18
 - 150000001412 amines Chemical class 0.000 claims description 16
 - 239000000843 powder Substances 0.000 claims description 15
 - XDDAORKBJWWYJS-UHFFFAOYSA-N glyphosate Chemical compound OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 claims description 11
 - 125000004432 carbon atom Chemical group C* 0.000 claims description 9
 - 239000007788 liquid Substances 0.000 claims description 9
 - 238000001816 cooling Methods 0.000 claims description 8
 - 229910052739 hydrogen Inorganic materials 0.000 claims description 8
 - 239000001257 hydrogen Substances 0.000 claims description 8
 - 239000008188 pellet Substances 0.000 claims description 7
 - 150000003839 salts Chemical class 0.000 claims description 7
 - 125000000217 alkyl group Chemical group 0.000 claims description 6
 - 239000008187 granular material Substances 0.000 claims description 6
 - 238000002844 melting Methods 0.000 claims description 6
 - 230000008018 melting Effects 0.000 claims description 6
 - 239000002245 particle Substances 0.000 claims description 6
 - 239000002253 acid Substances 0.000 claims description 5
 - 229920001400 block copolymer Polymers 0.000 claims description 5
 - 229910052757 nitrogen Inorganic materials 0.000 claims description 5
 - IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 4
 - GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 4
 - 238000002156 mixing Methods 0.000 claims description 4
 - 125000002877 alkyl aryl group Chemical group 0.000 claims description 3
 - 230000000694 effects Effects 0.000 claims description 3
 - GVNVAWHJIKLAGL-UHFFFAOYSA-N 2-(cyclohexen-1-yl)cyclohexan-1-one Chemical compound O=C1CCCCC1C1=CCCCC1 GVNVAWHJIKLAGL-UHFFFAOYSA-N 0.000 claims description 2
 - 101150065749 Churc1 gene Proteins 0.000 claims description 2
 - 102100038239 Protein Churchill Human genes 0.000 claims description 2
 - 125000000524 functional group Chemical group 0.000 claims description 2
 - 231100000252 nontoxic Toxicity 0.000 claims description 2
 - 230000003000 nontoxic effect Effects 0.000 claims description 2
 - 230000001747 exhibiting effect Effects 0.000 claims 1
 - 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 1
 - 229910001651 emery Inorganic materials 0.000 description 12
 - VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 9
 - 229920001983 poloxamer Polymers 0.000 description 9
 - 125000002091 cationic group Chemical group 0.000 description 8
 - 239000003085 diluting agent Substances 0.000 description 8
 - JJWLVOIRVHMVIS-UHFFFAOYSA-N isopropylamine Chemical class CC(C)N JJWLVOIRVHMVIS-UHFFFAOYSA-N 0.000 description 8
 - 239000002518 antifoaming agent Substances 0.000 description 7
 - XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
 - RVGRUAULSDPKGF-UHFFFAOYSA-N Poloxamer Chemical compound C1CO1.CC1CO1 RVGRUAULSDPKGF-UHFFFAOYSA-N 0.000 description 6
 - 230000002378 acidificating effect Effects 0.000 description 6
 - 229920001577 copolymer Polymers 0.000 description 6
 - 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 6
 - 239000012467 final product Substances 0.000 description 5
 - IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
 - LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
 - UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
 - 125000000129 anionic group Chemical group 0.000 description 4
 - 239000006185 dispersion Substances 0.000 description 4
 - 238000005187 foaming Methods 0.000 description 4
 - 150000002431 hydrogen Chemical class 0.000 description 4
 - 239000000243 solution Substances 0.000 description 4
 - 239000002904 solvent Substances 0.000 description 4
 - OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
 - IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 3
 - 229920002359 Tetronic® Polymers 0.000 description 3
 - 239000007864 aqueous solution Substances 0.000 description 3
 - HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 3
 - 229910052799 carbon Inorganic materials 0.000 description 3
 - 239000000194 fatty acid Substances 0.000 description 3
 - 239000002736 nonionic surfactant Substances 0.000 description 3
 - 125000001997 phenyl group Chemical class [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
 - 229920001451 polypropylene glycol Polymers 0.000 description 3
 - 239000000047 product Substances 0.000 description 3
 - 238000003860 storage Methods 0.000 description 3
 - 125000001424 substituent group Chemical group 0.000 description 3
 - FJLUATLTXUNBOT-UHFFFAOYSA-N 1-Hexadecylamine Chemical compound CCCCCCCCCCCCCCCCN FJLUATLTXUNBOT-UHFFFAOYSA-N 0.000 description 2
 - 241000196324 Embryophyta Species 0.000 description 2
 - VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
 - 239000005977 Ethylene Substances 0.000 description 2
 - 239000004606 Fillers/Extenders Substances 0.000 description 2
 - 241000124008 Mammalia Species 0.000 description 2
 - 229920002257 Plurafac® Polymers 0.000 description 2
 - 239000004480 active ingredient Substances 0.000 description 2
 - 239000002280 amphoteric surfactant Substances 0.000 description 2
 - 239000003945 anionic surfactant Substances 0.000 description 2
 - 239000003125 aqueous solvent Substances 0.000 description 2
 - 239000003093 cationic surfactant Substances 0.000 description 2
 - 235000014113 dietary fatty acids Nutrition 0.000 description 2
 - 238000004090 dissolution Methods 0.000 description 2
 - 238000001035 drying Methods 0.000 description 2
 - 229930195729 fatty acid Natural products 0.000 description 2
 - 150000004665 fatty acids Chemical class 0.000 description 2
 - 238000009472 formulation Methods 0.000 description 2
 - 230000002363 herbicidal effect Effects 0.000 description 2
 - 125000002768 hydroxyalkyl group Chemical group 0.000 description 2
 - 239000011159 matrix material Substances 0.000 description 2
 - 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 2
 - SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 2
 - 239000000377 silicon dioxide Substances 0.000 description 2
 - 239000012265 solid product Substances 0.000 description 2
 - JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical group OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
 - XFRVVPUIAFSTFO-UHFFFAOYSA-N 1-Tridecanol Chemical compound CCCCCCCCCCCCCO XFRVVPUIAFSTFO-UHFFFAOYSA-N 0.000 description 1
 - JKTAIYGNOFSMCE-UHFFFAOYSA-N 2,3-di(nonyl)phenol Chemical compound CCCCCCCCCC1=CC=CC(O)=C1CCCCCCCCC JKTAIYGNOFSMCE-UHFFFAOYSA-N 0.000 description 1
 - VGVRFARTWVJNQC-UHFFFAOYSA-N 2-(2,4-dichlorophenoxy)acetamide Chemical compound NC(=O)COC1=CC=C(Cl)C=C1Cl VGVRFARTWVJNQC-UHFFFAOYSA-N 0.000 description 1
 - DUIOKRXOKLLURE-UHFFFAOYSA-N 2-octylphenol Chemical compound CCCCCCCCC1=CC=CC=C1O DUIOKRXOKLLURE-UHFFFAOYSA-N 0.000 description 1
 - 229910002012 Aerosil® Inorganic materials 0.000 description 1
 - OKTJSMMVPCPJKN-IGMARMGPSA-N Carbon-12 Chemical compound [12C] OKTJSMMVPCPJKN-IGMARMGPSA-N 0.000 description 1
 - 235000013162 Cocos nucifera Nutrition 0.000 description 1
 - 244000060011 Cocos nucifera Species 0.000 description 1
 - MHZGKXUYDGKKIU-UHFFFAOYSA-N Decylamine Chemical compound CCCCCCCCCCN MHZGKXUYDGKKIU-UHFFFAOYSA-N 0.000 description 1
 - 229910001335 Galvanized steel Inorganic materials 0.000 description 1
 - ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
 - 239000002202 Polyethylene glycol Substances 0.000 description 1
 - 235000004443 Ricinus communis Nutrition 0.000 description 1
 - FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
 - 235000021355 Stearic acid Nutrition 0.000 description 1
 - 229910000831 Steel Inorganic materials 0.000 description 1
 - 208000027418 Wounds and injury Diseases 0.000 description 1
 - 239000002250 absorbent Substances 0.000 description 1
 - 230000002745 absorbent Effects 0.000 description 1
 - 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 1
 - 239000013543 active substance Substances 0.000 description 1
 - 239000000654 additive Substances 0.000 description 1
 - 239000002671 adjuvant Substances 0.000 description 1
 - 125000003342 alkenyl group Chemical group 0.000 description 1
 - 125000003545 alkoxy group Chemical group 0.000 description 1
 - 125000005233 alkylalcohol group Chemical group 0.000 description 1
 - 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 description 1
 - 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
 - 239000011230 binding agent Substances 0.000 description 1
 - 238000009835 boiling Methods 0.000 description 1
 - 150000003940 butylamines Chemical class 0.000 description 1
 - 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
 - 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
 - 125000004965 chloroalkyl group Chemical group 0.000 description 1
 - 238000007796 conventional method Methods 0.000 description 1
 - 125000004093 cyano group Chemical group *C#N 0.000 description 1
 - 230000006378 damage Effects 0.000 description 1
 - 230000007423 decrease Effects 0.000 description 1
 - 239000002270 dispersing agent Substances 0.000 description 1
 - LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
 - 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
 - 239000000839 emulsion Substances 0.000 description 1
 - 238000001704 evaporation Methods 0.000 description 1
 - 230000008020 evaporation Effects 0.000 description 1
 - 150000002191 fatty alcohols Chemical class 0.000 description 1
 - 239000006260 foam Substances 0.000 description 1
 - 125000002485 formyl group Chemical group [H]C(*)=O 0.000 description 1
 - 239000008397 galvanized steel Substances 0.000 description 1
 - 239000007789 gas Substances 0.000 description 1
 - OXHDYFKENBXUEM-UHFFFAOYSA-N glyphosine Chemical compound OC(=O)CN(CP(O)(O)=O)CP(O)(O)=O OXHDYFKENBXUEM-UHFFFAOYSA-N 0.000 description 1
 - 229910052736 halogen Inorganic materials 0.000 description 1
 - 150000002367 halogens Chemical class 0.000 description 1
 - 239000012760 heat stabilizer Substances 0.000 description 1
 - 239000004009 herbicide Substances 0.000 description 1
 - VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical class C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 description 1
 - 238000011065 in-situ storage Methods 0.000 description 1
 - 208000014674 injury Diseases 0.000 description 1
 - 239000011872 intimate mixture Substances 0.000 description 1
 - 231100000053 low toxicity Toxicity 0.000 description 1
 - VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
 - 239000004570 mortar (masonry) Substances 0.000 description 1
 - 231100000344 non-irritating Toxicity 0.000 description 1
 - QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
 - OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
 - 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
 - 238000004806 packaging method and process Methods 0.000 description 1
 - 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
 - VXTWEDPZMSVFEF-UHFFFAOYSA-N pheniprazine Chemical compound NNC(C)CC1=CC=CC=C1 VXTWEDPZMSVFEF-UHFFFAOYSA-N 0.000 description 1
 - 239000005648 plant growth regulator Substances 0.000 description 1
 - 239000004033 plastic Substances 0.000 description 1
 - 229920003023 plastic Polymers 0.000 description 1
 - 229920001223 polyethylene glycol Polymers 0.000 description 1
 - 229920001296 polysiloxane Polymers 0.000 description 1
 - 230000000630 rising effect Effects 0.000 description 1
 - 210000002374 sebum Anatomy 0.000 description 1
 - 239000011780 sodium chloride Substances 0.000 description 1
 - 238000007711 solidification Methods 0.000 description 1
 - 230000008023 solidification Effects 0.000 description 1
 - 238000005507 spraying Methods 0.000 description 1
 - 239000007858 starting material Substances 0.000 description 1
 - 239000008117 stearic acid Substances 0.000 description 1
 - 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
 - 239000010959 steel Substances 0.000 description 1
 - 239000000126 substance Substances 0.000 description 1
 - 239000003760 tallow Substances 0.000 description 1
 - 125000002813 thiocarbonyl group Chemical group *C(*)=S 0.000 description 1
 - 231100000331 toxic Toxicity 0.000 description 1
 - 230000002588 toxic effect Effects 0.000 description 1
 - 229940087291 tridecyl alcohol Drugs 0.000 description 1
 - 229940124543 ultraviolet light absorber Drugs 0.000 description 1
 - 239000002699 waste material Substances 0.000 description 1
 - 239000000080 wetting agent Substances 0.000 description 1
 
Classifications
- 
        
- C—CHEMISTRY; METALLURGY
 - C07—ORGANIC CHEMISTRY
 - C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
 - C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
 - C07F9/02—Phosphorus compounds
 - C07F9/28—Phosphorus compounds with one or more P—C bonds
 - C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
 - C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
 - C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
 - C07F9/3813—N-Phosphonomethylglycine; Salts or complexes thereof
 
 - 
        
- A—HUMAN NECESSITIES
 - A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
 - A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
 - A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
 - A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
 
 - 
        
- A—HUMAN NECESSITIES
 - A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
 - A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
 - A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
 - A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
 - A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
 
 
Landscapes
- Life Sciences & Earth Sciences (AREA)
 - General Health & Medical Sciences (AREA)
 - Health & Medical Sciences (AREA)
 - Chemical & Material Sciences (AREA)
 - Organic Chemistry (AREA)
 - Environmental Sciences (AREA)
 - Wood Science & Technology (AREA)
 - Agronomy & Crop Science (AREA)
 - Pest Control & Pesticides (AREA)
 - Plant Pathology (AREA)
 - Zoology (AREA)
 - Engineering & Computer Science (AREA)
 - Dentistry (AREA)
 - Molecular Biology (AREA)
 - Toxicology (AREA)
 - Biochemistry (AREA)
 - Agricultural Chemicals And Associated Chemicals (AREA)
 - Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
 - Pigments, Carbon Blacks, Or Wood Stains (AREA)
 - Glanulating (AREA)
 - Materials For Medical Uses (AREA)
 
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title | 
|---|---|---|---|
| US89724086A | 1986-08-18 | 1986-08-18 | |
| US89724086 | 1986-08-18 | 
Publications (3)
| Publication Number | Publication Date | 
|---|---|
| DK419287D0 DK419287D0 (da) | 1987-08-12 | 
| DK419287A DK419287A (da) | 1988-02-19 | 
| DK170456B1 true DK170456B1 (da) | 1995-09-11 | 
Family
ID=25407602
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date | 
|---|---|---|---|
| DK419287A DK170456B1 (da) | 1986-08-18 | 1987-08-12 | Fremgangsmåde til fremstilling af faste, fytoaktive midler | 
Country Status (17)
| Country | Link | 
|---|---|
| EP (1) | EP0256608B1 (forum.php) | 
| JP (1) | JPH0825849B2 (forum.php) | 
| AR (1) | AR247071A1 (forum.php) | 
| AT (1) | ATE74487T1 (forum.php) | 
| BR (1) | BR8704213A (forum.php) | 
| CA (1) | CA1309266C (forum.php) | 
| DE (1) | DE3778089D1 (forum.php) | 
| DK (1) | DK170456B1 (forum.php) | 
| ES (1) | ES2032290T3 (forum.php) | 
| FI (1) | FI85322C (forum.php) | 
| GR (1) | GR3004328T3 (forum.php) | 
| HU (1) | HU205614B (forum.php) | 
| IL (1) | IL83571A (forum.php) | 
| NO (1) | NO172023C (forum.php) | 
| RO (1) | RO98944B1 (forum.php) | 
| RU (1) | RU2038790C1 (forum.php) | 
| ZA (1) | ZA876068B (forum.php) | 
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title | 
|---|---|---|---|---|
| JP2784579B2 (ja) * | 1988-11-22 | 1998-08-06 | 大日本除蟲菊株式会社 | 屋内用粉剤およびその安定化方法 | 
| NZ231897A (en) * | 1988-12-30 | 1992-09-25 | Monsanto Co | Dry water-soluble granular composition comprising glyphosate and a liquid surfactant | 
| JP2770400B2 (ja) * | 1989-04-18 | 1998-07-02 | 住友化学工業株式会社 | 農薬固型製剤 | 
| ES2065680T3 (es) * | 1990-03-12 | 1995-02-16 | Du Pont | Granulos de plaguicida dispersables en agua o solubles en agua a partir de aglutinantes activados por calor. | 
| RU2096955C1 (ru) * | 1991-03-01 | 1997-11-27 | Е.И.Дюпон Де Немур Энд Компани | Вододиспергируемая гранулированная пестицидная композиция, получаемая методом экструзии, и способ ее получения | 
| HU212802B (en) | 1991-07-19 | 1996-11-28 | Monsanto Europe Sa | Phytoactive sack-like composition containing glyphosate-izopropylamine salt | 
| IL101539A (en) | 1991-04-16 | 1998-09-24 | Monsanto Europe Sa | Non-hygroscopic mono-ammonium salts of n-phosphonomethyl glycine derivatives their preparation and pesticidal compositons containing them | 
| MY111437A (en) * | 1992-07-31 | 2000-05-31 | Monsanto Co | Improved glyphosate herbicide formulation. | 
| GB9412722D0 (en) * | 1994-06-24 | 1994-08-17 | Zeneca Ltd | Herbicidal composition | 
| US5614468A (en) * | 1995-06-07 | 1997-03-25 | Monsanto Company | Preparation of ammonium glyphosate using aqueous ammonium hydroxide in a liquid-solid reaction system | 
| US5633397A (en) * | 1995-06-07 | 1997-05-27 | Monsanto Company | Preparation of ammonium glyphosate via a gas-solid reaction system | 
| PT755626E (pt) * | 1995-07-27 | 2001-08-30 | Micro Flo Co | Encapsulagem com agentes emulsionantes | 
| BRPI0207826B1 (pt) * | 2001-03-02 | 2018-09-25 | Monsanto Technology Llc | composições aquosas de concentrado pesticida contendo ácido oxálico | 
| US6734142B2 (en) | 2001-04-23 | 2004-05-11 | Monsanto Technology Llc | Ammonium glyphosate compositions and process for their preparation | 
| EP1538910A2 (en) | 2002-08-31 | 2005-06-15 | Monsanto Technology LLC | Process for the preparation of a dry pesticidal composition containing a dicarboxylate component | 
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title | 
|---|---|---|---|---|
| FR756242A (fr) * | 1932-06-30 | 1933-12-06 | Schering Kahlbaum Ag | Procédé permettant d'améliorer l'efficacité des insecticides végétaux | 
| US4183740A (en) * | 1978-01-05 | 1980-01-15 | American Cyanamid Company | Solid compositions of a liquid surfactant and a pyrazolium herbicide | 
| DE3035554A1 (de) * | 1980-09-20 | 1982-05-06 | Hoechst Ag, 6000 Frankfurt | Herbizide mittel | 
| FI86501C (fi) * | 1985-05-29 | 1992-09-10 | Stauffer Chemical Co | Fast, i huvudsak icke-hygroskopisk fytoaktiv blandning och dess framstaellningsfoerfarande. | 
- 
        1987
        
- 1987-08-12 DK DK419287A patent/DK170456B1/da not_active IP Right Cessation
 - 1987-08-12 JP JP62200123A patent/JPH0825849B2/ja not_active Expired - Lifetime
 - 1987-08-13 RO RO129444A patent/RO98944B1/ro unknown
 - 1987-08-13 BR BR8704213A patent/BR8704213A/pt not_active IP Right Cessation
 - 1987-08-14 AR AR87308453A patent/AR247071A1/es active
 - 1987-08-14 CA CA000544516A patent/CA1309266C/en not_active Expired - Lifetime
 - 1987-08-17 IL IL83571A patent/IL83571A/xx unknown
 - 1987-08-17 FI FI873549A patent/FI85322C/fi not_active IP Right Cessation
 - 1987-08-17 AT AT87201554T patent/ATE74487T1/de active
 - 1987-08-17 ZA ZA876068A patent/ZA876068B/xx unknown
 - 1987-08-17 DE DE8787201554T patent/DE3778089D1/de not_active Expired - Lifetime
 - 1987-08-17 RU SU874203108A patent/RU2038790C1/ru active
 - 1987-08-17 NO NO873454A patent/NO172023C/no unknown
 - 1987-08-17 HU HU873693A patent/HU205614B/hu not_active IP Right Cessation
 - 1987-08-17 ES ES198787201554T patent/ES2032290T3/es not_active Expired - Lifetime
 - 1987-08-17 EP EP87201554A patent/EP0256608B1/en not_active Expired - Lifetime
 
 - 
        1992
        
- 1992-04-09 GR GR920400653T patent/GR3004328T3/el unknown
 
 
Also Published As
| Publication number | Publication date | 
|---|---|
| HUT47952A (en) | 1989-04-28 | 
| EP0256608A3 (en) | 1989-03-08 | 
| EP0256608A2 (en) | 1988-02-24 | 
| FI85322C (fi) | 1992-04-10 | 
| NO873454L (no) | 1988-02-19 | 
| ATE74487T1 (de) | 1992-04-15 | 
| BR8704213A (pt) | 1988-04-12 | 
| JPS6351307A (ja) | 1988-03-04 | 
| CA1309266C (en) | 1992-10-27 | 
| RO98944B1 (ro) | 1990-05-30 | 
| EP0256608B1 (en) | 1992-04-08 | 
| AR247071A1 (es) | 1994-11-30 | 
| NO873454D0 (no) | 1987-08-17 | 
| IL83571A (en) | 1991-07-18 | 
| ZA876068B (en) | 1988-10-26 | 
| FI873549L (fi) | 1988-02-19 | 
| FI85322B (fi) | 1991-12-31 | 
| NO172023C (no) | 1993-06-02 | 
| JPH0825849B2 (ja) | 1996-03-13 | 
| FI873549A0 (fi) | 1987-08-17 | 
| RU2038790C1 (ru) | 1995-07-09 | 
| DE3778089D1 (de) | 1992-05-14 | 
| NO172023B (no) | 1993-02-22 | 
| GR3004328T3 (forum.php) | 1993-03-31 | 
| DK419287A (da) | 1988-02-19 | 
| ES2032290T3 (es) | 1993-02-01 | 
| HU205614B (en) | 1992-05-28 | 
| DK419287D0 (da) | 1987-08-12 | 
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Legal Events
| Date | Code | Title | Description | 
|---|---|---|---|
| B1 | Patent granted (law 1993) | ||
| PBP | Patent lapsed |