DK139873C - - Google Patents

Info

Publication number
DK139873C
DK139873C DK625274A DK625274A DK139873C DK 139873 C DK139873 C DK 139873C DK 625274 A DK625274 A DK 625274A DK 625274 A DK625274 A DK 625274A DK 139873 C DK139873 C DK 139873C
Authority
DK
Denmark
Application number
DK625274A
Other languages
Danish (da)
Other versions
DK625274A (pt
DK139873B (da
Inventor
W S Knowles
M J Sabacky
B D Vineyard
Original Assignee
Monsanto Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Monsanto Co filed Critical Monsanto Co
Publication of DK625274A publication Critical patent/DK625274A/da
Priority to DK245476A priority Critical patent/DK245476A/da
Priority to DK245376A priority patent/DK245376A/da
Publication of DK139873B publication Critical patent/DK139873B/da
Application granted granted Critical
Publication of DK139873C publication Critical patent/DK139873C/da

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2409Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2409Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
    • B01J31/2414Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom comprising aliphatic or saturated rings
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0073Rhodium compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0073Rhodium compounds
    • C07F15/008Rhodium compounds without a metal-carbon linkage
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/28Phosphorus compounds with one or more P—C bonds
    • C07F9/50Organo-phosphines
    • C07F9/5027Polyphosphines
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60Reduction reactions, e.g. hydrogenation
    • B01J2231/64Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B01J2231/645Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of C=C or C-C triple bonds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82Metals of the platinum group
    • B01J2531/821Ruthenium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82Metals of the platinum group
    • B01J2531/822Rhodium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82Metals of the platinum group
    • B01J2531/827Iridium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/1875Phosphinites (R2P(OR), their isomeric phosphine oxides (R3P=O) and RO-substitution derivatives thereof)

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
DK625274AA 1973-12-03 1974-12-02 Som katalysatorbestanddel tjenende optisk aktive bis-phosphin-forbindelser. DK139873B (da)

Priority Applications (2)

Application Number Priority Date Filing Date Title
DK245476A DK245476A (da) 1973-12-03 1976-06-03 Fremgangsmade til katalytisk hydrogenering
DK245376A DK245376A (da) 1973-12-03 1976-06-03 Som katalysator tjenende, koordineret komplex

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US42146373A 1973-12-03 1973-12-03
US05/514,987 US4008281A (en) 1973-12-03 1974-10-15 Asymmetric catalysis

Publications (3)

Publication Number Publication Date
DK625274A DK625274A (pt) 1975-07-28
DK139873B DK139873B (da) 1979-05-07
DK139873C true DK139873C (pt) 1979-10-01

Family

ID=27025254

Family Applications (3)

Application Number Title Priority Date Filing Date
DK625274AA DK139873B (da) 1973-12-03 1974-12-02 Som katalysatorbestanddel tjenende optisk aktive bis-phosphin-forbindelser.
DK245376A DK245376A (da) 1973-12-03 1976-06-03 Som katalysator tjenende, koordineret komplex
DK245476A DK245476A (da) 1973-12-03 1976-06-03 Fremgangsmade til katalytisk hydrogenering

Family Applications After (2)

Application Number Title Priority Date Filing Date
DK245376A DK245376A (da) 1973-12-03 1976-06-03 Som katalysator tjenende, koordineret komplex
DK245476A DK245476A (da) 1973-12-03 1976-06-03 Fremgangsmade til katalytisk hydrogenering

Country Status (23)

Country Link
US (2) US4008281A (pt)
JP (1) JPS5410352B2 (pt)
BE (1) BE822848A (pt)
BR (1) BR7410074A (pt)
CA (1) CA1051912A (pt)
CH (1) CH601142A5 (pt)
DE (2) DE2456937C3 (pt)
DK (3) DK139873B (pt)
FI (2) FI60215C (pt)
FR (1) FR2253026B1 (pt)
GB (1) GB1466803A (pt)
HU (1) HU172991B (pt)
IL (1) IL46108A (pt)
IN (2) IN145549B (pt)
IT (1) IT1026717B (pt)
MX (3) MX149399A (pt)
NL (1) NL166692C (pt)
NO (2) NO744324L (pt)
PL (1) PL107722B1 (pt)
RO (1) RO72485A (pt)
SE (2) SE421316B (pt)
SU (1) SU663273A3 (pt)
YU (1) YU318874A (pt)

Families Citing this family (47)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4124533A (en) * 1971-03-08 1978-11-07 Monsanto Company Metal coordination complexes containing optically active phosphine or arsine ligands
HU177239B (hu) * 1974-10-15 1981-08-28 Monsanto Co Eljárás N-acetamido-L-alanin-származékok előállítására α-acetamido-akrilsav-származékok aszimmetrikus katalitikus hídrogénezésével
US4515731A (en) * 1975-08-25 1985-05-07 Monsanto Company Asymmetric catalysis
US4123465A (en) * 1975-10-16 1978-10-31 Hoffmann-La Roche Inc. Chiral tertiary phosphines
US4166824A (en) * 1977-06-14 1979-09-04 American Cyanamid Company Chiral rhodium-diphosphine catalyst capable of catalytic reduction of a tetramisole precursor to give a significant excess of the desired S-(-)isomer, levamisole
US4120870A (en) * 1977-07-18 1978-10-17 Hoffmann-La Roche Inc. Metal phosphine complex
IT1087963B (it) * 1977-10-17 1985-06-04 Snam Progetti Idrogenazione asimmetrica di olefine prochirali mediante complessi di metalli di transazione immobilizzati in minerali argillosi.
US5147868A (en) * 1978-07-24 1992-09-15 Merck & Co., Inc. Thienamycin renal peptidase inhibitors
US4616038A (en) * 1978-07-24 1986-10-07 Merck & Co., Inc. Combination of thienamycin-type antibiotics with dipeptidase inhibitors
US4880793A (en) * 1978-07-24 1989-11-14 Merck & Co., Inc. Combination of thienamycin-type antibiotics with dipeptidase inhibitors
ZA793744B (en) * 1978-07-24 1981-02-25 Merck & Co Inc Z-2-acylamino-3-monsosubstituted propenoates
NL8020088A (nl) * 1979-02-12 1980-12-31 Exxon Research And Engineering Company Te Florham Park, New Jersey, Ver. St. V. Am. Tetraaelkylfosfonium-gesubstitueerde overgangsmetaal- complexen.
US4302401A (en) * 1980-01-23 1981-11-24 Exxon Research & Engineering Co. Tetraalkyl phosphonium substituted phosphine and amine transition metal complexes
US4204997A (en) * 1979-03-19 1980-05-27 Monsanto Company Asymmetric amination of 1,3-dienes
US4539208A (en) * 1980-09-17 1985-09-03 Merck & Co., Inc. Combination of thienamycin-type antibiotics with dipeptidase inhibitors
DE3000445C2 (de) * 1980-01-08 1982-12-02 Degussa Ag, 6000 Frankfurt Rhodiumkomplexe und deren Verwendung
US4473505A (en) * 1980-02-12 1984-09-25 Exxon Research And Engineering Co. Phosphine and phosphonium compounds and catalysts
US4331818A (en) * 1980-03-19 1982-05-25 The Procter & Gamble Company Chiral phospine ligand
DE3018388A1 (de) * 1980-05-14 1981-11-19 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von optisch aktiven verbindungen und deren verwendung zur herstellung von vitamin e
DE3039053C2 (de) * 1980-10-16 1984-05-24 Degussa Ag, 6000 Frankfurt Verfahren zur Herstellung von Dipeptiden
US4376870A (en) * 1980-12-05 1983-03-15 Monsanto Company Optically active phosphine compounds
US4343741A (en) * 1981-04-22 1982-08-10 Hoffmann-La Roche Inc. Chiral phosphines
US4393240A (en) * 1981-07-06 1983-07-12 Stille John K Optically active phosphines
US4440634A (en) * 1981-08-03 1984-04-03 Exxon Research And Engineering Co. Organic salt compositions in extraction processes
US4359596A (en) * 1981-08-03 1982-11-16 Exxon Research And Engineering Co. Liquid salt extraction of aromatics from process feed streams
US4422975A (en) * 1981-08-03 1983-12-27 Exxon Research And Engineering Co. Organic salt compositions in extraction processes
JPS5849179A (ja) * 1981-09-17 1983-03-23 ブラザー工業株式会社 2本針ミシンの制御装置
JPS6061587A (ja) * 1983-09-16 1985-04-09 Takasago Corp ロジウム−ホスフイン錯体
US4766226A (en) * 1984-02-01 1988-08-23 Smithkline Beckman Corporation Antitumor pharmaceutical compositions and methods for treating tumors employing α,ω-bis(disubstitutedphosphino)hydrocarbon derivatives or [α, ω-bis(disubstitutedphosphino)hydrocarbon] di
US4857549A (en) * 1984-02-01 1989-08-15 Smithkline Beckman Corporation Antitumor compounds
JPS6163690A (ja) * 1984-09-04 1986-04-01 Takasago Corp ルテニウム−ホスフイン錯体
US5011995A (en) * 1987-07-28 1991-04-30 Ciba-Geigy Corporation Process for the preparation of optically active secondary amines
US4912221A (en) * 1988-10-27 1990-03-27 Occidental Chemical Corporation Chiral 1,2,3,4-tetrahydroisoquinoline-3-carboxylic acid and precursors and preparation thereof
JPH0623150B2 (ja) * 1988-11-15 1994-03-30 高砂香料工業株式会社 光学活性3−ヒドロキシブタン酸類の製造方法
US5198561A (en) * 1989-06-22 1993-03-30 Monsanto Company Ruthenium-BINAP asymmetric hydrogenation catalyst
US5202474A (en) * 1989-06-22 1993-04-13 Monsanto Company Asymmetric catalytic hydrogenation of α-arylpropenoic acids
US5233084A (en) * 1989-06-22 1993-08-03 Monsanto Company Method for preparing α-arylpropionic acids
EP0512415B1 (de) * 1991-05-03 1997-08-06 Hoechst Aktiengesellschaft Verfahren zur enantioselektiven Synthese von 2(R)-Benzylbernsteinsäuremonoamid-Derivaten
US5744655A (en) * 1996-06-19 1998-04-28 The Dow Chemical Company Process to make 2,3-dihalopropanols
JP2972887B1 (ja) * 1998-10-29 1999-11-08 千葉大学長 光学活性ビスホスフィノメタン並びにそれらのロジウム又は銅錯体を用いる不斉合成
GB9823716D0 (en) * 1998-10-29 1998-12-23 Isis Innovation Diphosphines
JP4373013B2 (ja) 1998-12-18 2009-11-25 ダウ グローバル テクノロジーズ インコーポレイティド 2,3−ジハロプロパノールの製造方法
GB0004297D0 (en) 2000-02-23 2000-04-12 Ucb Sa 2-oxo-1 pyrrolidine derivatives process for preparing them and their uses
FR2887253A1 (fr) * 2005-06-20 2006-12-22 Phosphoenix Sarl Nouvelles arylphosphines p chirales ortho-fonctionnalisees et derives: leur preparation et utilisation en catalyse asymetrique
GB0707379D0 (en) * 2007-03-28 2007-05-23 Celtic Catalysts Ltd Chiral phosphorus compounds
CA3102006A1 (en) * 2018-06-08 2019-12-12 Board Of Supervisors Of Louisiana State University And Agricultural And Mechanical College Catalyst compositions for hydroformylation and methods of use thereof
CN110396072B (zh) * 2019-09-02 2022-09-13 上海欣海健伟实业有限公司 (s)-3-羟基四氢呋喃的制备方法

Family Cites Families (9)

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Publication number Priority date Publication date Assignee Title
NL134180C (pt) * 1961-03-29 1900-01-01
US3145227A (en) * 1961-06-14 1964-08-18 American Cyanamid Co Organic phosphine oxides and methods of preparing same
US3849480A (en) * 1968-09-09 1974-11-19 Monsanto Co Catalytic asymmetric hydrogenation
US3657298A (en) * 1970-01-06 1972-04-18 Pressure Chemical Co Arsenic and phosphorus containing polydentates
NL155004B (nl) 1970-05-11 1977-11-15 Monsanto Co Werkwijze voor het asymmetrisch hydrogeneren van een eventieel beta-gesubstitueerd alfa-acylaminoacrylzuur en/of een zout daarvan, alsmede werkwijze voor de bereiding van een katalysatoroplossing.
FR2116905A5 (fr) * 1970-12-10 1972-07-21 Inst Francais Du Petrole Nouveaux coordinats bidentes,leur fabrication et leurs applications
US4124533A (en) * 1971-03-08 1978-11-07 Monsanto Company Metal coordination complexes containing optically active phosphine or arsine ligands
US3780112A (en) * 1972-08-09 1973-12-18 Union Carbide Corp Substituted ethylene bis(phosphine oxides)
FR2230654B1 (pt) * 1973-05-21 1975-11-21 Rhone Poulenc Ind

Also Published As

Publication number Publication date
DE2463010C2 (de) 1982-11-25
CA1051912A (en) 1979-04-03
DE2456937B2 (de) 1980-09-04
SE7415029L (pt) 1975-06-04
HU172991B (hu) 1979-01-28
NO802008L (no) 1975-06-04
FI63216B (fi) 1983-01-31
FR2253026B1 (pt) 1978-05-05
FI60215B (fi) 1981-08-31
IT1026717B (it) 1978-10-20
BR7410074A (pt) 1976-06-08
US4008281A (en) 1977-02-15
MX148257A (es) 1983-04-04
JPS5410352B2 (pt) 1979-05-04
MX149399A (es) 1983-11-03
IL46108A (en) 1978-10-31
CH601142A5 (pt) 1978-06-30
FI60215C (fi) 1981-12-10
FI63216C (fi) 1983-05-10
PL107722B1 (pl) 1980-02-29
US4220590A (en) 1980-09-02
DK625274A (pt) 1975-07-28
SE8104949L (sv) 1981-08-21
MX5144E (es) 1983-04-04
FI802271A (fi) 1980-07-17
DE2456937C3 (de) 1981-07-16
DK245376A (da) 1976-06-03
FI348774A (pt) 1975-06-04
YU318874A (en) 1982-10-31
GB1466803A (en) 1977-03-09
JPS50113489A (pt) 1975-09-05
DK139873B (da) 1979-05-07
IL46108A0 (en) 1975-02-10
DK245476A (da) 1976-06-03
DE2456937A1 (de) 1975-06-26
NL166692C (nl) 1981-09-15
IN145549B (pt) 1978-11-04
RO72485A (ro) 1982-12-06
IN145550B (pt) 1978-11-04
SE421316B (sv) 1981-12-14
SU663273A3 (ru) 1979-05-15
AU7594574A (en) 1976-06-03
NL7415583A (nl) 1975-06-05
FR2253026A1 (pt) 1975-06-27
NO744324L (pt) 1975-06-30
NL166692B (nl) 1981-04-15
BE822848A (fr) 1975-06-02

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