DK0586849T3 - Aminoacrylater, en fremgangsmåde til deres fremstilling og deres anvendelse - Google Patents
Aminoacrylater, en fremgangsmåde til deres fremstilling og deres anvendelseInfo
- Publication number
- DK0586849T3 DK0586849T3 DK93111848.3T DK93111848T DK0586849T3 DK 0586849 T3 DK0586849 T3 DK 0586849T3 DK 93111848 T DK93111848 T DK 93111848T DK 0586849 T3 DK0586849 T3 DK 0586849T3
- Authority
- DK
- Denmark
- Prior art keywords
- molecular weight
- weight
- preparation
- aminoacrylates
- prepared
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 2
- QDHUQRBYCVAWEN-UHFFFAOYSA-N amino prop-2-enoate Chemical class NOC(=O)C=C QDHUQRBYCVAWEN-UHFFFAOYSA-N 0.000 title 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 2
- UQBOJOOOTLPNST-UHFFFAOYSA-N Dehydroalanine Chemical class NC(=C)C(O)=O UQBOJOOOTLPNST-UHFFFAOYSA-N 0.000 abstract 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 abstract 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical group CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 abstract 1
- 238000007259 addition reaction Methods 0.000 abstract 1
- 125000003277 amino group Chemical group 0.000 abstract 1
- 150000004985 diamines Chemical class 0.000 abstract 1
- 125000001033 ether group Chemical group 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 125000000896 monocarboxylic acid group Chemical group 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 150000005846 sugar alcohols Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/32—Polymers modified by chemical after-treatment
- C08G65/329—Polymers modified by chemical after-treatment with organic compounds
- C08G65/331—Polymers modified by chemical after-treatment with organic compounds containing oxygen
- C08G65/332—Polymers modified by chemical after-treatment with organic compounds containing oxygen containing carboxyl groups, or halides, or esters thereof
- C08G65/3322—Polymers modified by chemical after-treatment with organic compounds containing oxygen containing carboxyl groups, or halides, or esters thereof acyclic
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C227/00—Preparation of compounds containing amino and carboxyl groups bound to the same carbon skeleton
- C07C227/04—Formation of amino groups in compounds containing carboxyl groups
- C07C227/06—Formation of amino groups in compounds containing carboxyl groups by addition or substitution reactions, without increasing the number of carbon atoms in the carbon skeleton of the acid
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C229/00—Compounds containing amino and carboxyl groups bound to the same carbon skeleton
- C07C229/02—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton
- C07C229/04—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated
- C07C229/06—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having only one amino and one carboxyl group bound to the carbon skeleton
- C07C229/10—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having only one amino and one carboxyl group bound to the carbon skeleton the nitrogen atom of the amino group being further bound to acyclic carbon atoms or to carbon atoms of rings other than six-membered aromatic rings
- C07C229/12—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having only one amino and one carboxyl group bound to the carbon skeleton the nitrogen atom of the amino group being further bound to acyclic carbon atoms or to carbon atoms of rings other than six-membered aromatic rings to carbon atoms of acyclic carbon skeletons
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C229/00—Compounds containing amino and carboxyl groups bound to the same carbon skeleton
- C07C229/02—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton
- C07C229/04—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated
- C07C229/06—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having only one amino and one carboxyl group bound to the carbon skeleton
- C07C229/10—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having only one amino and one carboxyl group bound to the carbon skeleton the nitrogen atom of the amino group being further bound to acyclic carbon atoms or to carbon atoms of rings other than six-membered aromatic rings
- C07C229/14—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having only one amino and one carboxyl group bound to the carbon skeleton the nitrogen atom of the amino group being further bound to acyclic carbon atoms or to carbon atoms of rings other than six-membered aromatic rings to carbon atoms of carbon skeletons containing rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
- C07C69/533—Monocarboxylic acid esters having only one carbon-to-carbon double bond
- C07C69/54—Acrylic acid esters; Methacrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F299/00—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers
- C08F299/02—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates
- C08F299/022—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates from polycondensates with side or terminal unsaturations
- C08F299/024—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates from polycondensates with side or terminal unsaturations the unsaturation being in acrylic or methacrylic groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Paints Or Removers (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Adhesives Or Adhesive Processes (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4225921A DE4225921A1 (de) | 1992-08-05 | 1992-08-05 | Aminoacrylate, ein Verfahren zu ihrer Herstellung und ihre Verwendung |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DK0586849T3 true DK0586849T3 (da) | 1996-01-22 |
Family
ID=6464917
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DK93111848.3T DK0586849T3 (da) | 1992-08-05 | 1993-07-23 | Aminoacrylater, en fremgangsmåde til deres fremstilling og deres anvendelse |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US5482649A (https=) |
| EP (1) | EP0586849B1 (https=) |
| JP (1) | JPH0687804A (https=) |
| AT (1) | ATE129515T1 (https=) |
| CA (1) | CA2101769A1 (https=) |
| DE (2) | DE4225921A1 (https=) |
| DK (1) | DK0586849T3 (https=) |
| ES (1) | ES2080566T3 (https=) |
Families Citing this family (55)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4343246A1 (de) * | 1993-12-17 | 1995-06-22 | Thera Ges Fuer Patente | Prepolymere, daraus hergestellte radikalisch polymerisierbare Massen und deren Verwendung |
| DE19535936A1 (de) * | 1995-09-27 | 1997-04-03 | Basf Lacke & Farben | Acryliertes Polyetherpolyol und dessen Verwendung für strahlenhärtbare Formulierungen |
| DE19543464A1 (de) | 1995-11-22 | 1997-05-28 | Basf Ag | Verfahren zur Herstellung von (Meth)acrylsäureestern |
| DE19625753C2 (de) * | 1996-06-27 | 2000-05-18 | Basf Coatings Ag | Holzbeschichtungsfolie |
| US6517343B2 (en) | 1997-09-26 | 2003-02-11 | Arizona Chemical Company | Coated candles and coating compositions |
| JP2004511537A (ja) * | 2000-10-20 | 2004-04-15 | ユ セ ベ ソシエテ アノニム | 化合物、組成物及びプロセス |
| EP1314777A1 (en) * | 2001-11-27 | 2003-05-28 | The Procter & Gamble Company | Pro-perfume compositions used in cleaning or fabric treatment products |
| CA2488226A1 (en) * | 2002-06-11 | 2003-12-18 | Basf Aktiengesellschaft | (meth)acrylic esters of polyalkoxylated trimethylolpropane |
| CA2487030A1 (en) * | 2002-06-11 | 2003-12-18 | Basf Aktiengesellschaft | (meth)acrylic esters of polyalkoxylated glycerine |
| JP2005532432A (ja) * | 2002-06-11 | 2005-10-27 | ビーエーエスエフ アクチェンゲゼルシャフト | ポリアルコキシル化されたトリメチロールプロパンの（メタ）アクリルエステル |
| US20050124722A1 (en) * | 2003-12-03 | 2005-06-09 | Arthur Samuel D. | Branched highly-functional monomers exhibiting low polymerization shrinkage |
| EP1731541A1 (en) * | 2005-06-10 | 2006-12-13 | Cytec Surface Specialties, S.A. | Low extractable radiation curable compositions containing aminoacrylates |
| CN101801916B (zh) * | 2007-09-21 | 2015-09-09 | 帝斯曼知识产权资产管理有限公司 | 支化的聚酯胺丙烯酸酯 |
| JP5570529B2 (ja) | 2009-01-08 | 2014-08-13 | ビーエーエスエフ ソシエタス・ヨーロピア | 重合開始剤 |
| JP5650196B2 (ja) | 2009-03-24 | 2015-01-07 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | 新規なオリゴ官能性の光開始剤 |
| EP2236541A1 (en) | 2009-03-25 | 2010-10-06 | DSM IP Assets B.V. | Polyesteramide macromolecule and composition comprising such a macromolecule. |
| JP5717718B2 (ja) | 2009-03-30 | 2015-05-13 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | 重合可能な組成物 |
| JP5714008B2 (ja) | 2009-07-30 | 2015-05-07 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | 高分子光開始剤 |
| JP2011068783A (ja) | 2009-09-25 | 2011-04-07 | Fujifilm Corp | インク組成物、及び、インクジェット記録方法 |
| JP5937394B2 (ja) * | 2012-03-23 | 2016-06-22 | リケンテクノス株式会社 | 活性エネルギー線硬化性樹脂組成物 |
| ITVA20120010A1 (it) | 2012-05-03 | 2013-11-04 | Lamberti Spa | Alfa-dichetoni per fotopolimerizzazioni tramite led |
| WO2014060450A1 (en) | 2012-10-19 | 2014-04-24 | Basf Se | Hybrid photoinitiators |
| ITVA20120041A1 (it) | 2012-10-22 | 2014-04-23 | Lamberti Spa | 3-chetocumarine per fotopolimerizzazioni tramite led |
| WO2014064064A1 (en) | 2012-10-23 | 2014-05-01 | Basf Se | Iminoxytriazines as radical generators |
| EP2935393A4 (en) | 2012-12-18 | 2016-06-01 | Basf Se | SEMICONDUCTOR MATERIALS BASED ON NAPHTHALENDIIMIDE VINYLENE OLIGOTHIOPHENO VINYLENE POLYMERS |
| CN110845530A (zh) | 2012-12-19 | 2020-02-28 | Igm集团公司 | 双酰基次膦酸的衍生物、其制备及其作为光敏引发剂的用途 |
| AU2014288876B2 (en) | 2013-07-08 | 2018-11-22 | IGM Group B.V | Liquid bisacylphosphine oxide photoinitiator |
| JP6599446B2 (ja) | 2014-05-30 | 2019-10-30 | アイジーエム レシンス イタリア ソチエタ レスポンサビリタ リミタータ | 多官能性アシルホスフィンオキシド光重合開始剤 |
| CN107073759B (zh) | 2014-11-04 | 2019-12-20 | 蓝宝迪有限公司 | 可光固化组合物 |
| EP3353244B1 (en) | 2015-12-02 | 2021-09-01 | Sun Chemical Corporation | Polymeric aminoacrylates |
| WO2017160784A1 (en) | 2016-03-18 | 2017-09-21 | Sun Chemical Corporation | Energy curable compositions comprising polymeric aminoacrylates |
| WO2017174443A1 (de) * | 2016-04-08 | 2017-10-12 | Basf Se | Trimethylolpropan-derivate |
| JP6526725B2 (ja) * | 2017-01-11 | 2019-06-05 | リケンテクノス株式会社 | 粘着剤組成物 |
| EP3665162B1 (en) | 2017-08-09 | 2025-04-16 | IGM Group B.V. | Multifunctional polymeric photoinitiators |
| US11466161B2 (en) | 2017-12-11 | 2022-10-11 | Igm Resins Italia S.R.L. | Benzoyl-coumarin polymerizable photoinitiators |
| CN111601795B (zh) | 2017-12-14 | 2024-03-19 | 意大利艾坚蒙树脂有限公司 | 水溶性3-香豆素酮 |
| EP3539969A1 (en) | 2018-03-14 | 2019-09-18 | ETH Zurich | Novel photo-initiators and their application |
| EP3539924A1 (en) | 2018-03-14 | 2019-09-18 | ETH Zurich | Novel vinyl phosphines and photo-initiators obtainable therefrom |
| EP3847179A1 (en) | 2018-09-07 | 2021-07-14 | IGM Resins Italia S.r.l. | Multifunctional bisacylphosphine oxide photoinitiators |
| JP7472429B2 (ja) | 2018-12-28 | 2024-04-23 | アイジーエム レシンス イタリア ソチエタ レスポンサビリタ リミタータ | 光開始剤 |
| EP4041719A1 (en) | 2019-10-11 | 2022-08-17 | IGM Resins Italia S.r.l. | Coumarin glyoxylates for led photocuring |
| IT202000023815A1 (it) | 2020-10-09 | 2022-04-09 | Igm Resins Italia Srl | Ketoquinolones as photonitiators |
| IT202100014885A1 (it) | 2021-06-08 | 2022-12-08 | Igm Resins Italia Srl | Fotoiniziatori a base di silicio bifunzionali |
| IT202100025868A1 (it) | 2021-10-08 | 2023-04-08 | Igm Resins Italia Srl | Nuovi fotoiniziatori |
| EP4482881A1 (en) | 2022-02-24 | 2025-01-01 | IGM Resins Italia S.r.l. | Photoinitiators |
| EP4273200B1 (en) | 2022-05-06 | 2026-03-25 | IGM Group B.V. | Photoinitiator package comprising specialised bisacylphosphine oxide photoinitiators and optical brightener sensitizers |
| US20250297109A1 (en) | 2022-05-06 | 2025-09-25 | Igm Group B. V. | Photoinitiator package comprising phosphine oxide photoinitiators, oxazole-based sensitizers and amine additives |
| CN119137224A (zh) | 2022-05-06 | 2024-12-13 | Igm集团公司 | 包含氧化膦光引发剂、基于香豆素的敏化剂和胺添加剂的光引发剂包 |
| KR20250088509A (ko) | 2022-10-05 | 2025-06-17 | 아이지엠 레진스 이탈리아 에스.알.엘. | 폴리머 (메트)아크릴레이트 광개시제 |
| IT202300004737A1 (it) | 2023-03-14 | 2024-09-14 | Igm Resins Italia Srl | Uso di fotoiniziatori specifici in un processo di fotopolimerizzazione utilizzando lunghezze d’onda combinate di luce a led |
| CN121646581A (zh) | 2023-08-03 | 2026-03-10 | 意大利艾坚蒙树脂有限公司 | 10,11-二氢-5h-二苯并[b,f]氮杂䓬衍生物作为光聚合中的光引发剂用于光固化组合物 |
| EP4534614B1 (en) | 2023-10-02 | 2026-04-15 | IGM Group B.V. | Photoinitiator package comprising specialised bisacylphosphine oxide photoinitiators, further acylphosphine oxide photoinitiators and optical brightener sensitizers |
| IT202300028218A1 (it) | 2023-12-28 | 2025-06-28 | Igm Resins Italia Srl | Nuova forma solida di bis(2,4,6-trimetilbenzoil)-n-ottilfosfina ossido |
| EP4579344A1 (en) | 2023-12-29 | 2025-07-02 | IGM Group B.V. | Thioalkylcoumarin photosensitizers for photopolymerization |
| EP4578918A1 (en) | 2023-12-29 | 2025-07-02 | IGM Group B.V. | Photosensitizers for photopolymerization |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3914165A (en) * | 1972-09-18 | 1975-10-21 | Desoto Inc | Radiation curable non-gelled michael addition reaction products |
| US3844916A (en) * | 1972-09-18 | 1974-10-29 | Desoto Inc | Radiation curable non-gelled michael addition reaction products |
| US3925349A (en) * | 1972-09-18 | 1975-12-09 | Desoto Inc | Radiation curable non-gelled michael addition reaction products |
| DE3540464A1 (de) * | 1985-11-14 | 1987-05-21 | Polychemie Gmbh | Reaktive bindemittel |
| DE3706355A1 (de) * | 1987-02-27 | 1988-09-08 | Basf Ag | Additionsprodukte aus acrylaten und aminen sowie deren verwendung in strahlungshaertbaren massen |
| DE3836370A1 (de) * | 1988-10-26 | 1990-05-17 | Basf Lacke & Farben | Verfahren zum beschichten von holz, holzwerkstoffen und papier |
-
1992
- 1992-08-05 DE DE4225921A patent/DE4225921A1/de not_active Withdrawn
-
1993
- 1993-07-22 US US08/095,886 patent/US5482649A/en not_active Expired - Fee Related
- 1993-07-23 EP EP93111848A patent/EP0586849B1/de not_active Revoked
- 1993-07-23 ES ES93111848T patent/ES2080566T3/es not_active Expired - Lifetime
- 1993-07-23 AT AT93111848T patent/ATE129515T1/de not_active IP Right Cessation
- 1993-07-23 DE DE59300819T patent/DE59300819D1/de not_active Revoked
- 1993-07-23 DK DK93111848.3T patent/DK0586849T3/da active
- 1993-08-02 CA CA002101769A patent/CA2101769A1/en not_active Abandoned
- 1993-08-03 JP JP5209993A patent/JPH0687804A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| EP0586849A2 (de) | 1994-03-16 |
| CA2101769A1 (en) | 1994-02-06 |
| ES2080566T3 (es) | 1996-02-01 |
| ATE129515T1 (de) | 1995-11-15 |
| US5482649A (en) | 1996-01-09 |
| EP0586849A3 (https=) | 1994-04-27 |
| DE59300819D1 (de) | 1995-11-30 |
| EP0586849B1 (de) | 1995-10-25 |
| JPH0687804A (ja) | 1994-03-29 |
| DE4225921A1 (de) | 1994-02-10 |
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