DK0455307T3 - Fremgangsmåde til fremstilling af aluminiumoxidbaserede katalysatorer - Google Patents
Fremgangsmåde til fremstilling af aluminiumoxidbaserede katalysatorerInfo
- Publication number
- DK0455307T3 DK0455307T3 DK91201047.7T DK91201047T DK0455307T3 DK 0455307 T3 DK0455307 T3 DK 0455307T3 DK 91201047 T DK91201047 T DK 91201047T DK 0455307 T3 DK0455307 T3 DK 0455307T3
- Authority
- DK
- Denmark
- Prior art keywords
- preparation
- alumina
- mixture
- catalyst
- extrudate
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
- C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
- C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/75—Cobalt
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
- C10G3/42—Catalytic treatment
- C10G3/44—Catalytic treatment characterised by the catalyst used
- C10G3/45—Catalytic treatment characterised by the catalyst used containing iron group metals or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
- C10G3/42—Catalytic treatment
- C10G3/44—Catalytic treatment characterised by the catalyst used
- C10G3/48—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support
- C10G3/49—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support containing crystalline aluminosilicates, e.g. molecular sieves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
- B01J21/04—Alumina
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1022—Fischer-Tropsch products
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/20—C2-C4 olefins
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB909010075A GB9010075D0 (en) | 1990-05-04 | 1990-05-04 | Process for the preparation of alumina based extrudates |
Publications (1)
Publication Number | Publication Date |
---|---|
DK0455307T3 true DK0455307T3 (da) | 1994-09-26 |
Family
ID=10675492
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DK91201047.7T DK0455307T3 (da) | 1990-05-04 | 1991-05-02 | Fremgangsmåde til fremstilling af aluminiumoxidbaserede katalysatorer |
Country Status (15)
Country | Link |
---|---|
EP (1) | EP0455307B1 (da) |
JP (1) | JP3248925B2 (da) |
CN (1) | CN1030898C (da) |
AT (1) | ATE109681T1 (da) |
AU (1) | AU649249B2 (da) |
CA (1) | CA2041686C (da) |
DE (1) | DE69103319T2 (da) |
DK (1) | DK0455307T3 (da) |
ES (1) | ES2059035T3 (da) |
GB (1) | GB9010075D0 (da) |
MY (1) | MY107435A (da) |
NO (1) | NO305157B1 (da) |
NZ (1) | NZ238026A (da) |
RU (1) | RU1836146C (da) |
ZA (1) | ZA913304B (da) |
Families Citing this family (43)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB9108663D0 (en) * | 1991-04-23 | 1991-06-12 | Shell Int Research | Process for the preparation of a catalyst or catalyst precursor |
MY109378A (en) * | 1992-08-18 | 1997-01-31 | Shell Int Research | Process for the preparation of a catalyst for a catalyst precursor |
GB9221976D0 (en) * | 1992-10-20 | 1992-12-02 | Alcan Int Ltd | Shaped articles of zirconia |
FR2764208B1 (fr) * | 1997-06-10 | 1999-07-16 | Rhodia Chimie Sa | Extrudes d'alumine, leurs procedes de preparation et leur utilisation comme catalyseurs ou supports de catalyseurs |
KR100590415B1 (ko) * | 1997-12-30 | 2006-06-19 | 쉘 인터내셔날 리서치 마챠피즈 비.브이. | 코발트 기재의 피셔-트롭쉬 촉매 |
US6262132B1 (en) * | 1999-05-21 | 2001-07-17 | Energy International Corporation | Reducing fischer-tropsch catalyst attrition losses in high agitation reaction systems |
US6465529B1 (en) * | 2000-08-01 | 2002-10-15 | Exxonmobil Research And Engineering Company | Process for increasing cobalt catalyst hydrogenation activity via aqueous low temperature oxidation |
US6508999B1 (en) | 2000-11-21 | 2003-01-21 | Shell Oil Company | Aluminum trihydroxide phase |
MY139580A (en) * | 2002-06-07 | 2009-10-30 | Shell Int Research | Shaped catalyst particles for hydrocarbon synthesis |
AU2003277409C1 (en) * | 2002-10-16 | 2009-06-25 | Conocophillips Company | Fischer-Tropsch processes and catalysts using stabilized supports |
AU2003298268B2 (en) | 2002-11-04 | 2007-11-29 | Shell Internationale Research Maatschappij B.V. | Elongated shaped particles; use as a catalyst or support thereof |
EP1590084A1 (en) | 2002-12-20 | 2005-11-02 | Conocophillips Company | Attrition resistant bulk metal catalysts and methods of making and using same |
MY142111A (en) | 2004-04-16 | 2010-09-15 | Nippon Oil Corp | Catalyst for fischer-tropsch synthesis and process for producing hydrocarbons |
US20060060510A1 (en) * | 2004-09-17 | 2006-03-23 | Bhan Opinder K | High activity hydrodesulfurization catalyst, a method of making a high activity hydrodesulfurization catalyst, and a process for manufacturing an ultra-low sulfur distillate product |
RU2007124433A (ru) | 2004-11-29 | 2009-01-10 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. (NL) | СПОСОБ КАТАЛИТИЧЕСКОГО ПРЕВРАЩЕНИЯ ГИДРОКСИДА Co(II) В ОКСИДГИДРОКСИД Co(III) |
JP4698343B2 (ja) * | 2005-09-01 | 2011-06-08 | 新日本製鐵株式会社 | 合成ガスから炭化水素を製造する触媒とその触媒の製造方法、及び当該触媒を用いた合成ガスから炭化水素を製造する方法 |
MY148471A (en) | 2007-01-18 | 2013-04-30 | Shell Int Research | Catalyst, catalyst precursor, catalyst carrier, preparation and use of thereof in fischer-tropsch synthesis |
JP5025301B2 (ja) * | 2007-03-28 | 2012-09-12 | Jx日鉱日石エネルギー株式会社 | 炭化水素の製造方法 |
CN101293662B (zh) * | 2007-04-28 | 2011-03-30 | 中国石油化工股份有限公司石油化工科学研究院 | 一种γ-氧化铝的制备方法 |
US8507720B2 (en) | 2010-01-29 | 2013-08-13 | Lyondell Chemical Technology, L.P. | Titania-alumina supported palladium catalyst |
US8273682B2 (en) | 2009-12-16 | 2012-09-25 | Lyondell Chemical Technology, L.P. | Preparation of palladium-gold catalyst |
US8329611B2 (en) | 2009-12-16 | 2012-12-11 | Lyondell Chemical Technology, L,P. | Titania-containing extrudate |
JP5676120B2 (ja) | 2010-02-26 | 2015-02-25 | Jx日鉱日石エネルギー株式会社 | 活性化フィッシャー・トロプシュ合成触媒の製造方法及び炭化水素の製造方法 |
MY160868A (en) | 2010-03-05 | 2017-03-31 | Jx Nippon Oil & Energy Corp | Fischer-tropsch synthesis catalyst, manufacturing method therefor, and hydrocarbon manufacturing method |
JP5771358B2 (ja) | 2010-03-05 | 2015-08-26 | Jx日鉱日石エネルギー株式会社 | 再生フィッシャー・トロプシュ合成触媒の製造方法及び炭化水素の製造方法 |
US20110306748A1 (en) * | 2010-06-11 | 2011-12-15 | Daniel Travis Shay | Titania-alumina-tungsta extrudate and its use |
US9527061B2 (en) | 2011-04-28 | 2016-12-27 | Sasol Technology (Proprietary) Limited | Catalysts |
EP2898947A4 (en) | 2012-09-21 | 2016-10-05 | Jx Nippon Oil & Energy Corp | FISCHER-TROPSCH SYNTHESIS CATALYST, PROCESS FOR PRODUCING THE SAME, AND PROCESS FOR PRODUCING HYDROCARBONS |
JP6007167B2 (ja) | 2013-11-18 | 2016-10-12 | Jxエネルギー株式会社 | フィッシャー・トロプシュ合成用触媒の製造方法及び炭化水素の製造方法 |
JP6497351B2 (ja) * | 2016-04-15 | 2019-04-10 | トヨタ自動車株式会社 | 排ガス浄化用触媒の製造方法 |
EP3632546A4 (en) | 2017-05-31 | 2021-01-27 | Furukawa Electric Co., Ltd. | FISCHER-TROPSCH SYNTHESIS CATALYST STRUCTURE, MANUFACTURING METHODS FOR IT, MANUFACTURING METHODS FOR LIQUID HYDROCARBONS USING THE CATALYST STRUCTURE AND DEVICE FOR THE PRODUCTION OF HYDROCARBONS |
FR3076747B1 (fr) * | 2018-01-15 | 2022-06-10 | Ifp Energies Now | Procede de preparation d'un catalyseur particulier d'hydrogenation selective et d'hydrogenation des aromatiques par malaxage |
CN111867725A (zh) | 2018-03-20 | 2020-10-30 | 国际壳牌研究有限公司 | 含钴催化剂的制备 |
US20200055024A1 (en) * | 2018-08-14 | 2020-02-20 | Uop Llc | Hydroprocessing catalyst for heavy distillate streams, method of manufacture and application |
US20220023848A1 (en) | 2018-12-03 | 2022-01-27 | Furukawa Electric Co., Ltd. | Catalyst structure and method for producing same, and method for producing hydrocarbon by use of catalyst structure |
EP3892372A4 (en) | 2018-12-03 | 2022-08-31 | Furukawa Electric Co., Ltd. | CATALYST STRUCTURAL BODY AND METHOD FOR PRODUCTION THEREOF, AND METHOD FOR PRODUCTION OF HYDROCARBON USING CATALYST STRUCTURAL BODY |
EP3892603A4 (en) | 2018-12-03 | 2022-08-31 | Furukawa Electric Co., Ltd. | PRODUCTION DEVICE FOR HYDROCARBONS AND PRODUCTION PROCESS FOR HYDROCARBONS |
US11925930B2 (en) | 2018-12-03 | 2024-03-12 | Furukawa Electric Co., Ltd. | Apparatus for producing lower olefin-containing gas and method for producing lower olefin-containing gas |
WO2020116478A1 (ja) | 2018-12-03 | 2020-06-11 | 古河電気工業株式会社 | 炭化水素の製造装置および炭化水素の製造方法 |
WO2020116471A1 (ja) | 2018-12-03 | 2020-06-11 | 国立大学法人北海道大学 | 機能性構造体の前駆体および機能性構造体 |
JPWO2020116469A1 (ja) | 2018-12-03 | 2021-12-23 | 国立大学法人北海道大学 | 機能性構造体 |
CN113751017B (zh) * | 2020-06-05 | 2024-01-19 | 北京低碳清洁能源研究院 | 费托合成催化剂及其制备方法和应用 |
US12042785B1 (en) | 2023-09-13 | 2024-07-23 | Dimensional Energy, Inc. | Fischer-Tropsch catalysts |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4036784A (en) * | 1975-05-30 | 1977-07-19 | Uop Inc. | Method of producing an extruded catalyst composition |
US4388222A (en) * | 1976-03-29 | 1983-06-14 | Filtrol Corporation | Ni/Co Mo P On titania-alumina hydrodesulfurizing catalyst |
NL7614173A (en) * | 1976-12-21 | 1978-06-23 | Uop Inc | Extruded metal oxide catalysts, useful in fuel oil desulphurisation - by mixing a refractory metal oxide with a peptising agent under high shear, extruding and calcining |
US4124537A (en) * | 1977-09-12 | 1978-11-07 | Uop Inc. | Coextruded catalytic composite |
DE3673548D1 (de) * | 1985-04-24 | 1990-09-27 | Shell Int Research | Hydrokonversionskatalysator und verfahren. |
-
1990
- 1990-05-04 GB GB909010075A patent/GB9010075D0/en active Pending
-
1991
- 1991-04-29 AU AU76057/91A patent/AU649249B2/en not_active Ceased
- 1991-04-30 RU SU914895384A patent/RU1836146C/ru active
- 1991-05-02 ES ES91201047T patent/ES2059035T3/es not_active Expired - Lifetime
- 1991-05-02 MY MYPI91000742A patent/MY107435A/en unknown
- 1991-05-02 EP EP91201047A patent/EP0455307B1/en not_active Expired - Lifetime
- 1991-05-02 NZ NZ238026A patent/NZ238026A/xx unknown
- 1991-05-02 ZA ZA913304A patent/ZA913304B/xx unknown
- 1991-05-02 DE DE69103319T patent/DE69103319T2/de not_active Expired - Fee Related
- 1991-05-02 DK DK91201047.7T patent/DK0455307T3/da active
- 1991-05-02 JP JP12825191A patent/JP3248925B2/ja not_active Expired - Fee Related
- 1991-05-02 AT AT91201047T patent/ATE109681T1/de not_active IP Right Cessation
- 1991-05-02 CA CA002041686A patent/CA2041686C/en not_active Expired - Fee Related
- 1991-05-02 NO NO911719A patent/NO305157B1/no unknown
- 1991-05-03 CN CN91102770A patent/CN1030898C/zh not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
EP0455307B1 (en) | 1994-08-10 |
AU7605791A (en) | 1991-11-07 |
RU1836146C (ru) | 1993-08-23 |
NZ238026A (en) | 1993-06-25 |
JP3248925B2 (ja) | 2002-01-21 |
AU649249B2 (en) | 1994-05-19 |
MY107435A (en) | 1995-12-30 |
GB9010075D0 (en) | 1990-06-27 |
NO305157B1 (no) | 1999-04-12 |
JPH04227847A (ja) | 1992-08-17 |
ATE109681T1 (de) | 1994-08-15 |
CA2041686C (en) | 2001-10-16 |
CN1056069A (zh) | 1991-11-13 |
EP0455307A1 (en) | 1991-11-06 |
NO911719L (no) | 1991-11-05 |
NO911719D0 (no) | 1991-05-02 |
CN1030898C (zh) | 1996-02-07 |
ZA913304B (en) | 1992-01-29 |
ES2059035T3 (es) | 1994-11-01 |
CA2041686A1 (en) | 1991-11-05 |
DE69103319D1 (de) | 1994-09-15 |
DE69103319T2 (de) | 1994-12-01 |
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