DE69910038T2 - Korrosionsinhibitor für zementmischungen - Google Patents
Korrosionsinhibitor für zementmischungen Download PDFInfo
- Publication number
- DE69910038T2 DE69910038T2 DE69910038T DE69910038T DE69910038T2 DE 69910038 T2 DE69910038 T2 DE 69910038T2 DE 69910038 T DE69910038 T DE 69910038T DE 69910038 T DE69910038 T DE 69910038T DE 69910038 T2 DE69910038 T2 DE 69910038T2
- Authority
- DE
- Germany
- Prior art keywords
- acid
- alkyl
- corrosion
- represented
- atoms
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000005260 corrosion Methods 0.000 title claims abstract description 42
- 239000000203 mixture Substances 0.000 title claims abstract description 19
- 239000004568 cement Substances 0.000 title claims description 24
- 230000007797 corrosion Effects 0.000 title claims description 13
- 239000003112 inhibitor Substances 0.000 title 1
- 150000003973 alkyl amines Chemical class 0.000 claims abstract description 10
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 10
- 239000003795 chemical substances by application Substances 0.000 claims description 24
- 238000000034 method Methods 0.000 claims description 10
- -1 alkyl diamines Chemical class 0.000 claims description 9
- 229910000831 Steel Inorganic materials 0.000 claims description 8
- 239000010959 steel Substances 0.000 claims description 8
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 6
- 230000003014 reinforcing effect Effects 0.000 claims description 6
- HVBSAKJJOYLTQU-UHFFFAOYSA-N 4-aminobenzenesulfonic acid Chemical compound NC1=CC=C(S(O)(=O)=O)C=C1 HVBSAKJJOYLTQU-UHFFFAOYSA-N 0.000 claims description 4
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 4
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims description 4
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 4
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 4
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 4
- 239000012744 reinforcing agent Substances 0.000 claims description 4
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 claims description 4
- 239000003518 caustics Substances 0.000 claims description 3
- 150000007522 mineralic acids Chemical class 0.000 claims description 3
- 150000007524 organic acids Chemical class 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 2
- 239000005711 Benzoic acid Substances 0.000 claims description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 2
- IOVCWXUNBOPUCH-UHFFFAOYSA-N Nitrous acid Chemical compound ON=O IOVCWXUNBOPUCH-UHFFFAOYSA-N 0.000 claims description 2
- 235000011054 acetic acid Nutrition 0.000 claims description 2
- 239000001361 adipic acid Substances 0.000 claims description 2
- 235000011037 adipic acid Nutrition 0.000 claims description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 2
- 235000010323 ascorbic acid Nutrition 0.000 claims description 2
- 229960005070 ascorbic acid Drugs 0.000 claims description 2
- 239000011668 ascorbic acid Substances 0.000 claims description 2
- 235000010233 benzoic acid Nutrition 0.000 claims description 2
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 2
- 239000004327 boric acid Substances 0.000 claims description 2
- 235000015165 citric acid Nutrition 0.000 claims description 2
- 235000019253 formic acid Nutrition 0.000 claims description 2
- 239000004310 lactic acid Substances 0.000 claims description 2
- 235000014655 lactic acid Nutrition 0.000 claims description 2
- 229910017604 nitric acid Inorganic materials 0.000 claims description 2
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 claims description 2
- 229960004889 salicylic acid Drugs 0.000 claims description 2
- 229950000244 sulfanilic acid Drugs 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims 1
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 claims 1
- 230000007423 decrease Effects 0.000 abstract 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 20
- 230000000052 comparative effect Effects 0.000 description 15
- 239000004570 mortar (masonry) Substances 0.000 description 10
- 239000011780 sodium chloride Substances 0.000 description 10
- 239000004567 concrete Substances 0.000 description 9
- 230000000694 effects Effects 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 238000012360 testing method Methods 0.000 description 6
- 230000001629 suppression Effects 0.000 description 4
- 239000011440 grout Substances 0.000 description 3
- 239000008267 milk Substances 0.000 description 3
- 210000004080 milk Anatomy 0.000 description 3
- 235000013336 milk Nutrition 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 150000002826 nitrites Chemical class 0.000 description 2
- RAFRTSDUWORDLA-UHFFFAOYSA-N phenyl 3-chloropropanoate Chemical compound ClCCC(=O)OC1=CC=CC=C1 RAFRTSDUWORDLA-UHFFFAOYSA-N 0.000 description 2
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 1
- OPKOKAMJFNKNAS-UHFFFAOYSA-N N-methylethanolamine Chemical compound CNCCO OPKOKAMJFNKNAS-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001565 benzotriazoles Chemical class 0.000 description 1
- 239000011400 blast furnace cement Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical class [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- XPPKVPWEQAFLFU-UHFFFAOYSA-N diphosphoric acid Chemical compound OP(O)(=O)OP(O)(O)=O XPPKVPWEQAFLFU-UHFFFAOYSA-N 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000010881 fly ash Substances 0.000 description 1
- 229940093915 gynecological organic acid Drugs 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-M naphthalene-1-sulfonate Chemical compound C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-M 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 231100000989 no adverse effect Toxicity 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 229940005657 pyrophosphoric acid Drugs 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 235000010288 sodium nitrite Nutrition 0.000 description 1
- 239000002195 soluble material Substances 0.000 description 1
- 239000008030 superplasticizer Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
- C04B24/12—Nitrogen containing compounds organic derivatives of hydrazine
- C04B24/121—Amines, polyamines
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/26—Corrosion of reinforcement resistance
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP19101298 | 1998-06-23 | ||
| JP19101298A JP4216371B2 (ja) | 1998-06-23 | 1998-06-23 | セメント組成物用防錆剤 |
| PCT/EP1999/004293 WO1999067184A1 (en) | 1998-06-23 | 1999-06-22 | Corrosion inhibitor for cement compositions |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69910038D1 DE69910038D1 (de) | 2003-09-04 |
| DE69910038T2 true DE69910038T2 (de) | 2004-04-15 |
Family
ID=16267417
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69910038T Expired - Fee Related DE69910038T2 (de) | 1998-06-23 | 1999-06-22 | Korrosionsinhibitor für zementmischungen |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US6355100B1 (enExample) |
| EP (1) | EP1094995B1 (enExample) |
| JP (1) | JP4216371B2 (enExample) |
| AT (1) | ATE246156T1 (enExample) |
| AU (1) | AU737703B2 (enExample) |
| DE (1) | DE69910038T2 (enExample) |
| DK (1) | DK1094995T3 (enExample) |
| ES (1) | ES2205847T3 (enExample) |
| PT (1) | PT1094995E (enExample) |
| WO (1) | WO1999067184A1 (enExample) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6340438B1 (en) * | 1999-04-19 | 2002-01-22 | Tomahawk, Inc. | Corrosion inhibiting admixture for concrete |
| AU2003901529A0 (en) * | 2003-03-31 | 2003-05-01 | James Hardie International Finance B.V. | A durable high performance fibre cement product and method of making the same |
| MXPA05003691A (es) | 2002-10-07 | 2005-11-17 | James Hardie Int Finance Bv | Material mixto de fibrocemento de densidad media durable. |
| JP4916648B2 (ja) * | 2004-07-02 | 2012-04-18 | 電気化学工業株式会社 | 防錆処理方法 |
| US7998571B2 (en) | 2004-07-09 | 2011-08-16 | James Hardie Technology Limited | Composite cement article incorporating a powder coating and methods of making same |
| EP1731491A1 (fr) * | 2005-06-10 | 2006-12-13 | Lafarge | Compositions de liant rapide pour pièces et ouvrages en béton contenant un sel de calcium |
| NZ571874A (en) | 2006-04-12 | 2010-11-26 | Hardie James Technology Ltd | A surface sealed reinforced building element |
| US20100286312A1 (en) * | 2009-05-06 | 2010-11-11 | Boral Material Technologies Inc. | Amine Sacrificial Agents and Methods and Products Using Same |
| CN102190454B (zh) * | 2010-03-12 | 2012-10-03 | 中国科学院金属研究所 | 一种掺入型全有机混凝土钢筋阻锈剂 |
| CN102190455B (zh) * | 2010-03-12 | 2013-01-16 | 中国科学院金属研究所 | 一种掺入型非亚硝酸盐基混凝土钢筋阻锈剂 |
| KR101292181B1 (ko) * | 2011-10-27 | 2013-08-01 | 주식회사 삼표 | 폐 석영유리 미분말을 포함한 내구성 증진 콘크리트 조성물 |
| CN103880316B (zh) * | 2014-02-14 | 2016-06-01 | 辽宁科技学院 | 一种掺入型有机糖苷混凝土钢筋阻锈剂和应用 |
| JP6968087B2 (ja) | 2016-03-16 | 2021-11-17 | コンストラクション リサーチ アンド テクノロジー ゲーエムベーハーConstruction Research & Technology GmbH | 腐食防止剤が塗布された表面 |
| CN110183136B (zh) * | 2019-06-04 | 2022-01-04 | 福建省建筑科学研究院有限责任公司 | 一种混凝土防腐阻锈剂及其制备方法 |
| KR102322648B1 (ko) * | 2020-02-14 | 2021-11-09 | 맥스콘소재 주식회사 | 철근콘크리트 방청용 조성물 및 이의 제조방법 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4789523A (en) * | 1987-07-23 | 1988-12-06 | Westvaco Corporation | Cationic and anionic lignin amines corrosion inhibitors |
| JPH01164746A (ja) * | 1987-12-18 | 1989-06-28 | Chiyoda Kagaku Kenkyusho:Kk | モルタル又はコンクリート用防錆剤 |
| NZ239522A (en) * | 1990-09-04 | 1993-10-26 | Chapman Chem Co | Pesticidal compositions containing an amine salt of a phosphonic or orthophosphoric acid |
| DE59405440D1 (de) * | 1994-01-10 | 1998-04-16 | Henkel Kgaa | Formtrennmittel für hydraulische bindemittel |
-
1998
- 1998-06-23 JP JP19101298A patent/JP4216371B2/ja not_active Expired - Fee Related
-
1999
- 1999-06-22 US US09/701,472 patent/US6355100B1/en not_active Expired - Fee Related
- 1999-06-22 EP EP99931123A patent/EP1094995B1/en not_active Expired - Lifetime
- 1999-06-22 PT PT99931123T patent/PT1094995E/pt unknown
- 1999-06-22 WO PCT/EP1999/004293 patent/WO1999067184A1/en not_active Ceased
- 1999-06-22 AT AT99931123T patent/ATE246156T1/de not_active IP Right Cessation
- 1999-06-22 AU AU47749/99A patent/AU737703B2/en not_active Ceased
- 1999-06-22 ES ES99931123T patent/ES2205847T3/es not_active Expired - Lifetime
- 1999-06-22 DK DK99931123T patent/DK1094995T3/da active
- 1999-06-22 DE DE69910038T patent/DE69910038T2/de not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| AU4774999A (en) | 2000-01-10 |
| PT1094995E (pt) | 2003-12-31 |
| DE69910038D1 (de) | 2003-09-04 |
| DK1094995T3 (da) | 2003-09-08 |
| EP1094995B1 (en) | 2003-07-30 |
| WO1999067184A1 (en) | 1999-12-29 |
| US6355100B1 (en) | 2002-03-12 |
| JP2000007401A (ja) | 2000-01-11 |
| ES2205847T3 (es) | 2004-05-01 |
| AU737703B2 (en) | 2001-08-30 |
| ATE246156T1 (de) | 2003-08-15 |
| JP4216371B2 (ja) | 2009-01-28 |
| EP1094995A1 (en) | 2001-05-02 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8364 | No opposition during term of opposition | ||
| 8327 | Change in the person/name/address of the patent owner |
Owner name: CONSTRUCTION RESEARCH & TECHNOLOGY GMBH, 83308 TRO |
|
| 8339 | Ceased/non-payment of the annual fee |