DE69907721T2 - Methylen-verbrückte metallocene als olefin-polymerisationskatalysatorkomponente - Google Patents

Methylen-verbrückte metallocene als olefin-polymerisationskatalysatorkomponente Download PDF

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Publication number
DE69907721T2
DE69907721T2 DE69907721T DE69907721T DE69907721T2 DE 69907721 T2 DE69907721 T2 DE 69907721T2 DE 69907721 T DE69907721 T DE 69907721T DE 69907721 T DE69907721 T DE 69907721T DE 69907721 T2 DE69907721 T2 DE 69907721T2
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DE
Germany
Prior art keywords
indenyl
methylene
bis
formula
substituents
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
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DE69907721T
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German (de)
English (en)
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DE69907721D1 (de
Inventor
Luigi Resconi
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Basell Polyolefine GmbH
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Basell Polyolefine GmbH
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Publication date
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Publication of DE69907721T2 publication Critical patent/DE69907721T2/de
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Expired - Fee Related legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/862Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
    • C07C2/867Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms the non-hydrocarbon is an aldehyde or a ketone
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C13/00Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
    • C07C13/28Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
    • C07C13/32Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings
    • C07C13/45Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with a bicyclo ring system containing nine carbon atoms
    • C07C13/465Indenes; Completely or partially hydrogenated indenes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00Metallocenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2602/00Systems containing two condensed rings
    • C07C2602/02Systems containing two condensed rings the rings having only two atoms in common
    • C07C2602/04One of the condensed rings being a six-membered aromatic ring
    • C07C2602/08One of the condensed rings being a six-membered aromatic ring the other ring being five-membered, e.g. indane
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943Polymerization with metallocene catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
DE69907721T 1998-11-18 1999-11-10 Methylen-verbrückte metallocene als olefin-polymerisationskatalysatorkomponente Expired - Fee Related DE69907721T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP98203906 1998-11-18
EP98203906 1998-11-18
PCT/EP1999/008646 WO2000029415A1 (en) 1998-11-18 1999-11-10 Methylene bridged metallocenes as olefin-polymerization-catalyst components

Publications (2)

Publication Number Publication Date
DE69907721D1 DE69907721D1 (de) 2003-06-12
DE69907721T2 true DE69907721T2 (de) 2004-02-26

Family

ID=8234358

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69907721T Expired - Fee Related DE69907721T2 (de) 1998-11-18 1999-11-10 Methylen-verbrückte metallocene als olefin-polymerisationskatalysatorkomponente

Country Status (12)

Country Link
US (2) US6693156B1 (enExample)
EP (1) EP1131328B1 (enExample)
JP (1) JP2002530285A (enExample)
KR (1) KR20010101034A (enExample)
AR (1) AR021312A1 (enExample)
AU (1) AU1382200A (enExample)
BR (1) BR9916740A (enExample)
CA (1) CA2350542A1 (enExample)
DE (1) DE69907721T2 (enExample)
ES (1) ES2197714T3 (enExample)
IL (1) IL142979A0 (enExample)
WO (1) WO2000029415A1 (enExample)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6559251B1 (en) * 2002-08-02 2003-05-06 Equistar Chemicals, Lp Process for making low-density polyolefins
WO2010022878A1 (en) * 2008-08-25 2010-03-04 Basell Polyolefine Gmbh Preparation of ansa metallocene compounds
KR20140075589A (ko) 2012-12-11 2014-06-19 주식회사 엘지화학 신규한 리간드 화합물, 이의 제조방법, 전이금속 화합물, 및 이의 제조방법
WO2014092327A1 (ko) 2012-12-11 2014-06-19 주식회사 엘지화학 신규한 리간드 화합물, 이의 제조방법 및 상기 리간드 화합물을 포함하는 전이금속 화합물, 및 이의 제조방법
JP6326202B2 (ja) * 2013-05-16 2018-05-16 三井化学株式会社 オレフィン重合用固体触媒成分およびそれを用いたオレフィン系重合体の製造方法
CN110650965B (zh) 2017-04-04 2022-10-04 Sabic环球技术有限责任公司 用于烯烃聚合的二烃基-甲硅烷基-桥连-1,3二取代-2-茚基茂金属络合物
CN110650978B (zh) * 2017-04-04 2022-09-23 Sabic环球技术有限责任公司 用于烯烃聚合的二甲基-甲硅烷基-桥连的-1-取代-2-茚基茂金属复合物
EP3743431B1 (en) 2018-01-24 2025-04-16 SABIC Global Technologies B.V. 1,2-phenylene bridged 1-indenyl-2-indenyl metallocene complexes for olefin polymerisation
EP4110834B1 (en) * 2020-02-24 2024-04-03 ExxonMobil Chemical Patents Inc. Ansa-bis(inden-2-yl) catalysts for producing vinylidene-terminated polyalphaolefins

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3840772A1 (de) 1988-12-03 1990-06-07 Hoechst Ag Verfahren zur herstellung einer heterogenen metallocenkatalysatorkomponente
ES2071888T3 (es) 1990-11-12 1995-07-01 Hoechst Ag Bisindenilmetalocenos sustituidos en posicion 2, procedimiento para su preparacion y su utilizacion como catalizadores en la polimerizacion de olefinas.
IL106042A (en) 1992-06-18 1999-05-09 Montell Technology Company Bv Catalysts for the polymerization of olefins obtained from organometallic cyclopentadienyl compounds alumino-organic compounds and water and process for the preparation of an ethylene homo- and copolymer
NL9201970A (nl) * 1992-11-11 1994-06-01 Dsm Nv Indenylverbindingen en katalysatorcomponenten voor de polymerisatie van olefinen.
IT1273661B (it) 1994-07-20 1997-07-09 Spherilene Srl Catalizzatori per la polimerizzazione delle olefine
IT1272924B (it) 1995-01-23 1997-07-01 Spherilene Srl Procedimento per la preparazione di composti ciclopentadienilici e composti cosi' ottenibili
DE19637669A1 (de) * 1996-09-16 1998-03-19 Hoechst Ag Verfahren zur Herstellung einer methylenverbrückten Biscyclopentadienylverbindung
DE69803652T2 (de) * 1997-03-29 2002-08-14 Basell Technology Co. B.V., Hoofddorp Verfahren zur herstellung von cyclopentadienylverbindungen
US6559252B1 (en) 1997-10-29 2003-05-06 Basell Technology Company Bv Catalysts and processes for the polymerization of olefins
CA2283880A1 (en) 1998-01-14 1999-07-22 Montell Technology Company B.V. Process for the preparation of metallocene compounds
EP1214364B1 (en) 1999-09-22 2003-07-16 Basell Polyolefine GmbH Catalyst system and process for the polymerization of olefins

Also Published As

Publication number Publication date
CA2350542A1 (en) 2000-05-25
JP2002530285A (ja) 2002-09-17
WO2000029415A1 (en) 2000-05-25
EP1131328A1 (en) 2001-09-12
ES2197714T3 (es) 2004-01-01
AU1382200A (en) 2000-06-05
US6872863B2 (en) 2005-03-29
EP1131328B1 (en) 2003-05-07
US20040147695A1 (en) 2004-07-29
BR9916740A (pt) 2001-08-21
AR021312A1 (es) 2002-07-17
US6693156B1 (en) 2004-02-17
DE69907721D1 (de) 2003-06-12
IL142979A0 (en) 2002-04-21
KR20010101034A (ko) 2001-11-14

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