CA2350542A1 - Methylene bridged metallocenes as olefin-polymerization-catalyst components - Google Patents

Methylene bridged metallocenes as olefin-polymerization-catalyst components Download PDF

Info

Publication number
CA2350542A1
CA2350542A1 CA002350542A CA2350542A CA2350542A1 CA 2350542 A1 CA2350542 A1 CA 2350542A1 CA 002350542 A CA002350542 A CA 002350542A CA 2350542 A CA2350542 A CA 2350542A CA 2350542 A1 CA2350542 A1 CA 2350542A1
Authority
CA
Canada
Prior art keywords
methylene
indenyl
bis
formula
polymerization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA002350542A
Other languages
English (en)
French (fr)
Inventor
Luigi Resconi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Basell Technology Co BV
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2350542A1 publication Critical patent/CA2350542A1/en
Abandoned legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/862Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
    • C07C2/867Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms the non-hydrocarbon is an aldehyde or a ketone
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C13/00Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
    • C07C13/28Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
    • C07C13/32Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings
    • C07C13/45Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with a bicyclo ring system containing nine carbon atoms
    • C07C13/465Indenes; Completely or partially hydrogenated indenes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00Metallocenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2602/00Systems containing two condensed rings
    • C07C2602/02Systems containing two condensed rings the rings having only two atoms in common
    • C07C2602/04One of the condensed rings being a six-membered aromatic ring
    • C07C2602/08One of the condensed rings being a six-membered aromatic ring the other ring being five-membered, e.g. indane
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CA002350542A 1998-11-18 1999-11-10 Methylene bridged metallocenes as olefin-polymerization-catalyst components Abandoned CA2350542A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP98203906 1998-11-18
EP98203906.7 1998-11-18
PCT/EP1999/008646 WO2000029415A1 (en) 1998-11-18 1999-11-10 Methylene bridged metallocenes as olefin-polymerization-catalyst components

Publications (1)

Publication Number Publication Date
CA2350542A1 true CA2350542A1 (en) 2000-05-25

Family

ID=8234358

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002350542A Abandoned CA2350542A1 (en) 1998-11-18 1999-11-10 Methylene bridged metallocenes as olefin-polymerization-catalyst components

Country Status (12)

Country Link
US (2) US6693156B1 (enExample)
EP (1) EP1131328B1 (enExample)
JP (1) JP2002530285A (enExample)
KR (1) KR20010101034A (enExample)
AR (1) AR021312A1 (enExample)
AU (1) AU1382200A (enExample)
BR (1) BR9916740A (enExample)
CA (1) CA2350542A1 (enExample)
DE (1) DE69907721T2 (enExample)
ES (1) ES2197714T3 (enExample)
IL (1) IL142979A0 (enExample)
WO (1) WO2000029415A1 (enExample)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6559251B1 (en) * 2002-08-02 2003-05-06 Equistar Chemicals, Lp Process for making low-density polyolefins
WO2010022878A1 (en) * 2008-08-25 2010-03-04 Basell Polyolefine Gmbh Preparation of ansa metallocene compounds
KR20140075589A (ko) 2012-12-11 2014-06-19 주식회사 엘지화학 신규한 리간드 화합물, 이의 제조방법, 전이금속 화합물, 및 이의 제조방법
WO2014092327A1 (ko) 2012-12-11 2014-06-19 주식회사 엘지화학 신규한 리간드 화합물, 이의 제조방법 및 상기 리간드 화합물을 포함하는 전이금속 화합물, 및 이의 제조방법
JP6326202B2 (ja) * 2013-05-16 2018-05-16 三井化学株式会社 オレフィン重合用固体触媒成分およびそれを用いたオレフィン系重合体の製造方法
CN110650965B (zh) 2017-04-04 2022-10-04 Sabic环球技术有限责任公司 用于烯烃聚合的二烃基-甲硅烷基-桥连-1,3二取代-2-茚基茂金属络合物
CN110650978B (zh) * 2017-04-04 2022-09-23 Sabic环球技术有限责任公司 用于烯烃聚合的二甲基-甲硅烷基-桥连的-1-取代-2-茚基茂金属复合物
EP3743431B1 (en) 2018-01-24 2025-04-16 SABIC Global Technologies B.V. 1,2-phenylene bridged 1-indenyl-2-indenyl metallocene complexes for olefin polymerisation
EP4110834B1 (en) * 2020-02-24 2024-04-03 ExxonMobil Chemical Patents Inc. Ansa-bis(inden-2-yl) catalysts for producing vinylidene-terminated polyalphaolefins

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3840772A1 (de) 1988-12-03 1990-06-07 Hoechst Ag Verfahren zur herstellung einer heterogenen metallocenkatalysatorkomponente
ES2071888T3 (es) 1990-11-12 1995-07-01 Hoechst Ag Bisindenilmetalocenos sustituidos en posicion 2, procedimiento para su preparacion y su utilizacion como catalizadores en la polimerizacion de olefinas.
IL106042A (en) 1992-06-18 1999-05-09 Montell Technology Company Bv Catalysts for the polymerization of olefins obtained from organometallic cyclopentadienyl compounds alumino-organic compounds and water and process for the preparation of an ethylene homo- and copolymer
NL9201970A (nl) * 1992-11-11 1994-06-01 Dsm Nv Indenylverbindingen en katalysatorcomponenten voor de polymerisatie van olefinen.
IT1273661B (it) 1994-07-20 1997-07-09 Spherilene Srl Catalizzatori per la polimerizzazione delle olefine
IT1272924B (it) 1995-01-23 1997-07-01 Spherilene Srl Procedimento per la preparazione di composti ciclopentadienilici e composti cosi' ottenibili
DE19637669A1 (de) * 1996-09-16 1998-03-19 Hoechst Ag Verfahren zur Herstellung einer methylenverbrückten Biscyclopentadienylverbindung
DE69803652T2 (de) * 1997-03-29 2002-08-14 Basell Technology Co. B.V., Hoofddorp Verfahren zur herstellung von cyclopentadienylverbindungen
US6559252B1 (en) 1997-10-29 2003-05-06 Basell Technology Company Bv Catalysts and processes for the polymerization of olefins
CA2283880A1 (en) 1998-01-14 1999-07-22 Montell Technology Company B.V. Process for the preparation of metallocene compounds
EP1214364B1 (en) 1999-09-22 2003-07-16 Basell Polyolefine GmbH Catalyst system and process for the polymerization of olefins

Also Published As

Publication number Publication date
JP2002530285A (ja) 2002-09-17
WO2000029415A1 (en) 2000-05-25
EP1131328A1 (en) 2001-09-12
ES2197714T3 (es) 2004-01-01
AU1382200A (en) 2000-06-05
US6872863B2 (en) 2005-03-29
EP1131328B1 (en) 2003-05-07
US20040147695A1 (en) 2004-07-29
DE69907721T2 (de) 2004-02-26
BR9916740A (pt) 2001-08-21
AR021312A1 (es) 2002-07-17
US6693156B1 (en) 2004-02-17
DE69907721D1 (de) 2003-06-12
IL142979A0 (en) 2002-04-21
KR20010101034A (ko) 2001-11-14

Similar Documents

Publication Publication Date Title
EP0914323B1 (en) Metallocenes and catalysts for polymerization of olefins
RU2245341C2 (ru) Металлоценовые соединения, способ их получения, катализатор полимеризации олефинов, способ полимеризации
EP0991677B1 (en) Process for the preparation of copolymers of ethylene with alpha-olefins
EP3106475B1 (en) Method for producing ethylene/alpha-olefin copolymer
US7405261B2 (en) Organometallic transition metal compound, biscyclopentadienyl ligand system, catalyst system and process for preparing polyolefins
EP1047702B1 (en) Bis(tetrahyydro-indenyl) metallocenes as olefin-polymerization- catalyst
EP1049704B1 (en) Bridged metallocenes, preparation, use in catalytic systems
EP2045254A1 (en) Rare earth metal complex, catalyst for polymerization and process for producing polymer
EP1131328B1 (en) Methylene bridged metallocenes as olefin-polymerization-catalyst components
KR20170074678A (ko) 신규한 전이금속 화합물
KR20000016125A (ko) 메탈로센 및 올레핀 중합용 촉매_
MXPA00007023A (en) Bis(tetrahydro-indenyl) metallocenes as olefin-polymerisation-catalyst
MXPA98010099A (en) Metallocenes and catalysts for polymerization of olefins

Legal Events

Date Code Title Description
FZDE Discontinued
FZDE Discontinued

Effective date: 20021112