AR021312A1 - Metalocenos de puente de metileno, procedimiento para su preparacion y su uso como componentes cataliticos en la polimerizacion de olefinas. - Google Patents

Metalocenos de puente de metileno, procedimiento para su preparacion y su uso como componentes cataliticos en la polimerizacion de olefinas.

Info

Publication number
AR021312A1
AR021312A1 ARP990105862A ARP990105862A AR021312A1 AR 021312 A1 AR021312 A1 AR 021312A1 AR P990105862 A ARP990105862 A AR P990105862A AR P990105862 A ARP990105862 A AR P990105862A AR 021312 A1 AR021312 A1 AR 021312A1
Authority
AR
Argentina
Prior art keywords
methylene
preparation
procedure
catalytic components
olefine polymerization
Prior art date
Application number
ARP990105862A
Other languages
English (en)
Original Assignee
Montell Technology Company Bv
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Montell Technology Company Bv filed Critical Montell Technology Company Bv
Publication of AR021312A1 publication Critical patent/AR021312A1/es

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/862Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
    • C07C2/867Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms the non-hydrocarbon is an aldehyde or a ketone
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C13/00Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
    • C07C13/28Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
    • C07C13/32Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings
    • C07C13/45Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with a bicyclo ring system containing nine carbon atoms
    • C07C13/465Indenes; Completely or partially hydrogenated indenes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00Metallocenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2602/00Systems containing two condensed rings
    • C07C2602/02Systems containing two condensed rings the rings having only two atoms in common
    • C07C2602/04One of the condensed rings being a six-membered aromatic ring
    • C07C2602/08One of the condensed rings being a six-membered aromatic ring the other ring being five-membered, e.g. indane
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Se trata de una nueva clase de metalocenos de puente de metileno de formula 1 donde M es un metal de transicion del grupo 3, 4, 5, 6, lantánido o actínido;X es un ligando sigma monoanionico; R1 puede ser radicales de alquilo, cicloalquilo, arilo, alquilarilo o arilalquilo; R2 puede ser radical de halogeno,alquilo, cicloalquilo, arilo, alquilarilo o arilalquilo; p es de 0 a 3; m es de 0 a 2; y n es de 0 a 4. Además se describen los ligandos correspondientes, unnuevo procedimiento para su preparacion y sistemas de catalizadores que contienen dichos metalocenos de puente de metileno.
ARP990105862A 1998-11-18 1999-11-18 Metalocenos de puente de metileno, procedimiento para su preparacion y su uso como componentes cataliticos en la polimerizacion de olefinas. AR021312A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP98203906 1998-11-18

Publications (1)

Publication Number Publication Date
AR021312A1 true AR021312A1 (es) 2002-07-17

Family

ID=8234358

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP990105862A AR021312A1 (es) 1998-11-18 1999-11-18 Metalocenos de puente de metileno, procedimiento para su preparacion y su uso como componentes cataliticos en la polimerizacion de olefinas.

Country Status (12)

Country Link
US (2) US6693156B1 (es)
EP (1) EP1131328B1 (es)
JP (1) JP2002530285A (es)
KR (1) KR20010101034A (es)
AR (1) AR021312A1 (es)
AU (1) AU1382200A (es)
BR (1) BR9916740A (es)
CA (1) CA2350542A1 (es)
DE (1) DE69907721T2 (es)
ES (1) ES2197714T3 (es)
IL (1) IL142979A0 (es)
WO (1) WO2000029415A1 (es)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6559251B1 (en) * 2002-08-02 2003-05-06 Equistar Chemicals, Lp Process for making low-density polyolefins
EP2328906A1 (en) * 2008-08-25 2011-06-08 Basell Polyolefine GmbH Preparation of ansa metallocene compounds
US9260457B2 (en) 2012-12-11 2016-02-16 Lg Chem, Ltd. Ligand compound, a preparation method thereof, a transition metal compound including the ligand compound, and a preparation method thereof
KR20140075589A (ko) 2012-12-11 2014-06-19 주식회사 엘지화학 신규한 리간드 화합물, 이의 제조방법, 전이금속 화합물, 및 이의 제조방법
JP6326202B2 (ja) * 2013-05-16 2018-05-16 三井化学株式会社 オレフィン重合用固体触媒成分およびそれを用いたオレフィン系重合体の製造方法
CN110650965B (zh) 2017-04-04 2022-10-04 Sabic环球技术有限责任公司 用于烯烃聚合的二烃基-甲硅烷基-桥连-1,3二取代-2-茚基茂金属络合物
WO2018185173A1 (en) * 2017-04-04 2018-10-11 Sabic Global Technologies B.V. Dimethyl-silyl-bridged-1-substituted-2-indenyl metallocene complexes for olefin polymerization
US20210079032A1 (en) 2018-01-24 2021-03-18 Sabic Global Technologies B.V. 1,2-phenylene bridged 1-indenyl-2-indenyl metallocene complexes for olefin polymerisation
EP4110834B1 (en) 2020-02-24 2024-04-03 ExxonMobil Chemical Patents Inc. Ansa-bis(inden-2-yl) catalysts for producing vinylidene-terminated polyalphaolefins

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3840772A1 (de) 1988-12-03 1990-06-07 Hoechst Ag Verfahren zur herstellung einer heterogenen metallocenkatalysatorkomponente
ES2071888T3 (es) 1990-11-12 1995-07-01 Hoechst Ag Bisindenilmetalocenos sustituidos en posicion 2, procedimiento para su preparacion y su utilizacion como catalizadores en la polimerizacion de olefinas.
EP0575875B1 (en) 1992-06-18 2000-08-09 Montell Technology Company bv Catalysts for the polymerization of olefins
NL9201970A (nl) 1992-11-11 1994-06-01 Dsm Nv Indenylverbindingen en katalysatorcomponenten voor de polymerisatie van olefinen.
IT1273661B (it) 1994-07-20 1997-07-09 Spherilene Srl Catalizzatori per la polimerizzazione delle olefine
IT1272924B (it) 1995-01-23 1997-07-01 Spherilene Srl Procedimento per la preparazione di composti ciclopentadienilici e composti cosi' ottenibili
DE19637669A1 (de) 1996-09-16 1998-03-19 Hoechst Ag Verfahren zur Herstellung einer methylenverbrückten Biscyclopentadienylverbindung
WO1998043931A1 (en) 1997-03-29 1998-10-08 Montell Technology Company B.V. Process for preparing cyclopentadienyl compounds
US6559252B1 (en) 1997-10-29 2003-05-06 Basell Technology Company Bv Catalysts and processes for the polymerization of olefins
DE69903388T2 (de) 1998-01-14 2003-06-18 Basell Polyolefine Gmbh Verfahren zur herstellung von metallocenen
WO2001021674A1 (en) 1999-09-22 2001-03-29 Basell Technology Company B.V. Catalyst system and process for the polymerization of olefins

Also Published As

Publication number Publication date
US6693156B1 (en) 2004-02-17
WO2000029415A1 (en) 2000-05-25
EP1131328A1 (en) 2001-09-12
BR9916740A (pt) 2001-08-21
US6872863B2 (en) 2005-03-29
DE69907721T2 (de) 2004-02-26
AU1382200A (en) 2000-06-05
US20040147695A1 (en) 2004-07-29
EP1131328B1 (en) 2003-05-07
JP2002530285A (ja) 2002-09-17
CA2350542A1 (en) 2000-05-25
KR20010101034A (ko) 2001-11-14
DE69907721D1 (de) 2003-06-12
ES2197714T3 (es) 2004-01-01
IL142979A0 (en) 2002-04-21

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