AR021312A1 - Metalocenos de puente de metileno, procedimiento para su preparacion y su uso como componentes cataliticos en la polimerizacion de olefinas. - Google Patents
Metalocenos de puente de metileno, procedimiento para su preparacion y su uso como componentes cataliticos en la polimerizacion de olefinas.Info
- Publication number
- AR021312A1 AR021312A1 ARP990105862A ARP990105862A AR021312A1 AR 021312 A1 AR021312 A1 AR 021312A1 AR P990105862 A ARP990105862 A AR P990105862A AR P990105862 A ARP990105862 A AR P990105862A AR 021312 A1 AR021312 A1 AR 021312A1
- Authority
- AR
- Argentina
- Prior art keywords
- methylene
- preparation
- procedure
- catalytic components
- olefine polymerization
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
- C07C2/862—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
- C07C2/867—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms the non-hydrocarbon is an aldehyde or a ketone
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C13/00—Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
- C07C13/28—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
- C07C13/32—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings
- C07C13/45—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with a bicyclo ring system containing nine carbon atoms
- C07C13/465—Indenes; Completely or partially hydrogenated indenes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2602/00—Systems containing two condensed rings
- C07C2602/02—Systems containing two condensed rings the rings having only two atoms in common
- C07C2602/04—One of the condensed rings being a six-membered aromatic ring
- C07C2602/08—One of the condensed rings being a six-membered aromatic ring the other ring being five-membered, e.g. indane
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Se trata de una nueva clase de metalocenos de puente de metileno de formula 1 donde M es un metal de transicion del grupo 3, 4, 5, 6, lantánido o actínido;X es un ligando sigma monoanionico; R1 puede ser radicales de alquilo, cicloalquilo, arilo, alquilarilo o arilalquilo; R2 puede ser radical de halogeno,alquilo, cicloalquilo, arilo, alquilarilo o arilalquilo; p es de 0 a 3; m es de 0 a 2; y n es de 0 a 4. Además se describen los ligandos correspondientes, unnuevo procedimiento para su preparacion y sistemas de catalizadores que contienen dichos metalocenos de puente de metileno.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP98203906 | 1998-11-18 |
Publications (1)
Publication Number | Publication Date |
---|---|
AR021312A1 true AR021312A1 (es) | 2002-07-17 |
Family
ID=8234358
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ARP990105862A AR021312A1 (es) | 1998-11-18 | 1999-11-18 | Metalocenos de puente de metileno, procedimiento para su preparacion y su uso como componentes cataliticos en la polimerizacion de olefinas. |
Country Status (12)
Country | Link |
---|---|
US (2) | US6693156B1 (es) |
EP (1) | EP1131328B1 (es) |
JP (1) | JP2002530285A (es) |
KR (1) | KR20010101034A (es) |
AR (1) | AR021312A1 (es) |
AU (1) | AU1382200A (es) |
BR (1) | BR9916740A (es) |
CA (1) | CA2350542A1 (es) |
DE (1) | DE69907721T2 (es) |
ES (1) | ES2197714T3 (es) |
IL (1) | IL142979A0 (es) |
WO (1) | WO2000029415A1 (es) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6559251B1 (en) * | 2002-08-02 | 2003-05-06 | Equistar Chemicals, Lp | Process for making low-density polyolefins |
EP2328906A1 (en) * | 2008-08-25 | 2011-06-08 | Basell Polyolefine GmbH | Preparation of ansa metallocene compounds |
US9260457B2 (en) | 2012-12-11 | 2016-02-16 | Lg Chem, Ltd. | Ligand compound, a preparation method thereof, a transition metal compound including the ligand compound, and a preparation method thereof |
KR20140075589A (ko) | 2012-12-11 | 2014-06-19 | 주식회사 엘지화학 | 신규한 리간드 화합물, 이의 제조방법, 전이금속 화합물, 및 이의 제조방법 |
JP6326202B2 (ja) * | 2013-05-16 | 2018-05-16 | 三井化学株式会社 | オレフィン重合用固体触媒成分およびそれを用いたオレフィン系重合体の製造方法 |
CN110650965B (zh) | 2017-04-04 | 2022-10-04 | Sabic环球技术有限责任公司 | 用于烯烃聚合的二烃基-甲硅烷基-桥连-1,3二取代-2-茚基茂金属络合物 |
WO2018185173A1 (en) * | 2017-04-04 | 2018-10-11 | Sabic Global Technologies B.V. | Dimethyl-silyl-bridged-1-substituted-2-indenyl metallocene complexes for olefin polymerization |
US20210079032A1 (en) | 2018-01-24 | 2021-03-18 | Sabic Global Technologies B.V. | 1,2-phenylene bridged 1-indenyl-2-indenyl metallocene complexes for olefin polymerisation |
EP4110834B1 (en) | 2020-02-24 | 2024-04-03 | ExxonMobil Chemical Patents Inc. | Ansa-bis(inden-2-yl) catalysts for producing vinylidene-terminated polyalphaolefins |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3840772A1 (de) | 1988-12-03 | 1990-06-07 | Hoechst Ag | Verfahren zur herstellung einer heterogenen metallocenkatalysatorkomponente |
ES2071888T3 (es) | 1990-11-12 | 1995-07-01 | Hoechst Ag | Bisindenilmetalocenos sustituidos en posicion 2, procedimiento para su preparacion y su utilizacion como catalizadores en la polimerizacion de olefinas. |
EP0575875B1 (en) | 1992-06-18 | 2000-08-09 | Montell Technology Company bv | Catalysts for the polymerization of olefins |
NL9201970A (nl) | 1992-11-11 | 1994-06-01 | Dsm Nv | Indenylverbindingen en katalysatorcomponenten voor de polymerisatie van olefinen. |
IT1273661B (it) | 1994-07-20 | 1997-07-09 | Spherilene Srl | Catalizzatori per la polimerizzazione delle olefine |
IT1272924B (it) | 1995-01-23 | 1997-07-01 | Spherilene Srl | Procedimento per la preparazione di composti ciclopentadienilici e composti cosi' ottenibili |
DE19637669A1 (de) | 1996-09-16 | 1998-03-19 | Hoechst Ag | Verfahren zur Herstellung einer methylenverbrückten Biscyclopentadienylverbindung |
WO1998043931A1 (en) | 1997-03-29 | 1998-10-08 | Montell Technology Company B.V. | Process for preparing cyclopentadienyl compounds |
US6559252B1 (en) | 1997-10-29 | 2003-05-06 | Basell Technology Company Bv | Catalysts and processes for the polymerization of olefins |
DE69903388T2 (de) | 1998-01-14 | 2003-06-18 | Basell Polyolefine Gmbh | Verfahren zur herstellung von metallocenen |
WO2001021674A1 (en) | 1999-09-22 | 2001-03-29 | Basell Technology Company B.V. | Catalyst system and process for the polymerization of olefins |
-
1999
- 1999-11-10 AU AU13822/00A patent/AU1382200A/en not_active Abandoned
- 1999-11-10 EP EP99972216A patent/EP1131328B1/en not_active Expired - Lifetime
- 1999-11-10 JP JP2000582402A patent/JP2002530285A/ja active Pending
- 1999-11-10 DE DE69907721T patent/DE69907721T2/de not_active Expired - Fee Related
- 1999-11-10 KR KR1020017006322A patent/KR20010101034A/ko not_active Application Discontinuation
- 1999-11-10 US US09/831,960 patent/US6693156B1/en not_active Expired - Fee Related
- 1999-11-10 BR BR9916740-9A patent/BR9916740A/pt not_active Application Discontinuation
- 1999-11-10 CA CA002350542A patent/CA2350542A1/en not_active Abandoned
- 1999-11-10 ES ES99972216T patent/ES2197714T3/es not_active Expired - Lifetime
- 1999-11-10 WO PCT/EP1999/008646 patent/WO2000029415A1/en not_active Application Discontinuation
- 1999-11-10 IL IL14297999A patent/IL142979A0/xx unknown
- 1999-11-18 AR ARP990105862A patent/AR021312A1/es unknown
-
2003
- 2003-12-16 US US10/737,097 patent/US6872863B2/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
US6693156B1 (en) | 2004-02-17 |
WO2000029415A1 (en) | 2000-05-25 |
EP1131328A1 (en) | 2001-09-12 |
BR9916740A (pt) | 2001-08-21 |
US6872863B2 (en) | 2005-03-29 |
DE69907721T2 (de) | 2004-02-26 |
AU1382200A (en) | 2000-06-05 |
US20040147695A1 (en) | 2004-07-29 |
EP1131328B1 (en) | 2003-05-07 |
JP2002530285A (ja) | 2002-09-17 |
CA2350542A1 (en) | 2000-05-25 |
KR20010101034A (ko) | 2001-11-14 |
DE69907721D1 (de) | 2003-06-12 |
ES2197714T3 (es) | 2004-01-01 |
IL142979A0 (en) | 2002-04-21 |
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