DE69834092T2 - Polyolefinmaterialien mit verbesserter Oberflächenhaltbarkeit und Verfahren zu ihrer Herstellung durch Strahlung - Google Patents

Polyolefinmaterialien mit verbesserter Oberflächenhaltbarkeit und Verfahren zu ihrer Herstellung durch Strahlung Download PDF

Info

Publication number
DE69834092T2
DE69834092T2 DE69834092T DE69834092T DE69834092T2 DE 69834092 T2 DE69834092 T2 DE 69834092T2 DE 69834092 T DE69834092 T DE 69834092T DE 69834092 T DE69834092 T DE 69834092T DE 69834092 T2 DE69834092 T2 DE 69834092T2
Authority
DE
Germany
Prior art keywords
tert
butyl
bis
radiation
composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69834092T
Other languages
German (de)
English (en)
Other versions
DE69834092D1 (de
Inventor
Edmund Kwok-Leung Lau
Satchit Srinivasan
Peter James Perron
Peter Shelsey Solera
Anthony David Debellis
Chia-Hu Chang
Gerald Anthony Capocci
Joseph Steven Puglisi
Douglas Wayne Horsey
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Schweiz AG
LyondellBasell Advanced Polyolefins USA Inc
Original Assignee
Ciba Spezialitaetenchemie Holding AG
Ciba SC Holding AG
Solvay Engineered Polymers Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Spezialitaetenchemie Holding AG, Ciba SC Holding AG, Solvay Engineered Polymers Inc filed Critical Ciba Spezialitaetenchemie Holding AG
Application granted granted Critical
Publication of DE69834092D1 publication Critical patent/DE69834092D1/de
Publication of DE69834092T2 publication Critical patent/DE69834092T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/28—Treatment by wave energy or particle radiation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
    • C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16—Ethene-propene or ethene-propene-diene copolymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L21/00—Compositions of unspecified rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2312/00—Crosslinking
    • C08L2312/06—Crosslinking by radiation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C08L2666/04—Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polymerisation Methods In General (AREA)
  • Treatments Of Macromolecular Shaped Articles (AREA)
DE69834092T 1997-12-02 1998-11-24 Polyolefinmaterialien mit verbesserter Oberflächenhaltbarkeit und Verfahren zu ihrer Herstellung durch Strahlung Expired - Lifetime DE69834092T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US98250897A 1997-12-02 1997-12-02
US982508 1997-12-02

Publications (2)

Publication Number Publication Date
DE69834092D1 DE69834092D1 (de) 2006-05-18
DE69834092T2 true DE69834092T2 (de) 2006-09-21

Family

ID=25529236

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69834092T Expired - Lifetime DE69834092T2 (de) 1997-12-02 1998-11-24 Polyolefinmaterialien mit verbesserter Oberflächenhaltbarkeit und Verfahren zu ihrer Herstellung durch Strahlung

Country Status (7)

Country Link
US (2) US6488882B2 (enExample)
EP (1) EP0921152B1 (enExample)
JP (1) JP4340987B2 (enExample)
KR (1) KR100545752B1 (enExample)
CA (1) CA2254663C (enExample)
DE (1) DE69834092T2 (enExample)
ES (1) ES2260825T3 (enExample)

Families Citing this family (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0921152B1 (en) 1997-12-02 2006-04-05 Ciba SC Holding AG Polyolefin materials having enhanced surface durability and methods of making the same by exposure to radiation
US6541568B1 (en) 2000-06-01 2003-04-01 Solvay Engineered Polymers Polyolefin materials having enhanced surface durability
JP2003080583A (ja) * 2000-08-31 2003-03-19 Tokai Rubber Ind Ltd 燃料ホースの製法およびそれに用いる紫外線架橋組成物
EP1340788A3 (de) * 2002-02-22 2004-03-17 Nexans Verfahren zur Herstellung eines Compounds auf Basis eines thermoplastischen Kunststoffs
US7198576B2 (en) * 2003-06-17 2007-04-03 Acushnet Company Golf ball comprising UV-cured non-surface layer
US7323256B2 (en) * 2003-11-13 2008-01-29 Cree, Inc. Large area, uniformly low dislocation density GaN substrate and process for making the same
US7082050B2 (en) 2003-11-30 2006-07-25 Union Semiconductor Technology Corporation Method to equalize word current circuitry
BRPI0612023A2 (pt) * 2005-06-07 2010-10-13 Ciba Sc Holding Ag poliolefinas resistentes a arranhões
US20070056845A1 (en) * 2005-09-13 2007-03-15 Applied Materials, Inc. Multiple zone sputtering target created through conductive and insulation bonding
US7744803B2 (en) * 2006-08-02 2010-06-29 Shawcor Ltd. Photo-crosslinkable polyolefin compositions
KR101274622B1 (ko) * 2006-09-26 2013-06-14 삼성디스플레이 주식회사 밀봉제 및 이를 이용한 액정 표시 장치
US20080114091A1 (en) * 2006-11-15 2008-05-15 Sealed Air Corporation (Us) Apparatus and Method for Preparing a UV-Induced Crosslinked Foam
US7956520B2 (en) * 2006-11-24 2011-06-07 North Carolina State University Electroactive nanostructured polymers as tunable organic actuators
ATE500280T1 (de) † 2007-01-09 2011-03-15 Borealis Tech Oy Vernetzungsmittel
US20080289575A1 (en) * 2007-05-24 2008-11-27 Burrows Brian H Methods and apparatus for depositing a group iii-v film using a hydride vapor phase epitaxy process
EP2000200B1 (de) * 2007-05-30 2010-08-04 iie Gesellschaft für innovative Industrieelektronik mbH Vorrichtung zur Polymerisation
ATE479722T1 (de) 2007-12-21 2010-09-15 Borealis Tech Oy Polyolefinzusammensetzung für mitte-/hoch- /höchstspannungskabel mit verbesserter elektrischer durchbruchfestigkeit
CN101932623A (zh) * 2008-01-17 2010-12-29 巴斯夫欧洲公司 改性的烯烃聚合物
US8765832B2 (en) 2011-10-14 2014-07-01 Exxonmobil Chemical Patents Inc. Polyolefin-based crosslinked compositions and methods of making them
US7867433B2 (en) 2008-05-30 2011-01-11 Exxonmobil Chemical Patents Inc. Polyolefin-based crosslinked articles
ATE531756T1 (de) * 2008-09-09 2011-11-15 Borealis Ag Polyolefin-zusammensetzung für mittel-/hoch- /extrahoch-spannungskabel mit benzophenon- spannungsstabilisator
US20100264566A1 (en) * 2009-03-17 2010-10-21 Suss Microtec Inc Rapid fabrication of a microelectronic temporary support for inorganic substrates
EP2483351B1 (en) * 2009-10-02 2017-11-15 ExxonMobil Chemical Patents Inc. Crosslinked polyolefin polymer blends
RU2436814C2 (ru) * 2009-10-29 2011-12-20 Руслан Гиглович Дзадзамия Способ изготовления термоусаживающихся материалов
US9303138B2 (en) * 2011-09-21 2016-04-05 Exxonmobil Chemical Patents Inc. Elastomeric composition for pharmaceutical articles
EP2816381A1 (en) * 2012-02-16 2014-12-24 Nitto Denko Corporation Method for manufacturing infrared-reflective substrate
CN107513196B (zh) * 2016-06-17 2020-04-14 常州百思通复合材料有限公司 一种使用微波高效加热高分子聚合物的方法
GB2565587A (en) 2017-08-18 2019-02-20 Addivant Switzerland Gmbh Insulation composition
CN110563975A (zh) * 2019-09-16 2019-12-13 深圳市刚塑科技有限公司 一种聚合物材料表面用硬化防划伤处理方法

Family Cites Families (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4000216A (en) 1970-09-22 1976-12-28 Rohm And Haas Company Surface altering agent for thermoplastic polymers
US4153526A (en) 1976-05-03 1979-05-08 Ppg Industries, Inc. Laminated windshield with improved innerlayer
US4039720A (en) 1976-05-03 1977-08-02 Ppg Industries, Inc. Laminated windshield with improved innerlayer
US4227979A (en) 1977-10-05 1980-10-14 Ppg Industries, Inc. Radiation-curable coating compositions containing amide acrylate compounds
US4255303A (en) 1979-04-25 1981-03-10 Union Carbide Corporation Polyethylene composition containing talc filler for electrical applications
US4303697A (en) 1979-05-17 1981-12-01 E. I. Du Pont De Nemours And Company Process for improving the adhesion of paint to polyolefin surfaces
US4371566A (en) 1980-09-10 1983-02-01 Panelgraphic Corporation Abrasion resistant coating composition
JPS5765710A (en) 1980-10-09 1982-04-21 Bridgestone Corp Ultraviolet-or radiation-crosslinkable rubber plastic composition and waterproof sheet containing the same
US4478876A (en) 1980-12-18 1984-10-23 General Electric Company Process of coating a substrate with an abrasion resistant ultraviolet curable composition
JPS5898704A (ja) 1981-12-08 1983-06-11 Nippon Telegr & Teleph Corp <Ntt> 光フアイバ心線
JPS59187656A (ja) 1983-04-01 1984-10-24 松下電工株式会社 網
DE3616176A1 (de) 1986-05-14 1987-11-19 Roehm Gmbh Verfahren zur herstellung einer kratzfesten und witterungsbestaendigen beschichtung auf einem formkoerper
US4945005A (en) 1987-03-31 1990-07-31 Dexter Corporation Thermoplastic compositions and articles made therefrom
US4997720A (en) 1987-03-31 1991-03-05 Dexter Corporation Thermoplastic compositions and articles made therefrom
DE3736280A1 (de) 1987-10-27 1989-05-11 Roehm Gmbh Verfahren zur herstellung kratzfest beschichteter extrudierter kunststoffbahnen
US4902578A (en) * 1987-12-31 1990-02-20 General Electric Company Radiation-curable coating for thermoplastic substrates
JP2880725B2 (ja) 1988-06-14 1999-04-12 三井化学株式会社 架橋ポリオレフィンの製造方法
US5006436A (en) 1988-09-20 1991-04-09 Atochem North America, Inc. UV curable compositions for making tentable solder mask coating
EP0563251A1 (en) 1990-12-20 1993-10-06 Exxon Chemical Patents Inc. Uv/eb curable butyl copolymers for lithographic and corrosion-resistant coating applications
US5382604A (en) 1991-10-07 1995-01-17 Shell Oil Company Crosslinked epoxy functionalized polydiene block polymers and adhesives
US5202361A (en) * 1991-12-23 1993-04-13 Minnesota Mining And Manufacturing Company Pressure-sensitive adhesive
US5316791A (en) 1993-01-21 1994-05-31 Sdc Coatings Inc. Process for improving impact resistance of coated plastic substrates
EP0683727B1 (en) 1993-02-10 2001-05-02 Solvay Engineered Polymers Thermoplastic olefinic compositions
US5407970A (en) 1993-04-13 1995-04-18 Minnesota Mining And Manufacturing Company Radiation-curable poly(α-olefin) adhesives containing pendant olefinic funtionality
US5618586A (en) 1994-03-29 1997-04-08 Ppg Industries, Inc. N-alkoxymethyl (meth)acrylamide functional polymers and their use in self-crosslinkable coating compositions
DE4413436A1 (de) 1994-04-18 1995-10-19 Basf Lacke & Farben Verfahren zur Lackierung von Gegenständen unter Verwendung strahlungshärtbarer Pulverlacke
TW424172B (en) * 1995-04-19 2001-03-01 Hitachi Chemical Co Ltd Photosensitive resin composition and photosensitive element using the same
US6339112B1 (en) * 1997-11-13 2002-01-15 H.B. Fuller Licensing & Financing Inc. Radiation curable compositions comprising metallocene polyolefins
EP0921152B1 (en) 1997-12-02 2006-04-05 Ciba SC Holding AG Polyolefin materials having enhanced surface durability and methods of making the same by exposure to radiation

Also Published As

Publication number Publication date
US20010020047A1 (en) 2001-09-06
US6790874B2 (en) 2004-09-14
US20030013780A1 (en) 2003-01-16
DE69834092D1 (de) 2006-05-18
EP0921152A3 (en) 1999-08-25
KR100545752B1 (ko) 2006-06-29
CA2254663C (en) 2009-01-27
JPH11236467A (ja) 1999-08-31
EP0921152B1 (en) 2006-04-05
ES2260825T3 (es) 2006-11-01
EP0921152A2 (en) 1999-06-09
KR19990062664A (ko) 1999-07-26
US6488882B2 (en) 2002-12-03
JP4340987B2 (ja) 2009-10-07
CA2254663A1 (en) 1999-06-02

Similar Documents

Publication Publication Date Title
DE69834092T2 (de) Polyolefinmaterialien mit verbesserter Oberflächenhaltbarkeit und Verfahren zu ihrer Herstellung durch Strahlung
DE60309665T2 (de) Stabilisierung von polyolefinen, die in permanentem kontakt mit chloriertem wasser stehen
DE10116305B4 (de) Synergistische Gemische von UV-Absorptionsmitteln in Polyolefinen
DE10009416B4 (de) Verwendung einer Stabilisatorkombination für das Rotationsformverfahren und Verfahren zur Herstellung von Polyolefinhohlartikeln unter Zugabe der Stabilisatorkombination
EP2225318B1 (en) Flame retardant compositions comprising sterically hindered amines
EP1979406B1 (en) Stabilizer composition for polymers
JP5930318B2 (ja) ポリマー溶融物の流動特性を向上するための方法
DE60306371T2 (de) Amorphe feste modifikation von bis(2,4-dicumylphenyl) pentaerythritdiphosphit
JP5102624B2 (ja) 改善された変色耐性を有する抗菌性ポリマー組成物
RU2386652C2 (ru) Полиолефины, стойкие к царапанию
EP1892261B1 (de) Verwendung UV-Absorber enthaltender Polymerpulver zur Stabilisierung von Polymeren gegen die Einwirkung von UV-Strahlung
DE60203010T2 (de) Hochmolekulare hydroxyphenylbenzotriazolverbindungen als uv absorber für dünne filmanwendungen
DE69705426T2 (de) Lichtstabilisierte, flammfeste styrolhomopolymere und copolymere
EP1976925B1 (de) Stabilisatormischung
DE10051198A1 (de) Stabilisatoren für Emulsions-Rohkautschuke, synthetischen Latex und Naturkautschuklatex
US20200216589A1 (en) Additive mixture
JP2005538200A (ja) 永続的な防霧性、防靄性及び防曇性を有するフィルム組成物
JP4374563B2 (ja) 永続的表面改質剤
EP3259313B1 (en) Light stabilized polyolefin films, tapes and monofilaments
DE60027917T2 (de) Zusammensetzung und verfahren zur farbverbesserung von niroxyl enthaltenden polymeren
EP4402205A1 (en) Stabilizer formulation
JP2025519115A (ja) ヒドロキシフェニルトリアジンとｕｖ吸収剤の組合せを含むポリカーボネート組成物
DE10308197A1 (de) Verfahren zur Herstellung einer nicht-klebrigen Präparation, enthaltend gehinderte Amine auf Basis von Maleinsäureimid/α-Olefin-Copolymeren

Legal Events

Date Code Title Description
8328 Change in the person/name/address of the agent

Representative=s name: PFENNING MEINIG & PARTNER GBR, 80339 MUENCHEN

8364 No opposition during term of opposition
8327 Change in the person/name/address of the patent owner

Owner name: CIBA HOLDING INC., BASEL, CH

Owner name: SOLVAY ENGINEERED POLYMERS INC., GRAND PRAIRIE, US

8328 Change in the person/name/address of the agent

Representative=s name: MAIWALD PATENTANWALTSGESELLSCHAFT MBH, 80335 MUENC