DE69818137T2 - Thermoplastische Elastomerzusammensetzung mit einem guten Gleichgewicht der Haftung und der Haltbarkeit - Google Patents
Thermoplastische Elastomerzusammensetzung mit einem guten Gleichgewicht der Haftung und der Haltbarkeit Download PDFInfo
- Publication number
- DE69818137T2 DE69818137T2 DE69818137T DE69818137T DE69818137T2 DE 69818137 T2 DE69818137 T2 DE 69818137T2 DE 69818137 T DE69818137 T DE 69818137T DE 69818137 T DE69818137 T DE 69818137T DE 69818137 T2 DE69818137 T2 DE 69818137T2
- Authority
- DE
- Germany
- Prior art keywords
- ethylene
- olefin
- propylene
- copolymer
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000203 mixture Substances 0.000 title claims description 51
- 229920002725 thermoplastic elastomer Polymers 0.000 title description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 146
- 239000005977 Ethylene Substances 0.000 claims description 100
- 239000004711 α-olefin Substances 0.000 claims description 100
- 229920001577 copolymer Polymers 0.000 claims description 75
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 57
- 229920002397 thermoplastic olefin Polymers 0.000 claims description 48
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 39
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 30
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 28
- -1 propylene, ethylene Chemical group 0.000 claims description 23
- 239000008096 xylene Substances 0.000 claims description 21
- 239000002245 particle Substances 0.000 claims description 19
- 239000002861 polymer material Substances 0.000 claims description 19
- 229920001155 polypropylene Polymers 0.000 claims description 15
- 235000013873 oxidized polyethylene wax Nutrition 0.000 claims description 14
- 229920000573 polyethylene Polymers 0.000 claims description 14
- 150000001993 dienes Chemical class 0.000 claims description 13
- 238000002347 injection Methods 0.000 claims description 12
- 239000007924 injection Substances 0.000 claims description 12
- 239000004209 oxidized polyethylene wax Substances 0.000 claims description 11
- 229920001384 propylene homopolymer Polymers 0.000 claims description 11
- 150000001336 alkenes Chemical class 0.000 claims description 10
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 claims description 10
- 239000000155 melt Substances 0.000 claims description 9
- 238000000113 differential scanning calorimetry Methods 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 6
- 229920001038 ethylene copolymer Polymers 0.000 claims description 6
- 229920001519 homopolymer Polymers 0.000 claims description 5
- 239000011159 matrix material Substances 0.000 claims description 5
- 238000002844 melting Methods 0.000 claims description 5
- 230000008018 melting Effects 0.000 claims description 5
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 229920000098 polyolefin Polymers 0.000 claims description 4
- 229920001897 terpolymer Polymers 0.000 claims description 4
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 3
- 229920001169 thermoplastic Polymers 0.000 claims description 3
- 239000004416 thermosoftening plastic Substances 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims 5
- 238000000465 moulding Methods 0.000 claims 3
- 229920005604 random copolymer Polymers 0.000 claims 2
- 239000012071 phase Substances 0.000 description 19
- 239000000463 material Substances 0.000 description 15
- 230000000052 comparative effect Effects 0.000 description 12
- 239000003973 paint Substances 0.000 description 8
- 238000006116 polymerization reaction Methods 0.000 description 8
- 229920001971 elastomer Polymers 0.000 description 7
- 238000002156 mixing Methods 0.000 description 7
- 229920000642 polymer Polymers 0.000 description 7
- 239000001993 wax Substances 0.000 description 7
- 238000000576 coating method Methods 0.000 description 6
- 239000000806 elastomer Substances 0.000 description 5
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 4
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000009500 colour coating Methods 0.000 description 3
- 229920001903 high density polyethylene Polymers 0.000 description 3
- 239000004700 high-density polyethylene Substances 0.000 description 3
- 238000004898 kneading Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 3
- 238000001000 micrograph Methods 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical compound C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 description 2
- PRBHEGAFLDMLAL-UHFFFAOYSA-N 1,5-Hexadiene Natural products CC=CCC=C PRBHEGAFLDMLAL-UHFFFAOYSA-N 0.000 description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
- 229920000877 Melamine resin Polymers 0.000 description 2
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 2
- 239000011954 Ziegler–Natta catalyst Substances 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000002318 adhesion promoter Substances 0.000 description 2
- 229920000180 alkyd Polymers 0.000 description 2
- 125000000219 ethylidene group Chemical group [H]C(=[*])C([H])([H])[H] 0.000 description 2
- PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical compound C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- 229920000092 linear low density polyethylene Polymers 0.000 description 2
- 239000004707 linear low-density polyethylene Substances 0.000 description 2
- 239000012968 metallocene catalyst Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 230000000379 polymerizing effect Effects 0.000 description 2
- 239000005060 rubber Substances 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- 239000004705 High-molecular-weight polyethylene Substances 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 239000013536 elastomeric material Substances 0.000 description 1
- 239000003623 enhancer Substances 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 238000013038 hand mixing Methods 0.000 description 1
- 238000009863 impact test Methods 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 150000007974 melamines Chemical class 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 1
- 238000005453 pelletization Methods 0.000 description 1
- 238000009832 plasma treatment Methods 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920005606 polypropylene copolymer Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229920006301 statistical copolymer Polymers 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000010301 surface-oxidation reaction Methods 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- PHYFQTYBJUILEZ-IUPFWZBJSA-N triolein Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC PHYFQTYBJUILEZ-IUPFWZBJSA-N 0.000 description 1
- 150000003673 urethanes Chemical class 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/0053—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor combined with a final operation, e.g. shaping
- B29C45/0055—Shaping
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Ethene-propene or ethene-propene-diene copolymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2300/00—Characterised by the use of unspecified polymers
- C08J2300/22—Thermoplastic resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/01—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/02—Heterophasic composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
- C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Injection Moulding Of Plastics Or The Like (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US841018 | 1997-04-29 | ||
| US08/841,018 US6013734A (en) | 1997-04-29 | 1997-04-29 | Thermoplastic olefin composition containing an ethylene polymer for making molded parts having a good paint adhesion/durability balance |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69818137D1 DE69818137D1 (de) | 2003-10-23 |
| DE69818137T2 true DE69818137T2 (de) | 2004-07-08 |
Family
ID=25283808
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69818137T Expired - Fee Related DE69818137T2 (de) | 1997-04-29 | 1998-04-25 | Thermoplastische Elastomerzusammensetzung mit einem guten Gleichgewicht der Haftung und der Haltbarkeit |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US6013734A (enExample) |
| EP (1) | EP0875535B1 (enExample) |
| JP (1) | JPH10298368A (enExample) |
| KR (1) | KR19980081777A (enExample) |
| CN (1) | CN1198450A (enExample) |
| AR (1) | AR015612A1 (enExample) |
| AT (1) | ATE250103T1 (enExample) |
| AU (1) | AU735217B2 (enExample) |
| BR (1) | BR9801180A (enExample) |
| CA (1) | CA2235378A1 (enExample) |
| CZ (1) | CZ129298A3 (enExample) |
| DE (1) | DE69818137T2 (enExample) |
| NO (1) | NO981916L (enExample) |
| PL (1) | PL326059A1 (enExample) |
| TW (1) | TW464674B (enExample) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6552126B2 (en) * | 1997-03-03 | 2003-04-22 | Spalding Sports Worldwide, Inc. | Golf ball cover containing a blend of ionomer and plastomer, and method of making same |
| US5962573A (en) * | 1998-02-13 | 1999-10-05 | Montell North America Inc. | Directly paintable thermoplastic olefin composition containing oxidized polyethylene waxes |
| US6316393B1 (en) * | 1998-11-04 | 2001-11-13 | National Research Council Of Canada | Modified lubricated ferrous powder compositions for cold and warm pressing applications |
| FR2831794B1 (fr) * | 2001-11-05 | 2004-02-13 | Depuy France | Procede de selection d'elements de prothese de genou et dispositif pour sa mise en oeuvre |
| CA2467090A1 (en) * | 2002-09-17 | 2004-04-01 | Basell Poliolefine Italia S.P.A. | Polyolefin composition with improved abrasion resistance |
| EP1600480A1 (en) * | 2004-05-27 | 2005-11-30 | Borealis Technology OY | Novel propylene polymer compositions |
| ATE515533T1 (de) * | 2005-05-11 | 2011-07-15 | Basell Poliolefine Srl | Polymerisationsverfahren zur herstellung von polyolefinblends |
| EP2072576B1 (en) * | 2007-12-18 | 2010-04-28 | Borealis Technology OY | Cable layer of modified soft polypropylene |
| US9631094B2 (en) * | 2012-09-12 | 2017-04-25 | Honeywell International Inc. | Bitumen compositions and methods of making |
| CN106278976A (zh) * | 2016-08-09 | 2017-01-04 | 嘉必优生物技术（武汉）股份有限公司 | 制备β‑胡萝卜素晶体的方法 |
| CN106278977A (zh) * | 2016-08-09 | 2017-01-04 | 嘉必优生物技术（武汉）股份有限公司 | 制备β‑胡萝卜素晶体的方法 |
| CN106278978A (zh) * | 2016-08-09 | 2017-01-04 | 嘉必优生物技术（武汉）股份有限公司 | 制备β‑胡萝卜素晶体的方法 |
| CN106278975A (zh) * | 2016-08-09 | 2017-01-04 | 嘉必优生物技术（武汉）股份有限公司 | 制备β‑胡萝卜素晶体的方法 |
| US10513601B2 (en) | 2017-01-05 | 2019-12-24 | Exxonmobil Chemical Patents Inc. | Ethylene-propylene copolymers with amorphous and semi-crystalline components |
| WO2020148106A1 (en) | 2019-01-14 | 2020-07-23 | Basell Poliolefine Italia S.R.L. | Polyolefin composition |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5075173A (en) * | 1987-01-29 | 1991-12-24 | Copolymer Rubber & Chemical Corp. | Directly painted article fabricated from a thermoplastic polyolefin and ethylene polymers blend |
| US4990568A (en) * | 1987-01-29 | 1991-02-05 | Copolymer Rubber & Chemical Corporation | Thermoplastic polyolefin and ethylene copolymers with oxidized polyolefin |
| IT1230133B (it) * | 1989-04-28 | 1991-10-14 | Himont Inc | Composizioni polipropileniche plasto-elastiche |
| IL95097A0 (en) * | 1989-08-23 | 1991-06-10 | Himont Inc | Thermoplastic olefin polymer and its preparation |
| US5212246A (en) * | 1990-09-28 | 1993-05-18 | Himont Incorporated | Olefin polymer films |
| US5338801A (en) * | 1993-10-20 | 1994-08-16 | Himont Incorporated | Compositions of propylene polymer materials and olefin polymer materials with reduced gloss |
| US5763534A (en) * | 1994-08-25 | 1998-06-09 | Solvay Engineered Polymers | Thermoplastic polypropylene blends with mixtures of ethylene/butene and ethylene/octene copolymer elastomers |
-
1997
- 1997-04-29 US US08/841,018 patent/US6013734A/en not_active Expired - Fee Related
-
1998
- 1998-04-18 TW TW087105953A patent/TW464674B/zh active
- 1998-04-20 CA CA002235378A patent/CA2235378A1/en not_active Abandoned
- 1998-04-25 EP EP98107579A patent/EP0875535B1/en not_active Expired - Lifetime
- 1998-04-25 AT AT98107579T patent/ATE250103T1/de not_active IP Right Cessation
- 1998-04-25 DE DE69818137T patent/DE69818137T2/de not_active Expired - Fee Related
- 1998-04-27 CZ CZ981292A patent/CZ129298A3/cs unknown
- 1998-04-28 JP JP10134673A patent/JPH10298368A/ja active Pending
- 1998-04-28 AR ARP980101957A patent/AR015612A1/es unknown
- 1998-04-28 BR BR9801180-4A patent/BR9801180A/pt unknown
- 1998-04-28 AU AU63661/98A patent/AU735217B2/en not_active Ceased
- 1998-04-28 NO NO981916A patent/NO981916L/no not_active Application Discontinuation
- 1998-04-28 KR KR1019980015045A patent/KR19980081777A/ko not_active Withdrawn
- 1998-04-29 CN CN98107802A patent/CN1198450A/zh active Pending
- 1998-04-29 PL PL98326059A patent/PL326059A1/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| AU6366198A (en) | 1998-11-05 |
| AR015612A1 (es) | 2001-05-16 |
| EP0875535A2 (en) | 1998-11-04 |
| KR19980081777A (ko) | 1998-11-25 |
| NO981916D0 (no) | 1998-04-28 |
| CA2235378A1 (en) | 1998-10-29 |
| BR9801180A (pt) | 1999-12-21 |
| AU735217B2 (en) | 2001-07-05 |
| ATE250103T1 (de) | 2003-10-15 |
| TW464674B (en) | 2001-11-21 |
| EP0875535A3 (en) | 1999-07-07 |
| CN1198450A (zh) | 1998-11-11 |
| DE69818137D1 (de) | 2003-10-23 |
| NO981916L (no) | 1998-10-30 |
| PL326059A1 (en) | 1998-11-09 |
| US6013734A (en) | 2000-01-11 |
| EP0875535B1 (en) | 2003-09-17 |
| JPH10298368A (ja) | 1998-11-10 |
| CZ129298A3 (cs) | 1998-12-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE69818137T2 (de) | Thermoplastische Elastomerzusammensetzung mit einem guten Gleichgewicht der Haftung und der Haltbarkeit | |
| DE69525754T2 (de) | Chemisch veränderte olefinzusammensetzungen | |
| DE3211393C2 (enExample) | ||
| DE3043674C2 (enExample) | ||
| DE2855741C2 (de) | Thermoplastisches Elastomer | |
| DE69715015T2 (de) | Polydimethylsiloxan enthaltende polymermischungen | |
| DE69718926T2 (de) | Schlagfeste thermoplastische polyolefine und gegenstände daraus | |
| DE69503428T2 (de) | Aus thermoplastischem Elastomer gefertigten blattförmiger Gegenstand | |
| DE69724258T2 (de) | Vernetzte thermoplastische elastomere auf olefinbasis und ein verfahren zu deren herstellung | |
| DE3850365T3 (de) | Thermoplastische elastomere Zusammensetzungen und Verfahren zu deren Herstellung. | |
| DE60004120T2 (de) | Olefinharzzusammensetzung und Formteile | |
| DE69722808T2 (de) | Tpo mischungen enthaltend multimodale elastomere | |
| DE2939410A1 (de) | Kautschukartige aethylen/1-buten/polyen-copolymerisate und verfahren zu deren herstellung | |
| DE2714193A1 (de) | Thermoplastische elastomere | |
| DE60113534T2 (de) | Polyolefingegenstände mit verbesserter oberflächenhaltbarkeit | |
| DE69727284T2 (de) | Polyolefinzusammensetzungen für die Herstellung von geprägten Folien mit verbesserter Erhaltung der Narbenstruktur | |
| DE3821075A1 (de) | Harzmasse fuer kraftfahrzeug-stossstangen | |
| DE69305864T2 (de) | Niedrigviskose thermoplastische polyolefine | |
| DE2636096C2 (enExample) | ||
| EP0429504A1 (de) | Formmasse aus elastomeren polyolefinkautschuken, polyethylen und/oder ethylencopolymeren und zusatzstoffen sowie deren verwendung für elastische dichtungsbahnen. | |
| DE69510162T2 (de) | Hydrierte Polybutadien-Blockcopolymer enthaltende Polymermischungen | |
| DE69028867T2 (de) | Thermoplastische Formmasse und geformte Gegenstände mit leicht beschichtbarer Oberfläche | |
| EP0469693A2 (de) | Schlagzähe Polyamid-Formmassen | |
| DE3927719C2 (de) | Kunststofformmasse und Verwendung derselben | |
| EP0552681B1 (de) | Schlagzähe Polyolefin-Formmasse |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8364 | No opposition during term of opposition | ||
| 8339 | Ceased/non-payment of the annual fee |