DE69710838D1 - Katalysator zur polyolefinherstellung und polyolefinherstellungsverfahren - Google Patents

Katalysator zur polyolefinherstellung und polyolefinherstellungsverfahren

Info

Publication number
DE69710838D1
DE69710838D1 DE69710838T DE69710838T DE69710838D1 DE 69710838 D1 DE69710838 D1 DE 69710838D1 DE 69710838 T DE69710838 T DE 69710838T DE 69710838 T DE69710838 T DE 69710838T DE 69710838 D1 DE69710838 D1 DE 69710838D1
Authority
DE
Germany
Prior art keywords
polyolefin production
catalyst
production method
polyolefin
production catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69710838T
Other languages
English (en)
Other versions
DE69710838T2 (de
Inventor
Yoshikuni Okumura
Tsutomu Sakuragi
Michio Ono
Shintaro Inazawa
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SunAllomer Ltd
Original Assignee
Japan Polyolefins Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Japan Polyolefins Co Ltd filed Critical Japan Polyolefins Co Ltd
Application granted granted Critical
Publication of DE69710838D1 publication Critical patent/DE69710838D1/de
Publication of DE69710838T2 publication Critical patent/DE69710838T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
DE69710838T 1996-04-22 1997-04-22 Katalysator zur polyolefinherstellung und polyolefinherstellungsverfahren Expired - Lifetime DE69710838T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP9969696 1996-04-22
JP3343097 1997-02-18
PCT/JP1997/001387 WO1997040075A1 (fr) 1996-04-22 1997-04-22 Procede de production de polyolefine et catalyseur approprie

Publications (2)

Publication Number Publication Date
DE69710838D1 true DE69710838D1 (de) 2002-04-11
DE69710838T2 DE69710838T2 (de) 2002-10-31

Family

ID=26372110

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69710838T Expired - Lifetime DE69710838T2 (de) 1996-04-22 1997-04-22 Katalysator zur polyolefinherstellung und polyolefinherstellungsverfahren

Country Status (6)

Country Link
US (1) US6121182A (de)
EP (1) EP0834519B1 (de)
JP (1) JP3181920B2 (de)
KR (1) KR100405780B1 (de)
DE (1) DE69710838T2 (de)
WO (1) WO1997040075A1 (de)

Families Citing this family (38)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3845187B2 (ja) * 1997-12-11 2006-11-15 三菱化学株式会社 プロピレン系重合体
DE60034308T2 (de) * 1999-10-08 2007-12-20 Mitsui Chemicals, Inc. Metallocene, ein Verfahren zur deren Herstellung, Olefinpolymerisationskatalysator, und ein Verfahren zur Herstellung von Polyolefinen
CN100575324C (zh) * 1999-12-23 2009-12-30 巴塞尔聚烯烃有限公司 过渡金属化合物，配体体系，催化剂体系及其在烯烃的聚合反应和共聚反应中的用途
KR100743010B1 (ko) * 1999-12-23 2007-07-27 바젤 폴리올레핀 게엠베하 전이 금속 화합물, 리간드계, 촉매계와 올레핀의 중합 및공중합에 사용되는 이의 용도
US6376412B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376413B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376410B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6900321B2 (en) * 2000-11-07 2005-05-31 Symyx Technologies, Inc. Substituted pyridyl amine complexes, and catalysts
JP3964867B2 (ja) * 2001-08-07 2007-08-22 電気化学工業株式会社 重合体の製造方法
DE10158656A1 (de) 2001-11-30 2003-06-26 Basell Polyolefine Gmbh Organoübergangsmetallverbindung, Biscyclopentadienylligandsystem, Katalysatorsystem und Verfahren zur Herstellung von Polyolefinen
US6995279B2 (en) 2002-08-02 2006-02-07 Chisso Corporation Metallocene compounds, processes for the production of olefin polymers using catalysts containing the compounds, and olefin polymers produced by the processes
ATE364637T1 (de) 2003-02-07 2007-07-15 Basell Polyolefine Gmbh Polymerisationskatalysatoren, organische übergangsmetallverbindungen, verfahren zur herstellung von polyolefinen
DE602004019647D1 (de) * 2003-05-28 2009-04-09 Basell Polyolefine Gmbh Bisindenyl-zirconium-komplexe zur olefinpolymerisation
DE10358082A1 (de) 2003-12-10 2005-07-14 Basell Polyolefine Gmbh Organübergangsmetallverbindung, Bscyclopentadienyligandsystem, Katalysatorsystem und Hertellung von Polyolefinen
US7514509B2 (en) * 2005-12-16 2009-04-07 Fina Technology, Inc. Catalyst compositions and methods of forming isotactic polyproyplene
EP1847555A1 (de) 2006-04-18 2007-10-24 Borealis Technology Oy Mehrfach verzweigtes Polypropylen
EP2235071A2 (de) 2007-10-25 2010-10-06 Novolen Technology Holdings, C.V. Metallocenverbindungen, katalysatoren, die diese enthalten, verfahren zur herstellung eines olefinpolymers unter verwendung der katalysatoren und olefinhomo- und copolymere
WO2009054832A1 (en) * 2007-10-25 2009-04-30 Novolen Technology Holdings, C.V. Metallocene compounds, catalysts comprising them, process for producing an olefin polymer by use of the catalysts, and olefin homo-and copolymers
CN108409895A (zh) 2011-07-08 2018-08-17 博瑞立斯有限公司 催化剂
JP6033322B2 (ja) * 2012-09-25 2016-11-30 三井化学株式会社 遷移金属化合物、オレフィン重合用触媒およびオレフィン重合体の製造方法
EP3022238B1 (de) 2013-07-17 2017-09-20 ExxonMobil Chemical Patents Inc. Metallocene und katalysatorzusammensetzungen daraus
WO2015009480A1 (en) 2013-07-17 2015-01-22 Exxonmobil Chemical Patents Inc. Process using substituted metallocene catalysts and products therefrom
US9834628B2 (en) 2013-07-17 2017-12-05 Exxonmobil Chemical Patents Inc. Cyclopropyl substituted metallocene catalysts
US9938364B2 (en) 2013-07-17 2018-04-10 Exxonmobil Chemical Patents Inc. Substituted metallocene catalysts
SG11201510461SA (en) 2013-07-17 2016-01-28 Exxonmobil Chem Patents Inc Substituted metallocene catalysts
CN105358589B (zh) 2013-07-17 2018-07-03 埃克森美孚化学专利公司 金属茂和由其衍生的催化剂组合物
US10280233B2 (en) 2015-06-05 2019-05-07 Exxonmobil Chemical Patents Inc. Catalyst systems and methods of making and using the same
KR101926833B1 (ko) 2015-06-05 2019-03-07 주식회사 엘지화학 메탈로센 화합물
US10294316B2 (en) 2015-06-05 2019-05-21 Exxonmobil Chemical Patents Inc. Silica supports with high aluminoxane loading capability
US10280235B2 (en) 2015-06-05 2019-05-07 Exxonmobil Chemical Patents Inc. Catalyst system containing high surface area supports and sequential polymerization to produce heterophasic polymers
US9809664B2 (en) 2015-06-05 2017-11-07 Exxonmobil Chemical Patents Inc. Bimodal propylene polymers and sequential polymerization
US10329360B2 (en) 2015-06-05 2019-06-25 Exxonmobil Chemical Patents Inc. Catalyst system comprising supported alumoxane and unsupported alumoxane particles
WO2016196331A1 (en) 2015-06-05 2016-12-08 Exxonmobil Chemical Patents Inc. Supported metallocene catalyst systems for polymerization
EP3303422B1 (de) 2015-06-05 2021-03-17 ExxonMobil Chemical Patents Inc. Herstellung von heterophasischen polymeren in gas- oder schlämmephase
WO2016196334A1 (en) 2015-06-05 2016-12-08 Exxonmobil Chemical Patents Inc. Single reactor production of polymers in gas or slurry phase
US11059918B2 (en) 2016-05-27 2021-07-13 Exxonmobil Chemical Patents Inc. Metallocene catalyst compositions and polymerization process therewith
US11472828B2 (en) 2019-10-11 2022-10-18 Exxonmobil Chemical Patents Inc. Indacene based metallocene catalysts useful in the production of propylene polymers
CN118221849A (zh) * 2024-03-20 2024-06-21 亚培烯科技(上海)有限公司 一种茂金属催化剂组合物在聚α烯烃蜡制备中作为催化剂的用途

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3443087A1 (de) * 1984-11-27 1986-05-28 Hoechst Ag, 6230 Frankfurt Verfahren zur herstellung von polyolefinen
ES2082745T3 (es) * 1987-04-03 1996-04-01 Fina Technology Sistemas cataliticos metalocenos para la polimerizacion de las olefinas presentando un puente de hidrocarburo de silicio.
US5017714A (en) * 1988-03-21 1991-05-21 Exxon Chemical Patents Inc. Silicon-bridged transition metal compounds
EP0485823B1 (de) * 1990-11-12 1995-03-08 Hoechst Aktiengesellschaft 2-Substituierte Bisindenylmetallocene, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren bei der Olefinpolymerisation
US5239022A (en) * 1990-11-12 1993-08-24 Hoechst Aktiengesellschaft Process for the preparation of a syndiotactic polyolefin
US5243001A (en) * 1990-11-12 1993-09-07 Hoechst Aktiengesellschaft Process for the preparation of a high molecular weight olefin polymer
DE4120009A1 (de) * 1991-06-18 1992-12-24 Basf Ag Loesliche katalysatorsysteme zur herstellung von polyalk-1-enen mit hohen molmassen
TW300901B (de) * 1991-08-26 1997-03-21 Hoechst Ag
EP0537686B1 (de) * 1991-10-15 2005-01-12 Basell Polyolefine GmbH Verfahren zur Herstellung eines Olefinpolymers unter Verwendung von Metallocenen mit speziell substituierten Indenylliganden
JP3371118B2 (ja) * 1991-11-30 2003-01-27 バーゼル・ポリオレフィン・ゲゼルシャフト・ミト・ベシュレンクテル・ハフツング 配位子としてベンゼン融合したインデニル誘導体を持つメタロセン、その製造方法および触媒としてのその用途
TW294669B (de) * 1992-06-27 1997-01-01 Hoechst Ag
JPH0625343A (ja) * 1992-07-10 1994-02-01 Mitsui Petrochem Ind Ltd オレフィン重合用触媒およびオレフィンの重合方法
TW298593B (de) * 1993-02-12 1997-02-21 Hoechst Ag
EP1209165B1 (de) * 1993-06-07 2006-04-19 Mitsui Chemicals, Inc. Propylenelastomere
CA2125247C (en) * 1993-06-07 2001-02-20 Daisuke Fukuoka Transition metal compound, olefin polymerization catalyst component comprising said compound, olefin polymerization catalyst containing said catalyst component, process for olefinpolymerization using said catalyst , propylene homopolymer, propylene copolymer and propylene elastomer
DE4333569A1 (de) * 1993-10-01 1995-04-06 Hoechst Ag Verfahren zur Olefinpolymerisation
DE4344689A1 (de) * 1993-12-27 1995-06-29 Hoechst Ag Metallocenverbindung
JP3344841B2 (ja) * 1994-09-22 2002-11-18 昭和電工株式会社 プロピレン系重合体およびその製造方法
TW383314B (en) * 1994-12-20 2000-03-01 Mitsui Petrochemical Ind Ethylene-alpha-olefin-nonconjugated polyene random copolymer, rubber composition, and process for preparing the random copolymer
DE19517851A1 (de) * 1995-05-16 1996-11-21 Hoechst Ag Organometallverbindung

Also Published As

Publication number Publication date
KR19990022955A (ko) 1999-03-25
DE69710838T2 (de) 2002-10-31
US6121182A (en) 2000-09-19
EP0834519B1 (de) 2002-03-06
WO1997040075A1 (fr) 1997-10-30
KR100405780B1 (ko) 2004-03-30
EP0834519A4 (de) 2000-06-07
EP0834519A1 (de) 1998-04-08
JP3181920B2 (ja) 2001-07-03

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Owner name: SUNALLOMER LTD., TOKIO/TOKYO, JP