DE69705953D1 - Zwei-stufenverfahren zur herstellung von linearen alkylbenzolen durch alkylierung von benzol - Google Patents

Zwei-stufenverfahren zur herstellung von linearen alkylbenzolen durch alkylierung von benzol

Info

Publication number
DE69705953D1
DE69705953D1 DE69705953T DE69705953T DE69705953D1 DE 69705953 D1 DE69705953 D1 DE 69705953D1 DE 69705953 T DE69705953 T DE 69705953T DE 69705953 T DE69705953 T DE 69705953T DE 69705953 D1 DE69705953 D1 DE 69705953D1
Authority
DE
Germany
Prior art keywords
benzol
alkylating
stage process
linear alkylbenzene
producing linear
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69705953T
Other languages
English (en)
Other versions
DE69705953T2 (de
Inventor
F Knifton
Rao Anantaneni
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Huntsman Specialty Chemicals Corp
Huntsman Petrochemical LLC
Original Assignee
Huntsman Specialty Chemicals Corp
Huntsman Petrochemical LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Huntsman Specialty Chemicals Corp, Huntsman Petrochemical LLC filed Critical Huntsman Specialty Chemicals Corp
Application granted granted Critical
Publication of DE69705953D1 publication Critical patent/DE69705953D1/de
Publication of DE69705953T2 publication Critical patent/DE69705953T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66—Catalytic processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/14—Fractional distillation or use of a fractionation or rectification column
    • B01D3/32—Other features of fractionating columns ; Constructional details of fractionating columns not provided for in groups B01D3/16 - B01D3/30
    • B01D3/322—Reboiler specifications
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/16—Clays or other mineral silicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/22—Halogenating
    • B01J37/26—Fluorinating
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/026—After-treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/16—After treatment, characterised by the effect to be obtained to increase the Si/Al ratio; Dealumination
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/16—Clays or other mineral silicates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • C07C2529/16—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Polymerization Catalysts (AREA)
  • Color Printing (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
DE69705953T 1996-06-12 1997-05-08 Zwei-stufenverfahren zur herstellung von linearen alkylbenzolen durch alkylierung von benzol Expired - Fee Related DE69705953T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/662,786 US5777187A (en) 1996-02-08 1996-06-12 Two-step process for alkylation of benzene to form linear alkylbenzenes
PCT/US1997/008070 WO1997047573A1 (en) 1996-06-12 1997-05-08 Two-step process for alkylation of benzene to form linear alkylbenzenes

Publications (2)

Publication Number Publication Date
DE69705953D1 true DE69705953D1 (de) 2001-09-06
DE69705953T2 DE69705953T2 (de) 2001-11-22

Family

ID=24659217

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69705953T Expired - Fee Related DE69705953T2 (de) 1996-06-12 1997-05-08 Zwei-stufenverfahren zur herstellung von linearen alkylbenzolen durch alkylierung von benzol

Country Status (11)

Country Link
US (1) US5777187A (de)
EP (1) EP0918736B1 (de)
JP (1) JP2000511927A (de)
KR (1) KR20000016605A (de)
CN (1) CN1073539C (de)
DE (1) DE69705953T2 (de)
ES (1) ES2159397T3 (de)
ID (1) ID17942A (de)
RU (1) RU2173677C2 (de)
TW (1) TW426653B (de)
WO (1) WO1997047573A1 (de)

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US6133492A (en) * 1996-02-08 2000-10-17 Huntsman Petrochemical Corporation Alkylation of benzene to form linear alkylbenzenes using fluorine-containing mordenites
KR100358831B1 (ko) 1997-07-21 2002-10-31 더 프록터 앤드 갬블 캄파니 알킬벤젠설포네이트 계면활성제의 개선된 제조방법 및이렇게 제조된 계면활성제를 포함하는 제품
US6596680B2 (en) 1997-07-21 2003-07-22 The Procter & Gamble Company Enhanced alkylbenzene surfactant mixture
PH11998001775B1 (en) 1997-07-21 2004-02-11 Procter & Gamble Improved alkyl aryl sulfonate surfactants
AU737736B2 (en) 1997-07-21 2001-08-30 Procter & Gamble Company, The Improved alkylbenzenesulfonate surfactants
HUP0002572A3 (en) 1997-07-21 2001-04-28 Procter & Gamble Detergent compositions containing mixtures of crystallinity-disrupted surfactants
JP2001511471A (ja) 1997-07-21 2001-08-14 ザ、プロクター、エンド、ギャンブル、カンパニー ビニリデンオレフィンを経由して製造された改良アルキルアリールスルホネート界面活性剤を含んでなる洗浄製品およびそれらの製造方法
US6031144A (en) * 1997-08-06 2000-02-29 Chevron Chemical Company Llc Process for reducing the residual olefin content of an alkylation reaction product
AU763324B2 (en) * 1998-10-20 2003-07-17 Procter & Gamble Company, The Laundry detergents comprising modified alkylbenzene sulfonates
BR9914678A (pt) 1998-10-20 2001-10-09 Procter & Gamble Detergentes para a lavagem de roupas compreendendo sulfonatos de alquilbenzeno modificados
AU2311199A (en) * 1999-01-06 2000-07-24 Procter & Gamble Company, The Laundry detergent bar composition
EP1022326A1 (de) 1999-01-20 2000-07-26 The Procter & Gamble Company Reinigungszusammensetzungen für harte Oberflächen enthaltend modifizierte Alkylbenzylsulfonate
EP1022325A3 (de) 1999-01-20 2003-01-02 The Procter & Gamble Company Harte Oberflächenreiniger enthaltend modifizierte Alkylbenzolsulfonate
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US6521804B1 (en) 2001-08-24 2003-02-18 Uop Llc Process for producing phenyl-alkanes using dual zones
FR2832144B1 (fr) * 2001-11-15 2004-09-24 Inst Francais Du Petrole Procede de production de phenylalcanes utilisant une combinaison de deux catalyseurs
US6642425B2 (en) * 2002-03-05 2003-11-04 Sasol North America Inc. Reactive distillation process for the alkylation of aromatic hydrocarbons
US7189885B1 (en) 2003-10-07 2007-03-13 Uop Llc Staged process for producing linear 2-phenyl-alkanes
US7396968B1 (en) 2005-01-25 2008-07-08 Uop Llc Process and apparatus for alkylation of aromatic with olefin using impure aromatic recycle
US20090205945A1 (en) * 2005-01-25 2009-08-20 Sohn Stephen W Process and apparatus for alkylation of benzene with aliphatic mono-olefin compound
US7692054B2 (en) 2006-10-30 2010-04-06 Uop Llc Process and apparatus for alkylation of aromatic compound with aliphatic mono-olefin compound of 8 to 18 carbon atoms
KR101533875B1 (ko) * 2010-03-10 2015-07-03 엑손모빌 케미칼 패턴츠 인코포레이티드 알킬화 방향족 화합물의 제조 방법
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US20160186073A1 (en) * 2014-12-30 2016-06-30 Shell Oil Company Methods and systems for processing cellulosic biomass
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Also Published As

Publication number Publication date
DE69705953T2 (de) 2001-11-22
ES2159397T3 (es) 2001-10-01
WO1997047573A1 (en) 1997-12-18
ID17942A (id) 1998-02-12
JP2000511927A (ja) 2000-09-12
RU2173677C2 (ru) 2001-09-20
TW426653B (en) 2001-03-21
CN1222134A (zh) 1999-07-07
EP0918736A1 (de) 1999-06-02
CN1073539C (zh) 2001-10-24
EP0918736B1 (de) 2001-08-01
KR20000016605A (ko) 2000-03-25
US5777187A (en) 1998-07-07

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