DE69703855T2 - Verfahren zur Hydrierung konjugierter Dienpolymere und bei diesem Verfahren verwendbare Katalysatorzusammensetzungen - Google Patents

Verfahren zur Hydrierung konjugierter Dienpolymere und bei diesem Verfahren verwendbare Katalysatorzusammensetzungen

Info

Publication number
DE69703855T2
DE69703855T2 DE69703855T DE69703855T DE69703855T2 DE 69703855 T2 DE69703855 T2 DE 69703855T2 DE 69703855 T DE69703855 T DE 69703855T DE 69703855 T DE69703855 T DE 69703855T DE 69703855 T2 DE69703855 T2 DE 69703855T2
Authority
DE
Germany
Prior art keywords
hydrogenation
conjugated diene
compositions useful
catalyst compositions
diene polymers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69703855T
Other languages
English (en)
Other versions
DE69703855D1 (de
Inventor
Boer Eric Johannes Maria De
Bart Hessen
Der Huizen Adriaan Albert Van
Jong Wouter De
Der Linden Adrianus Johann Van
Bart Johan Ruisch
Lodewijk Schoon
Smet Heleen Johanna Augusta De
Der Steen Frederik Hendrik Van
Strien Hubertus Cornelis T Van
Alan Villena
Judith Johanna Berendin Walhof
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Publication of DE69703855D1 publication Critical patent/DE69703855D1/de
Application granted granted Critical
Publication of DE69703855T2 publication Critical patent/DE69703855T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0204—Ethers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0205—Oxygen-containing compounds comprising carbonyl groups or oxygen-containing derivatives, e.g. acetals, ketals, cyclic peroxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/121—Metal hydrides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/122—Metal aryl or alkyl compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber
    • C08C19/02—Hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/04—Reduction, e.g. hydrogenation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B01J2231/645—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of C=C or C-C triple bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/46—Titanium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
DE69703855T 1996-03-15 1997-03-14 Verfahren zur Hydrierung konjugierter Dienpolymere und bei diesem Verfahren verwendbare Katalysatorzusammensetzungen Expired - Fee Related DE69703855T2 (de)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
EP96301780 1996-03-15
EP96303882 1996-05-30
US08/816,538 US5925717A (en) 1996-03-15 1997-03-13 Process for hydrogenation of conjugated diene polymers and catalyst compositions suitable for use therein
EP97200774A EP0795564B1 (de) 1996-03-15 1997-03-14 Verfahren zur Hydrierung konjugierter Dienpolymere und bei diesem Verfahren verwendbare Katalysatorzusammensetzungen

Publications (2)

Publication Number Publication Date
DE69703855D1 DE69703855D1 (de) 2001-02-15
DE69703855T2 true DE69703855T2 (de) 2001-06-13

Family

ID=27237694

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69703855T Expired - Fee Related DE69703855T2 (de) 1996-03-15 1997-03-14 Verfahren zur Hydrierung konjugierter Dienpolymere und bei diesem Verfahren verwendbare Katalysatorzusammensetzungen

Country Status (9)

Country Link
US (1) US5925717A (de)
EP (1) EP0795564B1 (de)
JP (1) JP4076243B2 (de)
CN (1) CN1130383C (de)
BR (1) BR9701276A (de)
CA (1) CA2199915A1 (de)
DE (1) DE69703855T2 (de)
ES (1) ES2153632T3 (de)
MX (1) MX9701870A (de)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100267080B1 (ko) * 1998-08-03 2000-10-02 박찬구 공액디엔 중합체의 수소화 방법
TW583027B (en) * 1998-10-30 2004-04-11 Shell Int Research A method for preparing a hydrogenation catalyst system
KR100348761B1 (ko) * 1999-11-26 2002-08-13 금호석유화학 주식회사 공액디엔을 포함하는 중합체의 선택적 수소화 방법
US6469223B2 (en) 2000-01-04 2002-10-22 Fina Technology, Inc. Selective hydrogenation of dienes
KR100356533B1 (ko) * 2000-02-09 2002-10-18 금호석유화학 주식회사 공액디엔 중합체의 선택적 수소화 방법
ATE297415T1 (de) * 2000-07-28 2005-06-15 Kraton Polymers Res Bv Verfahren zur herstellung von teilhydrierten butadienpolymeren
EP1358270B1 (de) * 2000-12-01 2005-10-26 KRATON Polymers Research B.V. Bituminöse zusammensetzung mit verringerter gelierungsneigung
KR100515452B1 (ko) * 2003-01-04 2005-09-20 금호석유화학 주식회사 고속분사 노즐 장착 반응기로부터 제조된 리튬하이드라이드를 사용하여 선택적으로 수소화된 공역디엔 중합체를 제조하는 방법
WO2005030821A1 (en) * 2003-09-24 2005-04-07 Kraton Polymers Research B.V. Conjugated diene polymers and copolymer blocks having high vinyl content prepared using mixed microstructure control agents and process for preparing same
PL2272588T3 (pl) * 2009-06-22 2013-11-29 Dynasol Elastomeros Sa Katalizator do uwodornienia nienasyconych związków
JP2014511411A (ja) 2011-02-18 2014-05-15 クレイトン・ポリマーズ・ユー・エス・エル・エル・シー ケーブル充填用硬化性ポリマー組成物
US8487061B2 (en) * 2011-05-17 2013-07-16 Exxonmobil Research And Engineering Company Star hydrocarbon polymer, process for making, and a polymer blend composition having same
US11667777B2 (en) 2019-10-04 2023-06-06 Chevron Phillips Chemical Company Lp Bimodal polyethylene copolymers
US11186665B2 (en) * 2019-10-04 2021-11-30 Chevron Phillips Chemical Company Lp Catalyst composition and method for preparing polyethylene
CN113368903A (zh) * 2021-07-09 2021-09-10 浙江众立合成材料科技股份有限公司 一种用于制备氢化聚合物的三组分复合催化剂
CN113429499B (zh) * 2021-08-09 2022-05-31 中国科学院兰州化学物理研究所 一种腈橡胶的催化氢化方法

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE737574A (de) * 1968-09-05 1970-02-02
US3766300A (en) * 1971-04-05 1973-10-16 Shell Oil Co Process for hydrogenation of polar copolymers and complexed copolymercompositions
US3898208A (en) * 1971-06-21 1975-08-05 Dow Chemical Co Hydrogenation of oil-insoluble diene polymers
GB2134909B (en) * 1983-01-20 1986-08-20 Asahi Chemical Ind Catalytic hydrogenation of conjugated diene polymer
JPS60220147A (ja) * 1984-04-18 1985-11-02 Asahi Chem Ind Co Ltd オレフイン水添触媒および該触媒を用いた重合体の水添方法
JP2609534B2 (ja) * 1988-05-17 1997-05-14 旭化成工業株式会社 オレフィン性不飽和ポリマーの水添方法
JP2969771B2 (ja) * 1989-12-22 1999-11-02 ジェイエスアール株式会社 オレフィン性不飽和重合体の水素添加方法および水素添加用触媒組成物
US5039755A (en) * 1990-05-29 1991-08-13 Shell Oil Company Selective hydrogenation of conjugated diolefin polymers
US5141997A (en) * 1990-08-15 1992-08-25 Shell Oil Company Selective hydrogenation of conjugated diolefin polymers
US5206307A (en) * 1991-09-09 1993-04-27 Shell Oil Company Process for selective hydrogenation of conjugated diolefin polymers
US5270274A (en) * 1991-11-28 1993-12-14 Japan Synthetic Rubber Co., Ltd. Catalyst composition for hydrogenating olefinically unsaturated polymers
ES2053363B1 (es) * 1991-12-05 1995-02-16 Repsol Quimica Sa Procedimiento de hidrogenacion de olefinas.
US5173537A (en) * 1991-12-20 1992-12-22 Shell Oil Company Selective hydrogenation of conjugated diolefin poylmers
WO1995025136A1 (en) * 1992-03-05 1995-09-21 Exxon Research And Engineering Co. Sulfonated unhydrogenated copolymers of styrene and butadiene
US5242986A (en) * 1992-08-10 1993-09-07 Shell Oil Company Selective partial hydrogenation of conjugated diolefin polymers
ES2050620B1 (es) * 1992-11-03 1994-12-16 Repsol Quimica Sa Procedimiento de hidrogenacion en disolucion de los dobles enlaces de polimeros de dienos conjugados y copolimero bloque hidrogenado producido.
FI97141C (fi) * 1994-03-14 1996-10-25 Neste Oy Menetelmä tyydyttämättömien polymeerien selektiiviseksi hydrogenoimiseksi
US5541272A (en) * 1994-06-03 1996-07-30 Phillips Petroleum Company High activity ethylene selective metallocenes

Also Published As

Publication number Publication date
ES2153632T3 (es) 2001-03-01
DE69703855D1 (de) 2001-02-15
MX9701870A (es) 1998-04-30
EP0795564B1 (de) 2001-01-10
CN1163275A (zh) 1997-10-29
BR9701276A (pt) 1998-11-10
CN1130383C (zh) 2003-12-10
CA2199915A1 (en) 1997-09-15
US5925717A (en) 1999-07-20
JPH1017607A (ja) 1998-01-20
EP0795564A1 (de) 1997-09-17
JP4076243B2 (ja) 2008-04-16

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Legal Events

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8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee