DE69700309T2 - Verfahren zur Hydrierung konjugierter Dienpolymere und bei diesem Verfahren verwendbare Katalysatorzusammensetzungen - Google Patents

Verfahren zur Hydrierung konjugierter Dienpolymere und bei diesem Verfahren verwendbare Katalysatorzusammensetzungen

Info

Publication number
DE69700309T2
DE69700309T2 DE69700309T DE69700309T DE69700309T2 DE 69700309 T2 DE69700309 T2 DE 69700309T2 DE 69700309 T DE69700309 T DE 69700309T DE 69700309 T DE69700309 T DE 69700309T DE 69700309 T2 DE69700309 T2 DE 69700309T2
Authority
DE
Germany
Prior art keywords
hydrogenation
conjugated diene
compositions useful
catalyst compositions
diene polymers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69700309T
Other languages
English (en)
Other versions
DE69700309D1 (de
Inventor
Boer Eric Johannes Maria De
Bart Hessen
Der Huizen Adriaan Albert Van
Jong Wouter De
Der Linden Adrianus Johann Van
Bart Johan Ruisch
Lodewijk Schoon
Smet Heleen Johanna Augusta De
Der Steen Frederik Hendrik Van
Strien Hubertus Cornelis T Van
Alan Villena
Judith Johanna Berendin Walhof
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Application granted granted Critical
Publication of DE69700309D1 publication Critical patent/DE69700309D1/de
Publication of DE69700309T2 publication Critical patent/DE69700309T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0205—Oxygen-containing compounds comprising carbonyl groups or oxygen-containing derivatives, e.g. acetals, ketals, cyclic peroxides
    • B01J31/0208—Ketones or ketals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0204—Ethers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0205—Oxygen-containing compounds comprising carbonyl groups or oxygen-containing derivatives, e.g. acetals, ketals, cyclic peroxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/121—Metal hydrides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/146—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of boron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber
    • C08C19/02—Hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/04—Reduction, e.g. hydrogenation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B01J2231/645—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of C=C or C-C triple bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/46—Titanium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Catalysts (AREA)
DE69700309T 1996-04-12 1997-04-11 Verfahren zur Hydrierung konjugierter Dienpolymere und bei diesem Verfahren verwendbare Katalysatorzusammensetzungen Expired - Fee Related DE69700309T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP96302600 1996-04-12

Publications (2)

Publication Number Publication Date
DE69700309D1 DE69700309D1 (de) 1999-08-12
DE69700309T2 true DE69700309T2 (de) 2000-01-27

Family

ID=8224884

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69700309T Expired - Fee Related DE69700309T2 (de) 1996-04-12 1997-04-11 Verfahren zur Hydrierung konjugierter Dienpolymere und bei diesem Verfahren verwendbare Katalysatorzusammensetzungen

Country Status (6)

Country Link
US (1) US5814709A (de)
EP (1) EP0801079B1 (de)
JP (1) JPH1036421A (de)
DE (1) DE69700309T2 (de)
ES (1) ES2134050T3 (de)
TW (1) TW334452B (de)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
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JPH10101727A (ja) * 1996-09-24 1998-04-21 Shell Internatl Res Maatschappij Bv オレフィン又はポリマーを水素化するための触媒及び方法
KR100267080B1 (ko) * 1998-08-03 2000-10-02 박찬구 공액디엔 중합체의 수소화 방법
NL1009841C2 (nl) * 1998-08-11 2000-02-15 Dsm Nv Werkwijze voor de hydrogenering van koolstof-koolstof dubbele bindingen van een onverzadigd polymeer.
US6521694B2 (en) 1998-08-11 2003-02-18 Dsm N.V. Process for hydrogenation of carbon-carbon double bonds of an unsaturated polymer
KR100287961B1 (ko) * 1998-09-30 2001-05-02 박찬구 공역디엔을 포함하는 고분자의 수소첨가 방법
US6291386B1 (en) * 1999-05-25 2001-09-18 Equistar Chemicals, Lp Process for the in-situ preparation of single-site transition metal catalysts and polymerization process
KR100348761B1 (ko) * 1999-11-26 2002-08-13 금호석유화학 주식회사 공액디엔을 포함하는 중합체의 선택적 수소화 방법
US6881795B2 (en) 2001-03-28 2005-04-19 Firestone Polymers, Llc CO2 terminated rubber for plastics
ITMI20012267A1 (it) * 2001-10-29 2003-04-29 Chemi Spa Preparazione ed uso di un catalizzatore eterogeneo per l'idrogenerazione di un doppio legame di un composto carbonilico b-insaturo
ITMI20022052A1 (it) * 2002-09-27 2004-03-28 Polimeri Europa Spa Composti metallocenici stabilizzati di metalli di transizione del gruppo 4 e processo per la loro preparazione.
ITMI20022054A1 (it) 2002-09-27 2004-03-28 Polimeri Europa Spa Composizione catalitica per la (co)polimerizzazione delle alfa-olefine.
WO2005030821A1 (en) * 2003-09-24 2005-04-07 Kraton Polymers Research B.V. Conjugated diene polymers and copolymer blocks having high vinyl content prepared using mixed microstructure control agents and process for preparing same
ITMI20050860A1 (it) * 2005-05-13 2006-11-14 Polimeri Europa Spa Procedimento per la idrogenazione selettiva di copolimeri stirene-butadiene
US8716409B2 (en) * 2006-12-29 2014-05-06 Firestone Polymers, Llc Carboxylate terminated polymers and their use in impact-modified plastics
EP2204094A1 (de) 2008-12-29 2010-07-07 Bayer CropScience AG Verfahren zur verbesserten Verwendung des Herstellungspotentials von transgenen Pflanzen
ES2423762T3 (es) 2009-06-22 2013-09-24 Dynasol Elastómeros, S.A. Catalizador para la hidrogenación de compuestos insaturados
JP2012082186A (ja) 2010-09-15 2012-04-26 Bayer Cropscience Ag 殺虫性アリールピロリジン類
JP2014511411A (ja) 2011-02-18 2014-05-15 クレイトン・ポリマーズ・ユー・エス・エル・エル・シー ケーブル充填用硬化性ポリマー組成物
WO2012168124A1 (en) 2011-06-06 2012-12-13 Bayer Cropscience Nv Methods and means to modify a plant genome at a preselected site
IN2014DN00156A (de) 2011-08-10 2015-05-22 Bayer Ip Gmbh
EP2742059A1 (de) 2011-08-12 2014-06-18 Bayer CropScience NV Schliesszellspezifische expression von transgenen in baumwolle
EP2606732A1 (de) 2011-12-19 2013-06-26 Bayer CropScience AG Verwendung von Anthranildiamidderivaten mit heteroaromatischen und heterocyclischen Substituenten in Verbindung mit einem biologischen Steuermittel

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE737574A (de) * 1968-09-05 1970-02-02
US3766300A (en) * 1971-04-05 1973-10-16 Shell Oil Co Process for hydrogenation of polar copolymers and complexed copolymercompositions
US3898208A (en) * 1971-06-21 1975-08-05 Dow Chemical Co Hydrogenation of oil-insoluble diene polymers
GB2134909B (en) * 1983-01-20 1986-08-20 Asahi Chemical Ind Catalytic hydrogenation of conjugated diene polymer
JPS60220147A (ja) * 1984-04-18 1985-11-02 Asahi Chem Ind Co Ltd オレフイン水添触媒および該触媒を用いた重合体の水添方法
JP2609534B2 (ja) * 1988-05-17 1997-05-14 旭化成工業株式会社 オレフィン性不飽和ポリマーの水添方法
JP2969771B2 (ja) * 1989-12-22 1999-11-02 ジェイエスアール株式会社 オレフィン性不飽和重合体の水素添加方法および水素添加用触媒組成物
US5039755A (en) * 1990-05-29 1991-08-13 Shell Oil Company Selective hydrogenation of conjugated diolefin polymers
US5141997A (en) * 1990-08-15 1992-08-25 Shell Oil Company Selective hydrogenation of conjugated diolefin polymers
US5206307A (en) * 1991-09-09 1993-04-27 Shell Oil Company Process for selective hydrogenation of conjugated diolefin polymers
US5270274A (en) * 1991-11-28 1993-12-14 Japan Synthetic Rubber Co., Ltd. Catalyst composition for hydrogenating olefinically unsaturated polymers
ES2053363B1 (es) * 1991-12-05 1995-02-16 Repsol Quimica Sa Procedimiento de hidrogenacion de olefinas.
US5173537A (en) * 1991-12-20 1992-12-22 Shell Oil Company Selective hydrogenation of conjugated diolefin poylmers
WO1995025136A1 (en) * 1992-03-05 1995-09-21 Exxon Research And Engineering Co. Sulfonated unhydrogenated copolymers of styrene and butadiene
ES2050620B1 (es) * 1992-11-03 1994-12-16 Repsol Quimica Sa Procedimiento de hidrogenacion en disolucion de los dobles enlaces de polimeros de dienos conjugados y copolimero bloque hidrogenado producido.
US5541272A (en) * 1994-06-03 1996-07-30 Phillips Petroleum Company High activity ethylene selective metallocenes

Also Published As

Publication number Publication date
EP0801079A1 (de) 1997-10-15
ES2134050T3 (es) 1999-09-16
JPH1036421A (ja) 1998-02-10
US5814709A (en) 1998-09-29
DE69700309D1 (de) 1999-08-12
TW334452B (en) 1998-06-21
EP0801079B1 (de) 1999-07-07

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Legal Events

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8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee