DE69630498T2 - Verstärkungsglasfasern und in korrosiver Umgebung beständige Verbundwerkstoffe - Google Patents
Verstärkungsglasfasern und in korrosiver Umgebung beständige Verbundwerkstoffe Download PDFInfo
- Publication number
- DE69630498T2 DE69630498T2 DE69630498T DE69630498T DE69630498T2 DE 69630498 T2 DE69630498 T2 DE 69630498T2 DE 69630498 T DE69630498 T DE 69630498T DE 69630498 T DE69630498 T DE 69630498T DE 69630498 T2 DE69630498 T2 DE 69630498T2
- Authority
- DE
- Germany
- Prior art keywords
- glass fibers
- mixture
- fibers
- weight
- silane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000003365 glass fiber Substances 0.000 title claims description 82
- 239000002131 composite material Substances 0.000 title claims description 37
- 230000003014 reinforcing effect Effects 0.000 title description 5
- 239000000203 mixture Substances 0.000 claims description 89
- 239000000835 fiber Substances 0.000 claims description 61
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 50
- 229910000077 silane Inorganic materials 0.000 claims description 36
- 239000011521 glass Substances 0.000 claims description 29
- 239000000853 adhesive Substances 0.000 claims description 24
- 230000001070 adhesive effect Effects 0.000 claims description 24
- 239000000126 substance Substances 0.000 claims description 21
- 239000011368 organic material Substances 0.000 claims description 18
- 239000003513 alkali Substances 0.000 claims description 17
- 229910010272 inorganic material Inorganic materials 0.000 claims description 13
- 239000011147 inorganic material Substances 0.000 claims description 13
- 239000000463 material Substances 0.000 claims description 13
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 12
- 125000003700 epoxy group Chemical group 0.000 claims description 11
- 230000002787 reinforcement Effects 0.000 claims description 11
- 125000003545 alkoxy group Chemical group 0.000 claims description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 6
- 125000000217 alkyl group Chemical group 0.000 claims description 6
- 229910052799 carbon Inorganic materials 0.000 claims description 6
- 229910052757 nitrogen Inorganic materials 0.000 claims description 6
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 claims description 5
- 125000003277 amino group Chemical group 0.000 claims description 5
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 4
- 150000003007 phosphonic acid derivatives Chemical class 0.000 claims description 4
- 125000001931 aliphatic group Chemical group 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 230000021615 conjugation Effects 0.000 claims description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 2
- 230000032683 aging Effects 0.000 description 26
- 239000004568 cement Substances 0.000 description 20
- 230000006872 improvement Effects 0.000 description 16
- 238000004519 manufacturing process Methods 0.000 description 15
- 238000000034 method Methods 0.000 description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 13
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 11
- 229910004298 SiO 2 Inorganic materials 0.000 description 10
- 239000000243 solution Substances 0.000 description 10
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- 238000005452 bending Methods 0.000 description 9
- 230000007797 corrosion Effects 0.000 description 9
- 238000005260 corrosion Methods 0.000 description 9
- 239000000314 lubricant Substances 0.000 description 9
- 230000035882 stress Effects 0.000 description 9
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 8
- 239000011734 sodium Substances 0.000 description 8
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 230000002378 acidificating effect Effects 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 239000000395 magnesium oxide Substances 0.000 description 6
- 150000004756 silanes Chemical class 0.000 description 6
- 239000011780 sodium chloride Substances 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 239000000470 constituent Substances 0.000 description 5
- -1 hexamethylene diamino Chemical group 0.000 description 5
- 239000004615 ingredient Substances 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 229910010413 TiO 2 Inorganic materials 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 230000006735 deficit Effects 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- 229920001567 vinyl ester resin Polymers 0.000 description 4
- 239000004593 Epoxy Substances 0.000 description 3
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 3
- 229910000272 alkali metal oxide Inorganic materials 0.000 description 3
- 230000008878 coupling Effects 0.000 description 3
- 238000010168 coupling process Methods 0.000 description 3
- 238000005859 coupling reaction Methods 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 229910052731 fluorine Inorganic materials 0.000 description 3
- 239000011737 fluorine Substances 0.000 description 3
- LRDRGASHPNRJHP-UHFFFAOYSA-N n'-benzyl-n-(3-trimethoxysilylpropyl)ethane-1,2-diamine Chemical compound CO[Si](OC)(OC)CCCNCCNCC1=CC=CC=C1 LRDRGASHPNRJHP-UHFFFAOYSA-N 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 229920002689 polyvinyl acetate Polymers 0.000 description 3
- 239000011118 polyvinyl acetate Substances 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 229920001187 thermosetting polymer Polymers 0.000 description 3
- 238000009941 weaving Methods 0.000 description 3
- PLIKAWJENQZMHA-UHFFFAOYSA-N 4-aminophenol Chemical compound NC1=CC=C(O)C=C1 PLIKAWJENQZMHA-UHFFFAOYSA-N 0.000 description 2
- PXKLMJQFEQBVLD-UHFFFAOYSA-N Bisphenol F Natural products C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- 235000011941 Tilia x europaea Nutrition 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000007822 coupling agent Substances 0.000 description 2
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 229960004585 etidronic acid Drugs 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000004571 lime Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000006060 molten glass Substances 0.000 description 2
- 229920003986 novolac Polymers 0.000 description 2
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 2
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 2
- 229920001225 polyester resin Polymers 0.000 description 2
- 239000004645 polyester resin Substances 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 229910001928 zirconium oxide Inorganic materials 0.000 description 2
- PMDHMYFSRFZGIO-UHFFFAOYSA-N 1,4,7-trioxacyclotridecane-8,13-dione Chemical compound O=C1CCCCC(=O)OCCOCCO1 PMDHMYFSRFZGIO-UHFFFAOYSA-N 0.000 description 1
- BQPYFTUMNBOSNC-UHFFFAOYSA-N 2-(9-ethoxynonyl)phenol Chemical compound CCOCCCCCCCCCC1=CC=CC=C1O BQPYFTUMNBOSNC-UHFFFAOYSA-N 0.000 description 1
- HIGURUTWFKYJCH-UHFFFAOYSA-N 2-[[1-(oxiran-2-ylmethoxymethyl)cyclohexyl]methoxymethyl]oxirane Chemical compound C1OC1COCC1(COCC2OC2)CCCCC1 HIGURUTWFKYJCH-UHFFFAOYSA-N 0.000 description 1
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- LCFVJGUPQDGYKZ-UHFFFAOYSA-N Bisphenol A diglycidyl ether Chemical compound C=1C=C(OCC2OC2)C=CC=1C(C)(C)C(C=C1)=CC=C1OCC1CO1 LCFVJGUPQDGYKZ-UHFFFAOYSA-N 0.000 description 1
- MDNTXXADGNHVHA-UHFFFAOYSA-N CCCC.[Na] Chemical compound CCCC.[Na] MDNTXXADGNHVHA-UHFFFAOYSA-N 0.000 description 1
- 229910004261 CaF 2 Inorganic materials 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 229920003341 Epi-rez 3510-W-60 Polymers 0.000 description 1
- OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 1
- 229910018068 Li 2 O Inorganic materials 0.000 description 1
- FOAXWRGUMGFFRO-UHFFFAOYSA-N N'-benzyl-1-[dimethoxy(propyl)silyl]oxypropane-1,3-diamine Chemical compound C(C1=CC=CC=C1)NCCC(O[Si](OC)(OC)CCC)N FOAXWRGUMGFFRO-UHFFFAOYSA-N 0.000 description 1
- FQYUMYWMJTYZTK-UHFFFAOYSA-N Phenyl glycidyl ether Chemical compound C1OC1COC1=CC=CC=C1 FQYUMYWMJTYZTK-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000011398 Portland cement Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 101150107341 RERE gene Proteins 0.000 description 1
- 229910001294 Reinforcing steel Inorganic materials 0.000 description 1
- UKQZSQATELWRIO-UHFFFAOYSA-N [K].C=C.C=C Chemical group [K].C=C.C=C UKQZSQATELWRIO-UHFFFAOYSA-N 0.000 description 1
- YZCLSZPQXZWSCJ-UHFFFAOYSA-L [Na+].[Na+].CCO.[O-]P(=O)OP([O-])=O Chemical compound [Na+].[Na+].CCO.[O-]P(=O)OP([O-])=O YZCLSZPQXZWSCJ-UHFFFAOYSA-L 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical class C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 1
- 238000006664 bond formation reaction Methods 0.000 description 1
- CZBZUDVBLSSABA-UHFFFAOYSA-N butylated hydroxyanisole Chemical compound COC1=CC=C(O)C(C(C)(C)C)=C1.COC1=CC=C(O)C=C1C(C)(C)C CZBZUDVBLSSABA-UHFFFAOYSA-N 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- QAEKNCDIHIGLFI-UHFFFAOYSA-L cobalt(2+);2-ethylhexanoate Chemical compound [Co+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O QAEKNCDIHIGLFI-UHFFFAOYSA-L 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 229930003836 cresol Natural products 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 229940106012 diethylene glycol adipate Drugs 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920006332 epoxy adhesive Polymers 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 239000000374 eutectic mixture Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000011152 fibreglass Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000007849 furan resin Substances 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 210000000056 organ Anatomy 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 150000003009 phosphonic acids Chemical class 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 1
- 235000013824 polyphenols Nutrition 0.000 description 1
- 229920000053 polysorbate 80 Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000012783 reinforcing fiber Substances 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical compound [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 description 1
- XJKVPKYVPCWHFO-UHFFFAOYSA-N silicon;hydrate Chemical compound O.[Si] XJKVPKYVPCWHFO-UHFFFAOYSA-N 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 125000003698 tetramethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/24—Coatings containing organic materials
- C03C25/26—Macromolecular compounds or prepolymers
- C03C25/32—Macromolecular compounds or prepolymers obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
- C03C25/36—Epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/24—Coatings containing organic materials
- C03C25/40—Organo-silicon compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
- C07F7/1804—Compounds having Si-O-C linkages
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2938—Coating on discrete and individual rods, strands or filaments
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2964—Artificial fiber or filament
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Surface Treatment Of Glass Fibres Or Filaments (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Glass Compositions (AREA)
- Laminated Bodies (AREA)
- Adhesives Or Adhesive Processes (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9510316A FR2738241B1 (fr) | 1995-09-01 | 1995-09-01 | Fils de verre de renforcement et composites resistant en milieu corrosif |
| FR9510316 | 1995-09-01 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69630498D1 DE69630498D1 (de) | 2003-12-04 |
| DE69630498T2 true DE69630498T2 (de) | 2004-07-29 |
Family
ID=9482222
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69630498T Expired - Fee Related DE69630498T2 (de) | 1995-09-01 | 1996-08-07 | Verstärkungsglasfasern und in korrosiver Umgebung beständige Verbundwerkstoffe |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US5736246A (show.php) |
| EP (1) | EP0761619B1 (show.php) |
| JP (1) | JPH09142893A (show.php) |
| KR (1) | KR100472153B1 (show.php) |
| CN (1) | CN1124240C (show.php) |
| BR (1) | BR9603625A (show.php) |
| CA (1) | CA2184438A1 (show.php) |
| CZ (1) | CZ294592B6 (show.php) |
| DE (1) | DE69630498T2 (show.php) |
| ES (1) | ES2210343T3 (show.php) |
| FR (1) | FR2738241B1 (show.php) |
| IN (1) | IN189369B (show.php) |
| NO (1) | NO319149B1 (show.php) |
| RU (1) | RU2168471C2 (show.php) |
| SK (1) | SK284278B6 (show.php) |
| TR (1) | TR199600696A2 (show.php) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2809389B1 (fr) * | 2000-05-24 | 2002-10-25 | Vetrotex France Sa | Composition d'ensimage pour fils de verre, ces fils et leur utilisation dans des produits cimentaires |
| FR2823510B1 (fr) * | 2001-04-11 | 2003-06-06 | Saint Gobain Vetrotex | Procede, installation de fabrication de mats et utilisation associee |
| US7141284B2 (en) * | 2002-03-20 | 2006-11-28 | Saint-Gobain Technical Fabrics Canada, Ltd. | Drywall tape and joint |
| FR2837818B1 (fr) * | 2002-03-29 | 2005-02-11 | Saint Gobain Vetrotex | Fils de verre de renforcement et composites resistant en milieu corrosif |
| US7311964B2 (en) * | 2002-07-30 | 2007-12-25 | Saint-Gobain Technical Fabrics Canada, Ltd. | Inorganic matrix-fabric system and method |
| US20070036973A1 (en) * | 2005-08-11 | 2007-02-15 | Bruner Eric L | Composition for treating glass fibers and treated glass fibers |
| KR20080083689A (ko) * | 2005-12-30 | 2008-09-18 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 세라믹 옥사이드 섬유 |
| DE102007036774B4 (de) | 2007-08-03 | 2012-08-16 | S.D.R. Biotec Verwaltungs GmbH | Thermischbeständige Glasfasern, Verfahren zu deren Beschlichtung und Verwendung |
| FR2920763B1 (fr) * | 2007-09-06 | 2011-04-01 | Saint Gobain Technical Fabrics | Composition d'ensimage sous forme de gel physique pour fils de verre, fils de verre obtenus et composites comprenant lesdits fils. |
| US20110230615A1 (en) * | 2007-11-08 | 2011-09-22 | Van Der Woude Jacobus Hendricus Antonius | Fiber Glass Strands And Reinforced Products Comprising The Same |
| JP5449182B2 (ja) * | 2007-11-08 | 2014-03-19 | ピーピージー・インダストリーズ・オハイオ・インコーポレイテッド | ガラス繊維用のサイジング組成物、サイズ剤処理されたガラス繊維、およびこれらを含む強化された生成物 |
| TW200925344A (en) * | 2007-12-12 | 2009-06-16 | Everest Textile Co Ltd | Electric heating fabric device |
| HUE046253T2 (hu) * | 2010-06-30 | 2020-02-28 | Toray Industries | Eljárás írezõszerrel bevont karbonszálak elõállítására és írezõszerrel bevont karbonszálak |
| EP2583953A1 (en) * | 2011-10-20 | 2013-04-24 | 3B-Fibreglass SPRL | Sizing composition for glass fibres |
| EP3130633A1 (de) | 2015-08-13 | 2017-02-15 | Basf Se | Polyamide mit guter mechanik und schwindung |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1290528A (show.php) * | 1969-07-28 | 1972-09-27 | ||
| CA1101743A (en) * | 1974-05-24 | 1981-05-26 | Kevin M. Foley | Organo silane coupling agents |
| US3956353A (en) * | 1974-07-15 | 1976-05-11 | Dow Corning Corporation | Anionic coupling agents |
| JPS5214649A (en) * | 1975-07-25 | 1977-02-03 | Yoshizaki Kozo | Fiber-reinforced nitrillic thermo-plastic resin composition |
| AU1664876A (en) * | 1975-08-11 | 1978-02-09 | Du Pont | Caustic-resistant polymer coatings for glass |
| US4341877A (en) * | 1980-06-04 | 1982-07-27 | Ppg Industries, Inc. | Sizing composition and sized glass fibers and process |
| US4370157A (en) * | 1981-03-09 | 1983-01-25 | Ppg Industries, Inc. | Stable sizing compositions used during forming of glass fibers and resulting fiber |
| DD284216A5 (de) * | 1987-07-01 | 1990-11-07 | ������@��������@�������������@�������@����k�� | Schlichte zur behandlung von glasfasern |
| JPH01197568A (ja) * | 1988-02-01 | 1989-08-09 | Chisso Corp | プライマー |
| JPH01238592A (ja) * | 1988-03-18 | 1989-09-22 | Asahi Shiyueebell Kk | 新規シラン化合物及びそれを含有する紫外線吸収剤 |
| SU1606482A1 (ru) * | 1988-06-17 | 1990-11-15 | Всесоюзный Научно-Исследовательский Государственный Институт Стекла | Замасливатель дл стекл нного волокна |
| AU628146B2 (en) * | 1990-03-29 | 1992-09-10 | Basf Corporation | Room-temperature, moisture-curable, primerless, polyurethane-based adhesive composition and method |
| GB9008423D0 (en) * | 1990-04-12 | 1990-06-13 | Albright & Wilson | Treatment of fabrics |
| JPH0625973A (ja) * | 1992-07-06 | 1994-02-01 | Hitachi Chem Co Ltd | 無機質繊維基材及びエポキシ樹脂プリプレグ |
-
1995
- 1995-09-01 FR FR9510316A patent/FR2738241B1/fr not_active Expired - Fee Related
-
1996
- 1996-08-06 IN IN1411CA1996 patent/IN189369B/en unknown
- 1996-08-07 EP EP96401742A patent/EP0761619B1/fr not_active Expired - Lifetime
- 1996-08-07 DE DE69630498T patent/DE69630498T2/de not_active Expired - Fee Related
- 1996-08-07 ES ES96401742T patent/ES2210343T3/es not_active Expired - Lifetime
- 1996-08-22 CZ CZ19962488A patent/CZ294592B6/cs not_active IP Right Cessation
- 1996-08-22 SK SK1087-96A patent/SK284278B6/sk unknown
- 1996-08-29 TR TR96/00696A patent/TR199600696A2/xx unknown
- 1996-08-29 US US08/705,683 patent/US5736246A/en not_active Expired - Fee Related
- 1996-08-29 NO NO19963608A patent/NO319149B1/no unknown
- 1996-08-29 CA CA002184438A patent/CA2184438A1/fr not_active Abandoned
- 1996-08-29 JP JP8228608A patent/JPH09142893A/ja not_active Withdrawn
- 1996-08-30 BR BR9603625A patent/BR9603625A/pt not_active IP Right Cessation
- 1996-08-30 RU RU96118037/03A patent/RU2168471C2/ru not_active IP Right Cessation
- 1996-08-31 CN CN96113312A patent/CN1124240C/zh not_active Expired - Fee Related
- 1996-08-31 KR KR1019960037399A patent/KR100472153B1/ko not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| DE69630498D1 (de) | 2003-12-04 |
| IN189369B (show.php) | 2003-02-15 |
| CN1124240C (zh) | 2003-10-15 |
| KR100472153B1 (ko) | 2005-08-17 |
| FR2738241B1 (fr) | 1998-03-20 |
| JPH09142893A (ja) | 1997-06-03 |
| CA2184438A1 (fr) | 1997-03-02 |
| EP0761619A1 (fr) | 1997-03-12 |
| TR199600696A2 (tr) | 1997-03-21 |
| CZ248896A3 (en) | 1997-06-11 |
| FR2738241A1 (fr) | 1997-03-07 |
| US5736246A (en) | 1998-04-07 |
| BR9603625A (pt) | 1998-05-19 |
| NO319149B1 (no) | 2005-06-27 |
| NO963608L (no) | 1997-03-03 |
| KR970015511A (ko) | 1997-04-28 |
| SK108796A3 (en) | 1997-05-07 |
| CN1149561A (zh) | 1997-05-14 |
| NO963608D0 (no) | 1996-08-29 |
| ES2210343T3 (es) | 2004-07-01 |
| CZ294592B6 (cs) | 2005-02-16 |
| EP0761619B1 (fr) | 2003-10-29 |
| SK284278B6 (sk) | 2004-12-01 |
| RU2168471C2 (ru) | 2001-06-10 |
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