DE69401024D1 - Verfahren und Anlage für die thermische Behandlung von Vorformkörpern oder eines Zwischenbehälters aus thermoplastischem Material - Google Patents

Verfahren und Anlage für die thermische Behandlung von Vorformkörpern oder eines Zwischenbehälters aus thermoplastischem Material

Info

Publication number
DE69401024D1
DE69401024D1 DE69401024T DE69401024T DE69401024D1 DE 69401024 D1 DE69401024 D1 DE 69401024D1 DE 69401024 T DE69401024 T DE 69401024T DE 69401024 T DE69401024 T DE 69401024T DE 69401024 D1 DE69401024 D1 DE 69401024D1
Authority
DE
Germany
Prior art keywords
thermoplastic material
container made
preforms
plant
intermediate container
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69401024T
Other languages
English (en)
Other versions
DE69401024T2 (de
Inventor
Gerard Emmer
Barre Paul La
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sidel SA
Original Assignee
Sidel SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sidel SA filed Critical Sidel SA
Application granted granted Critical
Publication of DE69401024D1 publication Critical patent/DE69401024D1/de
Publication of DE69401024T2 publication Critical patent/DE69401024T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
    • B29C49/42—Component parts, details or accessories; Auxiliary operations
    • B29C49/64—Heating or cooling preforms, parisons or blown articles
    • B29C49/6409—Thermal conditioning of preforms
    • B29C49/6436—Thermal conditioning of preforms characterised by temperature differential
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
    • B29C49/42—Component parts, details or accessories; Auxiliary operations
    • B29C49/64—Heating or cooling preforms, parisons or blown articles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
    • B29C49/42—Component parts, details or accessories; Auxiliary operations
    • B29C49/64—Heating or cooling preforms, parisons or blown articles
    • B29C49/6409—Thermal conditioning of preforms
    • B29C49/6436—Thermal conditioning of preforms characterised by temperature differential
    • B29C49/6445—Thermal conditioning of preforms characterised by temperature differential through the preform length
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
    • B29C49/42—Component parts, details or accessories; Auxiliary operations
    • B29C49/64—Heating or cooling preforms, parisons or blown articles
    • B29C49/68—Ovens specially adapted for heating preforms or parisons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2949/00—Indexing scheme relating to blow-moulding
    • B29C2949/07—Preforms or parisons characterised by their configuration
    • B29C2949/0715—Preforms or parisons characterised by their configuration the preform having one end closed
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
    • B29C49/02—Combined blow-moulding and manufacture of the preform or the parison
    • B29C49/06—Injection blow-moulding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
    • B29C49/42—Component parts, details or accessories; Auxiliary operations
    • B29C49/64—Heating or cooling preforms, parisons or blown articles
    • B29C49/6409—Thermal conditioning of preforms
    • B29C49/6436—Thermal conditioning of preforms characterised by temperature differential
    • B29C49/6458—Thermal conditioning of preforms characterised by temperature differential tangentially, i.e. along circumference
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
    • B29C49/42—Component parts, details or accessories; Auxiliary operations
    • B29C49/64—Heating or cooling preforms, parisons or blown articles
    • B29C49/6409—Thermal conditioning of preforms
    • B29C49/6436—Thermal conditioning of preforms characterised by temperature differential
    • B29C49/6462—Thermal conditioning of preforms characterised by temperature differential by masking
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
    • B29C49/42—Component parts, details or accessories; Auxiliary operations
    • B29C49/64—Heating or cooling preforms, parisons or blown articles
    • B29C49/68—Ovens specially adapted for heating preforms or parisons
    • B29C49/6835—Ovens specially adapted for heating preforms or parisons using reflectors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
    • B29C49/42—Component parts, details or accessories; Auxiliary operations
    • B29C49/64—Heating or cooling preforms, parisons or blown articles
    • B29C49/68—Ovens specially adapted for heating preforms or parisons
    • B29C49/684—Ovens specially adapted for heating preforms or parisons using masking
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
    • B29K2995/0037—Other properties
    • B29K2995/0094—Geometrical properties
    • B29K2995/0097—Thickness
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00—Other particular articles
    • B29L2031/712—Containers; Packaging elements or accessories, Packages
    • B29L2031/7158—Bottles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D2501/00—Containers having bodies formed in one piece
    • B65D2501/0009—Bottles or similar containers with necks or like restricted apertures designed for pouring contents
    • B65D2501/0081—Bottles of non-circular cross-section
DE69401024T 1993-04-15 1994-04-13 Verfahren und Anlage für die thermische Behandlung von Vorformkörpern oder eines Zwischenbehälters aus thermoplastischem Material Expired - Lifetime DE69401024T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR9304447A FR2703944B1 (fr) 1993-04-15 1993-04-15 Procédé et installation pour le traitement thermique du corps d'une préforme en matériau thermoplastique.

Publications (2)

Publication Number Publication Date
DE69401024D1 true DE69401024D1 (de) 1997-01-16
DE69401024T2 DE69401024T2 (de) 1997-05-15

Family

ID=9446106

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69401024T Expired - Lifetime DE69401024T2 (de) 1993-04-15 1994-04-13 Verfahren und Anlage für die thermische Behandlung von Vorformkörpern oder eines Zwischenbehälters aus thermoplastischem Material

Country Status (15)

Country Link
US (2) US5681521A (de)
EP (1) EP0620099B1 (de)
JP (1) JP2569292B2 (de)
KR (1) KR100308342B1 (de)
CN (1) CN1051276C (de)
AT (1) ATE145855T1 (de)
AU (1) AU675839B2 (de)
BR (1) BR9406172A (de)
CA (1) CA2160541C (de)
DE (1) DE69401024T2 (de)
DK (1) DK0620099T3 (de)
ES (1) ES2095136T3 (de)
FR (1) FR2703944B1 (de)
GR (1) GR3022056T3 (de)
WO (1) WO1994023932A1 (de)

Families Citing this family (59)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2703944B1 (fr) * 1993-04-15 1995-06-23 Sidel Sa Procédé et installation pour le traitement thermique du corps d'une préforme en matériau thermoplastique.
IT1282433B1 (it) * 1995-10-02 1998-03-23 Sipa Spa Procedimento ed apparato monostadio per la produzione di contenitori in resina termoplastica
DE19608570A1 (de) 1996-03-06 1997-09-11 Krupp Corpoplast Masch Verfahren zur Temperierung von Vorformlingen sowie Vorrichtung zur Temperierung
DE19647260B4 (de) * 1996-11-15 2007-08-02 Beiersdorf Ag Behältnis und Verfahren zu seiner Herstellung
US5853775A (en) * 1997-12-05 1998-12-29 Electra Form, Inc. Non-Round container blow molding apparatus
DE19757818A1 (de) * 1997-12-24 1999-07-01 Krupp Corpoplast Masch Verfahren zur Temperierung von Vorformlingen sowie Vorrichtung zur Temperierung
US6361301B1 (en) 2000-02-21 2002-03-26 Plastipak Packaging, Inc. Heater assembly for blow molding plastic preforms
DE10012765A1 (de) * 2000-03-16 2001-09-20 Krupp Corpoplast Maschb Gmbh Verfahren zur Temperierung von Vorformlingen sowie Vorrichtung zur Temperierung
JP2002166916A (ja) * 2000-11-29 2002-06-11 Yoshino Kogyosho Co Ltd 合成樹脂製２軸延伸ブロー成形軽量壜体容器及びその製造方法
ITPN20010009A1 (it) * 2001-02-07 2002-08-07 Sipa Spa Procedimento per la produzione di contenitori in pet con bocca fuoricentro
US6696010B2 (en) * 2002-01-15 2004-02-24 Plastipak Packaging, Inc. Method and apparatus for forming blow molded plastic container with inclined mouth
US6888103B2 (en) 2002-05-30 2005-05-03 Ball Corporation Preform preheater
FR2871403B1 (fr) * 2004-06-15 2007-11-23 Sidel Sas Circuit de refroidissement perfectionne pour un four a preformes et procede de mise en oeuvre d'un tel circuit
FR2878185B1 (fr) 2004-11-22 2008-11-07 Sidel Sas Procede de fabrication de recipients comprenant une etape de chauffe au moyen d'un faisceau de rayonnement electromagnetique coherent
US7637733B2 (en) * 2004-12-02 2009-12-29 Graham Packaging Company, L.P. Method and apparatus for reforming a portion of a plastic container to include a three-dimensional feature or transferable element
US10857722B2 (en) 2004-12-03 2020-12-08 Pressco Ip Llc Method and system for laser-based, wavelength specific infrared irradiation treatment
US7425296B2 (en) 2004-12-03 2008-09-16 Pressco Technology Inc. Method and system for wavelength specific thermal irradiation and treatment
US20070042074A1 (en) * 2005-08-19 2007-02-22 Husky Injection Molding Systems Ltd. Apparatus & molding system for rotating molded articles
US20070126152A1 (en) * 2005-12-06 2007-06-07 Graham Packaging Company, L.P. Methods and apparatuses for reforming an upper portion of a blow molded plastic container
FR2907684B1 (fr) 2006-10-26 2009-12-04 Sidel Participations Procede de sterilisation d'une preforme, installation et four pour la fabrication de recipients steriles selon ce procede.
JP4831342B2 (ja) * 2006-12-08 2011-12-07 東洋製罐株式会社 プリフォーム加熱システム
FR2910329B1 (fr) 2006-12-20 2009-04-17 Sidel Participations Procede et dispositif de sterilisation de preformes
FR2913210B1 (fr) 2007-03-02 2009-05-29 Sidel Participations Perfectionnements a la chauffe des matieres plastiques par rayonnement infrarouge
US20080220114A1 (en) * 2007-03-05 2008-09-11 R & D Tool & Engineering Co. Method and apparatus for conditioning preforms in an injection stretch blow mold machine
FR2915418B1 (fr) 2007-04-25 2012-11-16 Sidel Participations Procede de chauffe d'ebauches pour la fabrication de recipients
FR2915475B1 (fr) 2007-04-30 2009-07-31 Sidel Participations Dispositif de transfert et installation de type lineaire pour la fabrication de recipients
FR2917005B1 (fr) 2007-06-11 2009-08-28 Sidel Participations Installation de chauffage des corps de preformes pour le soufflage de recipients
FR2934196A1 (fr) * 2008-07-28 2010-01-29 Sidel Participations Four de conditionnement thermique de preformes en matiere thermoplastique de construction modulaire
PL2416938T3 (pl) 2009-04-07 2015-03-31 Graham Packaging Co Sposób i urzadzenie do wtórnego kształtowania fragmentu pojemnika z tworzywa sztucznego z wykorzystaniem ogrzewania indukcyjnego
US8734709B2 (en) 2009-04-07 2014-05-27 Graham Packaging Company, L.P. Apparatus for reforming a portion of a plastic container
DE102009040559A1 (de) * 2009-09-08 2011-03-10 Krones Ag Verfahren und Vorrichtung zum Blasformen von Behältern
FR2960816B1 (fr) 2010-06-02 2012-07-13 Sidel Participations Four pour le conditionnement thermique de preformes et procede de commande d'un dispositif de refroidissement par air equipant un tel four
FR2964951B1 (fr) 2010-09-20 2013-08-09 Sidel Participations Recipient a portion annulaire cintree surepaissie.
FR2964901B1 (fr) 2010-09-20 2012-10-26 Sidel Participations Procede de formage d'un recipient par chauffe laser selective et soufflage libre.
FR2976842B1 (fr) 2011-06-23 2013-07-19 Sidel Participations Procede et machine de fabrication de recipients permettant une modification d'une cadence de chauffe
FR3003505B1 (fr) * 2013-03-19 2015-03-27 Sidel Participations "procede de realisation d'un recipient a partir d'une preforme comportant une portion a surchauffer comportant une couche de materiau susceptible d'etre surchauffe selectivement"
EP2813344B1 (de) * 2013-06-10 2016-11-16 Discma AG Vorrichtung und Verfahren zur Herstellung von Behältern
WO2014203975A1 (ja) 2013-06-21 2014-12-24 日精エー・エス・ビー機械株式会社 搬送装置
WO2015116549A1 (en) * 2014-01-28 2015-08-06 Gojo Industries, Inc. Apparatus and method for preheating two stage preforms
FR3028204B1 (fr) 2014-11-10 2017-04-21 Sidel Participations "installation de fabrication de recipients en matiere thermoplastique integrant un dispositif de broyage et un tel dispositif de broyage"
DE102015005769A1 (de) * 2015-05-08 2016-11-10 Henkel Ag & Co. Kgaa Verfahren zur inhomogenen Temperierung von Vorformlingen
FR3045446B1 (fr) * 2015-12-16 2018-01-12 Sidel Participations Indexation angulaire d'une preforme chauffee non uniformement par mesure de temperature
DE102016001755A1 (de) 2016-02-16 2017-08-17 Khs Corpoplast Gmbh Zangenanordnung für die Handhabung von Vorformlingen und Transferrad und Behälterbehandlungsmaschine mit einer solchen Zangenanordnung
FR3049489B1 (fr) * 2016-04-05 2018-04-13 Sidel Participations Procede de chauffe preferentielle d'un corps creux comportant une etape de marquage
DE102016004405B4 (de) 2016-04-14 2019-02-14 Khs Corpoplast Gmbh Heizvorrichtung und Verfahren zur thermischen Konditionierung von für die Blasformung vorgesehenen Vorformlingen
DE102016005272B4 (de) 2016-04-29 2020-03-12 Khs Corpoplast Gmbh Heizvorrichtung zur thermischen Konditionierung von für die Blasformung vorgesehenen Vorformlingen
FR3051675B1 (fr) 2016-05-25 2019-09-27 Sidel Participations Procede de traitement de corps creux et installation de fabrication de recipients integrant un tel procede
JP6907754B2 (ja) 2017-06-23 2021-07-21 大日本印刷株式会社 プリフォームの加熱装置及びプリフォームの加熱方法
FR3062643B1 (fr) 2017-08-04 2020-02-28 Sidel Participations Dispositif de transport tournant pour un corps creux
FR3070299B1 (fr) * 2017-08-28 2019-08-16 Sidel Participations Procede et unite de conditionnement thermique, qui comprend des emetteurs a allumage et extinction progressifs
DE102017011087A1 (de) 2017-11-30 2019-06-06 Khs Corpoplast Gmbh Verfahren und Vorrichtung für die Herstellung von gefüllten Behältern aus temperaturkonditionierten Vorformlingen
FR3080319B1 (fr) 2018-04-20 2022-01-07 Sidel Participations Procede de transport et dispositif de transport de type rotatif pour des preformes en matiere thermoplastique
CN111251492B (zh) * 2018-12-03 2021-12-28 宁波优禾新材料科技有限公司 色母粒生产过程中的风冷设备
FR3090603B1 (fr) 2018-12-19 2020-11-27 Sidel Participations « Dispositif de convoyage de préformes et procédé de commande d’un tel dispositif pour indexer angulairement les préformes dans une position de référence »
FR3090457A1 (fr) 2018-12-19 2020-06-26 Sidel Participations Procédé et système de traitement d’un flux de préformes en matière thermoplastique pour en orienter angulairement chacune des préformes dans une position de référence.
FR3094663A1 (fr) * 2019-04-04 2020-10-09 Sidel Participations Procédé d’orientation d’une préforme
DE102022100090A1 (de) 2022-01-04 2023-07-06 Khs Gmbh Heizverfahren und Heizvorrichtung zur thermischen Konditionierung von Vorformlingen mit temperaturausgezeichneten Umfangsbereichen (preferential heating)
WO2023204262A1 (ja) * 2022-04-21 2023-10-26 日精エー・エス・ビー機械株式会社 樹脂製容器の製造方法および製造装置
DE102022109966A1 (de) 2022-04-26 2023-10-26 Khs Gmbh Heizverfahren und Heizvorrichtung zur thermischen Konditionierung von Vorformlingen, sowie Behälterherstellungsmaschine für die Umformung von Vorformlingen mit einer Heizvorrichtung

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JPH0761675B2 (ja) * 1990-06-18 1995-07-05 凸版印刷株式会社 プラスチックボトルの製造方法
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US5853775A (en) * 1997-12-05 1998-12-29 Electra Form, Inc. Non-Round container blow molding apparatus

Also Published As

Publication number Publication date
FR2703944A1 (fr) 1994-10-21
JP2569292B2 (ja) 1997-01-08
WO1994023932A1 (fr) 1994-10-27
DK0620099T3 (da) 1997-06-02
AU675839B2 (en) 1997-02-20
CA2160541C (en) 1998-12-15
CN1120825A (zh) 1996-04-17
GR3022056T3 (en) 1997-03-31
EP0620099B1 (de) 1996-12-04
FR2703944B1 (fr) 1995-06-23
DE69401024T2 (de) 1997-05-15
KR960702377A (ko) 1996-04-27
US6113840A (en) 2000-09-05
EP0620099A1 (de) 1994-10-19
BR9406172A (pt) 1996-01-09
US5681521A (en) 1997-10-28
ES2095136T3 (es) 1997-02-01
CA2160541A1 (en) 1994-10-27
AU6571794A (en) 1994-11-08
ATE145855T1 (de) 1996-12-15
KR100308342B1 (ko) 2001-12-17
JPH08504699A (ja) 1996-05-21
CN1051276C (zh) 2000-04-12

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