DE69322139T2 - Katalysator und Verfahren zur Olefinpolymerisation - Google Patents

Katalysator und Verfahren zur Olefinpolymerisation

Info

Publication number
DE69322139T2
DE69322139T2 DE69322139T DE69322139T DE69322139T2 DE 69322139 T2 DE69322139 T2 DE 69322139T2 DE 69322139 T DE69322139 T DE 69322139T DE 69322139 T DE69322139 T DE 69322139T DE 69322139 T2 DE69322139 T2 DE 69322139T2
Authority
DE
Germany
Prior art keywords
radical
tetrakis
borate
aluminate
bis
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69322139T
Other languages
German (de)
English (en)
Other versions
DE69322139D1 (de
Inventor
Satoru Mie-Gun Mie-Ken Yamada
Akihiro Yokkaichi-Shi Mie-Ken Yano
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tosoh Corp
Original Assignee
Tosoh Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP22649792A external-priority patent/JPH0649122A/ja
Priority claimed from JP23511692A external-priority patent/JPH0656927A/ja
Application filed by Tosoh Corp filed Critical Tosoh Corp
Application granted granted Critical
Publication of DE69322139D1 publication Critical patent/DE69322139D1/de
Publication of DE69322139T2 publication Critical patent/DE69322139T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
DE69322139T 1992-08-04 1993-08-03 Katalysator und Verfahren zur Olefinpolymerisation Expired - Fee Related DE69322139T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP22649792A JPH0649122A (ja) 1992-08-04 1992-08-04 オレフィン重合用触媒およびオレフィンの重合方法
JP23511692A JPH0656927A (ja) 1992-08-12 1992-08-12 オレフィン重合用触媒及びオレフィンの重合方法
JP32667392 1992-12-07

Publications (2)

Publication Number Publication Date
DE69322139D1 DE69322139D1 (de) 1998-12-24
DE69322139T2 true DE69322139T2 (de) 1999-05-06

Family

ID=27331176

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69322139T Expired - Fee Related DE69322139T2 (de) 1992-08-04 1993-08-03 Katalysator und Verfahren zur Olefinpolymerisation

Country Status (5)

Country Link
US (1) US5407882A (enExample)
EP (1) EP0582268B1 (enExample)
KR (1) KR100292158B1 (enExample)
CA (1) CA2101805A1 (enExample)
DE (1) DE69322139T2 (enExample)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5763549A (en) * 1989-10-10 1998-06-09 Fina Technology, Inc. Cationic metallocene catalysts based on organoaluminum anions
JPH06100614A (ja) * 1992-08-06 1994-04-12 Mitsui Petrochem Ind Ltd オレフィン重合用触媒およびこれを用いるオレフィンの重合方法
US5817590A (en) * 1993-10-14 1998-10-06 Tosoh Corporation Catalyst for αE --olefin polymerization containing a Lewis base
US5576259A (en) * 1993-10-14 1996-11-19 Tosoh Corporation Process for producing α-olefin polymer
TW369547B (en) * 1994-09-21 1999-09-11 Mitsui Chemicals Inc Olefin polymerization catalyst and process for olefin polymerization
EP1063244A3 (en) * 1995-12-19 2003-11-26 ExxonMobil Chemical Patents Inc. High temperature olefin polymerization process
EP0927201B1 (en) * 1996-09-06 2004-04-14 Hyundai Petrochemical Co., Ltd. Catalyst system for (co)polymerization of olefins and process for the preparation of olefin (co)polymers using the catalyst system
US5895771A (en) * 1997-06-05 1999-04-20 Akzo Nobel Nv Fluorinated alkoxy and/or aryloxy aluminates as cocatalysts for metallocene-catalyzed olefin polymerizations
AU743376B2 (en) 1998-06-12 2002-01-24 Univation Technologies Llc Olefin polymerization process using activated lewis acid-base complexes
WO2000004058A1 (en) * 1998-07-16 2000-01-27 Univation Technologies Llc Aluminum-based lewis acid cocatalysts for olefin polymerization
ATE222257T1 (de) * 1998-08-11 2002-08-15 Dow Chemical Co Katalysatoraktivatorverbindung
DE69904603T2 (de) * 1998-08-11 2003-10-09 Dow Global Technologies, Inc. Ansa gruppe-4-metall bis(.mu.-aluminium) -substituierte metallocene
EP1104429B1 (en) * 1998-08-11 2002-05-08 The Dow Chemical Company Ansa group-4-metal bis (.mu.-substituted) aluminum complexes
ATE284422T1 (de) 1998-10-23 2004-12-15 Exxon Chemical Patents Inc Verbrückte metallocene zur olefincopolymerisation
ES2290309T3 (es) 2001-06-13 2008-02-16 Beta Technologie Ag Reactores de polimerizacion en masa y metodos de polimerizacion.
GB0220681D0 (en) 2002-09-05 2002-10-16 Borealis Tech Oy Process
KR101584350B1 (ko) * 2013-04-08 2016-01-13 한화케미칼 주식회사 대전 방지제를 포함하는 메탈로센 촉매 시스템 및 이를 이용한 폴리올레핀의 제조 방법
EP3774934A1 (en) 2018-03-30 2021-02-17 Dow Global Technologies LLC Highly soluble bis-borate as binuclear co-catalysts for olefin polymerizations
SG11202008655RA (en) 2018-03-30 2020-10-29 Dow Global Technologies Llc Highly soluble alkyl substituted carbenium borate as co-catalysts for olefin polymerizations

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IL85097A (en) * 1987-01-30 1992-02-16 Exxon Chemical Patents Inc Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes
PL276385A1 (en) * 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
US5241025A (en) * 1987-01-30 1993-08-31 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US5122491A (en) * 1987-04-20 1992-06-16 Mitsui Petrochemical Industries, Ltd. Catalyst for polymerizing an olefin and process for polymerizing an olefin
DE69107006T2 (de) * 1990-10-17 1995-09-21 Idemitsu Kosan Co Verfahren zur Herstellung von Oligomeren auf Basis von Propylen.
US5369196A (en) * 1990-11-30 1994-11-29 Idemitsu Kosan Co., Ltd. Production process of olefin based polymers

Also Published As

Publication number Publication date
KR940005677A (ko) 1994-03-22
EP0582268A3 (enExample) 1994-03-16
KR100292158B1 (ko) 2001-06-01
EP0582268B1 (en) 1998-11-18
DE69322139D1 (de) 1998-12-24
US5407882A (en) 1995-04-18
EP0582268A2 (en) 1994-02-09
CA2101805A1 (en) 1994-02-05

Similar Documents

Publication Publication Date Title
DE69322139T2 (de) Katalysator und Verfahren zur Olefinpolymerisation
DE69412047T2 (de) Olefinpolymerisationkatalysator und Verfahren zur Olefinpolymerisation
DE69130320T2 (de) Katalysator für alpha-olefinpolymerisation und herstellung von poly(alpha)olefinen damit
DE69307015T2 (de) Katalysatoren und Verfahren zur Herstellung von Olefinpolymeren
DE69321877T2 (de) Verfahren zur Herstellung eines katalytischen Systems, Verfahren zur Olefin(Ko)polymerisation und (Ko)polymere von mindestens einem Olefin
DE69501977T2 (de) Verfahren zur Verwendung eines geträgerten Metallocenkatalysator
DE69600892T2 (de) Katalysatoren für Olefinpolymerisation und Verfahren zur Herstellung von damit erhaltenen Olefinpolymeren
DE69805600T2 (de) Neues aktivatorsystem für metallocenverbindungen
DE69611554T2 (de) Katalysator für die Polymerisation von Olefinen und Verfahren zur Herstellung von Olefinpolymerisaten
DE69502028T2 (de) Katalytische zusammensetzung und verfahren zur olefinpolymerisation
DE69219699T2 (de) Olefinpolymerisationskatalysator
DE69520450T2 (de) Verfahren zur Herstellung von Polyolefinen in Gegenwart von Katalysatorsystemen sowie Katalysatorsysteme, die Azametallocene enthalten
EP0574370B1 (en) Metallocene catalyst component with good catalyst efficiency after aging
DE69407094T2 (de) Katalysator und Verfahren zur Olefinpolymerisation
US5770663A (en) Metallocene preparation and use
EP0942938B1 (de) Geträgertes katalysatorsystem, verfahren zu seiner herstellung und seine verwendung zur polymerisation von olefinen
US5387568A (en) Preparation of metallocene catalysts for polymerization of olefins
DE69325782T2 (de) Katalysator Komponente für die Polymerisation von Olefinen und deren Verwendung
DE69406693T2 (de) Verfahren zur Herstellung von Ethylen/Alpha-Olefin Copolymeren
DE69026907T2 (de) Metallocenkatalysator mit Lewissäure und Alkylaluminium
DE69313354T2 (de) Verfahren zur Herstellung von einem Ethylencopolymeren
EP0646604B1 (de) Verfahren zur Olefinpolymerisation
DE69502561T2 (de) Katalysator zur Olefinpolymerisation und Verfahren zur Olefinpolymerisation
DE69310101T2 (de) Katalysator für Olefinpolymerisation und Verfahren für Olefinpolymerisation unter Anwendung desselben
DE69319837T2 (de) Cyclopentadienylgruppe enthaltende Alpha-Olefin-Polymerisationskatalysatoren auf Basis von Chrom und Verfahren zur Polymerisation von Alpha-Olefinen

Legal Events

Date Code Title Description
8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee