DE69228967T2 - Verfahren zur Herstellung einer verbrückten Metallocenverbindung und einer Katalysatorkomponente sowie Verfahren für die Polymerisation von Olefinen - Google Patents

Verfahren zur Herstellung einer verbrückten Metallocenverbindung und einer Katalysatorkomponente sowie Verfahren für die Polymerisation von Olefinen

Info

Publication number
DE69228967T2
DE69228967T2 DE69228967T DE69228967T DE69228967T2 DE 69228967 T2 DE69228967 T2 DE 69228967T2 DE 69228967 T DE69228967 T DE 69228967T DE 69228967 T DE69228967 T DE 69228967T DE 69228967 T2 DE69228967 T2 DE 69228967T2
Authority
DE
Germany
Prior art keywords
olefins
polymerization
metallocene compound
bridged
bridged metallocene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69228967T
Other languages
English (en)
Other versions
DE69228967D1 (de
DE69228967T3 (de
Inventor
Johannus Antonius Maria V Beek
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Koninklijke DSM NV
Original Assignee
DSM NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=19859670&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=DE69228967(T2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by DSM NV filed Critical DSM NV
Publication of DE69228967D1 publication Critical patent/DE69228967D1/de
Application granted granted Critical
Publication of DE69228967T2 publication Critical patent/DE69228967T2/de
Publication of DE69228967T3 publication Critical patent/DE69228967T3/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C07F17/02—Metallocenes of metals of Groups 8, 9 or 10 of the Periodic System
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
DE69228967T 1991-09-06 1992-09-01 Verfahren zur Herstellung einer verbrückten Metallocenverbindung und einer Katalysatorkomponente sowie Verfahren für die Polymerisation von Olefinen Expired - Fee Related DE69228967T3 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
NL9101502A NL9101502A (nl) 1991-09-06 1991-09-06 Werkwijze voor het bereiden van een gebrugde metalloceenverbinding alsmede een katalysatorcomponent en een werkwijze voor de polymerisatie van een olefinen.
NL9101502 1991-09-06

Publications (3)

Publication Number Publication Date
DE69228967D1 DE69228967D1 (de) 1999-05-27
DE69228967T2 true DE69228967T2 (de) 1999-12-16
DE69228967T3 DE69228967T3 (de) 2004-07-22

Family

ID=19859670

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69228967T Expired - Fee Related DE69228967T3 (de) 1991-09-06 1992-09-01 Verfahren zur Herstellung einer verbrückten Metallocenverbindung und einer Katalysatorkomponente sowie Verfahren für die Polymerisation von Olefinen

Country Status (11)

Country Link
US (1) US5646083A (de)
EP (1) EP0530908B2 (de)
JP (1) JP3249192B2 (de)
CN (2) CN1070650A (de)
AT (1) ATE179177T1 (de)
CA (1) CA2077613C (de)
DE (1) DE69228967T3 (de)
ES (1) ES2131058T5 (de)
MX (1) MX9205050A (de)
NL (1) NL9101502A (de)
RU (1) RU2095364C1 (de)

Families Citing this family (57)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
USRE37573E1 (en) * 1990-11-12 2002-03-05 Basell Polyolefin Gmbh Process for the preparation of an olefin polymer using metallocenes containing specifically substituted indenyl ligands
DE59210001D1 (de) * 1991-10-15 2005-02-17 Basell Polyolefine Gmbh Verfahren zur Herstellung eines Olefinpolymers unter Verwendung von Metallocenen mit speziell substituierten Indenylliganden
DK0574597T3 (da) † 1992-06-13 1998-09-14 Targor Gmbh Fremgangsmåde til fremstilling af brosluttede chirale metallocenkatalysatorer af bisindenyltypen
US5710222A (en) * 1992-06-22 1998-01-20 Fina Technology, Inc. Method for controlling the melting points and molecular weights of syndiotactic polyolefins using metallocene catalyst systems
ATE165832T1 (de) * 1992-08-03 1998-05-15 Targor Gmbh Verfahren zur herstellung eines olefinpolymers unter verwendung von metallocenen mit speziell substituierten indenylliganden
IT1256259B (it) * 1992-12-30 1995-11-29 Montecatini Tecnologie Srl Composti mettallocenici aventi leganti di tipo fluorenilico
DE4333569A1 (de) * 1993-10-01 1995-04-06 Hoechst Ag Verfahren zur Olefinpolymerisation
US5504223A (en) * 1994-01-25 1996-04-02 The Dow Chemical Company Synthesis of cyclopentadienyl metal coordination complexes from metal hydrocarbyloxides
DE4402192A1 (de) * 1994-01-26 1995-07-27 Witco Gmbh Verfahren zur Herstellung von Biscyclopentadienyl-Verbindungen
DE4406109A1 (de) * 1994-02-25 1995-08-31 Witco Gmbh Verfahren zur Herstellung von verbrückten stereorigiden Metallocenen
DE4406110A1 (de) * 1994-02-25 1995-08-31 Witco Gmbh Verbrückte Cyclopentadienylmagnesium-Verbindungen und Verfahren zu ihrer Herstellung und ihre Verwendung zur Herstellung von Metallocenen
DE4406963A1 (de) * 1994-03-03 1995-09-07 Basf Ag Metallocenkomplexe mit heterofunktionellen Gruppen am Cyclopentadienylsystem
US5495035A (en) * 1994-06-01 1996-02-27 University Of Iowa Research Foundation Synthesis of ANSA-metallocene catalysts
US5597935A (en) * 1994-06-01 1997-01-28 University Of Iowa Research Foundation Synthesis of ansa-metallocene catalysts
ATE411343T1 (de) * 1994-06-13 2008-10-15 Basell Polyolefine Gmbh Uebergangsmetallverbindung
EP0709393A3 (de) * 1994-10-25 2003-04-16 Tosoh Corporation Olefinpolymerisationkatalysator und Verfahren zur Herstellung eines Olefinpolymers
US6639030B2 (en) 1994-10-25 2003-10-28 Tosoh Corporation Process for production of olefin polymer
KR100417970B1 (ko) 1994-11-22 2004-06-26 아토피나 리서치 올레핀중합촉매시스템에유용한가교메탈로센
IT1272922B (it) * 1995-01-23 1997-07-01 Spherilene Srl Procedimento per la preparazione di composti metallocenici
IT1275856B1 (it) * 1995-03-03 1997-10-24 Spherilene Srl Composti metallocenici bis-fluorenilici, procedimento per la loro preparazione e loro utilizzo in catalizzatori per la polimerizzazione
US5556997A (en) * 1995-04-24 1996-09-17 Albemarle Corporation Enhanced synthesis of racemic metallocenes
US5883278A (en) * 1995-04-24 1999-03-16 Albemarle Corporation Enhanced synthesis of racemic metallocenes
US5847175A (en) * 1995-04-24 1998-12-08 Albemarle Corporation Enhanced synthesis of racemic metallocenes
DE59507791D1 (de) * 1995-08-30 2000-03-16 Witco Gmbh Unsymmetrisch substituierte, an einem Cyclopentadienylring funktionalisierte Metallocene und deren Darstellung
ES2104455T3 (es) * 1995-09-13 1997-10-01 Witco Gmbh Procedimiento para la preparacion de sistemas cataliticos de metaloceno sobre materiales inertes de soporte, con utilizacion de reactores de fase de gas.
US5700748A (en) * 1995-09-29 1997-12-23 Union Carbide Chemicals & Plastics Technology Corporation Catalyst for the production of olefin polymers comprising a bridging allyl-cyclodienyl ligand on a metal atom
US6002033A (en) * 1995-11-22 1999-12-14 Fina Research, S.A. Bridged metallocenes for use in catalyst systems
US5679814A (en) * 1995-12-11 1997-10-21 Albemarle Corporation Purification of metallocenes
DE59609507D1 (de) * 1996-03-19 2002-09-05 Crompton Gmbh Stabile homogene Formulierungen von oxidationsempfindlichen metallorganischen Verbindungen in Paraffinen und Verfahren zu deren Herstellung
US5710299A (en) * 1996-06-27 1998-01-20 Albemarle Corporation Production of bridged metallocene complexes and intermediates therefor
EP0816371A1 (de) * 1996-06-28 1998-01-07 PCD-Polymere Gesellschaft m.b.H. Verfahren zur stereoselektiven Herstellung von chiralen Metallocenen
US6207608B1 (en) 1996-08-09 2001-03-27 University Of Iowa Research Foundation Olefin polymerization with direct use of ansa-metallocene amide complexes as catalysts
US5760262A (en) * 1996-09-17 1998-06-02 Albemarle Corporation Enhanced production of bridged hafnocenes
DK0835886T3 (da) * 1996-10-09 2004-05-17 Atofina Res Fremgangsmåde til fremstilling og anvendelse af meso/racemiske (bis(indenyl)ethan)zirconiumdichloridforbindelser
US5936108A (en) * 1996-10-17 1999-08-10 Albemarle Corporation Metallocene synthesis
ID19264A (id) * 1996-12-20 1998-06-28 Union Carbide Chem Plastic Pro-katalisator dan pengolahan untuk membuatnya
KR19980072719A (ko) * 1997-03-07 1998-11-05 박홍기 스티렌 중합용 탄소 및/또는 규소 다리화 두금속 메탈로센 촉매, 및 이를 이용한 스티렌 중합방법
DE59807129D1 (de) 1997-07-28 2003-03-13 Basell Polyolefine Gmbh Verfahren zur herstellung von metallocenen
EP0953582A1 (de) * 1998-04-27 1999-11-03 Fina Research S.A. Herstellung von Polyolefin
US6417405B2 (en) 1999-03-03 2002-07-09 The Dow Chemical Company Synthesis of cyclopentadiene or substituted cyclopentadiene compounds
CA2360507A1 (en) 1999-03-03 2000-09-08 The Dow Chemical Company Synthesis of 4-ketocyclopentene and cyclopentadiene compounds
DE19922020A1 (de) * 1999-05-12 2000-11-16 Targor Gmbh Übergangsmetallverbindung, Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen
FR2813079B1 (fr) * 2000-08-18 2003-07-25 Atofina Ligands avec au moins un substituant fluorosilicone pour la preparation de metallocenes
US8008412B2 (en) 2002-09-20 2011-08-30 Exxonmobil Chemical Patents Inc. Polymer production at supersolution conditions
WO2004046214A2 (en) 2002-10-15 2004-06-03 Exxonmobil Chemical Patents Inc. Multiple catalyst system for olefin polymerization and polymers produced therefrom
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
CN100381671C (zh) * 2004-11-02 2008-04-16 邱则有 一种砼填充用空心管
US7868197B2 (en) 2005-12-14 2011-01-11 Exxonmobil Chemical Patents Inc. Halogen substituted heteroatom-containing metallocene compounds for olefin polymerization
US8242237B2 (en) 2006-12-20 2012-08-14 Exxonmobil Chemical Patents Inc. Phase separator and monomer recycle for supercritical polymerization process
JP2010529253A (ja) 2007-06-04 2010-08-26 エクソンモービル・ケミカル・パテンツ・インク 非常に均一なプロピレンの溶液重合法
WO2009077115A1 (en) * 2007-12-18 2009-06-25 Basell Polyolefine Gmbh Process for preparing transition metal compounds for olefin polymerization
US7812104B2 (en) 2008-01-18 2010-10-12 Exxonmobil Chemical Patents Inc. Production of propylene-based polymers
US8318875B2 (en) 2008-01-18 2012-11-27 Exxonmobil Chemical Patents Inc. Super-solution homogeneous propylene polymerization and polypropylenes made therefrom
US9234054B2 (en) 2011-12-19 2016-01-12 Saudi Basic Industries Corporation Process for the preparation of metallocene complexes
EP2800754B1 (de) 2011-12-19 2017-06-28 Saudi Basic Industries Corporation (Sabic) Verfahren zur herstellung von metallocenkomplexen
US9932423B2 (en) 2015-09-24 2018-04-03 Exxonmobil Chemical Patents Inc. Hydrogenation of annulated cyclopentadienyl metal complexes and metallocene catalysts comprising such
JP2023547335A (ja) * 2020-10-15 2023-11-10 ダウ グローバル テクノロジーズ エルエルシー ６－アミノ－ｎ－アリールアザインドール配位子を有するオレフィン重合触媒

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5055438A (en) * 1989-09-13 1991-10-08 Exxon Chemical Patents, Inc. Olefin polymerization catalysts
DE3742934A1 (de) * 1987-12-18 1989-06-29 Hoechst Ag Verfahren zur herstellung einer chiralen, stereorigiden metallocen-verbindung
US5155080A (en) * 1988-07-15 1992-10-13 Fina Technology, Inc. Process and catalyst for producing syndiotactic polyolefins
US5158920A (en) * 1988-07-15 1992-10-27 Fina Technology, Inc. Process for producing stereospecific polymers
US4892851A (en) * 1988-07-15 1990-01-09 Fina Technology, Inc. Process and catalyst for producing syndiotactic polyolefins
DE3907964A1 (de) * 1989-03-11 1990-09-13 Hoechst Ag Verfahren zur herstellung eines syndiotaktischen polyolefins
EP0427697B1 (de) * 1989-10-10 1996-05-08 Fina Technology, Inc. Metallocenkatalysator mit Lewissäure und Alkylaluminium
US5117020A (en) * 1989-10-30 1992-05-26 Fina Research, S.A. Process for the preparation of metallocenes
JP2735658B2 (ja) * 1989-12-25 1998-04-02 三井東圧化学株式会社 新規遷移金属化合物及びその製造方法

Also Published As

Publication number Publication date
JP3249192B2 (ja) 2002-01-21
EP0530908B2 (de) 2003-06-04
ES2131058T5 (es) 2004-04-01
JPH05239083A (ja) 1993-09-17
CA2077613A1 (en) 1993-03-07
DE69228967D1 (de) 1999-05-27
CN1070650A (zh) 1993-04-07
ES2131058T3 (es) 1999-07-16
US5646083A (en) 1997-07-08
CN1049899C (zh) 2000-03-01
DE69228967T3 (de) 2004-07-22
CA2077613C (en) 1999-09-07
MX9205050A (es) 1993-03-01
ATE179177T1 (de) 1999-05-15
NL9101502A (nl) 1993-04-01
EP0530908A1 (de) 1993-03-10
CN1128272A (zh) 1996-08-07
EP0530908B1 (de) 1999-04-21
RU2095364C1 (ru) 1997-11-10

Similar Documents

Publication Publication Date Title
DE69228967D1 (de) Verfahren zur Herstellung einer verbrückten Metallocenverbindung und einer Katalysatorkomponente sowie Verfahren für die Polymerisation von Olefinen
DE59409642D1 (de) Metallocene, Verfahren zu ihrer Herstellung und ihrer Verwendung als Katalysatoren
DE69330674D1 (de) Verfahren zur Herstellung von Polyolefinkatalysatoren
BR9710881A (pt) Processo para a polimerização de olefinas e composto.
FR2586022B1 (fr) Polymerisation d'olefines en phase gazeuse avec un catalyseur ziegler-natta et deux composes organometalliques
DK269787A (da) Fremgangsmaade til fremstiling af olefinholdige polymerer
DE59409990D1 (de) Verfahren zur Herstellung von Polyolefinen
ZA981912B (en) Supported catalyst system, process for its preparation and its use for the polymerization or olefins.
DE59607205D1 (de) Verfahren zur Herstellung von stabilisierten Olefinpolymeren
DE69333535D1 (de) Verfahren zur (Co)Polymerisation von Olefinen
DE60006082D1 (de) Mehrstufiges verfahren zur (co)polymersation von olefinen
BR8804293A (pt) Processo para a preparacao de copolimeros e copolimeros de monoxido de carbono com um ou mais compostos olefinicamente insaturado
ATE73152T1 (de) Katalytische zusammensetzungen und verfahren zur copolymerisation von olefinen und kohlenstoffmonoxiden.
DE59305025D1 (de) 3,4-Dimethyl-2,5-6-tris(p-sulfonatophenyl)-1-phosphanorbornadien, Verfahren zu seiner Herstellung und Verfahren zur Hydroformylierung von olefinisch ungesättigten Verbindungen
DE59209320D1 (de) Metallocen(co)polymere, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren; Metallocene hierfür.
EP0970974A4 (de) Verfahren zur herstellung von olefinpolymeren
DE69408222T2 (de) Katalysatoren für die (Co)Polymerisation von Ethylen
DE69314620D1 (de) Verfahren zur Herstellung von Polymeren basierend auf Kohlenmonoxyd und Olefinen
ES2059037T3 (es) Composiciones cataliticas y procedimiento de polimerizacion, hexakisfosfinas y compuestos hexahalogenados.
EP0774479A3 (de) Verfahren zur Herstellung von Copolymeren aus Kohlenmonoxid und mindestens einer Verbindung mit olefinischer Ungesättigkeit
ATE136558T1 (de) Komponenten und katalysatoren zur polymerisation von olefinen
ES2044335T3 (es) Procedimiento de hidroformilacion.

Legal Events

Date Code Title Description
8363 Opposition against the patent
8366 Restricted maintained after opposition proceedings
8339 Ceased/non-payment of the annual fee