ES2059037T3 - Composiciones cataliticas y procedimiento de polimerizacion, hexakisfosfinas y compuestos hexahalogenados. - Google Patents

Composiciones cataliticas y procedimiento de polimerizacion, hexakisfosfinas y compuestos hexahalogenados.

Info

Publication number
ES2059037T3
ES2059037T3 ES91201062T ES91201062T ES2059037T3 ES 2059037 T3 ES2059037 T3 ES 2059037T3 ES 91201062 T ES91201062 T ES 91201062T ES 91201062 T ES91201062 T ES 91201062T ES 2059037 T3 ES2059037 T3 ES 2059037T3
Authority
ES
Spain
Prior art keywords
elevated
hexakisphosphine
compounds
catalytic compositions
hexahalogenated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES91201062T
Other languages
English (en)
Inventor
Johannes Jacobus Keijsper
Leeuwen Petrus Wilhelmus N Van
Der Made Alexander Willem Van
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Application granted granted Critical
Publication of ES2059037T3 publication Critical patent/ES2059037T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G67/00Macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing oxygen or oxygen and carbon, not provided for in groups C08G2/00 - C08G65/00
    • C08G67/02Copolymers of carbon monoxide and aliphatic unsaturated compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/06Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
    • B01J31/063Polymers comprising a characteristic microstructure
    • B01J31/064Dendrimers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/165Polymer immobilised coordination complexes, e.g. organometallic complexes
    • B01J31/1658Polymer immobilised coordination complexes, e.g. organometallic complexes immobilised by covalent linkages, i.e. pendant complexes with optional linking groups, e.g. on Wang or Merrifield resins
    • B01J31/1683Polymer immobilised coordination complexes, e.g. organometallic complexes immobilised by covalent linkages, i.e. pendant complexes with optional linking groups, e.g. on Wang or Merrifield resins the linkage being to a soluble polymer, e.g. PEG or dendrimer, i.e. molecular weight enlarged complexes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2409Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00Ethers; Compounds having groups, groups or groups
    • C07C43/02Ethers
    • C07C43/03Ethers having all ether-oxygen atoms bound to acyclic carbon atoms
    • C07C43/14Unsaturated ethers
    • C07C43/17Unsaturated ethers containing halogen
    • C07C43/174Unsaturated ethers containing halogen containing six-membered aromatic rings
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
    • C07F15/0006Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System compounds of the platinum group
    • C07F15/0013Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System compounds of the platinum group without a metal-carbon linkage
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
    • C07F15/0006Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System compounds of the platinum group
    • C07F15/006Palladium compounds
    • C07F15/0066Palladium compounds without a metal-carbon linkage
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02Phosphorus compounds
    • C07F9/28Phosphorus compounds with one or more P—C bonds
    • C07F9/50Organo-phosphines
    • C07F9/5027Polyphosphines
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0258Flexible ligands, e.g. mainly sp3-carbon framework as exemplified by the "tedicyp" ligand, i.e. cis-cis-cis-1,2,3,4-tetrakis(diphenylphosphinomethyl)cyclopentane
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82Metals of the platinum group
    • B01J2531/824Palladium

Abstract

COMPOSICIONES CATALITICAS QUE CONTIENEN UN METAL DEL GRUPO VIII Y UN HEXAKISFOSFINO DE LA FORMULA GENERAL (R ELEVADO 1 R (AL CUADRADO) P) SUB 6 R ELEVADO 5 EN LA CUAL R ELEVADO 1 Y R (AL CUADRADO) REPRESENTAN GRUPOS HIDROCARBILOS IDENTICOS O DIFERENTES OPCIONALMENTE SUSTITUIDOS POLARES Y EN LA CUAL R ELEVADO 5 ES UN GRUPO DE UNION HEXAVALENTE ORGANICO QUE CONECTA LOS SEIS ATOMOS DE FOSFORO, SON APROPIADAS PARA LA PREPARACION DE COPOLIMEROS DE MONOXIDO DE CARBON Y COMPUESTOS OLEFINICALMENTE NO SATURADOS. SON NUEVOS COMPUESTOS CIERTOS INTERMEDIARIOS UTILES PARA SU PREPARACION.
ES91201062T 1990-05-10 1991-05-03 Composiciones cataliticas y procedimiento de polimerizacion, hexakisfosfinas y compuestos hexahalogenados. Expired - Lifetime ES2059037T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
NL9001114A NL9001114A (nl) 1990-05-10 1990-05-10 Katalysatorcomposities.

Publications (1)

Publication Number Publication Date
ES2059037T3 true ES2059037T3 (es) 1994-11-01

Family

ID=19857083

Family Applications (1)

Application Number Title Priority Date Filing Date
ES91201062T Expired - Lifetime ES2059037T3 (es) 1990-05-10 1991-05-03 Composiciones cataliticas y procedimiento de polimerizacion, hexakisfosfinas y compuestos hexahalogenados.

Country Status (19)

Country Link
US (3) US5169926A (es)
EP (1) EP0456317B1 (es)
JP (1) JP3113311B2 (es)
KR (1) KR910020039A (es)
CN (1) CN1056444A (es)
AU (1) AU636475B2 (es)
BR (1) BR9101858A (es)
CA (1) CA2042127A1 (es)
CS (1) CS135791A2 (es)
DE (1) DE69100297T2 (es)
ES (1) ES2059037T3 (es)
FI (1) FI912223A (es)
MY (1) MY106165A (es)
NL (1) NL9001114A (es)
PL (1) PL290167A1 (es)
RU (1) RU2077542C1 (es)
SG (1) SG11394G (es)
TR (1) TR25566A (es)
ZA (1) ZA913495B (es)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5210177A (en) * 1991-05-31 1993-05-11 Shell Oil Company Polymerization of co/olefin with tetra ethyl diphosphine
WO1993025602A1 (en) * 1992-06-15 1993-12-23 Akzo N.V. Improved gas phase process for forming polyketones
US6586501B1 (en) 1999-01-20 2003-07-01 Cabot Corporation Aggregates having attached polymer groups and polymer foams
US6258864B1 (en) 1999-01-20 2001-07-10 Cabot Corporation Polymer foam containing chemically modified carbonaceous filler
CN104909982A (zh) * 2015-05-29 2015-09-16 长沙贝塔医药科技有限公司 一种直接从同位素标记苯环合成标记溴苄类化合物的方法

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3670032A (en) * 1969-03-19 1972-06-13 Exxon Research Engineering Co Preparation of unsaturated alcohols and ethers
US3694412A (en) * 1971-03-04 1972-09-26 Shell Oil Co Process for preparing interpolymers of carbon monoxide in the presence of aryl phosphine-palladium halide complex
US4183825A (en) * 1978-07-14 1980-01-15 Conoco, Inc. Method for the activation of polymer-bound bis(triphenylphosphine)rhodium carbonyl halide hydroformylation catalysts
DE3480845D1 (de) * 1983-04-06 1990-02-01 Shell Int Research Verfahren zur herstellung von polyketonen.
NL8403035A (nl) * 1984-10-05 1986-05-01 Shell Int Research Werkwijze ter bereiding van polyketonen.
IN166314B (es) * 1985-08-29 1990-04-07 Shell Int Research
IN171627B (es) * 1986-08-26 1992-11-28 Shell Int Research
NL8602164A (nl) * 1986-08-26 1988-03-16 Shell Int Research Katalysatorcomposities.
US4820802A (en) * 1987-02-03 1989-04-11 Shell Oil Company Improved process of preparing carbon monoxide/olefin copolymer with ortho substituted phosphine catalyst composition.
ATE121108T1 (de) * 1989-01-26 1995-04-15 Shell Int Research Katalysator-zusammensetzungen.
US5057599A (en) * 1989-07-14 1991-10-15 Shell Oil Company Polymerization of carbon monoxide/olefin with aromatic tetradentate phosphorus ligand

Also Published As

Publication number Publication date
RU2077542C1 (ru) 1997-04-20
ZA913495B (en) 1992-01-29
CS135791A2 (en) 1991-12-17
CA2042127A1 (en) 1991-11-11
US5212135A (en) 1993-05-18
NL9001114A (nl) 1991-12-02
BR9101858A (pt) 1991-12-17
DE69100297D1 (de) 1993-09-30
JPH04227727A (ja) 1992-08-17
PL290167A1 (es) 1993-02-08
EP0456317A1 (en) 1991-11-13
US5169926A (en) 1992-12-08
EP0456317B1 (en) 1993-08-25
TR25566A (tr) 1993-07-01
DE69100297T2 (de) 1994-01-13
FI912223A (fi) 1991-11-11
CN1056444A (zh) 1991-11-27
AU636475B2 (en) 1993-04-29
JP3113311B2 (ja) 2000-11-27
AU7525691A (en) 1991-11-14
SG11394G (en) 1994-04-15
US5243079A (en) 1993-09-07
FI912223A0 (fi) 1991-05-08
KR910020039A (ko) 1991-12-19
MY106165A (en) 1995-03-31

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