DE69114316D1 - Neue Initiatoren für kationische Polymerisation. - Google Patents
Neue Initiatoren für kationische Polymerisation.Info
- Publication number
- DE69114316D1 DE69114316D1 DE69114316T DE69114316T DE69114316D1 DE 69114316 D1 DE69114316 D1 DE 69114316D1 DE 69114316 T DE69114316 T DE 69114316T DE 69114316 T DE69114316 T DE 69114316T DE 69114316 D1 DE69114316 D1 DE 69114316D1
- Authority
- DE
- Germany
- Prior art keywords
- cationic polymerization
- new initiators
- initiators
- new
- cationic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000010538 cationic polymerization reaction Methods 0.000 title 1
- 239000003999 initiator Substances 0.000 title 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/003—Compounds containing elements of Groups 3 or 13 of the Periodic Table without C-Metal linkages
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/02—Iron compounds
- C07F15/025—Iron compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F19/00—Metal compounds according to more than one of main groups C07F1/00 - C07F17/00
- C07F19/005—Metal compounds according to more than one of main groups C07F1/00 - C07F17/00 without metal-C linkages
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/02—Boron compounds
- C07F5/022—Boron compounds without C-boron linkages
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/02—Boron compounds
- C07F5/04—Esters of boric acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/06—Aluminium compounds
- C07F5/069—Aluminium compounds without C-aluminium linkages
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/003—Compounds containing elements of Groups 4 or 14 of the Periodic Table without C-Metal linkages
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G4/00—Condensation polymers of aldehydes or ketones with polyalcohols; Addition polymers of heterocyclic oxygen compounds containing in the ring at least once the grouping —O—C—O—
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/68—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
- C08G59/687—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G6/00—Condensation polymers of aldehydes or ketones only
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/04—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
- C08G65/06—Cyclic ethers having no atoms other than carbon and hydrogen outside the ring
- C08G65/08—Saturated oxiranes
- C08G65/10—Saturated oxiranes characterised by the catalysts used
- C08G65/105—Onium compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/04—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
- C08G65/06—Cyclic ethers having no atoms other than carbon and hydrogen outside the ring
- C08G65/16—Cyclic ethers having four or more ring atoms
- C08G65/20—Tetrahydrofuran
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polymerization Catalysts (AREA)
- Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/478,939 US5084586A (en) | 1990-02-12 | 1990-02-12 | Novel initiators for cationic polymerization |
Publications (1)
Publication Number | Publication Date |
---|---|
DE69114316D1 true DE69114316D1 (de) | 1995-12-14 |
Family
ID=23902016
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69114316T Expired - Lifetime DE69114316D1 (de) | 1990-02-12 | 1991-01-31 | Neue Initiatoren für kationische Polymerisation. |
Country Status (7)
Country | Link |
---|---|
US (1) | US5084586A (de) |
EP (1) | EP0442635B1 (de) |
JP (1) | JPH04214704A (de) |
KR (1) | KR910015596A (de) |
AU (1) | AU631476B2 (de) |
CA (1) | CA2034168A1 (de) |
DE (1) | DE69114316D1 (de) |
Families Citing this family (86)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5254664A (en) * | 1991-12-31 | 1993-10-19 | Nippon Shokubai Co., Ltd. | Curing composition |
FR2688783A1 (fr) * | 1992-03-23 | 1993-09-24 | Rhone Poulenc Chimie | Nouveaux borates d'onium ou de complexe organometallique amorceurs cationiques de polymerisation. |
US6147184A (en) * | 1992-03-23 | 2000-11-14 | Rhone-Poulenc Chimie | Onium borates/borates of organometallic complexes and cationic initiation of polymerization therewith |
FR2688790B1 (fr) * | 1992-03-23 | 1994-05-13 | Rhone Poulenc Chimie | Compositions a base de polyorganosiloxanes a groupements fonctionnels reticulables et leur utilisation pour la realisation de revetements anti-adhesifs. |
US5541346A (en) * | 1992-10-21 | 1996-07-30 | E. I. Du Pont De Nemours And Company | Polymerization of, and depolymerization to, cyclic ethers using selected metal compound catalysts |
US5990264A (en) * | 1993-02-23 | 1999-11-23 | E. I. Du Pont De Nemours And Company | Copolymerization of tetrahydrofurans and cyclic anhydrides |
US5478920A (en) * | 1993-07-16 | 1995-12-26 | E. I. Du Pont De Nemours And Company | Cyclic ether polymerization using silicon compound accelerators |
US5514728A (en) * | 1993-07-23 | 1996-05-07 | Minnesota Mining And Manufacturing Company | Catalysts and initiators for polymerization |
US5430122A (en) * | 1994-02-17 | 1995-07-04 | E. I. Du Pont De Nemours And Company | Preparation of poly(ether-urethanes) from cyclic ethers and organic isocyanates |
US5677412A (en) * | 1994-02-17 | 1997-10-14 | E. I. Du Pont De Nemours And Company | Preparation of poly(ether-urethanes) from cyclic ethers and organic isocyanates |
US6008307A (en) * | 1994-04-28 | 1999-12-28 | Exxon Chemical Patents Inc | Process for producing olefin polymers using cationic catalysts |
US6291389B1 (en) * | 1994-04-28 | 2001-09-18 | Exxonmobil Chemical Patents Inc. | Cationic polymerization catalysts |
WO1996013540A1 (en) * | 1994-10-28 | 1996-05-09 | E.I. Du Pont De Nemours And Company | Polymerization of cyclic ethers using selected metal compound catalysts |
US5614650A (en) * | 1995-03-07 | 1997-03-25 | Sandler; Stanley R. | Zirconium compounds of sulfonic acids |
EP1586294B2 (de) * | 1999-10-28 | 2016-02-17 | 3M Innovative Properties Company | Siliziumdioxid-Nanoteilchen in Form eines trockenen Pulvers |
US6376590B2 (en) | 1999-10-28 | 2002-04-23 | 3M Innovative Properties Company | Zirconia sol, process of making and composite material |
US6730156B1 (en) | 1999-10-28 | 2004-05-04 | 3M Innovative Properties Company | Clustered particle dental fillers |
US6572693B1 (en) | 1999-10-28 | 2003-06-03 | 3M Innovative Properties Company | Aesthetic dental materials |
US6387981B1 (en) | 1999-10-28 | 2002-05-14 | 3M Innovative Properties Company | Radiopaque dental materials with nano-sized particles |
EP1598699A3 (de) | 2000-05-23 | 2009-05-20 | Aprilis, Inc. | Datenspeichermedium das ein kolloidales Metall enthält und Verfahren zur Herstellung |
US20020151626A1 (en) * | 2001-02-08 | 2002-10-17 | Hisashi Isaka | Curing composition |
KR100408290B1 (ko) * | 2001-07-06 | 2003-12-03 | 삼성전자주식회사 | 커버 낙하 방지용 탄성부재를 장착한 장치 |
CA2364756A1 (en) * | 2001-12-10 | 2003-06-10 | Nova Chemicals Corporation | Catalyst activator |
EP1471875A1 (de) * | 2002-01-31 | 2004-11-03 | 3M Innovative Properties Company | Dentalmassen, dentalartikel und verfahren |
US7091259B2 (en) * | 2002-07-03 | 2006-08-15 | 3M Innovative Properties Company | Dental fillers, pastes, and compositions prepared therefrom |
US7449146B2 (en) * | 2002-09-30 | 2008-11-11 | 3M Innovative Properties Company | Colorimetric sensor |
US20040062682A1 (en) * | 2002-09-30 | 2004-04-01 | Rakow Neal Anthony | Colorimetric sensor |
US6841333B2 (en) | 2002-11-01 | 2005-01-11 | 3M Innovative Properties Company | Ionic photoacid generators with segmented hydrocarbon-fluorocarbon sulfonate anions |
US7025791B2 (en) * | 2002-12-02 | 2006-04-11 | Gi Dynamics, Inc. | Bariatric sleeve |
US6777460B2 (en) * | 2002-12-23 | 2004-08-17 | 3M Innovative Properties Company | Curing agents for cationically curable compositions |
US6984261B2 (en) * | 2003-02-05 | 2006-01-10 | 3M Innovative Properties Company | Use of ceramics in dental and orthodontic applications |
US7122294B2 (en) * | 2003-05-22 | 2006-10-17 | 3M Innovative Properties Company | Photoacid generators with perfluorinated multifunctional anions |
US7064152B2 (en) * | 2003-09-26 | 2006-06-20 | 3M Innovative Properties Company | Arylsulfinate salts in photoinitiator systems for polymerization reactions |
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JP2006282633A (ja) * | 2005-04-04 | 2006-10-19 | Sanshin Chem Ind Co Ltd | スルホニウム化合物および重合組成物 |
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US20090000727A1 (en) * | 2007-06-29 | 2009-01-01 | Kanta Kumar | Hardcoat layers on release liners |
US20090155596A1 (en) * | 2007-12-12 | 2009-06-18 | 3M Innovative Properties Company | Nozzle sealing composition and method |
JP4901889B2 (ja) * | 2008-02-18 | 2012-03-21 | ソニーケミカル&インフォメーションデバイス株式会社 | 磁性シート組成物、磁性シート、及び磁性シートの製造方法 |
US8192590B1 (en) * | 2008-04-14 | 2012-06-05 | University Of Central Florida Research Foundation, Inc. | Microwave-assisted formation of sulfonium photoacid generators |
CN101942084B (zh) * | 2010-09-25 | 2012-01-25 | 浙江大学 | 用三氟甲磺酸稀土金属化合物催化合成聚四氢呋喃的方法 |
US8785517B2 (en) | 2011-05-25 | 2014-07-22 | 3M Innovative Properties Company | Pressure-sensitive adhesives with onium-epdxy crosslinking system |
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US10982122B2 (en) | 2014-09-05 | 2021-04-20 | 3M Innovative Properties Company | Heat conformable curable adhesive films |
EP3265049B1 (de) | 2015-03-05 | 2024-05-01 | Solventum Intellectual Properties Company | Verbundstoff mit keramischen fasern |
CN107532079B (zh) | 2015-04-16 | 2020-10-23 | 3M创新有限公司 | 具有硫醇-烯烃-环氧基体的量子点制品 |
JP6422598B2 (ja) | 2015-04-16 | 2018-11-14 | スリーエム イノベイティブ プロパティズ カンパニー | チオール−エポキシマトリックスを有する量子ドット物品 |
WO2017048608A1 (en) | 2015-09-15 | 2017-03-23 | 3M Innovative Properties Company | Additive stabilized composite nanoparticles |
EP3350284B1 (de) | 2015-09-15 | 2019-02-27 | 3M Innovative Properties Company | Additivstabilisierte kompositnanopartikel |
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KR20180084089A (ko) | 2015-11-18 | 2018-07-24 | 쓰리엠 이노베이티브 프로퍼티즈 캄파니 | 나노입자를 위한 공중합체성 안정화 담체 유체 |
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US11345849B2 (en) | 2016-07-20 | 2022-05-31 | 3M Innovative Properties Company | Stabilizing styrenic polymer for quantum dots |
EP3336111A1 (de) * | 2016-12-16 | 2018-06-20 | ARLANXEO Canada Inc. | Initiatorsystem zur katioinischen polymerisierung von olefinen |
CA2953163A1 (fr) | 2016-12-23 | 2018-06-23 | Sce France | Composes a base d'un element de la famille du bore et leur utilisation dans des compositions d'electrolytes |
TW201842164A (zh) | 2017-03-14 | 2018-12-01 | 美商3M新設資產公司 | 經添加劑穩定之複合奈米粒子 |
EP3725820B1 (de) | 2019-04-16 | 2022-04-06 | Henkel AG & Co. KGaA | Verwendung von funktionalisierten alpha-angelica-lactonen |
EP3798246B1 (de) | 2019-09-27 | 2024-01-31 | Henkel AG & Co. KGaA | Einkomponentige (1k) zusammensetzung auf basis von modifiziertem epoxidharz |
EP3831863B1 (de) | 2019-12-04 | 2023-07-05 | Henkel AG & Co. KGaA | Einkomponentige (1k) zusammensetzung auf der basis von epoxidharz |
EP3831862B1 (de) | 2019-12-04 | 2023-06-28 | Henkel AG & Co. KGaA | Einkomponentige (1k) zusammensetzung auf basis von epoxidharz |
WO2021124156A1 (en) | 2019-12-20 | 2021-06-24 | 3M Innovative Properties Company | Method of pattern coating adhesive composition comprising unpolymerized cyclic olefin and latent catalyst, adhesive compositions and articles |
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US20220111582A1 (en) | 2020-10-13 | 2022-04-14 | Cabot Corporation | Conductive photo-curable compositions for additive manufacturing |
EP4012000A1 (de) | 2020-12-11 | 2022-06-15 | Bostik SA | Lichthärtbare klebstoffzusammensetzung |
EP4050061A1 (de) | 2021-02-26 | 2022-08-31 | Henkel AG & Co. KGaA | Im nahinfrarotbereich (nir) sensibilisierte kleb- und dichtstoffzusammensetzungen |
EP4050060A1 (de) | 2021-02-26 | 2022-08-31 | Henkel AG & Co. KGaA | Photohärtbare klebe- oder dichtungsmasse |
EP4183807A1 (de) | 2021-11-18 | 2023-05-24 | Henkel AG & Co. KGaA | Copolymer und heissschmelzzusammensetzungen mit diesem copolymer |
WO2023111715A1 (en) | 2021-12-16 | 2023-06-22 | 3M Innovative Properties Company | Compositions comprising cleavable crosslinkers |
EP4332144A1 (de) | 2022-09-05 | 2024-03-06 | Henkel AG & Co. KGaA | Einkomponentige (1k) härtbare klebstoffzusammensetzung |
WO2024074908A1 (en) | 2022-10-03 | 2024-04-11 | 3M Innovative Properties Company | Adhesive composition comprising polar (meth)acrylate monomer and epoxy resin, articles and methods |
WO2024074909A1 (en) | 2022-10-07 | 2024-04-11 | 3M Innovative Properties Company | Articles comprising cyclic olefin, catalyst, and second polymerizable material, methods and compositions |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4610829A (en) * | 1968-08-21 | 1986-09-09 | Produits Chimiques Ugine Kuhlmann | Polyfluorinated sulphonic acids and their derivatives |
JPS4823554B1 (de) * | 1969-04-04 | 1973-07-14 | ||
US4108747A (en) * | 1976-07-14 | 1978-08-22 | General Electric Company | Curable compositions and method for curing such compositions |
IT1129809B (it) * | 1979-03-26 | 1986-06-11 | Ugine Kuhlmann | Composizione catalitica per la conversione di idrocarburi e procedimento per la disidratazione di acidi perfluoroalcansolfonici destinati a fare parte bella composizione |
US4472268A (en) * | 1983-01-18 | 1984-09-18 | El Paso Products Company | Upgrading of natural gasoline with trifluoromethane sulfonic acid, hydrofluoric acid and Lewis acid catalyst |
CN1005265B (zh) * | 1985-04-12 | 1989-09-27 | 福建师范大学 | 新型铝体系偶联剂 |
US4721559A (en) * | 1986-10-17 | 1988-01-26 | Olah George A | Boron, aluminum and gallium perfluoro alkanesulfonate and resinsulfonate catalysts |
CA2002873A1 (en) * | 1988-11-21 | 1990-05-21 | Franklin Donald Saeva | Onium salts and the use thereof as photoinitiators |
-
1990
- 1990-02-12 US US07/478,939 patent/US5084586A/en not_active Expired - Fee Related
-
1991
- 1991-01-09 AU AU69286/91A patent/AU631476B2/en not_active Ceased
- 1991-01-15 CA CA002034168A patent/CA2034168A1/en not_active Abandoned
- 1991-01-31 DE DE69114316T patent/DE69114316D1/de not_active Expired - Lifetime
- 1991-01-31 EP EP91300764A patent/EP0442635B1/de not_active Expired - Lifetime
- 1991-02-08 JP JP3017496A patent/JPH04214704A/ja active Pending
- 1991-02-11 KR KR1019910002268A patent/KR910015596A/ko not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
JPH04214704A (ja) | 1992-08-05 |
KR910015596A (ko) | 1991-09-30 |
US5084586A (en) | 1992-01-28 |
AU631476B2 (en) | 1992-11-26 |
CA2034168A1 (en) | 1991-08-13 |
EP0442635A1 (de) | 1991-08-21 |
AU6928691A (en) | 1991-08-15 |
EP0442635B1 (de) | 1995-11-08 |
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