DE69029472T2 - Verbesserte gerüststoffe enthaltende wässrige reinigungs-/entfettungs-mikroemulsionszusammensetzungen - Google Patents
Verbesserte gerüststoffe enthaltende wässrige reinigungs-/entfettungs-mikroemulsionszusammensetzungenInfo
- Publication number
- DE69029472T2 DE69029472T2 DE69029472T DE69029472T DE69029472T2 DE 69029472 T2 DE69029472 T2 DE 69029472T2 DE 69029472 T DE69029472 T DE 69029472T DE 69029472 T DE69029472 T DE 69029472T DE 69029472 T2 DE69029472 T2 DE 69029472T2
- Authority
- DE
- Germany
- Prior art keywords
- sodium
- microemulsion
- fat removal
- composition
- aqueous
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 194
- 239000004530 micro-emulsion Substances 0.000 title claims abstract description 108
- 238000005238 degreasing Methods 0.000 title claims abstract description 56
- 238000004140 cleaning Methods 0.000 title claims abstract description 43
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 53
- 239000003960 organic solvent Substances 0.000 claims abstract description 47
- 239000013527 degreasing agent Substances 0.000 claims abstract description 42
- 239000002904 solvent Substances 0.000 claims abstract description 35
- 239000004094 surface-active agent Substances 0.000 claims abstract description 32
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 9
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000004907 Macro-emulsion Substances 0.000 claims abstract description 7
- 125000000524 functional group Chemical group 0.000 claims abstract description 7
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 6
- 230000002209 hydrophobic effect Effects 0.000 claims abstract description 6
- 150000008282 halocarbons Chemical class 0.000 claims abstract description 5
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 4
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 4
- 239000001301 oxygen Substances 0.000 claims abstract description 4
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 4
- 239000011574 phosphorus Substances 0.000 claims abstract description 4
- 239000011734 sodium Substances 0.000 claims description 24
- 229910052708 sodium Inorganic materials 0.000 claims description 24
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 23
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 20
- 239000003599 detergent Substances 0.000 claims description 14
- 239000012459 cleaning agent Substances 0.000 claims description 12
- 229910019142 PO4 Inorganic materials 0.000 claims description 11
- 235000021317 phosphate Nutrition 0.000 claims description 11
- 238000005237 degreasing agent Methods 0.000 claims description 10
- 239000010452 phosphate Substances 0.000 claims description 10
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 9
- 239000004115 Sodium Silicate Substances 0.000 claims description 9
- 229910052700 potassium Inorganic materials 0.000 claims description 9
- 239000011591 potassium Substances 0.000 claims description 9
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical group [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 9
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 9
- IBLKWZIFZMJLFL-UHFFFAOYSA-N 1-phenoxypropan-2-ol Chemical compound CC(O)COC1=CC=CC=C1 IBLKWZIFZMJLFL-UHFFFAOYSA-N 0.000 claims description 8
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 8
- 235000019795 sodium metasilicate Nutrition 0.000 claims description 8
- WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 claims description 7
- 229940060296 dodecylbenzenesulfonic acid Drugs 0.000 claims description 7
- 239000003945 anionic surfactant Substances 0.000 claims description 6
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 claims description 6
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical group OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 claims description 5
- 229910021538 borax Inorganic materials 0.000 claims description 5
- 239000000356 contaminant Substances 0.000 claims description 5
- 239000002736 nonionic surfactant Substances 0.000 claims description 5
- 229960005323 phenoxyethanol Drugs 0.000 claims description 5
- 239000004328 sodium tetraborate Substances 0.000 claims description 5
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 5
- 229940048842 sodium xylenesulfonate Drugs 0.000 claims description 5
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 claims description 4
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 4
- 239000002280 amphoteric surfactant Substances 0.000 claims description 4
- 125000000129 anionic group Chemical group 0.000 claims description 4
- 150000007942 carboxylates Chemical class 0.000 claims description 4
- 239000003093 cationic surfactant Substances 0.000 claims description 4
- CCIVGXIOQKPBKL-UHFFFAOYSA-M ethanesulfonate Chemical compound CCS([O-])(=O)=O CCIVGXIOQKPBKL-UHFFFAOYSA-M 0.000 claims description 4
- HJOVHMDZYOCNQW-UHFFFAOYSA-N isophorone Chemical compound CC1=CC(=O)CC(C)(C)C1 HJOVHMDZYOCNQW-UHFFFAOYSA-N 0.000 claims description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 3
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 claims description 3
- 239000005864 Sulphur Substances 0.000 claims description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 3
- 235000011037 adipic acid Nutrition 0.000 claims description 3
- 150000001279 adipic acids Chemical class 0.000 claims description 3
- 150000001298 alcohols Chemical class 0.000 claims description 3
- 125000002091 cationic group Chemical group 0.000 claims description 3
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- 150000002148 esters Chemical group 0.000 claims description 3
- SFNALCNOMXIBKG-UHFFFAOYSA-N ethylene glycol monododecyl ether Chemical compound CCCCCCCCCCCCOCCO SFNALCNOMXIBKG-UHFFFAOYSA-N 0.000 claims description 3
- 150000002311 glutaric acids Chemical class 0.000 claims description 3
- 150000002576 ketones Chemical class 0.000 claims description 3
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 3
- 150000003444 succinic acids Chemical class 0.000 claims description 3
- KAKVFSYQVNHFBS-UHFFFAOYSA-N (5-hydroxycyclopenten-1-yl)-phenylmethanone Chemical compound OC1CCC=C1C(=O)C1=CC=CC=C1 KAKVFSYQVNHFBS-UHFFFAOYSA-N 0.000 claims description 2
- BTMZHHCFEOXAAN-UHFFFAOYSA-N 2-[bis(2-hydroxyethyl)amino]ethanol;2-dodecylbenzenesulfonic acid Chemical compound OCCN(CCO)CCO.CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O BTMZHHCFEOXAAN-UHFFFAOYSA-N 0.000 claims description 2
- NQBXSWAWVZHKBZ-UHFFFAOYSA-N 2-butoxyethyl acetate Chemical compound CCCCOCCOC(C)=O NQBXSWAWVZHKBZ-UHFFFAOYSA-N 0.000 claims description 2
- WRMNZCZEMHIOCP-UHFFFAOYSA-N 2-phenylethanol Chemical compound OCCC1=CC=CC=C1 WRMNZCZEMHIOCP-UHFFFAOYSA-N 0.000 claims description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims description 2
- MMFGZIGEGLQAET-UHFFFAOYSA-N C1COCCN1.CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 Chemical compound C1COCCN1.CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 MMFGZIGEGLQAET-UHFFFAOYSA-N 0.000 claims description 2
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 2
- BCKXLBQYZLBQEK-KVVVOXFISA-M Sodium oleate Chemical compound [Na+].CCCCCCCC\C=C/CCCCCCCC([O-])=O BCKXLBQYZLBQEK-KVVVOXFISA-M 0.000 claims description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 2
- IHUMNXSBUOIDQI-UHFFFAOYSA-N Triethanolamine myristate Chemical compound OCCN(CCO)CCO.CCCCCCCCCCCCCC(O)=O IHUMNXSBUOIDQI-UHFFFAOYSA-N 0.000 claims description 2
- JOBYPQKGZFMLPB-UHFFFAOYSA-N [K].CCOS(=O)(=O)C1=CC=CC=C1 Chemical compound [K].CCOS(=O)(=O)C1=CC=CC=C1 JOBYPQKGZFMLPB-UHFFFAOYSA-N 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- 150000001299 aldehydes Chemical class 0.000 claims description 2
- 229910052783 alkali metal Inorganic materials 0.000 claims description 2
- 229910000288 alkali metal carbonate Inorganic materials 0.000 claims description 2
- 150000008041 alkali metal carbonates Chemical class 0.000 claims description 2
- 150000008044 alkali metal hydroxides Chemical group 0.000 claims description 2
- 229910000318 alkali metal phosphate Inorganic materials 0.000 claims description 2
- 229910052910 alkali metal silicate Inorganic materials 0.000 claims description 2
- 229940047662 ammonium xylenesulfonate Drugs 0.000 claims description 2
- PLUHAVSIMCXBEX-UHFFFAOYSA-N azane;dodecyl benzenesulfonate Chemical compound N.CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 PLUHAVSIMCXBEX-UHFFFAOYSA-N 0.000 claims description 2
- FFSUESGPJHRICR-UHFFFAOYSA-N azanium;2-butoxyethyl sulfate Chemical compound [NH4+].CCCCOCCOS([O-])(=O)=O FFSUESGPJHRICR-UHFFFAOYSA-N 0.000 claims description 2
- MKHVZQXYWACUQC-UHFFFAOYSA-N bis(2-hydroxyethyl)azanium;dodecyl sulfate Chemical compound OCCNCCO.CCCCCCCCCCCCOS(O)(=O)=O MKHVZQXYWACUQC-UHFFFAOYSA-N 0.000 claims description 2
- 235000011180 diphosphates Nutrition 0.000 claims description 2
- QQXYKEKPPSATBQ-UHFFFAOYSA-L dipotassium;2-octadec-1-enylbutanedioate Chemical compound [K+].[K+].CCCCCCCCCCCCCCCCC=CC(C([O-])=O)CC([O-])=O QQXYKEKPPSATBQ-UHFFFAOYSA-L 0.000 claims description 2
- WJRMGBWBIGOIOF-UHFFFAOYSA-N dodecyl benzenesulfonate;propan-2-amine Chemical compound CC(C)N.CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 WJRMGBWBIGOIOF-UHFFFAOYSA-N 0.000 claims description 2
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims description 2
- 150000002170 ethers Chemical class 0.000 claims description 2
- JJWLVOIRVHMVIS-UHFFFAOYSA-N isopropylamine Chemical compound CC(C)N JJWLVOIRVHMVIS-UHFFFAOYSA-N 0.000 claims description 2
- HESSGHHCXGBPAJ-UHFFFAOYSA-N n-[3,5,6-trihydroxy-1-oxo-4-[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyhexan-2-yl]acetamide Chemical compound CC(=O)NC(C=O)C(O)C(C(O)CO)OC1OC(CO)C(O)C(O)C1O HESSGHHCXGBPAJ-UHFFFAOYSA-N 0.000 claims description 2
- 150000002825 nitriles Chemical class 0.000 claims description 2
- IZJIGIIPZHTWIU-UHFFFAOYSA-M potassium;2,3-didodecylbenzenesulfonate Chemical compound [K+].CCCCCCCCCCCCC1=CC=CC(S([O-])(=O)=O)=C1CCCCCCCCCCCC IZJIGIIPZHTWIU-UHFFFAOYSA-M 0.000 claims description 2
- FXLIRIZRZOEABT-UHFFFAOYSA-M potassium;2,3-dimethylnaphthalene-1-sulfonate Chemical compound [K+].C1=CC=C2C(S([O-])(=O)=O)=C(C)C(C)=CC2=C1 FXLIRIZRZOEABT-UHFFFAOYSA-M 0.000 claims description 2
- HSJXWMZKBLUOLQ-UHFFFAOYSA-M potassium;2-dodecylbenzenesulfonate Chemical compound [K+].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O HSJXWMZKBLUOLQ-UHFFFAOYSA-M 0.000 claims description 2
- 229940077386 sodium benzenesulfonate Drugs 0.000 claims description 2
- 229940079842 sodium cumenesulfonate Drugs 0.000 claims description 2
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims description 2
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 2
- FIPGLBXQFKCVDI-UHFFFAOYSA-M sodium;2,3-di(nonyl)benzenesulfonate Chemical compound [Na+].CCCCCCCCCC1=CC=CC(S([O-])(=O)=O)=C1CCCCCCCCC FIPGLBXQFKCVDI-UHFFFAOYSA-M 0.000 claims description 2
- VFOVBGNGALJINB-UHFFFAOYSA-M sodium;2-butoxyacetate Chemical compound [Na+].CCCCOCC([O-])=O VFOVBGNGALJINB-UHFFFAOYSA-M 0.000 claims description 2
- VYPDUQYOLCLEGS-UHFFFAOYSA-M sodium;2-ethylhexanoate Chemical compound [Na+].CCCCC(CC)C([O-])=O VYPDUQYOLCLEGS-UHFFFAOYSA-M 0.000 claims description 2
- DGSDBJMBHCQYGN-UHFFFAOYSA-M sodium;2-ethylhexyl sulfate Chemical compound [Na+].CCCCC(CC)COS([O-])(=O)=O DGSDBJMBHCQYGN-UHFFFAOYSA-M 0.000 claims description 2
- KVCGISUBCHHTDD-UHFFFAOYSA-M sodium;4-methylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1 KVCGISUBCHHTDD-UHFFFAOYSA-M 0.000 claims description 2
- QEKATQBVVAZOAY-UHFFFAOYSA-M sodium;4-propan-2-ylbenzenesulfonate Chemical compound [Na+].CC(C)C1=CC=C(S([O-])(=O)=O)C=C1 QEKATQBVVAZOAY-UHFFFAOYSA-M 0.000 claims description 2
- DUXXGJTXFHUORE-UHFFFAOYSA-M sodium;4-tridecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCCC1=CC=C(S([O-])(=O)=O)C=C1 DUXXGJTXFHUORE-UHFFFAOYSA-M 0.000 claims description 2
- MZSDGDXXBZSFTG-UHFFFAOYSA-M sodium;benzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=CC=C1 MZSDGDXXBZSFTG-UHFFFAOYSA-M 0.000 claims description 2
- PNGBYKXZVCIZRN-UHFFFAOYSA-M sodium;hexadecane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCCCCCS([O-])(=O)=O PNGBYKXZVCIZRN-UHFFFAOYSA-M 0.000 claims description 2
- LTOCMXUTASYUOC-UHFFFAOYSA-M sodium;nonanoate Chemical compound [Na+].CCCCCCCCC([O-])=O LTOCMXUTASYUOC-UHFFFAOYSA-M 0.000 claims description 2
- HRQDCDQDOPSGBR-UHFFFAOYSA-M sodium;octane-1-sulfonate Chemical compound [Na+].CCCCCCCCS([O-])(=O)=O HRQDCDQDOPSGBR-UHFFFAOYSA-M 0.000 claims description 2
- 229940105956 tea-dodecylbenzenesulfonate Drugs 0.000 claims description 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 claims 2
- AUVGOYQDXANGHO-UHFFFAOYSA-N 4,5-dihydro-1h-imidazole;sodium Chemical compound [Na].C1CN=CN1 AUVGOYQDXANGHO-UHFFFAOYSA-N 0.000 claims 1
- BYEFHDZWRALTEN-UHFFFAOYSA-N 4-ethyl-2,6,7-trioxa-1$l^{5}-phosphabicyclo[2.2.2]octane 1-oxide Chemical compound C1OP2(=O)OCC1(CC)CO2 BYEFHDZWRALTEN-UHFFFAOYSA-N 0.000 claims 1
- 150000001340 alkali metals Chemical class 0.000 claims 1
- 239000007822 coupling agent Substances 0.000 claims 1
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 claims 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 claims 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 claims 1
- 229940080230 sodium c12-14 olefin sulfonate Drugs 0.000 claims 1
- 229940114536 sodium capryloamphopropionate Drugs 0.000 claims 1
- WMLIJOUAGPIENT-UHFFFAOYSA-M sodium;3-[2-hydroxyethyl-[2-(octanoylamino)ethyl]amino]propanoate Chemical compound [Na+].CCCCCCCC(=O)NCCN(CCO)CCC([O-])=O WMLIJOUAGPIENT-UHFFFAOYSA-M 0.000 claims 1
- HSFQBFMEWSTNOW-UHFFFAOYSA-N sodium;carbanide Chemical group [CH3-].[Na+] HSFQBFMEWSTNOW-UHFFFAOYSA-N 0.000 claims 1
- 239000000654 additive Substances 0.000 abstract description 9
- 230000003381 solubilizing effect Effects 0.000 abstract description 6
- 230000000996 additive effect Effects 0.000 abstract description 5
- 229910052717 sulfur Inorganic materials 0.000 abstract 1
- 239000011593 sulfur Substances 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 28
- 239000007787 solid Substances 0.000 description 27
- 238000010998 test method Methods 0.000 description 26
- 239000004480 active ingredient Substances 0.000 description 21
- 239000003550 marker Substances 0.000 description 16
- 229910000831 Steel Inorganic materials 0.000 description 13
- 238000009472 formulation Methods 0.000 description 13
- 239000010959 steel Substances 0.000 description 13
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 12
- 238000003756 stirring Methods 0.000 description 12
- 239000000839 emulsion Substances 0.000 description 11
- 229920000180 alkyd Polymers 0.000 description 10
- 239000004615 ingredient Substances 0.000 description 10
- 239000003973 paint Substances 0.000 description 10
- 241000157282 Aesculus Species 0.000 description 9
- -1 builders Substances 0.000 description 9
- 235000010181 horse chestnut Nutrition 0.000 description 9
- 239000007864 aqueous solution Substances 0.000 description 8
- 238000010790 dilution Methods 0.000 description 8
- 239000012895 dilution Substances 0.000 description 8
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 230000009471 action Effects 0.000 description 6
- 125000004185 ester group Chemical group 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 239000002689 soil Substances 0.000 description 5
- 229930194542 Keto Natural products 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- 125000000468 ketone group Chemical group 0.000 description 4
- 235000019271 petrolatum Nutrition 0.000 description 4
- 239000012085 test solution Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 description 3
- WAEVWDZKMBQDEJ-UHFFFAOYSA-N 2-[2-(2-methoxypropoxy)propoxy]propan-1-ol Chemical compound COC(C)COC(C)COC(C)CO WAEVWDZKMBQDEJ-UHFFFAOYSA-N 0.000 description 3
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- JFDZBHWFFUWGJE-UHFFFAOYSA-N benzonitrile Chemical compound N#CC1=CC=CC=C1 JFDZBHWFFUWGJE-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000003205 fragrance Substances 0.000 description 3
- 239000004519 grease Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- YNAVUWVOSKDBBP-UHFFFAOYSA-O morpholinium Chemical compound [H+].C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-O 0.000 description 3
- 238000005063 solubilization Methods 0.000 description 3
- 230000007928 solubilization Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- JSPLKZUTYZBBKA-UHFFFAOYSA-N trioxidane Chemical group OOO JSPLKZUTYZBBKA-UHFFFAOYSA-N 0.000 description 3
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 2
- NTPLXRHDUXRPNE-UHFFFAOYSA-N 4-methoxyacetophenone Chemical compound COC1=CC=C(C(C)=O)C=C1 NTPLXRHDUXRPNE-UHFFFAOYSA-N 0.000 description 2
- FHQRDEDZJIFJAL-UHFFFAOYSA-N 4-phenylmorpholine Chemical compound C1COCCN1C1=CC=CC=C1 FHQRDEDZJIFJAL-UHFFFAOYSA-N 0.000 description 2
- FFWSICBKRCICMR-UHFFFAOYSA-N 5-methyl-2-hexanone Chemical compound CC(C)CCC(C)=O FFWSICBKRCICMR-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
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- 235000013162 Cocos nucifera Nutrition 0.000 description 2
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Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
- C11D17/0017—Multi-phase liquid compositions
- C11D17/0021—Aqueous microemulsions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/43—Solvents
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US37391089A | 1989-06-29 | 1989-06-29 | |
| PCT/US1990/003317 WO1991000337A1 (en) | 1989-06-29 | 1990-06-12 | Improved builder-containing aqueous cleaner/degreaser microemulsion compositions |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69029472D1 DE69029472D1 (de) | 1997-01-30 |
| DE69029472T2 true DE69029472T2 (de) | 1997-07-03 |
Family
ID=23474397
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69029472T Expired - Fee Related DE69029472T2 (de) | 1989-06-29 | 1990-06-12 | Verbesserte gerüststoffe enthaltende wässrige reinigungs-/entfettungs-mikroemulsionszusammensetzungen |
Country Status (9)
| Country | Link |
|---|---|
| EP (1) | EP0479888B1 (ja) |
| JP (1) | JP2671234B2 (ja) |
| AT (1) | ATE146521T1 (ja) |
| AU (1) | AU6031790A (ja) |
| CA (1) | CA2057027C (ja) |
| DE (1) | DE69029472T2 (ja) |
| DK (1) | DK0479888T3 (ja) |
| ES (1) | ES2100884T3 (ja) |
| WO (1) | WO1991000337A1 (ja) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2223995B1 (de) | 2007-09-19 | 2018-03-07 | intelligents fluids GmbH | Formulierungen zur entfernung von farbschichten und diversen schmutzschichten von oberflächen, verfahren zur herstellung des mittels und verfahren zur reinigung |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR960701189A (ko) * | 1993-03-30 | 1996-02-24 | 테릴 켄트 퀼리 | 세정 조성물 및 이의 사용방법(cleaning compositions and method of use) |
| JPH08508523A (ja) * | 1993-03-30 | 1996-09-10 | ミネソタ マイニング アンド マニュファクチャリング カンパニー | 改良した床塗膜除去用組成物および方法 |
| BR9406028A (pt) * | 1993-03-30 | 1995-12-26 | Minnesota Mining & Mfg | Composição e processo de limpeza |
| BR9609495A (pt) * | 1995-07-18 | 1999-03-02 | Unilever Nv | Composição e processos de remoção de gordura cozida sobre uma superfície de metal e de limpeza de uma área para estacionamento |
| US5922665A (en) * | 1997-05-28 | 1999-07-13 | Minnesota Mining And Manufacturing Company | Aqueous cleaning composition including a nonionic surfactant and a very slightly water-soluble organic solvent suitable for hydrophobic soil removal |
| FR2795088B1 (fr) * | 1999-06-21 | 2002-05-24 | Atofina | Compositions de nettoyage a froid du type microemulsions |
| US6407051B1 (en) * | 2000-02-07 | 2002-06-18 | Ecolab Inc. | Microemulsion detergent composition and method for removing hydrophobic soil from an article |
| GB2400375A (en) * | 2003-04-09 | 2004-10-13 | Hassan Scott Lisa | Non-emulsifying aqueous cleaner-degreaser |
| DE10353986A1 (de) * | 2003-11-19 | 2005-06-30 | Henkel Kgaa | Tensidgranulat mit hydrophoben Inhaltsstoffen |
| US8420586B2 (en) | 2008-04-18 | 2013-04-16 | Ecolab Usa Inc. | Thickened oven cleaner comprising a glutamic acid salt or disodium ethanol diglycine chelant |
| US8329630B2 (en) | 2008-04-18 | 2012-12-11 | Ecolab Usa Inc. | Ready to use thickened degreaser and associated methods |
| EP2304011B1 (en) * | 2008-07-14 | 2013-03-27 | The Procter & Gamble Company | Solvent system for microemulsion or protomicroemulsion and compositions using the solvent system |
| DE102009014380A1 (de) | 2009-03-26 | 2010-10-07 | Bubbles And Beyond Gmbh | Verfahren und Zusammensetzung zum Reinigen von Gegenständen |
| US20120252713A1 (en) * | 2010-09-24 | 2012-10-04 | Invista North America S.A.R.L. | Composition for surface treatment and process |
| ES2428799B1 (es) * | 2012-05-04 | 2014-09-29 | Javier DÍAZ RODRIGUEZ | Producto desengrasante de limpieza para múltiples superficies |
| WO2015193280A1 (de) * | 2014-06-17 | 2015-12-23 | Chemetall Gmbh | Reinigungsmittel zur schonenden entfernung von tinten und marker |
| CN112481621B (zh) * | 2020-11-27 | 2023-07-25 | 德旭新材料(佛冈)有限公司 | 一种金属清洗剂及其制备方法 |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4264466A (en) * | 1980-02-14 | 1981-04-28 | The Procter & Gamble Company | Mulls containing chain structure clay suspension aids |
| JPS56145998A (en) * | 1980-04-15 | 1981-11-13 | Ube Industries | Detergent |
| US4414128A (en) * | 1981-06-08 | 1983-11-08 | The Procter & Gamble Company | Liquid detergent compositions |
| US4472291A (en) * | 1983-03-07 | 1984-09-18 | Rosano Henri L | High viscosity microemulsions |
| JPS59176398A (ja) * | 1983-03-28 | 1984-10-05 | マークテック株式会社 | 液体洗浄剤 |
| GB2144763B (en) * | 1983-08-11 | 1987-10-28 | Procter & Gamble | Liquid detergent compositions with magnesium salts |
| FR2551766B1 (fr) * | 1983-09-13 | 1986-06-06 | Elf Aquitaine | Composition aqueuse pour la dispersion de substances hydrophobes applicable notamment au nettoyage d'objets souilles par une peinture ou similaire |
| US4758377A (en) * | 1985-09-24 | 1988-07-19 | The Proctor & Gamble Company | Viscous phase stable liquid scouring cleansers containing solvent |
| US5076954A (en) * | 1986-05-21 | 1991-12-31 | Colgate-Palmolive Company | Stable microemulsion cleaning composition |
| CA1283511C (en) * | 1986-09-02 | 1991-04-30 | Colgate-Palmolive | Laundry pre-spotter composition providing improved oily soil removal |
| US4769172A (en) * | 1986-09-22 | 1988-09-06 | The Proctor & Gamble Company | Built detergent compositions containing polyalkyleneglycoliminodiacetic acid |
| AU605858B2 (en) * | 1987-06-04 | 1991-01-24 | Minnesota Mining And Manufacturing Company | Aqueous-based composition for removing coatings |
| GB8802106D0 (en) * | 1988-01-30 | 1988-02-24 | Procter & Gamble | Hard-surface cleaning compositions |
| US4921629A (en) * | 1988-04-13 | 1990-05-01 | Colgate-Palmolive Company | Heavy duty hard surface liquid detergent |
-
1990
- 1990-06-12 ES ES90910985T patent/ES2100884T3/es not_active Expired - Lifetime
- 1990-06-12 DE DE69029472T patent/DE69029472T2/de not_active Expired - Fee Related
- 1990-06-12 JP JP2510224A patent/JP2671234B2/ja not_active Expired - Fee Related
- 1990-06-12 WO PCT/US1990/003317 patent/WO1991000337A1/en active IP Right Grant
- 1990-06-12 EP EP90910985A patent/EP0479888B1/en not_active Expired - Lifetime
- 1990-06-12 AT AT90910985T patent/ATE146521T1/de not_active IP Right Cessation
- 1990-06-12 CA CA002057027A patent/CA2057027C/en not_active Expired - Lifetime
- 1990-06-12 DK DK90910985.2T patent/DK0479888T3/da active
- 1990-06-12 AU AU60317/90A patent/AU6031790A/en not_active Abandoned
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2223995B1 (de) | 2007-09-19 | 2018-03-07 | intelligents fluids GmbH | Formulierungen zur entfernung von farbschichten und diversen schmutzschichten von oberflächen, verfahren zur herstellung des mittels und verfahren zur reinigung |
Also Published As
| Publication number | Publication date |
|---|---|
| WO1991000337A1 (en) | 1991-01-10 |
| EP0479888B1 (en) | 1996-12-18 |
| JPH05500675A (ja) | 1993-02-12 |
| CA2057027A1 (en) | 1990-12-30 |
| DK0479888T3 (da) | 1997-06-09 |
| DE69029472D1 (de) | 1997-01-30 |
| JP2671234B2 (ja) | 1997-10-29 |
| EP0479888A4 (en) | 1992-06-03 |
| ES2100884T3 (es) | 1997-07-01 |
| AU6031790A (en) | 1991-01-17 |
| CA2057027C (en) | 1999-04-06 |
| ATE146521T1 (de) | 1997-01-15 |
| EP0479888A1 (en) | 1992-04-15 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8364 | No opposition during term of opposition | ||
| 8339 | Ceased/non-payment of the annual fee |