DE69010743D1 - Silikometallatmolekularsiebe und deren Anwendung als Katalysatoren bei der Oxydierung von Alkanen. - Google Patents

Silikometallatmolekularsiebe und deren Anwendung als Katalysatoren bei der Oxydierung von Alkanen.

Info

Publication number
DE69010743D1
DE69010743D1 DE69010743T DE69010743T DE69010743D1 DE 69010743 D1 DE69010743 D1 DE 69010743D1 DE 69010743 T DE69010743 T DE 69010743T DE 69010743 T DE69010743 T DE 69010743T DE 69010743 D1 DE69010743 D1 DE 69010743D1
Authority
DE
Germany
Prior art keywords
silicometalate
alkanes
catalysts
oxidation
molecular sieves
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69010743T
Other languages
English (en)
Other versions
DE69010743T2 (de
Inventor
Vincent A Durante
Darrell W Walker
Steven M Gussow
James E Lyons
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sunoco Inc R&M
Original Assignee
Sunoco Inc R&M
Sun Co Inc R&M
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sunoco Inc R&M, Sun Co Inc R&M filed Critical Sunoco Inc R&M
Publication of DE69010743D1 publication Critical patent/DE69010743D1/de
Application granted granted Critical
Publication of DE69010743T2 publication Critical patent/DE69010743T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/37—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
    • C07C45/39—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups being a secondary hydroxyl group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/76—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
    • C07C2/82—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen oxidative coupling
    • C07C2/84—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen oxidative coupling catalytic
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
    • C07C29/50—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/36—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in compounds containing six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/37—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
    • C07C45/38—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups being a primary hydroxyl group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/88—Ferrosilicates; Ferroaluminosilicates
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
DE69010743T 1989-04-17 1990-04-09 Silikometallatmolekularsiebe und deren Anwendung als Katalysatoren bei der Oxydierung von Alkanen. Expired - Fee Related DE69010743T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/338,916 US4918249A (en) 1989-04-17 1989-04-17 Silicometallate molecular sieves and their use as catalysts in oxidation of alkanes

Publications (2)

Publication Number Publication Date
DE69010743D1 true DE69010743D1 (de) 1994-08-25
DE69010743T2 DE69010743T2 (de) 1995-03-16

Family

ID=23326681

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69010743T Expired - Fee Related DE69010743T2 (de) 1989-04-17 1990-04-09 Silikometallatmolekularsiebe und deren Anwendung als Katalysatoren bei der Oxydierung von Alkanen.

Country Status (6)

Country Link
US (1) US4918249A (de)
EP (1) EP0393895B1 (de)
JP (1) JP2844545B2 (de)
CA (1) CA2013805A1 (de)
DE (1) DE69010743T2 (de)
NO (1) NO901535L (de)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1243772B (it) * 1990-08-01 1994-06-28 Eniricerche Spa Procedimento per l'ossidazione di composti paraffinici con ossigeno
US5414157A (en) * 1990-10-17 1995-05-09 Sun Company, Inc. (R&M) Catalytic oxidation of alkanes
US5132472A (en) * 1990-10-17 1992-07-21 Sun Refining And Marketing Company Catalytic oxidation of alkanes
US5347057A (en) * 1993-01-25 1994-09-13 Khan Mirza M T Method for oxidation of methane and other hydro-carbons
NL9300149A (nl) * 1993-01-26 1994-08-16 Univ Delft Tech Werkwijze voor de gekatalyseerde autoxidatie van (cyclo)alkanen, (cyclo)alkylaromaten en daarvan afgeleide alcoholen.
US5345011A (en) * 1993-09-20 1994-09-06 Sun Company, Inc. (R&M) New manganese catalyst for light alkane oxidation
DE10054457A1 (de) * 2000-11-03 2002-05-08 Sued Chemie Ag Fe-dotierter Silica-Katalysator
US6709473B2 (en) * 2002-04-09 2004-03-23 Alan A. Cheney Pourable gas fireplace crackling composition
US7868201B2 (en) * 2005-07-01 2011-01-11 Exxonmobil Research And Engineering Company Process and catalyst for oxidation of hydrocarbons
JP5176426B2 (ja) * 2007-03-16 2013-04-03 住友化学株式会社 シクロアルカノール及び／又はシクロアルカノンの製造方法
US7812201B2 (en) 2008-10-01 2010-10-12 Targa Resources, Inc. Process and catalyst for converting alkanes
US20120259145A1 (en) 2011-04-06 2012-10-11 Stauffer John E Manufacture of methanol
CN104024191B (zh) * 2011-10-18 2017-08-08 卡迪夫大学学院顾问有限公司 使用氧气对烷烃的选择性氧化
WO2022056146A1 (en) 2020-09-14 2022-03-17 Chevron Phillips Chemical Company Lp Transition metal-catalyzed production of alcohol and carbonyl compounds from hydrocarbons

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3321547A (en) * 1964-11-23 1967-05-23 Phillips Petroleum Co Conversion of propane to diisopropyl
GB1244001A (en) * 1968-05-01 1971-08-25 Ici Ltd Oxygenated hydrocarbons production
US4165340A (en) * 1976-08-23 1979-08-21 Daikin Kogyo Co., Ltd. Process for preparing hexafluoropropanone-2
DE2743113C3 (de) * 1977-09-24 1980-09-04 Chemische Werke Huels Ag, 4370 Marl Verfahren zur Herstellung von Gemischen aus Formaldehyd und Methanol durch partielle Oxidation von Methan
US4707500A (en) * 1979-11-07 1987-11-17 National Distillers And Chemical Corporation Synthetic crystalline ferroborosilicate compositions, the preparation thereof and their use in the conversion of synthesis gas to low molecular weight hydrocarbons
EP0030088B1 (de) * 1979-11-30 1982-06-30 Mobil Oil Corporation Gleichzeitige Herstellung von 2-Alkanonen und Phenolen
US4472314A (en) * 1980-05-27 1984-09-18 Allied Corporation Bismuth-containing mixed oxides of perovskite structure in oxidation of acyclic hydrocarbons
US4604371A (en) * 1981-06-19 1986-08-05 Union Oil Company Of California Oxidation catalyst
US4607130A (en) * 1981-11-21 1986-08-19 Mobil Oil Corporation Acid-catalyzed organic compound conversion
FR2522322A1 (fr) * 1982-03-01 1983-09-02 British Petroleum Co Procede d'oxydation catalytique d'hydrocarbures paraffiniques en alcools
US4495041A (en) * 1982-04-15 1985-01-22 Mobil Oil Corporation Photochemical process using shape-selective photoassisted heterogenous catalyst compositions
DE3406751A1 (de) * 1982-10-07 1985-08-29 Baerns, Manfred, Prof. Dr., 4630 Bochum Verfahren der oxidativen kopplung von methan zu c(pfeil abwaerts)2(pfeil abwaerts)-kohlenwasserstoffen, verfahren zur herstellung der katalysatoren und vorrichtungen zur durchfuehrung der oxidativen kopplung
DE3237079A1 (de) * 1982-10-07 1984-04-12 Manfred Prof. Dr. 4630 Bochum Baerns Verfahren zur herstellung von ethan und bzw. oder ethylen aus methan
US4605805A (en) * 1983-02-14 1986-08-12 Mobil Oil Corporation Acid-catalyzed organic compound conversion
US4554396A (en) * 1984-09-18 1985-11-19 Mobil Oil Corporation Olefin upgrading with ferrosilicate zeolite catalyst
US4803187A (en) * 1987-07-20 1989-02-07 Sun Refining And Marketing Company Alkane oxidation catalysts

Also Published As

Publication number Publication date
JP2844545B2 (ja) 1999-01-06
EP0393895A2 (de) 1990-10-24
US4918249A (en) 1990-04-17
EP0393895A3 (de) 1991-03-13
CA2013805A1 (en) 1990-10-17
NO901535L (no) 1990-10-18
DE69010743T2 (de) 1995-03-16
JPH032132A (ja) 1991-01-08
EP0393895B1 (de) 1994-07-20
NO901535D0 (no) 1990-04-04

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Legal Events

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8339 Ceased/non-payment of the annual fee