DE3750154D1 - Oberflächeträgerkatalysatoren aus kernigen Metallverbindungen, deren Herstellung und deren Anwendung bei der Synthese von Kohlenwasserstoffen. - Google Patents

Oberflächeträgerkatalysatoren aus kernigen Metallverbindungen, deren Herstellung und deren Anwendung bei der Synthese von Kohlenwasserstoffen.

Info

Publication number
DE3750154D1
DE3750154D1 DE3750154T DE3750154T DE3750154D1 DE 3750154 D1 DE3750154 D1 DE 3750154D1 DE 3750154 T DE3750154 T DE 3750154T DE 3750154 T DE3750154 T DE 3750154T DE 3750154 D1 DE3750154 D1 DE 3750154D1
Authority
DE
Germany
Prior art keywords
hydrocarbons
synthesis
production
metal compounds
supported catalysts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE3750154T
Other languages
English (en)
Other versions
DE3750154T2 (de
Inventor
William Claus Behrmann
Charles Harrison Mauldin
Kym Brian Arcuri
Mordechay Herskowitz
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Research and Engineering Co filed Critical Exxon Research and Engineering Co
Application granted granted Critical
Publication of DE3750154D1 publication Critical patent/DE3750154D1/de
Publication of DE3750154T2 publication Critical patent/DE3750154T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889—Manganese, technetium or rhenium
    • B01J23/8896—Rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8913—Cobalt and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0232—Coating by pulverisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C07C1/043—Catalysts; their physical properties characterised by the composition
    • C07C1/0435—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C07C1/0445—Preparation; Activation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/396—Distribution of the active metal ingredient
    • B01J35/397—Egg shell like
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of rare earths
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/12—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of actinides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/32—Manganese, technetium or rhenium
    • C07C2523/36—Rhenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/46—Ruthenium, rhodium, osmium or iridium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/75—Cobalt
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
    • C07C2523/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36 with rare earths or actinides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
    • C07C2523/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/889—Manganese, technetium or rhenium
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
DE3750154T 1986-10-03 1987-10-02 Oberflächeträgerkatalysatoren aus kernigen Metallverbindungen, deren Herstellung und deren Anwendung bei der Synthese von Kohlenwasserstoffen. Expired - Lifetime DE3750154T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US91478186A 1986-10-03 1986-10-03
US4664987A 1987-05-07 1987-05-07
US7251787A 1987-07-13 1987-07-13

Publications (2)

Publication Number Publication Date
DE3750154D1 true DE3750154D1 (de) 1994-08-04
DE3750154T2 DE3750154T2 (de) 1994-10-20

Family

ID=27366947

Family Applications (1)

Application Number Title Priority Date Filing Date
DE3750154T Expired - Lifetime DE3750154T2 (de) 1986-10-03 1987-10-02 Oberflächeträgerkatalysatoren aus kernigen Metallverbindungen, deren Herstellung und deren Anwendung bei der Synthese von Kohlenwasserstoffen.

Country Status (7)

Country Link
EP (1) EP0266898B1 (de)
JP (1) JP2572079B2 (de)
AU (1) AU589806B2 (de)
CA (1) CA1312066C (de)
DE (1) DE3750154T2 (de)
MY (1) MY130055A (de)
NO (1) NO178611C (de)

Families Citing this family (30)

* Cited by examiner, † Cited by third party
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CN1016684B (zh) * 1985-09-12 1992-05-20 埃克森研究工程公司 一种使用改进的钴催化剂转化甲醇的方法
US5227407A (en) * 1985-12-30 1993-07-13 Exxon Research And Engineering Company Water addition for increased CO/H2 hydrocarbon synthesis activity over catalysts comprising cobalt, ruthenium and mixtures thereof which may include a promoter metal
US5036032A (en) * 1988-03-25 1991-07-30 Exxon Research And Engineering Company Selective catalysts and their preparation for catalytic hydrocarbon synthesis
CA1340441C (en) * 1988-04-25 1999-03-16 Chang Jung Kim Water addition for increased co/h2 hydrocarbon synthesis activity over catalysts comprising rhenium promoted cobalt on titania
US5070064A (en) * 1989-08-07 1991-12-03 Exxon Research And Engineering Company Catalyst pretreatment method
US5028634A (en) * 1989-08-23 1991-07-02 Exxon Research & Engineering Company Two stage process for hydrocarbon synthesis
US5168091A (en) * 1990-10-15 1992-12-01 Exxon Research And Engineering Company Activation conditions to maximize the HSC activity of supported cobalt catalysts
DZ2013A1 (fr) * 1995-04-07 2002-10-23 Sastech Ltd Catalyseurs.
US5689031A (en) 1995-10-17 1997-11-18 Exxon Research & Engineering Company Synthetic diesel fuel and process for its production
US6296757B1 (en) 1995-10-17 2001-10-02 Exxon Research And Engineering Company Synthetic diesel fuel and process for its production
US5766274A (en) 1997-02-07 1998-06-16 Exxon Research And Engineering Company Synthetic jet fuel and process for its production
US6117814A (en) * 1998-02-10 2000-09-12 Exxon Research And Engineering Co. Titania catalysts their preparation and use in fischer-tropsch synthesis
US6333294B1 (en) 1998-05-22 2001-12-25 Conoco Inc. Fischer-tropsch processes and catalysts with promoters
US6776898B1 (en) * 2000-04-04 2004-08-17 Exxonmobil Research And Engineering Company Process for softening fischer-tropsch wax with mild hydrotreating
US6695965B1 (en) 2000-04-04 2004-02-24 Exxonmobil Research And Engineering Company Process for adjusting the hardness of Fischer-Tropsch wax by blending
US6900151B2 (en) * 2001-11-13 2005-05-31 Exxonmobil Research And Engineering Company In situ catalyst regeneration/activation process
US6774148B2 (en) * 2002-06-25 2004-08-10 Chevron U.S.A. Inc. Process for conversion of LPG and CH4 to syngas and higher valued products
GB0222240D0 (en) 2002-09-25 2002-10-30 Ici Plc Cobalt catalysts
WO2004058401A1 (en) 2002-12-20 2004-07-15 Conocophillips Company Attrition resistant bulk metal catalysts and methods of making and using same
TW200526321A (en) * 2003-09-26 2005-08-16 Basf Ag Process for producing a catalyst for gas-phase oxidations
RU2412001C2 (ru) * 2005-12-16 2011-02-20 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Способ приготовления катализатора синтеза углеводородов
AU2008215570B2 (en) * 2007-02-14 2012-05-10 Nippon Oil Corporation Process for production of hydrocarbons by reduction of carbon monoxide
JP5025301B2 (ja) * 2007-03-28 2012-09-12 Ｊｘ日鉱日石エネルギー株式会社 炭化水素の製造方法
JP5013919B2 (ja) * 2007-03-28 2012-08-29 Ｊｘ日鉱日石エネルギー株式会社 炭化水素製造触媒とその調製法
US8722570B2 (en) 2007-10-26 2014-05-13 Exxonmobil Research And Engineering Company Cobalt catalyst with improved activity maintenance
WO2010061623A1 (ja) * 2008-11-28 2010-06-03 財団法人北九州産業学術推進機構 炭化水素製造用触媒の製造方法及び炭化水素製造用触媒、並びに炭化水素の製造方法
US9647284B2 (en) 2013-03-15 2017-05-09 Exxonmobil Research And Engineering Company Integration of molten carbonate fuel cells in Fischer-Tropsch synthesis
US20180037825A1 (en) * 2014-12-12 2018-02-08 Bp P.L.C. Fischer-tropsch process using reductively-activated cobalt catalyst
KR20180124094A (ko) 2016-03-17 2018-11-20 엑손모빌 리서치 앤드 엔지니어링 컴퍼니 용융 카보네이트 연료 전지의 통합 작동 방법
WO2023283038A1 (en) 2021-07-08 2023-01-12 ExxonMobil Technology and Engineering Company Conversion of synthesis gas to liquid fuels

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BE605998A (de) * 1950-10-30
EP0109702B1 (de) * 1982-11-22 1988-03-09 Shell Internationale Researchmaatschappij B.V. Verfahren zur Herstellung von Kohlenwasserstoffen
US4465789A (en) * 1983-04-04 1984-08-14 American Cyanamid Company Hydrotreating catalyst support having dual pore structure
DE3340569A1 (de) * 1983-11-09 1985-05-23 Sued Chemie Ag Katalysator zur herstellung von synthesegas bzw. von wasserstoff und verfahren zu dessen herstellung
US4568663A (en) * 1984-06-29 1986-02-04 Exxon Research And Engineering Co. Cobalt catalysts for the conversion of methanol to hydrocarbons and for Fischer-Tropsch synthesis
US4542122A (en) * 1984-06-29 1985-09-17 Exxon Research And Engineering Co. Cobalt catalysts for the preparation of hydrocarbons from synthesis gas and from methanol
US4558030A (en) * 1984-06-29 1985-12-10 Exxon Research And Engineering Co. Ruthenium-rhenium catalyst on titania support for Fischer-Tropsch synthesis
JPH0587297A (ja) * 1991-09-30 1993-04-06 Ishikawajima Harima Heavy Ind Co Ltd 輸送船からの低温液払出し方法

Also Published As

Publication number Publication date
DE3750154T2 (de) 1994-10-20
JPS63147545A (ja) 1988-06-20
NO178611C (no) 1996-05-02
CA1312066C (en) 1992-12-29
NO178611B (no) 1996-01-22
EP0266898A3 (en) 1989-03-22
EP0266898B1 (de) 1994-06-29
NO874162L (no) 1988-04-05
AU589806B2 (en) 1989-10-19
EP0266898A2 (de) 1988-05-11
MY130055A (en) 2007-05-31
JP2572079B2 (ja) 1997-01-16
AU7930687A (en) 1988-04-14
NO874162D0 (no) 1987-10-02

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