DE69022337D1 - 2-Stufenverfahren zur Synthese von Kohlenwasserstoffen. - Google Patents

2-Stufenverfahren zur Synthese von Kohlenwasserstoffen.

Info

Publication number
DE69022337D1
DE69022337D1 DE69022337T DE69022337T DE69022337D1 DE 69022337 D1 DE69022337 D1 DE 69022337D1 DE 69022337 T DE69022337 T DE 69022337T DE 69022337 T DE69022337 T DE 69022337T DE 69022337 D1 DE69022337 D1 DE 69022337D1
Authority
DE
Germany
Prior art keywords
hydrocarbons
synthesis
step process
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69022337T
Other languages
English (en)
Other versions
DE69022337T2 (de
Inventor
Rocco Anthony Fiato
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Research and Engineering Co filed Critical Exxon Research and Engineering Co
Application granted granted Critical
Publication of DE69022337D1 publication Critical patent/DE69022337D1/de
Publication of DE69022337T2 publication Critical patent/DE69022337T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/333—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the platinum-group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0485—Set-up of reactors or accessories; Multi-step processes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of rare earths
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/32—Manganese, technetium or rhenium
    • C07C2523/36—Rhenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/46—Ruthenium, rhodium, osmium or iridium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/75—Cobalt

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
DE69022337T 1989-08-23 1990-08-23 2-Stufenverfahren zur Synthese von Kohlenwasserstoffen. Expired - Fee Related DE69022337T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/397,219 US5028634A (en) 1989-08-23 1989-08-23 Two stage process for hydrocarbon synthesis

Publications (2)

Publication Number Publication Date
DE69022337D1 true DE69022337D1 (de) 1995-10-19
DE69022337T2 DE69022337T2 (de) 1996-04-25

Family

ID=23570310

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69022337T Expired - Fee Related DE69022337T2 (de) 1989-08-23 1990-08-23 2-Stufenverfahren zur Synthese von Kohlenwasserstoffen.

Country Status (7)

Country Link
US (1) US5028634A (de)
EP (1) EP0414555B1 (de)
AU (1) AU623573B2 (de)
CA (1) CA2022353C (de)
DE (1) DE69022337T2 (de)
MY (1) MY108535A (de)
NO (1) NO180713C (de)

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5258411A (en) * 1990-10-15 1993-11-02 Exxon Research And Engineering Co. Activation conditions to maximize the HCS activity of supported cobalt catalysts (OP-3706)
ZA935964B (en) * 1992-08-18 1994-03-15 Shell Res Ltd Process for the preparation of hydrocarbon fuels
US5498638A (en) * 1994-04-29 1996-03-12 Exxon Research & Engineering Co. Staged hydrocarbon synthesis process
AU740616B2 (en) * 1996-06-21 2001-11-08 Syntroleum Corporation Synthesis gas production system and method
MY118075A (en) 1996-07-09 2004-08-30 Syntroleum Corp Process for converting gas to liquids
US5950732A (en) * 1997-04-02 1999-09-14 Syntroleum Corporation System and method for hydrate recovery
US6011073A (en) * 1997-10-10 2000-01-04 Syntroleum Corporation System and method for converting light hydrocarbons to heavier hydrocarbons with separation of water into oxygen and hydrogen
US6368997B2 (en) * 1998-05-22 2002-04-09 Conoco Inc. Fischer-Tropsch processes and catalysts using fluorided supports
US6191066B1 (en) 1998-05-27 2001-02-20 Energy International Corporation Fischer-Tropsch activity for non-promoted cobalt-on-alumina catalysts
AU746882B2 (en) * 1998-08-20 2002-05-02 Conoco Inc. Fischer-tropsch processes using xerogel and aerogel catalysts by destabilizing aqueous colloids
US6319872B1 (en) 1998-08-20 2001-11-20 Conoco Inc Fischer-Tropsch processes using catalysts on mesoporous supports
US6262132B1 (en) 1999-05-21 2001-07-17 Energy International Corporation Reducing fischer-tropsch catalyst attrition losses in high agitation reaction systems
US6344491B1 (en) 1999-09-16 2002-02-05 Syntroleum Corporation Method for operating a fischer-tropsch process using a high pressure autothermal reactor as the pressure source for the process
US6169120B1 (en) * 1999-09-17 2001-01-02 Syntroleum Corporation Extended catalyst life two stage hydrocarbon synthesis process
US6331573B1 (en) * 2000-02-29 2001-12-18 Chevron U.S.A. Inc. Increased liquid sensitivity during fischer-tropsch synthesis by olefin incorporation
US6794417B2 (en) 2002-06-19 2004-09-21 Syntroleum Corporation System and method for treatment of water and disposal of contaminants produced by converting lighter hydrocarbons into heavier hydrocarbon
DE60307885T3 (de) † 2002-12-02 2010-12-16 Compactgtl Plc, Abingdon Katalytisches verfahren
GB0314790D0 (en) * 2003-06-25 2003-07-30 Accentus Plc Catalytic reactor and process
JP5155147B2 (ja) * 2005-03-16 2013-02-27 フュエルコア エルエルシー 合成炭化水素化合物を生成するためのシステム、方法、および組成物
US7855234B2 (en) 2005-07-20 2010-12-21 Shell Oil Company Fischer-tropsch process and reactor assembly
KR100920504B1 (ko) * 2007-09-04 2009-10-08 한국화학연구원 연속 흐름식 2중 촉매 반응 장치를 이용한 합성가스의피셔-트롭시 반응으로 액상의 탄화수소 혼합물 제조방법
GB201000971D0 (en) 2010-01-21 2010-03-10 Johnson Matthey Plc Process for the convertion of synthesis gas
GB201000993D0 (en) 2010-01-22 2010-03-10 Johnson Matthey Plc Catalyst support
KR101211376B1 (ko) * 2010-09-30 2012-12-13 한국에너지기술연구원 복합 반응이 가능한 ｆ-ｔ 기포탑 반응기
DE102021110735A1 (de) * 2021-04-27 2022-10-27 Ineratec Gmbh Verfahren zur Herstellung von Kohlenwasserstoffen

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2685596A (en) * 1949-08-30 1954-08-03 Standard Oil Dev Co Two-stage hydrocarbon synthesis process
US4568663A (en) * 1984-06-29 1986-02-04 Exxon Research And Engineering Co. Cobalt catalysts for the conversion of methanol to hydrocarbons and for Fischer-Tropsch synthesis
CA1312066C (en) * 1986-10-03 1992-12-29 William C. Behrmann Surface supported particulate metal compound catalysts, their use in hydrocarbon synthesis reactions and their preparation
US4801573A (en) * 1987-10-23 1989-01-31 501 Den Norske Stats Oljeslenskap A.S. Catalyst for production of hydrocarbons
ZA907530B (en) * 1989-11-14 1992-05-27 Sasol Ind Pty Ltd Fixed bed fischer-tropsch catalyst and manufacture thereof
CA2038773C (en) * 1990-04-04 1999-06-08 Kym B. Arcuri Slurry fischer-tropsch process with co/ti02 catalyst
CA2038772C (en) * 1990-04-04 2001-12-25 Eric Herbolzheimer Catalyst fluidization improvements

Also Published As

Publication number Publication date
US5028634A (en) 1991-07-02
DE69022337T2 (de) 1996-04-25
NO903689L (no) 1991-02-25
NO180713C (no) 1997-06-04
AU6120090A (en) 1991-02-28
CA2022353A1 (en) 1991-02-24
AU623573B2 (en) 1992-05-14
NO180713B (no) 1997-02-24
NO903689D0 (no) 1990-08-22
MY108535A (en) 1996-10-31
EP0414555A1 (de) 1991-02-27
EP0414555B1 (de) 1995-09-13
CA2022353C (en) 2000-06-06

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Legal Events

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8339 Ceased/non-payment of the annual fee