DE69004712D1 - Verfahren zur Herstellung von Polybutadien mit verbesserter Verarbeitkeit. - Google Patents

Verfahren zur Herstellung von Polybutadien mit verbesserter Verarbeitkeit.

Info

Publication number
DE69004712D1
DE69004712D1 DE90200300T DE69004712T DE69004712D1 DE 69004712 D1 DE69004712 D1 DE 69004712D1 DE 90200300 T DE90200300 T DE 90200300T DE 69004712 T DE69004712 T DE 69004712T DE 69004712 D1 DE69004712 D1 DE 69004712D1
Authority
DE
Germany
Prior art keywords
polybutadiene
preparation
improved processability
processability
improved
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE90200300T
Other languages
English (en)
Other versions
DE69004712T2 (de
Inventor
Piero Andreussi
Renzo Bianchi
Mario Bruzzone
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Enichem Elastomers Ltd
Original Assignee
Enichem Elastomers Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Enichem Elastomers Ltd filed Critical Enichem Elastomers Ltd
Publication of DE69004712D1 publication Critical patent/DE69004712D1/de
Application granted granted Critical
Publication of DE69004712T2 publication Critical patent/DE69004712T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08CTREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00Chemical modification of rubber
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F136/00Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F136/02Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F136/04Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F136/06Butadiene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
DE90200300T 1989-02-17 1990-02-09 Verfahren zur Herstellung von Polybutadien mit verbesserter Verarbeitkeit. Expired - Lifetime DE69004712T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT8919484A IT1230756B (it) 1989-02-17 1989-02-17 Metodo per la preparazione di polibutadiene a lavorabilita' migliorata.

Publications (2)

Publication Number Publication Date
DE69004712D1 true DE69004712D1 (de) 1994-01-05
DE69004712T2 DE69004712T2 (de) 1994-04-28

Family

ID=11158417

Family Applications (1)

Application Number Title Priority Date Filing Date
DE90200300T Expired - Lifetime DE69004712T2 (de) 1989-02-17 1990-02-09 Verfahren zur Herstellung von Polybutadien mit verbesserter Verarbeitkeit.

Country Status (8)

Country Link
US (1) US4990573A (de)
EP (1) EP0386808B1 (de)
JP (1) JP2964256B2 (de)
CA (1) CA2010284C (de)
DE (1) DE69004712T2 (de)
DK (1) DK0386808T3 (de)
ES (1) ES2059984T3 (de)
IT (1) IT1230756B (de)

Families Citing this family (90)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5314967A (en) * 1993-08-24 1994-05-24 Bridgestone/Firestone, Inc. Process and isomerizing agent for isomerizing partially hydrogenated diene polymers
US5310817A (en) * 1993-08-24 1994-05-10 Bridgestone/Firestone, Inc. Process and catalyst for producing partially hydrogenated diene polymers containing endo and exo chain trisubstituted unsaturation
JPH07268132A (ja) * 1994-03-28 1995-10-17 Sumitomo Rubber Ind Ltd ソリッドゴルフボール
US5453471B1 (en) * 1994-08-02 1999-02-09 Carbide Chemicals & Plastics T Gas phase polymerization process
DE4436059A1 (de) * 1994-10-10 1996-04-11 Bayer Ag Verfahren zur Herstellung von mittels Nd-Katalysatoren polymerisierten Dienkautschuken mit niedrigem cold-flow und geringem Eigengeruch
US6018007A (en) * 1997-09-22 2000-01-25 Bridgestone Corporation Synthesis of 1,4-trans-polybutadiene using a lanthanide organic acid salt catalyst
KR100365581B1 (ko) * 1999-02-25 2003-01-15 금호석유화학 주식회사 높은 1,4-시스 함량을 갖는 폴리부타디엔의 제조방법
KR100403090B1 (ko) * 1999-07-27 2003-10-30 금호석유화학 주식회사 높은 1,4-시스 함량을 갖는 폴리부타디엔의 제조방법
JP4898045B2 (ja) * 1999-11-12 2012-03-14 株式会社ブリヂストン ランタニドを基にした触媒を用いて製造した変性重合体
US6977281B1 (en) * 1999-11-12 2005-12-20 Bridgestone Corporation Modified polymers prepared with lanthanide-based catalysts
KR100352764B1 (ko) * 2000-03-16 2002-09-16 금호석유화학 주식회사 신규한 단분자 니오디뮴 카르복실레이트 화합물 및 이를포함하는 디엔 중합용 촉매
JP4965055B2 (ja) * 2000-11-10 2012-07-04 株式会社ブリヂストン 新規な官能化剤を用いて製造した官能化高シス−1,4−ポリブタジエン
KR100472649B1 (ko) 2002-11-22 2005-03-11 금호석유화학 주식회사 조절된 저온흐름성을 갖는 고 1,4-시스 폴리부타디엔의제조방법
ITMI20040076A1 (it) * 2004-01-22 2004-04-22 Polimeri Europa Spa Procedimento per la preparazione di polibutadiene a basso grado di ranificazione
WO2005087824A1 (en) 2004-03-02 2005-09-22 Bridgestone Corporation Bulk polymerization process
ITMI20042022A1 (it) * 2004-10-25 2005-01-25 Polimeri Europa Spa Processo per la preparazione di polibutadiene a basso grado di ramificazione
US7879952B2 (en) * 2005-12-28 2011-02-01 Bridgestone Corporation Functionalized polymers
US7671138B2 (en) * 2006-05-26 2010-03-02 Bridgestone Corporation Polymers functionized with hydrobenzamides
US20080006833A1 (en) * 2006-06-02 2008-01-10 Semiconductor Energy Laboratory Co., Ltd. Lighting device and liquid crystal display device
JP2007323544A (ja) * 2006-06-05 2007-12-13 Sony Corp 情報処理システム、情報処理装置、および方法、並びにコンピュータ・プログラム
US7732534B2 (en) * 2006-08-28 2010-06-08 Bridgestone Corporation Polymers functionalized with nitro compounds
CN101563398B (zh) 2006-10-06 2012-10-24 株式会社普利司通 支化聚合物及其合成和使用方法
US8088868B2 (en) 2006-12-19 2012-01-03 Bridgestone Corporation Polymers functionalized with protected oxime compounds
ZA200711158B (en) * 2006-12-28 2009-03-25 Bridgestone Corp A method for producing functionalized cis-1,4-polydienes having high cis-1,4-linkage content and high functionality
US8324329B2 (en) 2007-08-07 2012-12-04 Bridgestone Corporation Process for producing functionalized polymers
US7879958B2 (en) 2007-08-07 2011-02-01 Bridgestone Corporation Polyhydroxy compounds as polymerization quenching agents
US8314189B2 (en) 2007-10-12 2012-11-20 Bridgestone Corporation Polymers functionalized with heterocyclic nitrile compounds
KR100970767B1 (ko) 2007-12-12 2010-07-16 금호석유화학 주식회사 방향족 유기황화합물로 기능화된 1,4-시스 폴리부타디엔
ES2429447T3 (es) * 2007-12-28 2013-11-14 Bridgestone Corporation Polímero funcionalizado y métodos para su preparación y uso
RU2515980C2 (ru) 2007-12-31 2014-05-20 Бриджстоун Корпорейшн Способ получения полидиенов полимеризацией в объеме
US7825201B2 (en) 2007-12-31 2010-11-02 Bridgestone Corporation Process for producing polydienes
US8268933B2 (en) * 2007-12-31 2012-09-18 Bridgestone Corporation Polymers functionalized with polyimine compounds
RU2485146C2 (ru) * 2007-12-31 2013-06-20 Бриджстоун Корпорейшн Способ получения полимерной композиции и полимерная композиция
US7741418B2 (en) * 2007-12-31 2010-06-22 Bridgestone Corporation Process for producing polydienes
US7807763B2 (en) * 2008-04-07 2010-10-05 Bridgestone Corporation Method for bulk polymerization
US7906592B2 (en) * 2008-07-03 2011-03-15 Bridgestone Corporation Polymers functionalized with imide compounds containing a protected amino group
ATE510880T1 (de) * 2008-08-05 2011-06-15 Bridgestone Corp Verfahren zur verbesserung der kaltflussbeständigkeit von polymeren
US8188195B2 (en) * 2008-12-31 2012-05-29 Bridgestone Corporation Polymers functionalized with nitroso compounds
CN102361887B (zh) 2009-01-23 2013-06-26 株式会社普利司通 用包含被保护氨基的腈化合物官能化的聚合物
ES2616272T3 (es) 2009-01-23 2017-06-12 Bridgestone Corporation Polímeros funcionalizados con compuestos de policiano
US7902309B2 (en) 2009-02-23 2011-03-08 Bridgestone Corporation Process and catalyst system for polydiene production
US8623975B2 (en) 2009-06-24 2014-01-07 Bridgestone Corporation Process for producing polydienes
US20110077325A1 (en) 2009-09-30 2011-03-31 Bridgestone Corporation Functionalized polymers and methods for their manufacture
US8338544B2 (en) 2009-12-21 2012-12-25 Bridgestone Corporation Polymers functionalized with polyoxime compounds and methods for their manufacture
US20120296041A1 (en) 2010-01-22 2012-11-22 Steven Luo Polymers functionalized with nitrile compounds containing a protected amino group
RU2569673C2 (ru) 2010-09-23 2015-11-27 Бриджстоун Корпорейшн Способ получения полидиенов
US8748531B2 (en) 2010-12-10 2014-06-10 Bridgestone Corporation Polymers functionalized with oxime compounds containing an acyl group
US9273165B2 (en) 2011-02-05 2016-03-01 Bridgestone Corporation Lanthanide complex catalyst and polymerization method employing same
BR112013025124B1 (pt) 2011-03-29 2022-03-29 Bridgestone Corporation Polímeros funcionalizados com um éster carboxílico ou tiocarboxílico contendo um grupo amino sililado
JP2014528988A (ja) 2011-08-31 2014-10-30 株式会社ブリヂストン 保護されたアミノ基を含むラクトンまたはチオラクトンで官能化されたポリマー
US8962766B2 (en) 2011-09-15 2015-02-24 Bridgestone Corporation Polymers functionalized with polyhydrazone compounds
EP2780381B1 (de) 2011-11-17 2015-10-07 Bridgestone Corporation Verfahren zur herstellung von polydienen
WO2013075074A1 (en) 2011-11-18 2013-05-23 Bridgestone Corporation Method for producing polydienes and polydiene copolymers with reduced cold flow
WO2013086480A2 (en) 2011-12-09 2013-06-13 Bridgestone Corporation Method for producing polydienes and polydiene copolymers with reduced cold flow
RU2523799C1 (ru) 2011-12-20 2014-07-27 Чайна Петролеум Энд Кемикал Корпорейшн Добавка и способ для обрыва полимеризации и/или снижения вязкости раствора полимера
WO2013101648A1 (en) 2011-12-31 2013-07-04 Bridgestone Corporation Functionalized polymer
KR101975074B1 (ko) 2012-02-27 2019-05-03 가부시키가이샤 브리지스톤 고-시스 폴리디엔들의 제조 방법들
WO2013138270A1 (en) 2012-03-14 2013-09-19 Bridgestsone Corporation Process for producing polydienes
US8952090B2 (en) 2012-06-08 2015-02-10 Bridgestone Corporation Method for producing polydienes and polydiene copolymers with reduced cold flow
US9469706B2 (en) 2012-06-08 2016-10-18 Bridgestone Corporation Polymers functionalized with unsaturated heterocycles containing a protected amino group
US9115231B2 (en) 2012-07-26 2015-08-25 Bridgestone Corporation Polymers functionalized with protected hydrazone compounds containing an acyl group
EP2900702B1 (de) 2012-09-30 2018-05-02 Bridgestone Corporation Polymerisationsverfahren damit einem organometallischer katalysatorkomplex
US9663637B2 (en) 2012-12-31 2017-05-30 Bridgestone Corporation Polymers functionalized with unsaturated heterocycles containing an azolinyl group
US9127092B2 (en) 2012-12-31 2015-09-08 Bridgestone Corporation Method for producing polydienes and polydiene copolymers with reduced cold flow
US9315599B2 (en) 2013-01-02 2016-04-19 Bridgestone Corporation Functionalized polymers
SG11201507489VA (en) 2013-03-15 2015-10-29 Bridgestone Corp Polymers functionalized with heterocyclic imines
KR102456909B1 (ko) 2013-10-02 2022-10-21 가부시키가이샤 브리지스톤 시아노 기를 함유하는 이민 화합물로 작용화된 중합체
CN112048111B (zh) 2013-12-03 2022-12-02 株式会社普利司通 用于制备顺式-1,4-聚丁二烯和间同立构1,2-聚丁二烯的共混物的方法
US10030083B2 (en) 2014-05-15 2018-07-24 Bridgestone Corporation Polymers functionalized with protected oxime compounds containing a cyano group
EP3738927A1 (de) 2014-05-31 2020-11-18 Bridgestone Corporation Metallkomplexkatalysator polymerisationsverfahren damit und polymerprodukte dafür
WO2016057388A1 (en) 2014-10-07 2016-04-14 Bridgestone Corporation Method for producing polydienes and polydiene copolymers with reduced cold flow
CN107001522A (zh) 2014-10-10 2017-08-01 株式会社普利司通 聚合催化剂组合物及采用聚合催化剂组合物的方法
CN107207654A (zh) 2014-11-17 2017-09-26 株式会社普利司通 具有预成形催化剂的聚异戊二烯的本体聚合
WO2016123319A1 (en) 2015-01-28 2016-08-04 Bridgestone Corporation Aged lanthanide-based catalyst systems and their use in the preparation of cis-1,4-polydienes
CN113105573A (zh) 2015-01-28 2021-07-13 株式会社普利司通 具有改善的耐冷流性的顺式-1,4-聚二烯
US9884928B2 (en) 2015-04-01 2018-02-06 Bridgestone Corporation Polymers functionalized with activated nitrogen heterocycles containing a pendant functional group
US9738738B2 (en) 2015-04-01 2017-08-22 Bridgestone Corporation Polymers functionalized with activated nitrogen heterocycles containing a pendant functional group
US10370460B1 (en) 2015-05-20 2019-08-06 Bridgestone Corporation Process for producing functionalized polymers
US10077323B2 (en) 2015-07-24 2018-09-18 Bridgestone Corporation Polymers functionalized with imine compounds containing a protected thiol group
US10202474B2 (en) 2015-09-11 2019-02-12 Bridgestone Corporation Process for producing polydienes
CN109415457B (zh) 2016-05-19 2021-05-25 株式会社普利司通 制备官能化聚合物的方法
WO2018022994A1 (en) 2016-07-29 2018-02-01 Bridgestone Corporation Process for producing high cis-1,4-polydiene with lanthanide-based catalyst compositions
US10899718B2 (en) 2016-09-02 2021-01-26 Bridgestone Corporation Polymers functionalized with N-protected hydantoin compounds
CN109641482B (zh) 2016-09-02 2021-11-05 株式会社普利司通 具有通过聚合物胶水的原位硅氢加成制备的多个硅烷官能团的顺式-1,4-聚二烯的制备
JP6928102B2 (ja) 2016-11-09 2021-09-01 株式会社ブリヂストン ポリブタジエンとポリイソプレンとの高シス−1,4ブロックコポリマー
US10730985B2 (en) 2016-12-19 2020-08-04 Bridgestone Corporation Functionalized polymer, process for preparing and rubber compositions containing the functionalized polymer
JP7019818B2 (ja) 2017-12-15 2022-02-15 株式会社ブリヂストン 官能化ポリマー、官能化ポリマーの調製プロセス、及び官能化ポリマーを含有するゴム組成物
JP7059378B2 (ja) 2017-12-30 2022-04-25 株式会社ブリヂストン 複数の末端官能化ポリマーを含む組成物
US11702497B2 (en) 2018-12-21 2023-07-18 Lg Chem, Ltd. Modified conjugated diene-based polymer and method for preparing same
US11584808B2 (en) 2019-12-30 2023-02-21 Bridgestone Corporation Polymerization catalyst composition and method of employing same

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3704286A (en) * 1964-07-30 1972-11-28 Huels Chemische Werke Ag Production of unsaturated polymeric hydrocarbons having high mooney viscosities
DE1495370A1 (de) * 1964-07-30 1969-04-03 Huels Chemische Werke Ag Verfahren zur definierten Erhoehung des Molekulargewichtes ungesaettigter,polymerer Kohlenwasserstoffe
IT1151542B (it) * 1982-04-15 1986-12-24 Anic Spa Procedimento per la polimerizzazione di diolefine coniugate e mezzi adatti allo scopo
IT1164238B (it) * 1983-05-25 1987-04-08 Anic Spa Procedimento per la polimerizzazione del butadiene
IT1191612B (it) * 1985-05-15 1988-03-23 Enichem Elastomers Procedimento migliorato per la polimerizzazione o copolimerizzazione del butadiene
IT1186747B (it) * 1985-07-01 1987-12-16 Enichem Elastomers Procedimento migliorato per la polimerizzazione o copolimerizzazione del butadiene

Also Published As

Publication number Publication date
CA2010284C (en) 2000-05-16
IT1230756B (it) 1991-10-29
DK0386808T3 (da) 1994-02-07
CA2010284A1 (en) 1990-08-17
US4990573A (en) 1991-02-05
ES2059984T3 (es) 1994-11-16
EP0386808B1 (de) 1993-11-24
JPH02269704A (ja) 1990-11-05
IT8919484A0 (it) 1989-02-17
JP2964256B2 (ja) 1999-10-18
EP0386808A1 (de) 1990-09-12
DE69004712T2 (de) 1994-04-28

Similar Documents

Publication Publication Date Title
DE69004712D1 (de) Verfahren zur Herstellung von Polybutadien mit verbesserter Verarbeitkeit.
DE3854643T2 (de) Verfahren zur Herstellung von Polysiloxanoxyalkylen-Copolymeren.
DE3889393T2 (de) Verfahren zur Herstellung von 2,2,6,6-Tetramethyl-4-piperidylaminen.
DE3885366D1 (de) Verfahren zur Herstellung von Pyrrolo-(3,4-c)pyrrolen.
DE68907795T2 (de) Verfahren zur Herstellung von Bisphenolen.
DE59003791D1 (de) Verfahren zur Herstellung von 1,3,3-Trimethyl-5-oxo-cyclohexan-carbonitril.
DE69020830D1 (de) Verfahren zur Herstellung von (S)-4-Hydroxymethyl-gamma-lacton.
DE69019788D1 (de) Verfahren zur Herstellung von Organohalogensilanen.
DE68912039D1 (de) Verfahren zur Herstellung von Bisphenolen.
DE69006789T2 (de) Verfahren zur Herstellung von sulfoalkyl-substituierten Hydroxylaminen.
DE68915584D1 (de) Verfahren zur Herstellung von Difruktose-Dianhydrid III.
DE59007330D1 (de) Verfahren zur Herstellung von symmetrischen Diarylacetylenen.
DE68922714D1 (de) Verfahren zur Herstellung von 2-Phenylbenzotriazolen.
DE69014576D1 (de) Verfahren zur Herstellung von 3-Dibutylamino-6-methyl-7-anilinofluoran.
DE59005793D1 (de) Verfahren zur Herstellung von 2-Chlor-5-aminomethylpyridin.
DE69010608D1 (de) Verfahren zur Herstellung von 1,1-Diarylethanen.
DE59002525D1 (de) Verfahren zur Herstellung von 2-Chlor-4-nitro-alkylbenzol.
DE59003539D1 (de) Verfahren zur Herstellung von Polychlor-fluor-cyclopentenen.
DE59006329D1 (de) Verfahren zur Herstellung von Phenyloxdiazolylanilinen.
ATE115139T1 (de) Verfahren zur herstellung von 2,4-diamino-6- piperidinyl-pyrimidin-3-n-oxid.
DE3881103T2 (de) Verfahren zur Herstellung von 1,3,2-Oxazaphosphorinan.
DE68906465T2 (de) Verfahren zur Herstellung von 2,3-Dimethoxy-5-Methylbenzochinon.
DE59006003D1 (de) Verfahren zur Herstellung von Epoxysulfonaten.
DE59005732D1 (de) Verfahren zur Herstellung von 3-Trichlormethyl-pyridin.
DE69011996D1 (de) Verfahren zur Herstellung von 1,4-Dihydroxy-2-arylnaphthoat.

Legal Events

Date Code Title Description
8364 No opposition during term of opposition