DE68927745T2 - Waschmittelzusammensetzungen und Verfahren zu deren Herstellung - Google Patents
Waschmittelzusammensetzungen und Verfahren zu deren HerstellungInfo
- Publication number
- DE68927745T2 DE68927745T2 DE68927745T DE68927745T DE68927745T2 DE 68927745 T2 DE68927745 T2 DE 68927745T2 DE 68927745 T DE68927745 T DE 68927745T DE 68927745 T DE68927745 T DE 68927745T DE 68927745 T2 DE68927745 T2 DE 68927745T2
- Authority
- DE
- Germany
- Prior art keywords
- detergent
- weight
- granulation
- mixer
- soap
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Revoked
Links
- 239000003599 detergent Substances 0.000 title claims description 54
- 238000000034 method Methods 0.000 title claims description 42
- 239000000203 mixture Substances 0.000 title description 41
- 239000000843 powder Substances 0.000 claims description 70
- 238000005469 granulation Methods 0.000 claims description 48
- 230000003179 granulation Effects 0.000 claims description 48
- 238000005520 cutting process Methods 0.000 claims description 29
- 229910000503 Na-aluminosilicate Inorganic materials 0.000 claims description 26
- 235000012217 sodium aluminium silicate Nutrition 0.000 claims description 26
- 239000000429 sodium aluminium silicate Substances 0.000 claims description 25
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims description 25
- 238000003756 stirring Methods 0.000 claims description 24
- 239000008187 granular material Substances 0.000 claims description 22
- 239000000344 soap Substances 0.000 claims description 22
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 21
- 239000002245 particle Substances 0.000 claims description 18
- 239000003795 chemical substances by application Substances 0.000 claims description 15
- 229910000323 aluminium silicate Inorganic materials 0.000 claims description 14
- 239000010457 zeolite Substances 0.000 claims description 13
- 229910021536 Zeolite Inorganic materials 0.000 claims description 11
- 239000011230 binding agent Substances 0.000 claims description 10
- 239000007858 starting material Substances 0.000 claims description 10
- 238000002156 mixing Methods 0.000 claims description 9
- 230000000694 effects Effects 0.000 claims description 5
- 229910019142 PO4 Inorganic materials 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 4
- 239000010452 phosphate Substances 0.000 claims description 4
- 238000005056 compaction Methods 0.000 claims description 3
- 239000004094 surface-active agent Substances 0.000 description 22
- 239000007921 spray Substances 0.000 description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 16
- 229910000632 Alusil Inorganic materials 0.000 description 15
- 238000009472 formulation Methods 0.000 description 15
- 239000002585 base Substances 0.000 description 13
- 238000010298 pulverizing process Methods 0.000 description 12
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 10
- 239000004615 ingredient Substances 0.000 description 10
- 239000000047 product Substances 0.000 description 10
- 239000003945 anionic surfactant Substances 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- -1 alkylbenzene sulfonates Chemical class 0.000 description 8
- 238000001694 spray drying Methods 0.000 description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 239000002736 nonionic surfactant Substances 0.000 description 6
- 238000005406 washing Methods 0.000 description 6
- 229910000029 sodium carbonate Inorganic materials 0.000 description 5
- 238000000280 densification Methods 0.000 description 4
- 230000000704 physical effect Effects 0.000 description 4
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 230000001965 increasing effect Effects 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- 102000004190 Enzymes Human genes 0.000 description 2
- 108090000790 Enzymes Proteins 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 235000010724 Wisteria floribunda Nutrition 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- 239000011149 active material Substances 0.000 description 2
- 238000013019 agitation Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- MQRJBSHKWOFOGF-UHFFFAOYSA-L disodium;carbonate;hydrate Chemical compound O.[Na+].[Na+].[O-]C([O-])=O MQRJBSHKWOFOGF-UHFFFAOYSA-L 0.000 description 2
- 238000007580 dry-mixing Methods 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 239000010419 fine particle Substances 0.000 description 2
- 239000011236 particulate material Substances 0.000 description 2
- 239000002304 perfume Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- 235000019832 sodium triphosphate Nutrition 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical group [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- 102000005158 Subtilisins Human genes 0.000 description 1
- 108010056079 Subtilisins Proteins 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 150000008051 alkyl sulfates Chemical group 0.000 description 1
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 239000000378 calcium silicate Substances 0.000 description 1
- 229910052918 calcium silicate Inorganic materials 0.000 description 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 239000002178 crystalline material Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 239000003623 enhancer Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000012458 free base Substances 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000011812 mixed powder Substances 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 229920005646 polycarboxylate Polymers 0.000 description 1
- 239000012254 powdered material Substances 0.000 description 1
- 150000003138 primary alcohols Chemical class 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 150000003333 secondary alcohols Chemical class 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229910001388 sodium aluminate Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/82—Compounds containing silicon
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
- C11D17/065—High-density particulate detergent compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/128—Aluminium silicates, e.g. zeolites
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB888810193A GB8810193D0 (en) | 1988-04-29 | 1988-04-29 | Detergent compositions & process for preparing them |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE68927745D1 DE68927745D1 (de) | 1997-03-20 |
| DE68927745T2 true DE68927745T2 (de) | 1997-05-28 |
Family
ID=10636108
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE68927745T Revoked DE68927745T2 (de) | 1988-04-29 | 1989-04-27 | Waschmittelzusammensetzungen und Verfahren zu deren Herstellung |
Country Status (14)
Families Citing this family (53)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1323277C (en) * | 1988-04-29 | 1993-10-19 | Robert Donaldson | Process for preparing detergent compositions |
| GB8826110D0 (en) * | 1988-11-08 | 1988-12-14 | Unilever Plc | Enzyme-containing detergent compositions |
| GB8926718D0 (en) * | 1989-11-27 | 1990-01-17 | Unilever Plc | Process for the preparation of detergent compositions |
| GB9001285D0 (en) * | 1990-01-19 | 1990-03-21 | Unilever Plc | Detergent compositions and process for preparing them |
| GB9012612D0 (en) * | 1990-06-06 | 1990-07-25 | Unilever Plc | Detergents compositions |
| GB9012613D0 (en) * | 1990-06-06 | 1990-07-25 | Unilever Plc | Soap powder compositions |
| US5108646A (en) * | 1990-10-26 | 1992-04-28 | The Procter & Gamble Company | Process for agglomerating aluminosilicate or layered silicate detergent builders |
| DE4100306A1 (de) * | 1991-01-08 | 1992-07-09 | Henkel Kgaa | Kornfoermige, leicht loesliche trockenkonzentrate von inhaltsstoffen aus wasch- und/oder reinigungsmitteln und verfahren zu ihrer herstellung |
| GB9125035D0 (en) * | 1991-11-26 | 1992-01-22 | Unilever Plc | Detergent compositions and process for preparing them |
| DE4221736A1 (de) * | 1992-07-02 | 1994-01-05 | Henkel Kgaa | Feste waschaktive Zubereitung mit verbessertem Einspülverhalten |
| GB9225609D0 (en) * | 1992-12-08 | 1993-01-27 | Unilever Plc | Detergent composition |
| GB9305599D0 (en) * | 1993-03-18 | 1993-05-05 | Unilever Plc | Detergent compositions |
| US5610131A (en) * | 1993-04-30 | 1997-03-11 | The Procter & Gamble Company | Structuring liquid nonionic surfactants prior to granulation process |
| USH1604H (en) * | 1993-06-25 | 1996-11-05 | Welch; Robert G. | Process for continuous production of high density detergent agglomerates in a single mixer/densifier |
| AU673926B2 (en) * | 1993-07-13 | 1996-11-28 | Colgate-Palmolive Company, The | Process for preparing detergent composition having high bulk density |
| US5968891A (en) * | 1993-07-13 | 1999-10-19 | Colgate-Palmolive Co. | Process for preparing detergent composition having high bulk density |
| EP0643129A1 (en) * | 1993-09-07 | 1995-03-15 | The Procter & Gamble Company | Process for preparing detergent compositions |
| GB9322530D0 (en) * | 1993-11-02 | 1993-12-22 | Unilever Plc | Process for the production of a detergent composition |
| GB9323300D0 (en) * | 1993-11-11 | 1994-01-05 | Unilever Plc | Detergent composition |
| US5565137A (en) * | 1994-05-20 | 1996-10-15 | The Proctor & Gamble Co. | Process for making a high density detergent composition from starting detergent ingredients |
| GB9410677D0 (en) | 1994-05-27 | 1994-07-13 | Unilever Plc | Detergent compositions |
| GB9417354D0 (en) * | 1994-08-26 | 1994-10-19 | Unilever Plc | Detergent particles and process for their production |
| GB9417356D0 (en) * | 1994-08-26 | 1994-10-19 | Unilever Plc | Detergent particles and process for their production |
| HU225218B1 (en) * | 1995-09-04 | 2006-08-28 | Unilever Nv | Particulate detergent composition its preparation, and use of detergent builder or soil release polymers for the preparation of the detergent composition |
| GB9524494D0 (en) * | 1995-11-30 | 1996-01-31 | Unilever Plc | Detergent compositions containing soil release polymers |
| GB9524491D0 (en) * | 1995-11-30 | 1996-01-31 | Unilever Plc | Detergent compositions containing soil release polymers |
| GB9524488D0 (en) * | 1995-11-30 | 1996-01-31 | Unilever Plc | Detergent compositions containing soil release polymers |
| GB9525773D0 (en) | 1995-12-16 | 1996-02-14 | Unilever Plc | Detergent composition |
| DE19600466A1 (de) * | 1996-01-09 | 1997-07-10 | Henkel Kgaa | Verfahren zur Herstellung von granularen Wasch- oder Reinigungsmitteln bzw. Komponenten hierfür |
| GB9604000D0 (en) * | 1996-02-26 | 1996-04-24 | Unilever Plc | Production of anionic detergent particles |
| GB9604022D0 (en) * | 1996-02-26 | 1996-04-24 | Unilever Plc | Anionic detergent particles |
| GB9605534D0 (en) * | 1996-03-15 | 1996-05-15 | Unilever Plc | Detergent compositions |
| GB9606913D0 (en) | 1996-04-02 | 1996-06-05 | Unilever Plc | Surfactant blends processes for preparing them and particulate detergent compositions containing them |
| GB9609699D0 (en) * | 1996-05-09 | 1996-07-10 | Unilever Plc | Detergent compositions |
| GB9620093D0 (en) * | 1996-09-26 | 1996-11-13 | Unilever Plc | Photofading inhibitor derivatives and their use in fabric treatment compositions |
| DE19758811B4 (de) | 1997-03-11 | 2008-12-18 | Henkel Ag & Co. Kgaa | Waschmittelpressling |
| DE19710254A1 (de) * | 1997-03-13 | 1998-09-17 | Henkel Kgaa | Wasch- oder reinigungsaktive Formkörper für den Gebrauch im Haushalt |
| DE19721885A1 (de) † | 1997-05-26 | 1998-12-03 | Henkel Kgaa | Verfahren zur Herstellung kationtensidhaltiger Granulate |
| GB9711829D0 (en) | 1997-06-06 | 1997-08-06 | Unilever Plc | Detergent compositions |
| GB9711831D0 (en) * | 1997-06-06 | 1997-08-06 | Unilever Plc | Cleaning compositions |
| BR9907807A (pt) * | 1998-02-10 | 2000-10-17 | Unilever Nv | Processo para a fabricação de tabletes de composição detergente para a lavagem de tecidos, uso de uma camada elastomérica em uma área superficial, e, tablete de composição detergente particulada compactada |
| DE19912031A1 (de) | 1999-03-17 | 2000-09-21 | Basf Ag | Verwendung von quervernetztem Polyvinylpyrrolidon zur Erhöhung der Zerfallgeschwindigkeit von kompakten teilchenförmigen Wasch- und Reinigungsmitteln |
| US6900165B2 (en) | 2000-03-10 | 2005-05-31 | Basf Aktiengesellschaft | Use of cross-linked polyvinylpyrrolidone as a disintegrant in compact, particulate detergents and cleaning agents |
| GB0127036D0 (en) | 2001-11-09 | 2002-01-02 | Unilever Plc | Polymers for laundry applications |
| EP1578821A2 (en) | 2002-12-23 | 2005-09-28 | Ciba SC Holding AG | Hydrophobically modified polymers as laundry additives |
| GB0524659D0 (en) | 2005-12-02 | 2006-01-11 | Unilever Plc | Improvements relating to fabric treatment compositions |
| GB0904700D0 (en) | 2009-03-19 | 2009-04-29 | Unilever Plc | Improvements relating to benefit agent delivery |
| GB201011905D0 (en) | 2010-07-15 | 2010-09-01 | Unilever Plc | Benefit delivery particle,process for preparing said particle,compositions comprising said particles and a method for treating substrates |
| PH12013500304A1 (en) | 2010-10-22 | 2013-03-25 | Unilever Ip Holdings B V | Improvements relating to laundry products |
| EP2791309B1 (en) | 2011-12-16 | 2018-02-07 | Unilever Plc. | Improvements relating to fabric treatment compositions |
| CN104781383B (zh) | 2012-11-19 | 2018-06-01 | 荷兰联合利华有限公司 | 涉及包封的有益剂的改进 |
| EP4359498B1 (en) | 2021-06-24 | 2025-02-12 | Unilever IP Holdings B.V. | Unit dose cleaning composition |
| CN114949928A (zh) * | 2022-06-08 | 2022-08-30 | 史宏霞 | 一种低熔点表面活性剂粉剂化的制备方法及其应用 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ATE10010T1 (de) * | 1981-03-20 | 1984-11-15 | Unilever Nv | Verfahren zur herstellung von reinigungsmittelzusammensetzungen, die natriumaluminiumsilikate enthalten. |
| GB8334017D0 (en) * | 1983-12-21 | 1984-02-01 | Unilever Plc | Detergent composition |
| JPS6169897A (ja) * | 1984-09-14 | 1986-04-10 | 花王株式会社 | 流動性の改良された高密度の粒状洗剤の製法 |
| JPH0680160B2 (ja) * | 1984-09-14 | 1994-10-12 | 花王株式会社 | 流動性の改良された高密度の粒状洗剤の製法 |
| DE3444960A1 (de) * | 1984-12-10 | 1986-06-12 | Henkel KGaA, 4000 Düsseldorf | Koerniges adsorptionsmittel |
| GB8609043D0 (en) * | 1986-04-14 | 1986-05-21 | Unilever Plc | Detergent powders |
| JPH0631430B2 (ja) * | 1985-05-29 | 1994-04-27 | ライオン株式会社 | 高嵩密度粒状洗剤組成物の製造方法 |
| JPS62253699A (ja) * | 1986-04-09 | 1987-11-05 | 花王株式会社 | 高密度粒状洗剤組成物 |
| JPH0765077B2 (ja) * | 1986-04-08 | 1995-07-12 | ライオン株式会社 | 高嵩密度洗剤組成物の製法 |
| GB8626082D0 (en) * | 1986-10-31 | 1986-12-03 | Unilever Plc | Detergent powders |
| CA1323277C (en) * | 1988-04-29 | 1993-10-19 | Robert Donaldson | Process for preparing detergent compositions |
-
1988
- 1988-04-29 GB GB888810193A patent/GB8810193D0/en active Pending
-
1989
- 1989-04-24 CA CA000597593A patent/CA1336668C/en not_active Expired - Fee Related
- 1989-04-27 EP EP89304242A patent/EP0340013B1/en not_active Revoked
- 1989-04-27 DE DE68927745T patent/DE68927745T2/de not_active Revoked
- 1989-04-27 ES ES89304242T patent/ES2097741T3/es not_active Expired - Lifetime
- 1989-04-27 AU AU33750/89A patent/AU621611B2/en not_active Ceased
- 1989-04-28 KR KR1019890005621A patent/KR950004824B1/ko not_active Expired - Fee Related
- 1989-04-28 IN IN112/BOM/89A patent/IN170471B/en unknown
- 1989-04-28 JP JP1111945A patent/JPH0768553B2/ja not_active Expired - Fee Related
- 1989-04-28 PH PH38586A patent/PH24897A/en unknown
- 1989-04-28 ZA ZA893190A patent/ZA893190B/xx unknown
- 1989-04-28 MY MYPI89000575A patent/MY104967A/en unknown
- 1989-04-28 TR TR89/0321A patent/TR24508A/xx unknown
- 1989-04-28 BR BR898902004A patent/BR8902004A/pt not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| JPH01318097A (ja) | 1989-12-22 |
| BR8902004A (pt) | 1989-12-05 |
| TR24508A (tr) | 1991-11-12 |
| ZA893190B (en) | 1990-12-28 |
| ES2097741T3 (es) | 1997-04-16 |
| AU3375089A (en) | 1989-11-02 |
| EP0340013A2 (en) | 1989-11-02 |
| CA1336668C (en) | 1995-08-15 |
| PH24897A (en) | 1990-12-26 |
| MY104967A (en) | 1994-07-30 |
| DE68927745D1 (de) | 1997-03-20 |
| KR950004824B1 (ko) | 1995-05-13 |
| EP0340013A3 (en) | 1991-05-29 |
| GB8810193D0 (en) | 1988-06-02 |
| KR890016152A (ko) | 1989-11-28 |
| JPH0768553B2 (ja) | 1995-07-26 |
| IN170471B (enrdf_load_stackoverflow) | 1992-03-28 |
| AU621611B2 (en) | 1992-03-19 |
| EP0340013B1 (en) | 1997-02-05 |
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