DE68925288T2 - Verfahren zur ermässigung des ausstosses von schwefeloxyden während der verbrennung von schwefel enthaltenden brennstoffen - Google Patents
Verfahren zur ermässigung des ausstosses von schwefeloxyden während der verbrennung von schwefel enthaltenden brennstoffenInfo
- Publication number
- DE68925288T2 DE68925288T2 DE68925288T DE68925288T DE68925288T2 DE 68925288 T2 DE68925288 T2 DE 68925288T2 DE 68925288 T DE68925288 T DE 68925288T DE 68925288 T DE68925288 T DE 68925288T DE 68925288 T2 DE68925288 T2 DE 68925288T2
- Authority
- DE
- Germany
- Prior art keywords
- sulfur
- viscous
- sorbent
- fuel
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000446 fuel Substances 0.000 title claims abstract description 122
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title claims abstract description 109
- 229910052717 sulfur Inorganic materials 0.000 title claims abstract description 96
- 239000011593 sulfur Substances 0.000 title claims abstract description 92
- 238000000034 method Methods 0.000 title claims abstract description 48
- 238000002485 combustion reaction Methods 0.000 title claims abstract description 43
- 239000002594 sorbent Substances 0.000 claims abstract description 96
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 93
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 92
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 68
- 239000004094 surface-active agent Substances 0.000 claims description 96
- 239000000203 mixture Substances 0.000 claims description 57
- 239000004215 Carbon black (E152) Substances 0.000 claims description 54
- 239000003208 petroleum Substances 0.000 claims description 39
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 36
- 239000000463 material Substances 0.000 claims description 26
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 24
- 239000003245 coal Substances 0.000 claims description 23
- VSGNNIFQASZAOI-UHFFFAOYSA-L calcium acetate Chemical compound [Ca+2].CC([O-])=O.CC([O-])=O VSGNNIFQASZAOI-UHFFFAOYSA-L 0.000 claims description 21
- 239000001639 calcium acetate Substances 0.000 claims description 21
- 235000011092 calcium acetate Nutrition 0.000 claims description 21
- 229960005147 calcium acetate Drugs 0.000 claims description 21
- 230000008569 process Effects 0.000 claims description 21
- 239000002002 slurry Substances 0.000 claims description 19
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- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 17
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- 239000010459 dolomite Substances 0.000 claims description 4
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims description 4
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 claims description 3
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- JKTAIYGNOFSMCE-UHFFFAOYSA-N 2,3-di(nonyl)phenol Chemical compound CCCCCCCCCC1=CC=CC(O)=C1CCCCCCCCC JKTAIYGNOFSMCE-UHFFFAOYSA-N 0.000 claims 2
- 241000588810 Alcaligenes sp. Species 0.000 claims 2
- CBOCVOKPQGJKKJ-UHFFFAOYSA-L Calcium formate Chemical compound [Ca+2].[O-]C=O.[O-]C=O CBOCVOKPQGJKKJ-UHFFFAOYSA-L 0.000 claims 2
- BCZXFFBUYPCTSJ-UHFFFAOYSA-L Calcium propionate Chemical compound [Ca+2].CCC([O-])=O.CCC([O-])=O BCZXFFBUYPCTSJ-UHFFFAOYSA-L 0.000 claims 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims 2
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- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 claims 2
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- 235000010331 calcium propionate Nutrition 0.000 claims 2
- 125000005587 carbonate group Chemical group 0.000 claims 2
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims 2
- 229920005610 lignin Polymers 0.000 claims 2
- UEGPKNKPLBYCNK-UHFFFAOYSA-L magnesium acetate Chemical compound [Mg+2].CC([O-])=O.CC([O-])=O UEGPKNKPLBYCNK-UHFFFAOYSA-L 0.000 claims 2
- 239000011654 magnesium acetate Substances 0.000 claims 2
- 235000011285 magnesium acetate Nutrition 0.000 claims 2
- 229940069446 magnesium acetate Drugs 0.000 claims 2
- CQQJGTPWCKCEOQ-UHFFFAOYSA-L magnesium dipropionate Chemical compound [Mg+2].CCC([O-])=O.CCC([O-])=O CQQJGTPWCKCEOQ-UHFFFAOYSA-L 0.000 claims 2
- GMDNUWQNDQDBNQ-UHFFFAOYSA-L magnesium;diformate Chemical compound [Mg+2].[O-]C=O.[O-]C=O GMDNUWQNDQDBNQ-UHFFFAOYSA-L 0.000 claims 2
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 claims 2
- 239000001632 sodium acetate Substances 0.000 claims 2
- 235000017281 sodium acetate Nutrition 0.000 claims 2
- HLBBKKJFGFRGMU-UHFFFAOYSA-M sodium formate Chemical compound [Na+].[O-]C=O HLBBKKJFGFRGMU-UHFFFAOYSA-M 0.000 claims 2
- 235000019254 sodium formate Nutrition 0.000 claims 2
- JXKPEJDQGNYQSM-UHFFFAOYSA-M sodium propionate Chemical compound [Na+].CCC([O-])=O JXKPEJDQGNYQSM-UHFFFAOYSA-M 0.000 claims 2
- 239000004324 sodium propionate Substances 0.000 claims 2
- 235000010334 sodium propionate Nutrition 0.000 claims 2
- 229960003212 sodium propionate Drugs 0.000 claims 2
- 230000009467 reduction Effects 0.000 abstract description 25
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- 150000001875 compounds Chemical class 0.000 abstract description 6
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- 239000000126 substance Substances 0.000 description 32
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- 238000004519 manufacturing process Methods 0.000 description 18
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- 230000005484 gravity Effects 0.000 description 17
- 235000010633 broth Nutrition 0.000 description 16
- 235000014113 dietary fatty acids Nutrition 0.000 description 16
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- 125000003118 aryl group Chemical group 0.000 description 15
- 239000002245 particle Substances 0.000 description 15
- 238000012360 testing method Methods 0.000 description 14
- 125000004432 carbon atom Chemical group C* 0.000 description 13
- 239000007788 liquid Substances 0.000 description 13
- 239000007791 liquid phase Substances 0.000 description 13
- 230000002829 reductive effect Effects 0.000 description 13
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 12
- 102000004190 Enzymes Human genes 0.000 description 12
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- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 11
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- 238000002360 preparation method Methods 0.000 description 9
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L10/00—Use of additives to fuels or fires for particular purposes
- C10L10/02—Use of additives to fuels or fires for particular purposes for reducing smoke development
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/12—Inorganic compounds
- C10L1/1233—Inorganic compounds oxygen containing compounds, e.g. oxides, hydroxides, acids and salts thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/32—Liquid carbonaceous fuels consisting of coal-oil suspensions or aqueous emulsions or oil emulsions
- C10L1/326—Coal-water suspensions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/32—Liquid carbonaceous fuels consisting of coal-oil suspensions or aqueous emulsions or oil emulsions
- C10L1/328—Oil emulsions containing water or any other hydrophilic phase
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/188—Carboxylic acids; metal salts thereof
- C10L1/1881—Carboxylic acids; metal salts thereof carboxylic group attached to an aliphatic carbon atom
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
- Treating Waste Gases (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/US1989/004121 WO1991004310A1 (fr) | 1989-09-20 | 1989-09-20 | Procede de reduction des degagements d'oxydes de soufre pendant la combustion des compositions combustibles a teneur en soufre |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE68925288D1 DE68925288D1 (de) | 1996-02-08 |
| DE68925288T2 true DE68925288T2 (de) | 1996-06-13 |
Family
ID=22215245
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE68925288T Expired - Lifetime DE68925288T2 (de) | 1989-09-20 | 1989-09-20 | Verfahren zur ermässigung des ausstosses von schwefeloxyden während der verbrennung von schwefel enthaltenden brennstoffen |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP0494860B1 (fr) |
| JP (1) | JP2892155B2 (fr) |
| AT (1) | ATE132179T1 (fr) |
| DE (1) | DE68925288T2 (fr) |
| WO (1) | WO1991004310A1 (fr) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IL101531A (en) * | 1991-04-11 | 1996-10-31 | Ormat Inc | Method and means for utilizing sulfur-rich fuel |
| GB9110079D0 (en) * | 1991-05-09 | 1991-07-03 | British Petroleum Co Plc | Fuel composition |
| IL104509A (en) * | 1992-01-29 | 1999-10-28 | Ormat Inc | Method and means for producing flammable gases from solid fuels with low caloric value |
| RU2122682C1 (ru) * | 1992-02-14 | 1998-11-27 | ОРМАТ, Инк. | Способ подготовки к сжиганию серосодержащего топлива и устройство для подготовки к сжиганию серосодержащего топлива |
| CZ289723B6 (cs) * | 1992-06-28 | 2002-03-13 | Ormat Industries Ltd. | Způsob výroby spalitelných plynů z pevného paliva a zařízení k provádění tohoto způsobu |
| FR2731504A1 (fr) * | 1995-03-07 | 1996-09-13 | Merobel | Dispositif d'alimentation d'un bruleur a mazout reduisant la pollution |
| FR2827871A1 (fr) * | 2001-07-26 | 2003-01-31 | Richard Deutsch | Procede de traitement des dechets hydrocarbures pateux ou solides par emulsification pour la production d'un fuel |
| ES2341830B1 (es) * | 2008-10-16 | 2011-05-09 | Fundación Investigación E Innovación Para El Desarrollo Social | Producto para obtener una mayor eficiencia energetica mediante la adicion de formiato sodico a las gasolinas y gasoleos. |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3514273A (en) * | 1968-11-25 | 1970-05-26 | Canadian Patents Dev | Fuel oil additive |
| US3876391A (en) * | 1969-02-28 | 1975-04-08 | Texaco Inc | Process of preparing novel micro emulsions |
| US3640016A (en) * | 1969-03-28 | 1972-02-08 | Inst Gas Technology | Desulfurization of coal |
| US3837820A (en) * | 1971-09-01 | 1974-09-24 | Apollo Chem | Combustion control by additives introduced in both hot and cold zones |
| US4002435A (en) * | 1971-11-17 | 1977-01-11 | Wenzel Edward C | Clear and stable liquid fuel compositions for internal combustion engines |
| US3948617A (en) * | 1972-10-11 | 1976-04-06 | Benjamin Withorn | Method of reducing sulphur dioxide emissions from combustible materials |
| US3902869A (en) * | 1973-08-24 | 1975-09-02 | Svenska Utvecklings Ab | Fuel composition with increased octane number |
| US4158551A (en) * | 1975-01-27 | 1979-06-19 | Feuerman Arnold I | Gasoline-water emulsion |
| US4046519A (en) * | 1975-10-31 | 1977-09-06 | Mobil Oil Corporation | Novel microemulsions |
| US4226601A (en) * | 1977-01-03 | 1980-10-07 | Atlantic Richfield Company | Process for reducing sulfur contaminant emissions from burning coal or lignite that contains sulfur |
| US4162143A (en) * | 1978-03-13 | 1979-07-24 | Ici Americas Inc. | Emulsifier blend and aqueous fuel oil emulsions |
| US4224038A (en) * | 1978-06-19 | 1980-09-23 | Atlantic Richfield Company | Process for removing sulfur from coal |
| US4456688A (en) * | 1978-07-28 | 1984-06-26 | The Ohio State University | Microbiological desulfurization of coal |
| US4230460A (en) * | 1978-10-31 | 1980-10-28 | Maust Jr Edwin E | Method for enhancing the utilization of powdered coal |
| US4270926A (en) * | 1979-06-19 | 1981-06-02 | Atlantic Richfield Company | Process for removal of sulfur and ash from coal |
| JPS56159291A (en) * | 1980-05-12 | 1981-12-08 | Hirakawa Tekkosho:Kk | Removal of sulfur oxide and nitrogen oxide |
| US4477258A (en) * | 1980-10-30 | 1984-10-16 | Labofina, S.A. | Diesel fuel compositions and process for their production |
| US4445908A (en) * | 1980-12-01 | 1984-05-01 | The United States Of America As Represented By The United States Department Of Energy | Extracting alcohols from aqueous solutions |
| US4616574A (en) * | 1984-05-25 | 1986-10-14 | Empire State Electric Energy Research Corp. (Eseerco) | Process for treating combustion systems with pressure-hydrated dolomitic lime |
| US4801304A (en) * | 1986-06-17 | 1989-01-31 | Intevep, S.A. | Process for the production and burning of a natural-emulsified liquid fuel |
-
1989
- 1989-09-20 JP JP2506401A patent/JP2892155B2/ja not_active Expired - Lifetime
- 1989-09-20 EP EP90905073A patent/EP0494860B1/fr not_active Expired - Lifetime
- 1989-09-20 AT AT90905073T patent/ATE132179T1/de not_active IP Right Cessation
- 1989-09-20 DE DE68925288T patent/DE68925288T2/de not_active Expired - Lifetime
- 1989-09-20 WO PCT/US1989/004121 patent/WO1991004310A1/fr active IP Right Grant
Also Published As
| Publication number | Publication date |
|---|---|
| ATE132179T1 (de) | 1996-01-15 |
| JP2892155B2 (ja) | 1999-05-17 |
| WO1991004310A1 (fr) | 1991-04-04 |
| EP0494860A1 (fr) | 1992-07-22 |
| JPH05501889A (ja) | 1993-04-08 |
| DE68925288D1 (de) | 1996-02-08 |
| EP0494860A4 (en) | 1992-11-25 |
| EP0494860B1 (fr) | 1995-12-27 |
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| Date | Code | Title | Description |
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| 8364 | No opposition during term of opposition |