DE60315166T2 - Feuchttücher mit ionenaktivierbaren kationischen polymeren - Google Patents
Feuchttücher mit ionenaktivierbaren kationischen polymeren Download PDFInfo
- Publication number
- DE60315166T2 DE60315166T2 DE2003615166 DE60315166T DE60315166T2 DE 60315166 T2 DE60315166 T2 DE 60315166T2 DE 2003615166 DE2003615166 DE 2003615166 DE 60315166 T DE60315166 T DE 60315166T DE 60315166 T2 DE60315166 T2 DE 60315166T2
- Authority
- DE
- Germany
- Prior art keywords
- ethyl
- binder
- wet wipe
- acryloxy
- methacryloxy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 claims description 286
- 239000011230 binding agent Substances 0.000 claims description 266
- 229920000642 polymer Polymers 0.000 claims description 109
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 103
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 92
- 150000002500 ions Chemical class 0.000 claims description 77
- -1 ethylhexyl Chemical group 0.000 claims description 69
- 150000003839 salts Chemical class 0.000 claims description 56
- 239000011780 sodium chloride Substances 0.000 claims description 50
- 239000000178 monomer Substances 0.000 claims description 35
- 125000002091 cationic group Chemical group 0.000 claims description 28
- 238000009736 wetting Methods 0.000 claims description 17
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 14
- 238000006116 polymerization reaction Methods 0.000 claims description 13
- 229910052708 sodium Inorganic materials 0.000 claims description 11
- 239000002657 fibrous material Substances 0.000 claims description 8
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 7
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 6
- 239000001257 hydrogen Substances 0.000 claims description 6
- 229910052739 hydrogen Inorganic materials 0.000 claims description 6
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 6
- 229920002554 vinyl polymer Polymers 0.000 claims description 6
- 229920001451 polypropylene glycol Polymers 0.000 claims description 5
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 claims description 4
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims description 4
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims description 4
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 4
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 4
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 4
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 4
- 150000002431 hydrogen Chemical class 0.000 claims description 4
- JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 claims description 4
- FZGFBJMPSHGTRQ-UHFFFAOYSA-M trimethyl(2-prop-2-enoyloxyethyl)azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CCOC(=O)C=C FZGFBJMPSHGTRQ-UHFFFAOYSA-M 0.000 claims description 4
- SSZXAJUPVKMUJH-UHFFFAOYSA-N 2-(dimethylamino)ethyl prop-2-enoate;hydrochloride Chemical compound Cl.CN(C)CCOC(=O)C=C SSZXAJUPVKMUJH-UHFFFAOYSA-N 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 3
- 125000005250 alkyl acrylate group Chemical group 0.000 claims description 3
- ZGCZDEVLEULNLJ-UHFFFAOYSA-M benzyl-dimethyl-(2-prop-2-enoyloxyethyl)azanium;chloride Chemical compound [Cl-].C=CC(=O)OCC[N+](C)(C)CC1=CC=CC=C1 ZGCZDEVLEULNLJ-UHFFFAOYSA-M 0.000 claims description 3
- JCRDPEHHTDKTGB-UHFFFAOYSA-N dimethyl-[2-(2-methylprop-2-enoyloxy)ethyl]azanium;chloride Chemical compound Cl.CN(C)CCOC(=O)C(C)=C JCRDPEHHTDKTGB-UHFFFAOYSA-N 0.000 claims description 3
- 150000002734 metacrylic acid derivatives Chemical class 0.000 claims description 3
- RRHXZLALVWBDKH-UHFFFAOYSA-M trimethyl-[2-(2-methylprop-2-enoyloxy)ethyl]azanium;chloride Chemical compound [Cl-].CC(=C)C(=O)OCC[N+](C)(C)C RRHXZLALVWBDKH-UHFFFAOYSA-M 0.000 claims description 3
- OEIXGLMQZVLOQX-UHFFFAOYSA-N trimethyl-[3-(prop-2-enoylamino)propyl]azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CCCNC(=O)C=C OEIXGLMQZVLOQX-UHFFFAOYSA-N 0.000 claims description 3
- JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 claims description 2
- DPBJAVGHACCNRL-UHFFFAOYSA-N 2-(dimethylamino)ethyl prop-2-enoate Chemical compound CN(C)CCOC(=O)C=C DPBJAVGHACCNRL-UHFFFAOYSA-N 0.000 claims description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- 229910001508 alkali metal halide Inorganic materials 0.000 claims description 2
- 150000008045 alkali metal halides Chemical group 0.000 claims description 2
- 125000005210 alkyl ammonium group Chemical group 0.000 claims description 2
- WGQKYBSKWIADBV-UHFFFAOYSA-O benzylaminium Chemical group [NH3+]CC1=CC=CC=C1 WGQKYBSKWIADBV-UHFFFAOYSA-O 0.000 claims description 2
- 239000002243 precursor Substances 0.000 claims description 2
- CRGOPMLUWCMMCK-UHFFFAOYSA-M benzyl-dimethyl-[2-(2-methylprop-2-enoyloxy)ethyl]azanium;chloride Chemical compound [Cl-].CC(=C)C(=O)OCC[N+](C)(C)CC1=CC=CC=C1 CRGOPMLUWCMMCK-UHFFFAOYSA-M 0.000 claims 2
- HYTWSJWXLMPIKR-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate;hydrobromide Chemical compound [Br-].C[NH+](C)CCOC(=O)C(C)=C HYTWSJWXLMPIKR-UHFFFAOYSA-N 0.000 claims 1
- FDRMJKDXTZDBHQ-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate;methyl hydrogen sulfate Chemical compound COS([O-])(=O)=O.C[NH+](C)CCOC(=O)C(C)=C FDRMJKDXTZDBHQ-UHFFFAOYSA-N 0.000 claims 1
- RFPLNIBCLGFBKV-UHFFFAOYSA-N 2-(dimethylamino)ethyl prop-2-enoate;methyl hydrogen sulfate Chemical compound COS([O-])(=O)=O.C[NH+](C)CCOC(=O)C=C RFPLNIBCLGFBKV-UHFFFAOYSA-N 0.000 claims 1
- PTRDVLQWHOXQGD-UHFFFAOYSA-M benzyl-dimethyl-(2-prop-2-enoyloxyethyl)azanium;bromide Chemical compound [Br-].C=CC(=O)OCC[N+](C)(C)CC1=CC=CC=C1 PTRDVLQWHOXQGD-UHFFFAOYSA-M 0.000 claims 1
- FHISDDXCIFZLOI-UHFFFAOYSA-M benzyl-dimethyl-(2-prop-2-enoyloxyethyl)azanium;iodide Chemical compound [I-].C=CC(=O)OCC[N+](C)(C)CC1=CC=CC=C1 FHISDDXCIFZLOI-UHFFFAOYSA-M 0.000 claims 1
- XUBGIXGGUBUOGB-UHFFFAOYSA-M benzyl-dimethyl-(2-prop-2-enoyloxyethyl)azanium;methyl sulfate Chemical compound COS([O-])(=O)=O.C=CC(=O)OCC[N+](C)(C)CC1=CC=CC=C1 XUBGIXGGUBUOGB-UHFFFAOYSA-M 0.000 claims 1
- AJVIGYSWIQOVGW-UHFFFAOYSA-M benzyl-dimethyl-[2-(2-methylprop-2-enoyloxy)ethyl]azanium;bromide Chemical compound [Br-].CC(=C)C(=O)OCC[N+](C)(C)CC1=CC=CC=C1 AJVIGYSWIQOVGW-UHFFFAOYSA-M 0.000 claims 1
- GHRDYPUVXYUERT-UHFFFAOYSA-M benzyl-dimethyl-[2-(2-methylprop-2-enoyloxy)ethyl]azanium;iodide Chemical compound [I-].CC(=C)C(=O)OCC[N+](C)(C)CC1=CC=CC=C1 GHRDYPUVXYUERT-UHFFFAOYSA-M 0.000 claims 1
- HFENIDITYBFMOZ-UHFFFAOYSA-M benzyl-dimethyl-[2-(2-methylprop-2-enoyloxy)ethyl]azanium;methyl sulfate Chemical compound COS([O-])(=O)=O.CC(=C)C(=O)OCC[N+](C)(C)CC1=CC=CC=C1 HFENIDITYBFMOZ-UHFFFAOYSA-M 0.000 claims 1
- SPRQFBXYBNVYAK-UHFFFAOYSA-N dimethyl(2-prop-2-enoyloxyethyl)azanium;bromide Chemical compound [Br-].C[NH+](C)CCOC(=O)C=C SPRQFBXYBNVYAK-UHFFFAOYSA-N 0.000 claims 1
- NWEHGGVCPBIHRU-UHFFFAOYSA-N dimethyl(2-prop-2-enoyloxyethyl)azanium;iodide Chemical compound [I-].C[NH+](C)CCOC(=O)C=C NWEHGGVCPBIHRU-UHFFFAOYSA-N 0.000 claims 1
- REXIOVXEJWTNGB-UHFFFAOYSA-N dimethyl-[2-(2-methylprop-2-enoyloxy)ethyl]azanium;iodide Chemical compound [I-].C[NH+](C)CCOC(=O)C(C)=C REXIOVXEJWTNGB-UHFFFAOYSA-N 0.000 claims 1
- UZLGVMYVDYNSCS-UHFFFAOYSA-M methyl sulfate;trimethyl(2-prop-2-enoyloxyethyl)azanium Chemical compound COS([O-])(=O)=O.C[N+](C)(C)CCOC(=O)C=C UZLGVMYVDYNSCS-UHFFFAOYSA-M 0.000 claims 1
- IHBKAGRPNRKYAO-UHFFFAOYSA-M methyl sulfate;trimethyl-[2-(2-methylprop-2-enoyloxy)ethyl]azanium Chemical compound COS([O-])(=O)=O.CC(=C)C(=O)OCC[N+](C)(C)C IHBKAGRPNRKYAO-UHFFFAOYSA-M 0.000 claims 1
- VVZUOWXPWDYTEA-UHFFFAOYSA-N methyl sulfate;trimethyl-[3-(prop-2-enoylamino)propyl]azanium Chemical compound COS([O-])(=O)=O.C[N+](C)(C)CCCNC(=O)C=C VVZUOWXPWDYTEA-UHFFFAOYSA-N 0.000 claims 1
- 238000005956 quaternization reaction Methods 0.000 claims 1
- IVPAUJSYKHFIOD-UHFFFAOYSA-M trimethyl(2-prop-2-enoyloxyethyl)azanium;iodide Chemical compound [I-].C[N+](C)(C)CCOC(=O)C=C IVPAUJSYKHFIOD-UHFFFAOYSA-M 0.000 claims 1
- FGKCGMMQJOWMFW-UHFFFAOYSA-M trimethyl-[2-(2-methylprop-2-enoyloxy)ethyl]azanium;bromide Chemical compound [Br-].CC(=C)C(=O)OCC[N+](C)(C)C FGKCGMMQJOWMFW-UHFFFAOYSA-M 0.000 claims 1
- XIXDXIUWZQJVHJ-UHFFFAOYSA-M trimethyl-[2-(2-methylprop-2-enoyloxy)ethyl]azanium;iodide Chemical compound [I-].CC(=C)C(=O)OCC[N+](C)(C)C XIXDXIUWZQJVHJ-UHFFFAOYSA-M 0.000 claims 1
- XYAHMUGLVOAFIU-UHFFFAOYSA-N trimethyl-[3-(prop-2-enoylamino)propyl]azanium;bromide Chemical compound [Br-].C[N+](C)(C)CCCNC(=O)C=C XYAHMUGLVOAFIU-UHFFFAOYSA-N 0.000 claims 1
- PFTXCWNJFWPRTO-UHFFFAOYSA-N trimethyl-[3-(prop-2-enoylamino)propyl]azanium;iodide Chemical compound [I-].C[N+](C)(C)CCCNC(=O)C=C PFTXCWNJFWPRTO-UHFFFAOYSA-N 0.000 claims 1
- AISMNBXOJRHCIA-UHFFFAOYSA-N trimethylazanium;bromide Chemical compound Br.CN(C)C AISMNBXOJRHCIA-UHFFFAOYSA-N 0.000 claims 1
- 230000003020 moisturizing effect Effects 0.000 description 135
- 239000000758 substrate Substances 0.000 description 96
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- 239000000835 fiber Substances 0.000 description 83
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- 239000008233 hard water Substances 0.000 description 46
- 239000000463 material Substances 0.000 description 45
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- 239000002245 particle Substances 0.000 description 36
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- 229920001296 polysiloxane Polymers 0.000 description 32
- 239000002585 base Substances 0.000 description 30
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 27
- 239000004816 latex Substances 0.000 description 24
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- 239000000523 sample Substances 0.000 description 24
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- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 18
- 239000007921 spray Substances 0.000 description 18
- 238000012360 testing method Methods 0.000 description 18
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- A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
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- Y10T442/2508—Coating or impregnation absorbs chemical material other than water
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y10T442/2525—Coating or impregnation functions biologically [e.g., insect repellent, antiseptic, insecticide, bactericide, etc.]
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/689—Hydroentangled nonwoven fabric
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Veterinary Medicine (AREA)
- Chemical & Material Sciences (AREA)
- Public Health (AREA)
- Animal Behavior & Ethology (AREA)
- Epidemiology (AREA)
- Engineering & Computer Science (AREA)
- Birds (AREA)
- Organic Chemistry (AREA)
- Hematology (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Biomedical Technology (AREA)
- Dermatology (AREA)
- Materials Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Nonwoven Fabrics (AREA)
- Detergent Compositions (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Cleaning Implements For Floors, Carpets, Furniture, Walls, And The Like (AREA)
- Orthopedics, Nursing, And Contraception (AREA)
- Paper (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US251610 | 2002-09-20 | ||
| US10/251,610 US7157389B2 (en) | 2002-09-20 | 2002-09-20 | Ion triggerable, cationic polymers, a method of making same and items using same |
| PCT/US2003/028244 WO2004026354A1 (en) | 2002-09-20 | 2003-09-08 | Ion triggerable, cationic polymers, a method of making same and items using same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE60315166D1 DE60315166D1 (de) | 2007-09-06 |
| DE60315166T2 true DE60315166T2 (de) | 2008-04-10 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2003615166 Expired - Lifetime DE60315166T2 (de) | 2002-09-20 | 2003-09-08 | Feuchttücher mit ionenaktivierbaren kationischen polymeren |
Country Status (13)
| Country | Link |
|---|---|
| US (2) | US7157389B2 (enExample) |
| EP (1) | EP1539259B1 (enExample) |
| JP (1) | JP4711679B2 (enExample) |
| KR (1) | KR101057900B1 (enExample) |
| CN (1) | CN100382853C (enExample) |
| AR (1) | AR041236A1 (enExample) |
| AU (1) | AU2003266008B2 (enExample) |
| BR (1) | BRPI0314054B1 (enExample) |
| DE (1) | DE60315166T2 (enExample) |
| MX (1) | MXPA05002432A (enExample) |
| RU (1) | RU2005106210A (enExample) |
| WO (1) | WO2004026354A1 (enExample) |
| ZA (1) | ZA200501927B (enExample) |
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-
2002
- 2002-09-20 US US10/251,610 patent/US7157389B2/en not_active Expired - Lifetime
-
2003
- 2003-09-08 AU AU2003266008A patent/AU2003266008B2/en not_active Expired
- 2003-09-08 CN CNB038212323A patent/CN100382853C/zh not_active Expired - Fee Related
- 2003-09-08 RU RU2005106210/15A patent/RU2005106210A/ru not_active Application Discontinuation
- 2003-09-08 JP JP2004537751A patent/JP4711679B2/ja not_active Expired - Fee Related
- 2003-09-08 EP EP03797891A patent/EP1539259B1/en not_active Expired - Lifetime
- 2003-09-08 BR BRPI0314054-7A patent/BRPI0314054B1/pt not_active IP Right Cessation
- 2003-09-08 WO PCT/US2003/028244 patent/WO2004026354A1/en not_active Ceased
- 2003-09-08 DE DE2003615166 patent/DE60315166T2/de not_active Expired - Lifetime
- 2003-09-08 MX MXPA05002432A patent/MXPA05002432A/es active IP Right Grant
- 2003-09-08 KR KR1020057003811A patent/KR101057900B1/ko not_active Expired - Fee Related
- 2003-09-11 AR ARP030103296 patent/AR041236A1/es not_active Application Discontinuation
-
2005
- 2005-01-01 ZA ZA200501927A patent/ZA200501927B/en unknown
-
2006
- 2006-09-12 US US11/520,169 patent/US7456117B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| AU2003266008A1 (en) | 2004-04-08 |
| DE60315166D1 (de) | 2007-09-06 |
| US7456117B2 (en) | 2008-11-25 |
| AR041236A1 (es) | 2005-05-11 |
| ZA200501927B (en) | 2006-05-31 |
| CN1681539A (zh) | 2005-10-12 |
| MXPA05002432A (es) | 2005-08-16 |
| AU2003266008B2 (en) | 2008-07-03 |
| BR0314054A (pt) | 2005-07-05 |
| WO2004026354A1 (en) | 2004-04-01 |
| US7157389B2 (en) | 2007-01-02 |
| KR101057900B1 (ko) | 2011-08-19 |
| US20040058606A1 (en) | 2004-03-25 |
| CN100382853C (zh) | 2008-04-23 |
| US20070010155A1 (en) | 2007-01-11 |
| EP1539259A1 (en) | 2005-06-15 |
| JP2006500101A (ja) | 2006-01-05 |
| BRPI0314054B1 (pt) | 2015-06-30 |
| RU2005106210A (ru) | 2006-01-20 |
| EP1539259B1 (en) | 2007-07-25 |
| KR20050057202A (ko) | 2005-06-16 |
| JP4711679B2 (ja) | 2011-06-29 |
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