DE60222399T2 - Dinatriumhexahydrophthalatsalzzusammensetzungen und derartige zusammensetzungen enthaltende nukleierte polymere - Google Patents
Dinatriumhexahydrophthalatsalzzusammensetzungen und derartige zusammensetzungen enthaltende nukleierte polymere Download PDFInfo
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- DE60222399T2 DE60222399T2 DE60222399T DE60222399T DE60222399T2 DE 60222399 T2 DE60222399 T2 DE 60222399T2 DE 60222399 T DE60222399 T DE 60222399T DE 60222399 T DE60222399 T DE 60222399T DE 60222399 T2 DE60222399 T2 DE 60222399T2
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- 239000000203 mixture Substances 0.000 title claims abstract description 78
- 239000004642 Polyimide Substances 0.000 title 1
- ZTUZDYWYNQDJKR-UHFFFAOYSA-N diethyl cyclohexane-1,2-dicarboxylate Chemical class CCOC(=O)C1CCCCC1C(=O)OCC ZTUZDYWYNQDJKR-UHFFFAOYSA-N 0.000 title 1
- 229920001721 polyimide Polymers 0.000 title 1
- 229920000098 polyolefin Polymers 0.000 claims abstract description 50
- 239000002253 acid Substances 0.000 claims abstract description 48
- 229920000642 polymer Polymers 0.000 claims abstract description 28
- 239000002516 radical scavenger Substances 0.000 claims abstract description 23
- 239000008116 calcium stearate Substances 0.000 claims abstract description 19
- 235000013539 calcium stearate Nutrition 0.000 claims abstract description 19
- 150000003839 salts Chemical class 0.000 claims abstract description 10
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000011575 calcium Substances 0.000 claims abstract description 3
- 229910052791 calcium Inorganic materials 0.000 claims abstract 2
- -1 carboxylate salts Chemical class 0.000 claims description 47
- 150000001875 compounds Chemical class 0.000 claims description 36
- 229920001169 thermoplastic Polymers 0.000 claims description 25
- 239000004416 thermosoftening plastic Substances 0.000 claims description 22
- 239000004743 Polypropylene Substances 0.000 claims description 19
- 229920001155 polypropylene Polymers 0.000 claims description 19
- 239000000654 additive Substances 0.000 claims description 15
- 238000009472 formulation Methods 0.000 claims description 12
- 239000011734 sodium Substances 0.000 claims description 11
- 229910052708 sodium Inorganic materials 0.000 claims description 11
- QSAWQNUELGIYBC-UHFFFAOYSA-N cyclohexane-1,2-dicarboxylic acid Chemical compound OC(=O)C1CCCCC1C(O)=O QSAWQNUELGIYBC-UHFFFAOYSA-N 0.000 claims description 9
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 8
- 239000000843 powder Substances 0.000 claims description 8
- 230000000996 additive effect Effects 0.000 claims description 7
- 125000000217 alkyl group Chemical group 0.000 claims description 6
- 239000003963 antioxidant agent Substances 0.000 claims description 6
- 229910052739 hydrogen Inorganic materials 0.000 claims description 5
- 239000001257 hydrogen Substances 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 4
- 239000002216 antistatic agent Substances 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 239000003063 flame retardant Substances 0.000 claims description 3
- 239000004611 light stabiliser Substances 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- 239000008188 pellet Substances 0.000 claims description 3
- 239000004014 plasticizer Substances 0.000 claims description 3
- 239000004604 Blowing Agent Substances 0.000 claims description 2
- 125000003545 alkoxy group Chemical group 0.000 claims description 2
- 125000005529 alkyleneoxy group Chemical group 0.000 claims description 2
- 239000004599 antimicrobial Substances 0.000 claims description 2
- 125000002837 carbocyclic group Chemical group 0.000 claims description 2
- PKVQSSWKJIPMRR-UHFFFAOYSA-L disodium;cyclohexane-1,2-dicarboxylate Chemical compound [Na+].[Na+].[O-]C(=O)C1CCCCC1C([O-])=O PKVQSSWKJIPMRR-UHFFFAOYSA-L 0.000 claims description 2
- 229910052736 halogen Inorganic materials 0.000 claims description 2
- 150000002367 halogens Chemical class 0.000 claims description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 2
- 229920005672 polyolefin resin Polymers 0.000 claims description 2
- 230000002000 scavenging effect Effects 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims description 2
- 150000002431 hydrogen Chemical class 0.000 claims 2
- 239000000049 pigment Substances 0.000 claims 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 1
- 230000000845 anti-microbial effect Effects 0.000 claims 1
- 229910052744 lithium Inorganic materials 0.000 claims 1
- 239000003380 propellant Substances 0.000 claims 1
- 229910052725 zinc Inorganic materials 0.000 claims 1
- 239000011701 zinc Substances 0.000 claims 1
- 238000002425 crystallisation Methods 0.000 abstract description 19
- 230000008025 crystallization Effects 0.000 abstract description 19
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 abstract description 18
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 abstract description 16
- 235000010234 sodium benzoate Nutrition 0.000 abstract description 16
- 239000004299 sodium benzoate Substances 0.000 abstract description 16
- 159000000007 calcium salts Chemical class 0.000 abstract description 10
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 abstract description 5
- 159000000000 sodium salts Chemical class 0.000 abstract description 4
- MUTGBJKUEZFXGO-UHFFFAOYSA-N hexahydrophthalic anhydride Chemical class C1CCCC2C(=O)OC(=O)C21 MUTGBJKUEZFXGO-UHFFFAOYSA-N 0.000 abstract 2
- 239000002667 nucleating agent Substances 0.000 description 30
- 239000000047 product Substances 0.000 description 11
- 229940078456 calcium stearate Drugs 0.000 description 9
- HGPXWXLYXNVULB-UHFFFAOYSA-M lithium stearate Chemical compound [Li+].CCCCCCCCCCCCCCCCCC([O-])=O HGPXWXLYXNVULB-UHFFFAOYSA-M 0.000 description 9
- ZHROMWXOTYBIMF-UHFFFAOYSA-M sodium;1,3,7,9-tetratert-butyl-11-oxido-5h-benzo[d][1,3,2]benzodioxaphosphocine 11-oxide Chemical compound [Na+].C1C2=CC(C(C)(C)C)=CC(C(C)(C)C)=C2OP([O-])(=O)OC2=C1C=C(C(C)(C)C)C=C2C(C)(C)C ZHROMWXOTYBIMF-UHFFFAOYSA-M 0.000 description 8
- 238000001125 extrusion Methods 0.000 description 7
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- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 229920001577 copolymer Polymers 0.000 description 6
- 239000004698 Polyethylene Substances 0.000 description 5
- 238000001816 cooling Methods 0.000 description 5
- 239000013078 crystal Substances 0.000 description 5
- 238000002844 melting Methods 0.000 description 5
- 230000008018 melting Effects 0.000 description 5
- 229920000573 polyethylene Polymers 0.000 description 5
- 238000003860 storage Methods 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 238000001746 injection moulding Methods 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 230000000704 physical effect Effects 0.000 description 4
- 229920000139 polyethylene terephthalate Polymers 0.000 description 4
- 239000005020 polyethylene terephthalate Substances 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 229920001748 polybutylene Polymers 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- FMZUHGYZWYNSOA-VVBFYGJXSA-N (1r)-1-[(4r,4ar,8as)-2,6-diphenyl-4,4a,8,8a-tetrahydro-[1,3]dioxino[5,4-d][1,3]dioxin-4-yl]ethane-1,2-diol Chemical compound C([C@@H]1OC(O[C@@H]([C@@H]1O1)[C@H](O)CO)C=2C=CC=CC=2)OC1C1=CC=CC=C1 FMZUHGYZWYNSOA-VVBFYGJXSA-N 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- 238000005481 NMR spectroscopy Methods 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- 238000005054 agglomeration Methods 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- MKJXYGKVIBWPFZ-UHFFFAOYSA-L calcium lactate Chemical compound [Ca+2].CC(O)C([O-])=O.CC(O)C([O-])=O MKJXYGKVIBWPFZ-UHFFFAOYSA-L 0.000 description 2
- 239000001527 calcium lactate Substances 0.000 description 2
- 229960002401 calcium lactate Drugs 0.000 description 2
- 235000011086 calcium lactate Nutrition 0.000 description 2
- OEUVSBXAMBLPES-UHFFFAOYSA-L calcium stearoyl-2-lactylate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC(=O)OC(C)C(=O)OC(C)C([O-])=O.CCCCCCCCCCCCCCCCCC(=O)OC(C)C(=O)OC(C)C([O-])=O OEUVSBXAMBLPES-UHFFFAOYSA-L 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 2
- 229920001684 low density polyethylene Polymers 0.000 description 2
- 239000004702 low-density polyethylene Substances 0.000 description 2
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- 230000035939 shock Effects 0.000 description 2
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
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- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 2
- YWEWWNPYDDHZDI-JJKKTNRVSA-N (1r)-1-[(4r,4ar,8as)-2,6-bis(3,4-dimethylphenyl)-4,4a,8,8a-tetrahydro-[1,3]dioxino[5,4-d][1,3]dioxin-4-yl]ethane-1,2-diol Chemical compound C1=C(C)C(C)=CC=C1C1O[C@H]2[C@@H]([C@H](O)CO)OC(C=3C=C(C)C(C)=CC=3)O[C@H]2CO1 YWEWWNPYDDHZDI-JJKKTNRVSA-N 0.000 description 1
- QSAWQNUELGIYBC-PHDIDXHHSA-N (1r,2r)-cyclohexane-1,2-dicarboxylic acid Chemical compound OC(=O)[C@@H]1CCCC[C@H]1C(O)=O QSAWQNUELGIYBC-PHDIDXHHSA-N 0.000 description 1
- MUTGBJKUEZFXGO-OLQVQODUSA-N (3as,7ar)-3a,4,5,6,7,7a-hexahydro-2-benzofuran-1,3-dione Chemical compound C1CCC[C@@H]2C(=O)OC(=O)[C@@H]21 MUTGBJKUEZFXGO-OLQVQODUSA-N 0.000 description 1
- 0 *C(*)(*1C(O)=O)C(*)(*)C(*)(*)C(*)(*)*1C(O)=O Chemical compound *C(*)(*1C(O)=O)C(*)(*)C(*)(*)C(*)(*)*1C(O)=O 0.000 description 1
- SDRZFSPCVYEJTP-UHFFFAOYSA-N 1-ethenylcyclohexene Chemical compound C=CC1=CCCCC1 SDRZFSPCVYEJTP-UHFFFAOYSA-N 0.000 description 1
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 229920002943 EPDM rubber Polymers 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- 239000004594 Masterbatch (MB) Substances 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 229920002292 Nylon 6 Polymers 0.000 description 1
- 229920002302 Nylon 6,6 Polymers 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- CEGOLXSVJUTHNZ-UHFFFAOYSA-K aluminium tristearate Chemical compound [Al+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CEGOLXSVJUTHNZ-UHFFFAOYSA-K 0.000 description 1
- 229940063655 aluminum stearate Drugs 0.000 description 1
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- 239000008280 blood Substances 0.000 description 1
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- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 229960005069 calcium Drugs 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 239000003916 calcium stearoyl-2-lactylate Substances 0.000 description 1
- 235000010957 calcium stearoyl-2-lactylate Nutrition 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
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- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 description 1
- 229940087101 dibenzylidene sorbitol Drugs 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
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- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
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- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical class CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
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- 239000002244 precipitate Substances 0.000 description 1
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- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
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- 229910052709 silver Inorganic materials 0.000 description 1
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- 238000003856 thermoforming Methods 0.000 description 1
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- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 230000004584 weight gain Effects 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0083—Nucleating agents promoting the crystallisation of the polymer matrix
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/820,578 US6562890B2 (en) | 2001-03-29 | 2001-03-29 | Disodium hexahydrophthalate salt compositions and nucleated polymers comprising such compositions |
| US820578 | 2001-03-29 | ||
| PCT/US2002/006449 WO2002079312A1 (en) | 2001-03-29 | 2002-03-05 | Disodium hexahydrophthalate salt compositions and nucleated polymers comprising such compositions |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE60222399D1 DE60222399D1 (de) | 2007-10-25 |
| DE60222399T2 true DE60222399T2 (de) | 2008-06-05 |
Family
ID=25231197
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE60222399T Expired - Lifetime DE60222399T2 (de) | 2001-03-29 | 2002-03-05 | Dinatriumhexahydrophthalatsalzzusammensetzungen und derartige zusammensetzungen enthaltende nukleierte polymere |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US6562890B2 (https=) |
| EP (1) | EP1383831B1 (https=) |
| JP (1) | JP3958215B2 (https=) |
| CN (1) | CN1267483C (https=) |
| AT (1) | ATE373041T1 (https=) |
| DE (1) | DE60222399T2 (https=) |
| WO (1) | WO2002079312A1 (https=) |
Families Citing this family (37)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6599971B2 (en) * | 2001-03-29 | 2003-07-29 | Milliken & Company | Metals salts of hexahydrophthalic acid as nucleating additives for crystalline thermoplastics |
| JP3952797B2 (ja) * | 2002-02-14 | 2007-08-01 | 住友化学株式会社 | ポリプロピレン系樹脂組成物 |
| US7129323B2 (en) * | 2002-06-14 | 2006-10-31 | Milliken & Company | Bimolecular nucleation methods for thermoplastics |
| CA2500715A1 (en) * | 2002-10-03 | 2004-04-15 | Epimmune Inc. | Hla binding peptides and their uses |
| JP2006117776A (ja) * | 2004-10-21 | 2006-05-11 | Sumitomo Chemical Co Ltd | ポリプロピレン系樹脂組成物 |
| US20060142452A1 (en) * | 2004-12-23 | 2006-06-29 | Sonya Wolters | Polyolfins, methods of making polyolefins and related plastic additive compositions |
| SG123780A1 (en) * | 2005-01-07 | 2006-07-26 | Sumitomo Chemical Co | Polypropylene resin composition and formed article |
| US20070036960A1 (en) * | 2005-08-09 | 2007-02-15 | Lambert William S | Film and methods of making film |
| US7786203B2 (en) * | 2005-09-16 | 2010-08-31 | Milliken & Company | Polymer compositions comprising nucleating or clarifying agents and articles made using such compositions |
| US20070080485A1 (en) * | 2005-10-07 | 2007-04-12 | Kerscher Christopher S | Film and methods of making film |
| US7566797B2 (en) * | 2006-03-03 | 2009-07-28 | Milliken & Company | Metal carboxylate salt nucleating or clarifying agent compounds and related polymer compositions and methods |
| US7659336B2 (en) | 2006-03-08 | 2010-02-09 | Milliken & Company | Nucleating agent additive compositions and methods |
| US7662978B2 (en) * | 2006-04-24 | 2010-02-16 | Milliken & Company | Dibenzylidene sorbitol (DBS)-based compounds, compositions and methods for using such compounds |
| US7491762B2 (en) * | 2006-07-03 | 2009-02-17 | Milliken & Company | Compositions comprising metal salts of hexahydrophthalic acid and methods of employing such compositions in polyolefin resins |
| US8436085B2 (en) * | 2007-03-14 | 2013-05-07 | Equistar Chemicals, Lp | Barrier properties of substantially linear HDPE film with nucleating agents |
| JP5602352B2 (ja) | 2007-09-21 | 2014-10-08 | 住友化学株式会社 | 光安定化ポリプロピレン |
| JP2011111579A (ja) * | 2009-11-30 | 2011-06-09 | Asahi Kasei Chemicals Corp | ボトルキャップ用ポリエチレン樹脂組成物 |
| EP2523999A2 (en) | 2010-01-15 | 2012-11-21 | Reliance Industries Limited | Nucleating agents for polyolefins based on metal salts |
| CN102181092B (zh) * | 2011-03-31 | 2013-01-16 | 广州呈和科技有限公司 | 四氢苯酐的羧酸金属盐作为聚丙烯β晶型成核剂的应用 |
| US9771474B2 (en) * | 2012-07-30 | 2017-09-26 | Sabic Global Technologies B.V. | Hydrostability of polybutylene terephthalate composition |
| CN104736653B (zh) * | 2012-10-12 | 2017-07-21 | 埃克森美孚化学专利公司 | 包含用于改进的固化时间的成核剂的聚烯烃粘合剂组合物 |
| CN110105623B (zh) * | 2012-12-21 | 2021-05-25 | 美利肯公司 | 添加剂组合物和其使用方法 |
| CN104974377A (zh) * | 2014-04-14 | 2015-10-14 | 中国石油化工股份有限公司 | 一种含有环状羧酸金属盐的成核剂组合物 |
| US9994692B2 (en) | 2014-11-25 | 2018-06-12 | Milliken & Company | Process for extruding polypropylene |
| US9994695B2 (en) * | 2014-11-25 | 2018-06-12 | Milliken & Company | Process for extruding polypropylene |
| CN106478985A (zh) * | 2015-08-31 | 2017-03-08 | 中国石油化工股份有限公司 | 一种成核剂组合物及其应用 |
| EP3162844B1 (en) * | 2015-10-26 | 2018-11-28 | SABIC Global Technologies B.V. | Polypropylene composition comprising a nucleating composition comprising aluminosilicate and an organic nucleating agent |
| CN106810715A (zh) * | 2015-11-27 | 2017-06-09 | 中国石油化工股份有限公司 | 一种成核剂组合物及其应用 |
| CN106810714A (zh) * | 2015-11-27 | 2017-06-09 | 中国石油化工股份有限公司 | 一种成核剂组合物及其应用 |
| GB2549504B (en) * | 2016-04-19 | 2020-03-04 | Njc Europe Ltd | Method for identifying a blend of nucleators useful for preparing a nucleated polyolefin material |
| KR102468609B1 (ko) | 2016-08-11 | 2022-11-17 | 밀리켄 앤드 캄파니 | 첨가제 조성물 및 이를 함유하는 중합체 조성물 |
| CN107722415A (zh) * | 2017-11-09 | 2018-02-23 | 山西省化工研究所（有限公司） | 一种聚烯烃成核剂组合物的制备及其应用 |
| EP3851432A4 (en) * | 2018-09-11 | 2022-06-08 | New Japan Chemical Co., Ltd. | Metal salt of an alicyclic dicarboxylic acid with excellent dispersability in polyolefin resin, procedure for the production of this metal salt of an alicyclic dicarbonic acid, crystal germ form for polyolefin resin with this metal salt of an alicyclic dicarboxylic acid, crystal germ composition with this crystal germal composition and formed. |
| US11753535B2 (en) | 2018-10-23 | 2023-09-12 | Sumitomo Chemical Company, Limited | Propylene resin composition and shaped body comprising same |
| WO2021177386A1 (ja) * | 2020-03-06 | 2021-09-10 | 新日本理化株式会社 | ポリオレフィン系樹脂用の結晶核剤組成物、及び該結晶核剤組成物を含むポリオレフィン系樹脂組成物 |
| CN113773550B (zh) * | 2020-06-09 | 2022-10-11 | 中国科学院化学研究所 | 一种热塑性塑料用纳米复合成核剂、制备方法及其在聚丙烯中的应用 |
| CN114956984A (zh) * | 2022-05-07 | 2022-08-30 | 呈和科技股份有限公司 | 一种精准控制水合数的六氢邻苯二甲酸钙水合物的生产方法及产品与应用 |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL266092A (https=) | 1960-12-21 | |||
| US3207737A (en) | 1961-12-18 | 1965-09-21 | Shell Oil Co | Polymer crystallization method |
| BE631471A (https=) | 1962-04-26 | |||
| US5597786A (en) * | 1994-05-31 | 1997-01-28 | Nicca Chemical Co., Ltd. | Lubricant for plastic working |
| JP2974574B2 (ja) * | 1994-05-31 | 1999-11-10 | 日華化学株式会社 | 塑性加工用潤滑剤 |
| JP3575865B2 (ja) * | 1995-04-21 | 2004-10-13 | 出光石油化学株式会社 | ポリプロピレン組成物 |
| EP0745638A1 (de) * | 1995-05-31 | 1996-12-04 | Hoechst Aktiengesellschaft | Biaxial orientierte Polypropylenfolie mit verbessertem Weiterreisswiderstand |
| JPH0977925A (ja) * | 1995-09-13 | 1997-03-25 | Tonen Chem Corp | 低溶出性ポリプロピレン樹脂中空成形品 |
| EP0863183B2 (en) * | 1995-11-24 | 2008-05-28 | Chisso Corporation | Propylene composition, process for preparing the same, polypropylene composition, and molded articles |
| US5981636A (en) * | 1996-12-27 | 1999-11-09 | 3M Innovative Properties Company | Modifying agents for polyolefins |
| PE20001571A1 (es) * | 1998-12-14 | 2001-01-26 | Shell Int Research | Carboxilatos en la hidrolisis catalitica de oxidos de alquileno |
| US6153801A (en) * | 1998-12-14 | 2000-11-28 | Shell Oil Company | Carboxylates in catalytic hydrolysis of alkylene oxides |
| US6534574B1 (en) * | 2001-03-24 | 2003-03-18 | Milliken & Company | Highly nucleated thermoplastic articles |
-
2001
- 2001-03-29 US US09/820,578 patent/US6562890B2/en not_active Expired - Lifetime
-
2002
- 2002-03-05 AT AT02757776T patent/ATE373041T1/de not_active IP Right Cessation
- 2002-03-05 JP JP2002578324A patent/JP3958215B2/ja not_active Expired - Lifetime
- 2002-03-05 EP EP02757776A patent/EP1383831B1/en not_active Expired - Lifetime
- 2002-03-05 WO PCT/US2002/006449 patent/WO2002079312A1/en not_active Ceased
- 2002-03-05 CN CNB028074971A patent/CN1267483C/zh not_active Expired - Lifetime
- 2002-03-05 DE DE60222399T patent/DE60222399T2/de not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| US6562890B2 (en) | 2003-05-13 |
| CN1267483C (zh) | 2006-08-02 |
| DE60222399D1 (de) | 2007-10-25 |
| EP1383831B1 (en) | 2007-09-12 |
| JP2004524417A (ja) | 2004-08-12 |
| WO2002079312A1 (en) | 2002-10-10 |
| CN1525992A (zh) | 2004-09-01 |
| US20030027909A1 (en) | 2003-02-06 |
| JP3958215B2 (ja) | 2007-08-15 |
| EP1383831A1 (en) | 2004-01-28 |
| ATE373041T1 (de) | 2007-09-15 |
| EP1383831A4 (en) | 2005-05-11 |
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