DE60204306D1 - Geträgerter ziegler - metallocene polymerisationskatalysator und dessen benutzung für die polymerisation von olefinen - Google Patents

Geträgerter ziegler - metallocene polymerisationskatalysator und dessen benutzung für die polymerisation von olefinen

Info

Publication number
DE60204306D1
DE60204306D1 DE60204306T DE60204306T DE60204306D1 DE 60204306 D1 DE60204306 D1 DE 60204306D1 DE 60204306 T DE60204306 T DE 60204306T DE 60204306 T DE60204306 T DE 60204306T DE 60204306 D1 DE60204306 D1 DE 60204306D1
Authority
DE
Germany
Prior art keywords
olefins
polymerization
compound
metallocene
supported ziegler
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE60204306T
Other languages
English (en)
Other versions
DE60204306T2 (de
Inventor
Akhlaq Moman
Orass Hamed
Atieh Abu-Raquabah
Khalid Al-Bahily
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Saudi Basic Industries Corp
Original Assignee
Saudi Basic Industries Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Saudi Basic Industries Corp filed Critical Saudi Basic Industries Corp
Application granted granted Critical
Publication of DE60204306D1 publication Critical patent/DE60204306D1/de
Publication of DE60204306T2 publication Critical patent/DE60204306T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
DE60204306T 2002-07-12 2002-07-12 Geträgerter Ziegler - Metallocenepolymerisationskatalysator und dessen Benutzung für die Polymerisation von Olefinen Expired - Lifetime DE60204306T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP02015565A EP1380601B1 (de) 2002-07-12 2002-07-12 Geträgerter ziegler - metallocene polymerisationskatalysator und dessen benutzung für die polymerisation von olefinen

Publications (2)

Publication Number Publication Date
DE60204306D1 true DE60204306D1 (de) 2005-06-30
DE60204306T2 DE60204306T2 (de) 2005-10-20

Family

ID=29724440

Family Applications (1)

Application Number Title Priority Date Filing Date
DE60204306T Expired - Lifetime DE60204306T2 (de) 2002-07-12 2002-07-12 Geträgerter Ziegler - Metallocenepolymerisationskatalysator und dessen Benutzung für die Polymerisation von Olefinen

Country Status (7)

Country Link
US (1) US20040038806A1 (de)
EP (1) EP1380601B1 (de)
JP (1) JP4089968B2 (de)
CN (1) CN1296395C (de)
AT (1) ATE296319T1 (de)
DE (1) DE60204306T2 (de)
ES (1) ES2240613T3 (de)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1328310C (zh) * 2004-11-05 2007-07-25 中国科学院化学研究所 聚烯烃复合材料及其制备方法
CN102108104B (zh) * 2009-12-23 2012-11-14 中国石油天然气股份有限公司 合成宽或双峰分子量分布聚烯烃催化剂及其制备方法
CN102127176A (zh) * 2011-01-28 2011-07-20 中国科学院化学研究所 一种高熔体强度聚丙烯及其制备方法
US8664461B2 (en) 2012-03-19 2014-03-04 Exxonmobil Chemical Patents Inc. Catalysts for producing polyalpha-olefins and processes related thereto
JP2022542254A (ja) * 2019-07-31 2022-09-30 ダウ グローバル テクノロジーズ エルエルシー チーグラー・ナッタ触媒および水素化触媒を使用する溶液プロセスにおけるエチレンの重合

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BG17623A3 (de) * 1968-06-27 1973-11-10
US3676415A (en) * 1968-06-27 1972-07-11 Hoechst Ag Process for polymerizing {60 -olefins
FR2082153A5 (fr) * 1970-03-05 1971-12-10 Solvay Catalyseurs et procede perfectionnes pour la polymerisation et la copolymerisation des olefines
US3678019A (en) * 1970-03-16 1972-07-18 Exxon Research Engineering Co Novel process for olefin polymerization
US4496661A (en) * 1983-10-24 1985-01-29 The Dow Chemical Company High efficiency catalyst for polymerizing olefins
BE1007040A3 (fr) * 1993-05-25 1995-02-28 Solvay Support de catalyseur et catalyseur de polymerisation des alpha-olefines; procedes pour leur obtention et polymerisation des alpha-olefines en presence du catalyseur.
NZ268270A (en) * 1993-06-24 1997-10-24 Dow Chemical Co Titanium (ii)- or zirconium (ii)- containing complexes and addition polymerisation catalysts therefrom (m is ti or zr)
US5614456A (en) * 1993-11-15 1997-03-25 Mobil Oil Corporation Catalyst for bimodal molecular weight distribution ethylene polymers and copolymers
US5595950A (en) * 1993-12-20 1997-01-21 Exxon Chemical Patents, Inc. Polymerization catalyst systems, their production and use
IT1270070B (it) * 1994-07-08 1997-04-28 Spherilene Srl Componenti e catalizzatori per la polimerizzazione di olefine
US5625015A (en) * 1994-11-23 1997-04-29 Exxon Chemical Patents Inc. Method for making supported catalyst systems and catalyst systems therefrom
US5670439A (en) * 1995-03-29 1997-09-23 Quantum Chemical Corporation Vanadium-containing catalyst system
US5534472A (en) * 1995-03-29 1996-07-09 Quantum Chemical Corporation Vanadium-containing catalyst system
US6417130B1 (en) * 1996-03-25 2002-07-09 Exxonmobil Oil Corporation One pot preparation of bimetallic catalysts for ethylene 1-olefin copolymerization
DE19706409A1 (de) * 1997-02-19 1998-08-20 Buna Sow Leuna Olefinverb Gmbh Verfahren und Katalysator zur Herstellung von mittel- bis ultrahochmolekularen Polyolefinen
CA2206944C (en) * 1997-05-30 2006-08-29 Douglas W. Stephan High temperature solution polymerization process
JP4865127B2 (ja) * 1998-10-16 2012-02-01 サウディ ベーシック インダストリーズ コーポレイション 坦持チーグラー−ナッタ触媒系によるオレフィンの重合方法
CN1096474C (zh) * 1998-12-30 2002-12-18 化学工业部北京化工研究院 用于合成宽分布乙烯聚合物的复合催化剂及其制法和应用
US6403520B1 (en) * 1999-09-17 2002-06-11 Saudi Basic Industries Corporation Catalyst compositions for polymerizing olefins to multimodal molecular weight distribution polymer, processes for production and use of the catalyst
GC0000293A (en) * 2000-10-10 2006-11-01 Saudi Basic Ind Corp Catalyst composition and process for olfin polymerization and copolymerization using supported metallocene catalyst systems
US6964937B2 (en) * 2000-11-30 2005-11-15 Univation Technologies, Llc Bimetallic catalyst for producing polyethylene resins with bimodal molecular weight distribution, its preparation and use
DE60104809T2 (de) * 2001-02-07 2005-01-05 Saudi Basic Industries Corp. Katalysatorzusammensetzung für die Olefinpolymerisation und Verfahren zu ihrer Herstellung
US7172987B2 (en) * 2002-12-31 2007-02-06 Univation Technologies, Llc Bimetallic catalyst, method of polymerization and bimodal polyolefins therefrom

Also Published As

Publication number Publication date
CN1495202A (zh) 2004-05-12
ATE296319T1 (de) 2005-06-15
JP2004035893A (ja) 2004-02-05
EP1380601B1 (de) 2005-05-25
ES2240613T3 (es) 2005-10-16
US20040038806A1 (en) 2004-02-26
CN1296395C (zh) 2007-01-24
EP1380601A1 (de) 2004-01-14
DE60204306T2 (de) 2005-10-20
JP4089968B2 (ja) 2008-05-28

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