DE60205368D1 - Aktivierung von "single site" polymerisationskatalysatoren durch (dialkylalumino)broronsäureester - Google Patents

Aktivierung von "single site" polymerisationskatalysatoren durch (dialkylalumino)broronsäureester

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Publication number
DE60205368D1
DE60205368D1 DE60205368T DE60205368T DE60205368D1 DE 60205368 D1 DE60205368 D1 DE 60205368D1 DE 60205368 T DE60205368 T DE 60205368T DE 60205368 T DE60205368 T DE 60205368T DE 60205368 D1 DE60205368 D1 DE 60205368D1
Authority
DE
Germany
Prior art keywords
catalyst systems
broroic
alumino
dialkyl
activation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE60205368T
Other languages
English (en)
Other versions
DE60205368T2 (de
Inventor
W Lynch
C Meverden
Sandor Nagy
L Neal-Hawkins
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Equistar Chemicals LP
Original Assignee
Equistar Chemicals LP
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Equistar Chemicals LP filed Critical Equistar Chemicals LP
Publication of DE60205368D1 publication Critical patent/DE60205368D1/de
Application granted granted Critical
Publication of DE60205368T2 publication Critical patent/DE60205368T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
DE60205368T 2001-06-04 2002-05-09 Aktivierung von "single site" polymerisationskatalysatoren durch (dialkylalumino)broronsäureester Expired - Fee Related DE60205368T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US873713 2001-06-04
US09/873,713 US6759361B2 (en) 2001-06-04 2001-06-04 Aluminoboronate activators for single-site olefin polymerization catalysts
PCT/US2002/014656 WO2002098930A1 (en) 2001-06-04 2002-05-09 Aluminoboranate activators for single-site olefin polymerization catalysts

Publications (2)

Publication Number Publication Date
DE60205368D1 true DE60205368D1 (de) 2005-09-08
DE60205368T2 DE60205368T2 (de) 2006-06-01

Family

ID=25362177

Family Applications (1)

Application Number Title Priority Date Filing Date
DE60205368T Expired - Fee Related DE60205368T2 (de) 2001-06-04 2002-05-09 Aktivierung von "single site" polymerisationskatalysatoren durch (dialkylalumino)broronsäureester

Country Status (7)

Country Link
US (2) US6759361B2 (de)
EP (1) EP1392738B1 (de)
AT (1) ATE301141T1 (de)
CA (1) CA2449133A1 (de)
DE (1) DE60205368T2 (de)
ES (1) ES2245735T3 (de)
WO (1) WO2002098930A1 (de)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6908972B2 (en) * 2002-04-16 2005-06-21 Equistar Chemicals, Lp Method for making polyolefins
AU2003257456A1 (en) * 2002-07-15 2004-02-02 Basell Polyolefine Gmbh Preparation of supported catalyst systems
US6765074B2 (en) * 2002-09-27 2004-07-20 Equistar Chemicals, Lp Olefin polymerization process
US6794468B1 (en) * 2003-05-12 2004-09-21 Equistar Chemicals, Lp Olefin polymerization process
US6998451B2 (en) * 2003-07-01 2006-02-14 Equistar Chemicals, Lp Olefin polymerization process
KR20060118563A (ko) 2003-12-23 2006-11-23 바젤 폴리올레핀 게엠베하 지지 조촉매의 제조 방법
EP1735354A1 (de) 2004-04-16 2006-12-27 Exxonmobil Chemical Company Inc. Heterocyclylsubstituierte metallocenverbindungen für die olefinpolymerisation
DE102004058578A1 (de) * 2004-12-03 2006-06-08 Basell Polyolefine Gmbh Verfahren zur Herstellung von Katalysatorsystemen später Übergangsmetalle
US7230056B2 (en) * 2005-07-01 2007-06-12 Equistar Chemicals, Lp Catalyst preparation method
US7868197B2 (en) 2005-12-14 2011-01-11 Exxonmobil Chemical Patents Inc. Halogen substituted heteroatom-containing metallocene compounds for olefin polymerization
US7423098B2 (en) * 2006-01-17 2008-09-09 Equistar Chemicals, Lp Polyethylene process
US7429635B2 (en) * 2006-09-28 2008-09-30 Equistar Chemicals, Lp Preparation of ultra high molecular weight linear low density polyethylene
US8076259B2 (en) * 2007-10-04 2011-12-13 Basell Polyolefine Gmbh Process for the preparation of catalyst paste and products thereof
US7812104B2 (en) 2008-01-18 2010-10-12 Exxonmobil Chemical Patents Inc. Production of propylene-based polymers
US7816478B2 (en) * 2008-09-03 2010-10-19 Equistar Chemicals, Lp Polyethylene thick film and process for preparing polyethylene
EP2172493A1 (de) * 2008-10-02 2010-04-07 Total Petrochemicals Research Feluy Aktivierungsträger auf Basis von perfluorierten Borsäuren
WO2012080294A1 (en) * 2010-12-15 2012-06-21 Basell Polyolefine Gmbh Method of preparing metallocene catalysts
KR102002983B1 (ko) * 2016-02-24 2019-07-23 주식회사 엘지화학 혼성 담지 메탈로센 촉매 및 이를 이용한 폴리올레핀의 제조 방법
CN114437273B (zh) * 2020-10-30 2023-07-25 中国石油天然气股份有限公司 一种丁基橡胶的制备方法

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4791180A (en) 1985-12-12 1988-12-13 Exxon Chemical Patents Inc. New polymerization catalyst
US4752597A (en) 1985-12-12 1988-06-21 Exxon Chemical Patents Inc. New polymerization catalyst
US5153157A (en) 1987-01-30 1992-10-06 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US5198401A (en) 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US5241025A (en) 1987-01-30 1993-08-31 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US5645440A (en) * 1995-10-16 1997-07-08 Masimo Corporation Patient cable connector
US5449650A (en) * 1992-12-08 1995-09-12 Mitsubishi Petrochemical Company Limited Catalyst components for polymerization of olefins and use thereof
JPH08508523A (ja) * 1993-03-30 1996-09-10 ミネソタ マイニング アンド マニュファクチャリング カンパニー 改良した床塗膜除去用組成物および方法
US5414180A (en) * 1993-07-14 1995-05-09 Phillips Petroleum Company Organo-aluminoxy product and use
US5539124A (en) 1994-12-19 1996-07-23 Occidental Chemical Corporation Polymerization catalysts based on transition metal complexes with ligands containing pyrrolyl ring
US5554775A (en) 1995-01-17 1996-09-10 Occidental Chemical Corporation Borabenzene based olefin polymerization catalysts
US5637660A (en) 1995-04-17 1997-06-10 Lyondell Petrochemical Company Polymerization of α-olefins with transition metal catalysts based on bidentate ligands containing pyridine or quinoline moiety
AU5314796A (en) 1995-04-25 1996-11-18 Lyondell Petrochemical Company Azaborolinyl metal complexes as olefin polymerization catalysts
US6034027A (en) 1996-05-17 2000-03-07 Equistar Chemicals, Lp Borabenzene based olefin polymerization catalysts containing a group 3-10 metal
US6451724B1 (en) * 1997-11-12 2002-09-17 Basell Technology Company Bv Metallocenes and catalysts for olefin-polymerisation
US6211311B1 (en) * 1999-05-25 2001-04-03 Equistar Chemicals, L.P. Supported olefin polymerization catalysts
US6232260B1 (en) 1999-10-14 2001-05-15 Equistar Chemicals, L.P. Single-site catalysts for olefin polymerization
ES2239665T3 (es) 2000-01-18 2005-10-01 Basell Polyolefine Gmbh Procedimiento para producir polimeros aa base de propileno, substancialmente amorfos.
US6559251B1 (en) * 2002-08-02 2003-05-06 Equistar Chemicals, Lp Process for making low-density polyolefins

Also Published As

Publication number Publication date
ATE301141T1 (de) 2005-08-15
US6759361B2 (en) 2004-07-06
ES2245735T3 (es) 2006-01-16
US20030004052A1 (en) 2003-01-02
US20040181017A1 (en) 2004-09-16
WO2002098930A1 (en) 2002-12-12
DE60205368T2 (de) 2006-06-01
EP1392738B1 (de) 2005-08-03
EP1392738A1 (de) 2004-03-03
CA2449133A1 (en) 2002-12-12
US6933354B2 (en) 2005-08-23

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Legal Events

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8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee