DE602004010802T2 - Hochverträglicher und nicht migrierender polymerer uv-absorber - Google Patents

Info

Publication number

DE602004010802T2

DE602004010802T2 DE602004010802T DE602004010802T DE602004010802T2 DE 602004010802 T2 DE602004010802 T2 DE 602004010802T2 DE 602004010802 T DE602004010802 T DE 602004010802T DE 602004010802 T DE602004010802 T DE 602004010802T DE 602004010802 T2 DE602004010802 T2 DE 602004010802T2

Authority

DE

Germany

Prior art keywords

tert

butyl

bis

formula

alkylene

Prior art date

2003-05-26

Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Expired - Lifetime

Links

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• 239000006096 absorbing agent Substances 0.000 title claims abstract description 30
• 229920000642 polymer Polymers 0.000 title description 55
• 229920003023 plastic Polymers 0.000 claims abstract description 33
• 229940123973 Oxygen scavenger Drugs 0.000 claims abstract description 17
• 230000005855 radiation Effects 0.000 claims abstract description 11
• 229920000620 organic polymer Polymers 0.000 claims abstract description 9
• -1 C 1 -C 4 alkyl Substances 0.000 claims description 166
• 239000000203 mixture Substances 0.000 claims description 71
• 150000001875 compounds Chemical class 0.000 claims description 36
• 239000000654 additive Substances 0.000 claims description 33
• 125000002947 alkylene group Chemical group 0.000 claims description 33
• 229910052739 hydrogen Inorganic materials 0.000 claims description 30
• 239000004033 plastic Substances 0.000 claims description 27
• 239000001257 hydrogen Substances 0.000 claims description 25
• 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 22
• 125000000217 alkyl group Chemical group 0.000 claims description 21
• 229920000728 polyester Polymers 0.000 claims description 20
• 235000013305 food Nutrition 0.000 claims description 17
• 239000004417 polycarbonate Substances 0.000 claims description 17
• 125000004432 carbon atom Chemical group C* 0.000 claims description 16
• 239000002861 polymer material Substances 0.000 claims description 16
• UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 15
• 239000011888 foil Substances 0.000 claims description 15
• 150000001412 amines Chemical class 0.000 claims description 14
• 238000004806 packaging method and process Methods 0.000 claims description 14
• 238000000034 method Methods 0.000 claims description 13
• 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 12
• XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 11
• 239000003054 catalyst Substances 0.000 claims description 10
• 125000002993 cycloalkylene group Chemical group 0.000 claims description 10
• 150000002431 hydrogen Chemical class 0.000 claims description 10
• 229920002601 oligoester Polymers 0.000 claims description 9
• 229920000098 polyolefin Polymers 0.000 claims description 9
• 239000002253 acid Substances 0.000 claims description 8
• 229920000515 polycarbonate Polymers 0.000 claims description 8
• OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 7
• AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 claims description 7
• 238000007539 photo-oxidation reaction Methods 0.000 claims description 7
• IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 claims description 6
• 125000001931 aliphatic group Chemical group 0.000 claims description 6
• 125000005037 alkyl phenyl group Chemical group 0.000 claims description 6
• 229910052799 carbon Inorganic materials 0.000 claims description 6
• 125000005724 cycloalkenylene group Chemical group 0.000 claims description 6
• 150000002009 diols Chemical class 0.000 claims description 6
• 229910052736 halogen Inorganic materials 0.000 claims description 6
• 150000002367 halogens Chemical class 0.000 claims description 6
• 238000010348 incorporation Methods 0.000 claims description 6
• 230000003287 optical effect Effects 0.000 claims description 6
• 230000000694 effects Effects 0.000 claims description 5
• 125000004430 oxygen atom Chemical group O* 0.000 claims description 5
• 235000021485 packed food Nutrition 0.000 claims description 5
• XRBCRPZXSCBRTK-UHFFFAOYSA-N phosphonous acid Chemical class OPO XRBCRPZXSCBRTK-UHFFFAOYSA-N 0.000 claims description 5
• 230000008569 process Effects 0.000 claims description 5
• 229920001169 thermoplastic Polymers 0.000 claims description 5
• 239000006057 Non-nutritive feed additive Substances 0.000 claims description 4
• 125000004450 alkenylene group Chemical group 0.000 claims description 4
• 125000003302 alkenyloxy group Chemical group 0.000 claims description 4
• 125000003545 alkoxy group Chemical group 0.000 claims description 4
• 125000000000 cycloalkoxy group Chemical group 0.000 claims description 4
• 125000000753 cycloalkyl group Chemical group 0.000 claims description 4
• 235000014113 dietary fatty acids Nutrition 0.000 claims description 4
• 239000000194 fatty acid Substances 0.000 claims description 4
• 229930195729 fatty acid Natural products 0.000 claims description 4
• 150000004665 fatty acids Chemical class 0.000 claims description 4
• 229910044991 metal oxide Inorganic materials 0.000 claims description 4
• 150000004706 metal oxides Chemical class 0.000 claims description 4
• 125000000896 monocarboxylic acid group Chemical group 0.000 claims description 4
• 229920002689 polyvinyl acetate Polymers 0.000 claims description 4
• 229920002451 polyvinyl alcohol Polymers 0.000 claims description 4
• 239000004372 Polyvinyl alcohol Substances 0.000 claims description 3
• 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 3
• 239000003795 chemical substances by application Substances 0.000 claims description 3
• 230000002542 deteriorative effect Effects 0.000 claims description 3
• 239000002530 phenolic antioxidant Substances 0.000 claims description 3
• 239000004014 plasticizer Substances 0.000 claims description 3
• 239000011118 polyvinyl acetate Substances 0.000 claims description 3
• 125000006710 (C2-C12) alkenyl group Chemical group 0.000 claims description 2
• JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical group C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 claims description 2
• 229910052783 alkali metal Inorganic materials 0.000 claims description 2
• 239000002216 antistatic agent Substances 0.000 claims description 2
• 239000003995 emulsifying agent Substances 0.000 claims description 2
• 239000000945 filler Substances 0.000 claims description 2
• 239000003063 flame retardant Substances 0.000 claims description 2
• 125000002768 hydroxyalkyl group Chemical group 0.000 claims description 2
• 239000000314 lubricant Substances 0.000 claims description 2
• 239000000049 pigment Substances 0.000 claims description 2
• 230000004224 protection Effects 0.000 claims description 2
• 238000000518 rheometry Methods 0.000 claims description 2
• 230000035515 penetration Effects 0.000 claims 1
• 239000003380 propellant Substances 0.000 claims 1
• 239000000463 material Substances 0.000 abstract description 22
• 239000002537 cosmetic Substances 0.000 abstract description 6
• VMRIVYANZGSGRV-UHFFFAOYSA-N 4-phenyl-2h-triazin-5-one Chemical compound OC1=CN=NN=C1C1=CC=CC=C1 VMRIVYANZGSGRV-UHFFFAOYSA-N 0.000 abstract description 5
• 239000003814 drug Substances 0.000 abstract description 5
• 235000013372 meat Nutrition 0.000 abstract description 4
• 235000013361 beverage Nutrition 0.000 abstract description 3
• 239000002453 shampoo Substances 0.000 abstract description 3
• 235000013311 vegetables Nutrition 0.000 abstract description 2
• 230000002939 deleterious effect Effects 0.000 abstract 1
• 229920001577 copolymer Polymers 0.000 description 88
• PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 79
• VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 36
• OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 33
• NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 26
• 229920000573 polyethylene Polymers 0.000 description 26
• 229920001155 polypropylene Polymers 0.000 description 25
• LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 24
• LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 23
• 229910052757 nitrogen Inorganic materials 0.000 description 23
• 150000002148 esters Chemical class 0.000 description 22
• 229920002647 polyamide Polymers 0.000 description 22
• 239000004743 Polypropylene Substances 0.000 description 19
• 229920001684 low density polyethylene Polymers 0.000 description 18
• 239000004702 low-density polyethylene Substances 0.000 description 18
• 229920002857 polybutadiene Polymers 0.000 description 17
• 239000000047 product Substances 0.000 description 17
• 239000004952 Polyamide Substances 0.000 description 16
• KBPLFHHGFOOTCA-UHFFFAOYSA-N caprylic alcohol Natural products CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 16
• MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 16
• GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 16
• 229920000092 linear low density polyethylene Polymers 0.000 description 15
• 239000004707 linear low-density polyethylene Substances 0.000 description 15
• 239000000126 substance Substances 0.000 description 15
• 239000005977 Ethylene Substances 0.000 description 14
• 239000010410 layer Substances 0.000 description 13
• 229910052760 oxygen Inorganic materials 0.000 description 13
• 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 12
• QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 12
• 239000001301 oxygen Substances 0.000 description 12
• 229920006324 polyoxymethylene Polymers 0.000 description 12
• 229920000915 polyvinyl chloride Polymers 0.000 description 12
• 239000004698 Polyethylene Substances 0.000 description 11
• 238000005227 gel permeation chromatography Methods 0.000 description 11
• XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 11
• 239000004800 polyvinyl chloride Substances 0.000 description 11
• 239000007983 Tris buffer Substances 0.000 description 10
• 230000000996 additive effect Effects 0.000 description 10
• 229920001903 high density polyethylene Polymers 0.000 description 10
• 239000004700 high-density polyethylene Substances 0.000 description 10
• 229910052751 metal Inorganic materials 0.000 description 10
• 239000002184 metal Substances 0.000 description 10
• 239000000178 monomer Substances 0.000 description 10
• KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 9
• CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 9
• 239000000243 solution Substances 0.000 description 9
• 239000008096 xylene Substances 0.000 description 9
• ALVZNPYWJMLXKV-UHFFFAOYSA-N 1,9-Nonanediol Chemical compound OCCCCCCCCCO ALVZNPYWJMLXKV-UHFFFAOYSA-N 0.000 description 8
• YEWBOZCFGXOUQW-UHFFFAOYSA-N 2,6,7-trioxa-1-phosphabicyclo[2.2.2]octan-4-ylmethanol Chemical compound C1OP2OCC1(CO)CO2 YEWBOZCFGXOUQW-UHFFFAOYSA-N 0.000 description 8
• KXPXKNBDCUOENF-UHFFFAOYSA-N 2-(Octylthio)ethanol Chemical compound CCCCCCCCSCCO KXPXKNBDCUOENF-UHFFFAOYSA-N 0.000 description 8
• ZPIRWAHWDCHWLM-UHFFFAOYSA-N 2-dodecylsulfanylethanol Chemical compound CCCCCCCCCCCCSCCO ZPIRWAHWDCHWLM-UHFFFAOYSA-N 0.000 description 8
• CKPKHTKLLYPGFM-UHFFFAOYSA-N 6,6-dimethylheptane-1,1-diol Chemical compound CC(CCCCC(O)O)(C)C CKPKHTKLLYPGFM-UHFFFAOYSA-N 0.000 description 8
• 239000005062 Polybutadiene Substances 0.000 description 8
• 239000004721 Polyphenylene oxide Substances 0.000 description 8
• QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 8
• DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 8
• ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 8
• 239000012298 atmosphere Substances 0.000 description 8
• QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 8
• 238000006243 chemical reaction Methods 0.000 description 8
• FPQJEXTVQZHURJ-UHFFFAOYSA-N n,n'-bis(2-hydroxyethyl)oxamide Chemical compound OCCNC(=O)C(=O)NCCO FPQJEXTVQZHURJ-UHFFFAOYSA-N 0.000 description 8
• SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 8
• 229940117969 neopentyl glycol Drugs 0.000 description 8
• 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 8
• 229920000139 polyethylene terephthalate Polymers 0.000 description 8
• 229920006380 polyphenylene oxide Polymers 0.000 description 8
• 239000004814 polyurethane Substances 0.000 description 8
• 239000003381 stabilizer Substances 0.000 description 8
• ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 8
• CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Natural products OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 7
• 238000010521 absorption reaction Methods 0.000 description 7
• 150000001993 dienes Chemical class 0.000 description 7
• 239000005038 ethylene vinyl acetate Substances 0.000 description 7
• 238000002844 melting Methods 0.000 description 7
• 230000008018 melting Effects 0.000 description 7
• 229920003229 poly(methyl methacrylate) Polymers 0.000 description 7
• 239000005020 polyethylene terephthalate Substances 0.000 description 7
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
• RXFCIXRFAJRBSG-UHFFFAOYSA-N 3,2,3-tetramine Chemical compound NCCCNCCNCCCN RXFCIXRFAJRBSG-UHFFFAOYSA-N 0.000 description 6
• 229920000089 Cyclic olefin copolymer Polymers 0.000 description 6
• YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
• 229920002943 EPDM rubber Polymers 0.000 description 6
• BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 6
• WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 6
• 125000003118 aryl group Chemical group 0.000 description 6
• 230000005540 biological transmission Effects 0.000 description 6
• DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 6
• 229920001971 elastomer Polymers 0.000 description 6
• 229920001519 homopolymer Polymers 0.000 description 6
• UKJARPDLRWBRAX-UHFFFAOYSA-N n,n'-bis(2,2,6,6-tetramethylpiperidin-4-yl)hexane-1,6-diamine Chemical compound C1C(C)(C)NC(C)(C)CC1NCCCCCCNC1CC(C)(C)NC(C)(C)C1 UKJARPDLRWBRAX-UHFFFAOYSA-N 0.000 description 6
• 239000003921 oil Substances 0.000 description 6
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• JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 6
• 238000004383 yellowing Methods 0.000 description 6
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• 238000001125 extrusion Methods 0.000 description 5
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• WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 5
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• 229920001897 terpolymer Polymers 0.000 description 5
• 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 5
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• HJIAMFHSAAEUKR-UHFFFAOYSA-N (2-hydroxyphenyl)-phenylmethanone Chemical compound OC1=CC=CC=C1C(=O)C1=CC=CC=C1 HJIAMFHSAAEUKR-UHFFFAOYSA-N 0.000 description 4
• ZEBMSMUPGIOANU-UHFFFAOYSA-N (3,5-ditert-butyl-4-hydroxyphenyl)methylphosphonic acid Chemical compound CC(C)(C)C1=CC(CP(O)(O)=O)=CC(C(C)(C)C)=C1O ZEBMSMUPGIOANU-UHFFFAOYSA-N 0.000 description 4
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• GVJHHUAWPYXKBD-UHFFFAOYSA-N (±)-α-Tocopherol Chemical compound OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 4
• BPXVHIRIPLPOPT-UHFFFAOYSA-N 1,3,5-tris(2-hydroxyethyl)-1,3,5-triazinane-2,4,6-trione Chemical compound OCCN1C(=O)N(CCO)C(=O)N(CCO)C1=O BPXVHIRIPLPOPT-UHFFFAOYSA-N 0.000 description 4
• YHMYGUUIMTVXNW-UHFFFAOYSA-N 1,3-dihydrobenzimidazole-2-thione Chemical compound C1=CC=C2NC(S)=NC2=C1 YHMYGUUIMTVXNW-UHFFFAOYSA-N 0.000 description 4
• BWJKLDGAAPQXGO-UHFFFAOYSA-N 2,2,6,6-tetramethyl-4-octadecoxypiperidine Chemical compound CCCCCCCCCCCCCCCCCCOC1CC(C)(C)NC(C)(C)C1 BWJKLDGAAPQXGO-UHFFFAOYSA-N 0.000 description 4
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• WPMYUUITDBHVQZ-UHFFFAOYSA-N 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoic acid Chemical compound CC(C)(C)C1=CC(CCC(O)=O)=CC(C(C)(C)C)=C1O WPMYUUITDBHVQZ-UHFFFAOYSA-N 0.000 description 4
• SAEZGDDJKSBNPT-UHFFFAOYSA-N 3-dodecyl-1-(1,2,2,6,6-pentamethylpiperidin-4-yl)pyrrolidine-2,5-dione Chemical compound O=C1C(CCCCCCCCCCCC)CC(=O)N1C1CC(C)(C)N(C)C(C)(C)C1 SAEZGDDJKSBNPT-UHFFFAOYSA-N 0.000 description 4
• FBIXXCXCZOZFCO-UHFFFAOYSA-N 3-dodecyl-1-(2,2,6,6-tetramethylpiperidin-4-yl)pyrrolidine-2,5-dione Chemical compound O=C1C(CCCCCCCCCCCC)CC(=O)N1C1CC(C)(C)NC(C)(C)C1 FBIXXCXCZOZFCO-UHFFFAOYSA-N 0.000 description 4
• STEYNUVPFMIUOY-UHFFFAOYSA-N 4-Hydroxy-1-(2-hydroxyethyl)-2,2,6,6-tetramethylpiperidine Chemical compound CC1(C)CC(O)CC(C)(C)N1CCO STEYNUVPFMIUOY-UHFFFAOYSA-N 0.000 description 4
• NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 4
• XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
• IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
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• 150000007513 acids Chemical class 0.000 description 4
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• 239000012964 benzotriazole Substances 0.000 description 4
• RSOILICUEWXSLA-UHFFFAOYSA-N bis(1,2,2,6,6-pentamethylpiperidin-4-yl) decanedioate Chemical compound C1C(C)(C)N(C)C(C)(C)CC1OC(=O)CCCCCCCCC(=O)OC1CC(C)(C)N(C)C(C)(C)C1 RSOILICUEWXSLA-UHFFFAOYSA-N 0.000 description 4
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• ZYGHJZDHTFUPRJ-UHFFFAOYSA-N coumarin Chemical compound C1=CC=C2OC(=O)C=CC2=C1 ZYGHJZDHTFUPRJ-UHFFFAOYSA-N 0.000 description 4
• 239000000806 elastomer Substances 0.000 description 4
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• 229940093476 ethylene glycol Drugs 0.000 description 4
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