TW200427751A - Highly compatible and non-migratory polymeric UV-absorber - Google Patents

Info

Publication number

TW200427751A

TW200427751A TW093114617A TW93114617A TW200427751A TW 200427751 A TW200427751 A TW 200427751A TW 093114617 A TW093114617 A TW 093114617A TW 93114617 A TW93114617 A TW 93114617A TW 200427751 A TW200427751 A TW 200427751A

Authority

TW

Taiwan

Prior art keywords

formula

film

butyl

bis

alkyl

Prior art date

2003-05-26

Links

• Espacenet
• Global Dossier
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• 239000006096 absorbing agent Substances 0.000 title claims abstract description 26
• 230000001617 migratory effect Effects 0.000 title 1
• 229920003023 plastic Polymers 0.000 claims abstract description 36
• 229940123973 Oxygen scavenger Drugs 0.000 claims abstract description 16
• 229920000620 organic polymer Polymers 0.000 claims abstract description 9
• 230000005855 radiation Effects 0.000 claims abstract description 7
• -1 Alkali metal salts Chemical class 0.000 claims description 162
• 239000000203 mixture Substances 0.000 claims description 66
• 150000001875 compounds Chemical class 0.000 claims description 44
• 239000000126 substance Substances 0.000 claims description 41
• 239000004033 plastic Substances 0.000 claims description 28
• 125000000217 alkyl group Chemical group 0.000 claims description 25
• 125000002947 alkylene group Chemical group 0.000 claims description 25
• 239000000654 additive Substances 0.000 claims description 24
• 229910052739 hydrogen Inorganic materials 0.000 claims description 22
• 239000001257 hydrogen Substances 0.000 claims description 21
• 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 18
• 229920000728 polyester Polymers 0.000 claims description 17
• 150000001412 amines Chemical class 0.000 claims description 16
• 235000013305 food Nutrition 0.000 claims description 15
• 238000000034 method Methods 0.000 claims description 15
• 125000004432 carbon atom Chemical group C* 0.000 claims description 14
• 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 14
• 239000004417 polycarbonate Substances 0.000 claims description 14
• 229910052799 carbon Inorganic materials 0.000 claims description 12
• 238000006243 chemical reaction Methods 0.000 claims description 12
• 125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 claims description 12
• QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 11
• 239000003054 catalyst Substances 0.000 claims description 11
• 150000002148 esters Chemical class 0.000 claims description 11
• 229910052751 metal Inorganic materials 0.000 claims description 11
• 239000002184 metal Substances 0.000 claims description 11
• NIHNNTQXNPWCJQ-UHFFFAOYSA-N o-biphenylenemethane Natural products C1=CC=C2CC3=CC=CC=C3C2=C1 NIHNNTQXNPWCJQ-UHFFFAOYSA-N 0.000 claims description 10
• 229920000098 polyolefin Polymers 0.000 claims description 10
• XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 9
• ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 9
• 150000002431 hydrogen Chemical group 0.000 claims description 9
• OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 8
• 238000010521 absorption reaction Methods 0.000 claims description 8
• 238000007539 photo-oxidation reaction Methods 0.000 claims description 8
• 229920000515 polycarbonate Polymers 0.000 claims description 8
• 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 7
• 239000004615 ingredient Substances 0.000 claims description 7
• UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 6
• 239000003795 chemical substances by application Substances 0.000 claims description 6
• 230000003287 optical effect Effects 0.000 claims description 6
• ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 claims description 5
• 230000000996 additive effect Effects 0.000 claims description 5
• 125000003342 alkenyl group Chemical group 0.000 claims description 5
• 125000005037 alkyl phenyl group Chemical group 0.000 claims description 5
• 150000002009 diols Chemical class 0.000 claims description 5
• 230000009931 harmful effect Effects 0.000 claims description 5
• 125000004464 hydroxyphenyl group Chemical group 0.000 claims description 5
• 125000004430 oxygen atom Chemical group O* 0.000 claims description 5
• 235000021485 packed food Nutrition 0.000 claims description 5
• 150000003839 salts Chemical class 0.000 claims description 5
• 229920001169 thermoplastic Polymers 0.000 claims description 5
• JIHQDMXYYFUGFV-UHFFFAOYSA-N 1,3,5-triazine Chemical compound C1=NC=NC=N1 JIHQDMXYYFUGFV-UHFFFAOYSA-N 0.000 claims description 4
• IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 claims description 4
• OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
• 125000003545 alkoxy group Chemical group 0.000 claims description 4
• 239000003963 antioxidant agent Substances 0.000 claims description 4
• 239000002585 base Substances 0.000 claims description 4
• 125000002993 cycloalkylene group Chemical group 0.000 claims description 4
• 229910052742 iron Inorganic materials 0.000 claims description 4
• 229910044991 metal oxide Inorganic materials 0.000 claims description 4
• 150000004706 metal oxides Chemical class 0.000 claims description 4
• 230000035515 penetration Effects 0.000 claims description 4
• 239000000454 talc Substances 0.000 claims description 4
• 229910052623 talc Inorganic materials 0.000 claims description 4
• 239000006057 Non-nutritive feed additive Substances 0.000 claims description 3
• 235000014113 dietary fatty acids Nutrition 0.000 claims description 3
• 239000000194 fatty acid Substances 0.000 claims description 3
• 229930195729 fatty acid Natural products 0.000 claims description 3
• 150000004665 fatty acids Chemical class 0.000 claims description 3
• 229910052736 halogen Inorganic materials 0.000 claims description 3
• 150000002367 halogens Chemical class 0.000 claims description 3
• 150000002506 iron compounds Chemical class 0.000 claims description 3
• 239000004014 plasticizer Substances 0.000 claims description 3
• 239000011118 polyvinyl acetate Substances 0.000 claims description 3
• 229920002689 polyvinyl acetate Polymers 0.000 claims description 3
• JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical group C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 claims description 2
• 125000001931 aliphatic group Chemical group 0.000 claims description 2
• 125000003302 alkenyloxy group Chemical group 0.000 claims description 2
• 239000002216 antistatic agent Substances 0.000 claims description 2
• 239000003995 emulsifying agent Substances 0.000 claims description 2
• 239000000945 filler Substances 0.000 claims description 2
• 239000003063 flame retardant Substances 0.000 claims description 2
• 239000000314 lubricant Substances 0.000 claims description 2
• AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 claims description 2
• 239000006254 rheological additive Substances 0.000 claims description 2
• 229920002601 oligoester Polymers 0.000 claims 7
• 239000004372 Polyvinyl alcohol Substances 0.000 claims 2
• 229920002451 polyvinyl alcohol Polymers 0.000 claims 2
• 229910052783 alkali metal Inorganic materials 0.000 claims 1
• 125000000000 cycloalkoxy group Chemical group 0.000 claims 1
• 125000000753 cycloalkyl group Chemical group 0.000 claims 1
• 239000004088 foaming agent Substances 0.000 claims 1
• 125000000896 monocarboxylic acid group Chemical group 0.000 claims 1
• 239000000049 pigment Substances 0.000 claims 1
• 239000000463 material Substances 0.000 abstract description 12
• 239000002537 cosmetic Substances 0.000 abstract description 5
• 239000003814 drug Substances 0.000 abstract description 5
• 235000013361 beverage Nutrition 0.000 abstract description 4
• VMRIVYANZGSGRV-UHFFFAOYSA-N 4-phenyl-2h-triazin-5-one Chemical compound OC1=CN=NN=C1C1=CC=CC=C1 VMRIVYANZGSGRV-UHFFFAOYSA-N 0.000 abstract description 3
• 239000002453 shampoo Substances 0.000 abstract description 3
• 230000002939 deleterious effect Effects 0.000 abstract description 2
• 235000013372 meat Nutrition 0.000 abstract description 2
• 235000013311 vegetables Nutrition 0.000 abstract 1
• 239000010408 film Substances 0.000 description 61
• 229920000642 polymer Polymers 0.000 description 60
• 229910052757 nitrogen Inorganic materials 0.000 description 49
• 229920001577 copolymer Polymers 0.000 description 44
• PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 39
• VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 33
• 239000005977 Ethylene Substances 0.000 description 29
• 239000002253 acid Substances 0.000 description 23
• LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 22
• LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 19
• 239000000047 product Substances 0.000 description 19
• OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical class OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 15
• 239000010410 layer Substances 0.000 description 15
• 239000004743 Polypropylene Substances 0.000 description 14
• QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 14
• 239000012964 benzotriazole Substances 0.000 description 14
• 239000001301 oxygen Substances 0.000 description 14
• 229910052760 oxygen Inorganic materials 0.000 description 14
• 239000007983 Tris buffer Substances 0.000 description 13
• ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 12
• 239000007789 gas Substances 0.000 description 12
• NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 12
• 238000002834 transmittance Methods 0.000 description 12
• 239000004698 Polyethylene Substances 0.000 description 11
• 238000004806 packaging method and process Methods 0.000 description 11
• 229920000573 polyethylene Polymers 0.000 description 11
• 239000000243 solution Substances 0.000 description 11
• 239000000178 monomer Substances 0.000 description 10
• 229920001155 polypropylene Polymers 0.000 description 10
• 239000005062 Polybutadiene Substances 0.000 description 9
• DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 9
• 238000005227 gel permeation chromatography Methods 0.000 description 9
• 229920002857 polybutadiene Polymers 0.000 description 9
• KAKZBPTYRLMSJV-UHFFFAOYSA-N vinyl-ethylene Natural products C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 9
• NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 8
• OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 8
• 239000007859 condensation product Substances 0.000 description 8
• 239000011521 glass Substances 0.000 description 8
• NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 7
• UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 7
• 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 7
• 239000004700 high-density polyethylene Substances 0.000 description 7
• 229920006324 polyoxymethylene Polymers 0.000 description 7
• 239000002244 precipitate Substances 0.000 description 7
• 235000021419 vinegar Nutrition 0.000 description 7
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
• 239000004952 Polyamide Substances 0.000 description 6
• 239000002250 absorbent Substances 0.000 description 6
• 150000007513 acids Chemical class 0.000 description 6
• 150000001993 dienes Chemical class 0.000 description 6
• 229920001971 elastomer Polymers 0.000 description 6
• 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 6
• 229920001903 high density polyethylene Polymers 0.000 description 6
• 229920000092 linear low density polyethylene Polymers 0.000 description 6
• 239000004707 linear low-density polyethylene Substances 0.000 description 6
• 238000002844 melting Methods 0.000 description 6
• 230000008018 melting Effects 0.000 description 6
• IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
• GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 6
• 229920002647 polyamide Polymers 0.000 description 6
• 238000006116 polymerization reaction Methods 0.000 description 6
• 239000001294 propane Substances 0.000 description 6
• 239000002904 solvent Substances 0.000 description 6
• 239000003381 stabilizer Substances 0.000 description 6
• 239000000052 vinegar Substances 0.000 description 6
• 229920002554 vinyl polymer Polymers 0.000 description 6
• 238000004383 yellowing Methods 0.000 description 6
• RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 5
• XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 5
• GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 5
• 230000002745 absorbent Effects 0.000 description 5
• 150000001298 alcohols Chemical class 0.000 description 5
• 125000003118 aryl group Chemical group 0.000 description 5
• 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 5
• KBPLFHHGFOOTCA-UHFFFAOYSA-N caprylic alcohol Natural products CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 5
• 239000000539 dimer Substances 0.000 description 5
• 239000000806 elastomer Substances 0.000 description 5
• WNLRTRBMVRJNCN-UHFFFAOYSA-N hexanedioic acid Natural products OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 5
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• 238000012545 processing Methods 0.000 description 5
• 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 5
• SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 4
• KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 4
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• FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 4
• GHKOFFNLGXMVNJ-UHFFFAOYSA-N Didodecyl thiobispropanoate Chemical compound CCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCC GHKOFFNLGXMVNJ-UHFFFAOYSA-N 0.000 description 4
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• 239000004305 biphenyl Substances 0.000 description 4
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• 150000001925 cycloalkenes Chemical class 0.000 description 4
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• 229920001684 low density polyethylene Polymers 0.000 description 4
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• KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 description 3
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• KIPGIZCKZDHTJB-UHFFFAOYSA-N 2-(4-phenylphenyl)-1,3,5-triazine Chemical compound C1=CC=CC=C1C1=CC=C(C=2N=CN=CN=2)C=C1 KIPGIZCKZDHTJB-UHFFFAOYSA-N 0.000 description 3
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• 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 3
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• 238000005984 hydrogenation reaction Methods 0.000 description 3
• FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 3
• 239000011572 manganese Substances 0.000 description 3
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• YODZTKMDCQEPHD-UHFFFAOYSA-N thiodiglycol Chemical compound OCCSCCO YODZTKMDCQEPHD-UHFFFAOYSA-N 0.000 description 3
• XFNJVJPLKCPIBV-UHFFFAOYSA-N trimethylenediamine Chemical compound NCCCN XFNJVJPLKCPIBV-UHFFFAOYSA-N 0.000 description 3
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