DE602004008166T2 - Verfahren zur Herstellung eines feinkörnigen Hartmetalles - Google Patents
Verfahren zur Herstellung eines feinkörnigen Hartmetalles Download PDFInfo
- Publication number
- DE602004008166T2 DE602004008166T2 DE602004008166T DE602004008166T DE602004008166T2 DE 602004008166 T2 DE602004008166 T2 DE 602004008166T2 DE 602004008166 T DE602004008166 T DE 602004008166T DE 602004008166 T DE602004008166 T DE 602004008166T DE 602004008166 T2 DE602004008166 T2 DE 602004008166T2
- Authority
- DE
- Germany
- Prior art keywords
- nitrogen
- sintering
- temperature
- grains
- inserts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims description 19
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 78
- 238000005245 sintering Methods 0.000 claims abstract description 39
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 38
- 239000012298 atmosphere Substances 0.000 claims abstract description 13
- 239000011148 porous material Substances 0.000 claims abstract description 10
- 238000004519 manufacturing process Methods 0.000 claims abstract description 9
- 238000003801 milling Methods 0.000 claims abstract 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 20
- 230000001681 protective effect Effects 0.000 claims description 13
- 229910009043 WC-Co Inorganic materials 0.000 claims description 12
- 229910052786 argon Inorganic materials 0.000 claims description 10
- 239000003966 growth inhibitor Substances 0.000 claims description 9
- 239000000843 powder Substances 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 6
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- 150000004767 nitrides Chemical class 0.000 claims description 4
- 150000002739 metals Chemical class 0.000 claims description 3
- -1 Compounds Carbides Chemical class 0.000 claims 1
- 238000007789 sealing Methods 0.000 claims 1
- UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 abstract description 13
- 230000002159 abnormal effect Effects 0.000 abstract description 12
- 239000010941 cobalt Substances 0.000 abstract description 4
- 229910017052 cobalt Inorganic materials 0.000 abstract description 4
- 238000009826 distribution Methods 0.000 description 14
- 239000011230 binding agent Substances 0.000 description 12
- 238000001816 cooling Methods 0.000 description 12
- 238000005520 cutting process Methods 0.000 description 12
- 238000011049 filling Methods 0.000 description 11
- 229910045601 alloy Inorganic materials 0.000 description 10
- 239000000956 alloy Substances 0.000 description 10
- 239000011651 chromium Substances 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 8
- 238000001000 micrograph Methods 0.000 description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 7
- 229910052799 carbon Inorganic materials 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 239000002245 particle Substances 0.000 description 5
- 229910052721 tungsten Inorganic materials 0.000 description 5
- 239000010937 tungsten Substances 0.000 description 5
- 239000003153 chemical reaction reagent Substances 0.000 description 4
- 238000009770 conventional sintering Methods 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 3
- 229910052804 chromium Inorganic materials 0.000 description 3
- 229910052720 vanadium Inorganic materials 0.000 description 3
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 3
- 238000007792 addition Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 229910001873 dinitrogen Inorganic materials 0.000 description 2
- 238000003754 machining Methods 0.000 description 2
- 150000001247 metal acetylides Chemical class 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 229910000531 Co alloy Inorganic materials 0.000 description 1
- 229910001199 N alloy Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000010955 niobium Substances 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 238000004663 powder metallurgy Methods 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- UDKYUQZDRMRDOR-UHFFFAOYSA-N tungsten Chemical compound [W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W] UDKYUQZDRMRDOR-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/10—Sintering only
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/04—Making non-ferrous alloys by powder metallurgy
- C22C1/05—Mixtures of metal powder with non-metallic powder
- C22C1/051—Making hard metals based on borides, carbides, nitrides, oxides or silicides; Preparation of the powder mixture used as the starting material therefor
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C29/00—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
- C22C29/02—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides
- C22C29/06—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds
- C22C29/08—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds based on tungsten carbide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F5/00—Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product
- B22F2005/001—Cutting tools, earth boring or grinding tool other than table ware
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
- B22F2998/10—Processes characterised by the sequence of their steps
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2999/00—Aspects linked to processes or compositions used in powder metallurgy
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Powder Metallurgy (AREA)
- Carbon And Carbon Compounds (AREA)
- Materials For Medical Uses (AREA)
- Cutting Tools, Boring Holders, And Turrets (AREA)
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SE0302131 | 2003-07-25 | ||
SE0302131A SE0302131D0 (sv) | 2003-07-25 | 2003-07-25 | Method of making a fine grained cemented carbide |
SE0302835 | 2003-10-28 | ||
SE0302835A SE527173C2 (sv) | 2003-07-25 | 2003-10-28 | Sätt att tillverka en finkorning hårdmetall |
Publications (2)
Publication Number | Publication Date |
---|---|
DE602004008166D1 DE602004008166D1 (de) | 2007-09-27 |
DE602004008166T2 true DE602004008166T2 (de) | 2008-04-30 |
Family
ID=29552453
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE602004008166T Expired - Lifetime DE602004008166T2 (de) | 2003-07-25 | 2004-06-21 | Verfahren zur Herstellung eines feinkörnigen Hartmetalles |
Country Status (8)
Country | Link |
---|---|
US (2) | US20050025657A1 (ko) |
EP (1) | EP1500713B1 (ko) |
JP (1) | JP2005042201A (ko) |
KR (1) | KR101202225B1 (ko) |
AT (1) | ATE370257T1 (ko) |
DE (1) | DE602004008166T2 (ko) |
IL (1) | IL162686A (ko) |
SE (1) | SE527173C2 (ko) |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101151386B (zh) | 2005-03-28 | 2010-05-19 | 京瓷株式会社 | 超硬合金及切削工具 |
SE530516C2 (sv) | 2006-06-15 | 2008-06-24 | Sandvik Intellectual Property | Belagt hårdmetallskär, metod att tillverka detta samt dess användning vid fräsning av gjutjärn |
SE530861C2 (sv) | 2006-12-15 | 2008-09-30 | Sandvik Intellectual Property | Belagd hårdmetallpinnfräs för medel- och finbearbetning av härdade stål och förfarande för dess framställning |
SE0700800L (sv) * | 2006-12-15 | 2008-06-16 | Sandvik Intellectual Property | Belagt skärverktyg |
SE0701449L (sv) | 2007-06-01 | 2008-12-02 | Sandvik Intellectual Property | Finkornig hårdmetall med förfinad struktur |
SE0701760L (sv) * | 2007-06-01 | 2008-12-02 | Sandvik Intellectual Property | Hårdmetallskär för avstickning, spårstickning och gängning |
US8455116B2 (en) | 2007-06-01 | 2013-06-04 | Sandvik Intellectual Property Ab | Coated cemented carbide cutting tool insert |
SE0701761L (sv) | 2007-06-01 | 2008-12-02 | Sandvik Intellectual Property | Finkornig hårdmetall för svarvning i varmhållfasta superlegeringar (HRSA) och rostfria stål |
SE531971C2 (sv) * | 2007-08-24 | 2009-09-15 | Seco Tools Ab | Belagt skärverktyg för allmän svarvning i varmhållfast superlegeringar (HRSA) |
DE102012018067A1 (de) * | 2012-09-13 | 2014-03-13 | Tutec Gmbh | Hexagonales WC-Pulver, Verfahren zu dessen Herstellung sowie Verwendung dieses Pulvers |
US10308558B2 (en) * | 2013-05-31 | 2019-06-04 | Sandvik Intellectual Property Ab | Process of manufacturing cemented carbide and a product obtained thereof |
RU2015156229A (ru) * | 2013-05-31 | 2017-07-06 | Сандвик Интеллекчуал Проперти Аб | Новый способ получения цементированного карбида и получаемый при его помощи продукт |
CN105899706A (zh) * | 2013-12-27 | 2016-08-24 | 山特维克知识产权股份有限公司 | 耐蚀性二联钢合金,由其制成的物体和制造该合金的方法 |
CN113322389A (zh) * | 2021-06-01 | 2021-08-31 | 株洲硬质合金集团有限公司 | 一种耐磨损耐腐蚀超细硬质合金的烧结方法 |
Family Cites Families (29)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1549615A (en) * | 1923-10-31 | 1925-08-11 | Gen Electric | Hard-metal alloy and the process of making same |
US1728909A (en) * | 1925-12-12 | 1929-09-17 | Gen Electric | Method of making tools from hard-metal alloys produced by sintering |
US1794300A (en) * | 1928-01-07 | 1931-02-24 | Gen Electric | Hard metal composition |
US1811068A (en) * | 1928-12-03 | 1931-06-23 | Richard R Walter | Alloy |
US1864567A (en) * | 1929-08-05 | 1932-06-28 | Richard R Walter | Alloy of azotized character |
US2036245A (en) * | 1932-01-11 | 1936-04-07 | Richard R Walter | Alloy |
US2263520A (en) * | 1938-11-04 | 1941-11-18 | Hartford Nat Bank & Trust Co | Method of making sintered hard metal alloys |
US3647401A (en) * | 1969-06-04 | 1972-03-07 | Du Pont | Anisodimensional tungsten carbide platelets bonded with cobalt |
US3628921A (en) * | 1969-08-18 | 1971-12-21 | Parker Pen Co | Corrosion resistant binder for tungsten carbide materials and titanium carbide materials |
US4070184A (en) * | 1976-09-24 | 1978-01-24 | Gte Sylvania Incorporated | Process for producing refractory carbide grade powder |
US4427446A (en) * | 1981-04-13 | 1984-01-24 | Japan Steel Works, Ltd. | Corrosion-resistant and abrasive wear-resistant composite material for centrifugally cast linings |
US4548786A (en) * | 1983-04-28 | 1985-10-22 | General Electric Company | Coated carbide cutting tool insert |
JPS60224781A (ja) * | 1984-04-20 | 1985-11-09 | Mitsubishi Metal Corp | 切削工具用被覆超硬質焼結合金の製造法 |
US4649084A (en) * | 1985-05-06 | 1987-03-10 | General Electric Company | Process for adhering an oxide coating on a cobalt-enriched zone, and articles made from said process |
US4923512A (en) * | 1989-04-07 | 1990-05-08 | The Dow Chemical Company | Cobalt-bound tungsten carbide metal matrix composites and cutting tools formed therefrom |
JPH05271842A (ja) * | 1990-09-12 | 1993-10-19 | Hitachi Metals Ltd | サーメット合金及びその製造方法 |
JP2943895B2 (ja) * | 1992-03-05 | 1999-08-30 | 住友電気工業株式会社 | 被覆超硬合金 |
WO1994021835A1 (de) * | 1993-03-23 | 1994-09-29 | Krupp Widia Gmbh | Cermet und verfahren zu seiner herstellung |
EP0698002B1 (en) * | 1993-04-30 | 1997-11-05 | The Dow Chemical Company | Densified micrograin refractory metal or solid solution (mixed metal) carbide ceramics |
JP3458533B2 (ja) * | 1995-05-15 | 2003-10-20 | 三菱マテリアル株式会社 | Wc基超硬合金製切削工具の製造方法 |
SE517474C2 (sv) * | 1996-10-11 | 2002-06-11 | Sandvik Ab | Sätt att tillverka hårdmetall med bindefasanrikad ytzon |
US6063333A (en) * | 1996-10-15 | 2000-05-16 | Penn State Research Foundation | Method and apparatus for fabrication of cobalt alloy composite inserts |
JP3292949B2 (ja) * | 1997-05-26 | 2002-06-17 | 株式会社アライドマテリアル | 微粒超硬合金及びその製造方法 |
JPH1142503A (ja) | 1997-07-29 | 1999-02-16 | Mitsubishi Materials Corp | 耐熱塑性変形性にすぐれた表面被覆炭化タングステン基超硬合金製切削工具 |
JP3496135B2 (ja) * | 1997-11-19 | 2004-02-09 | 株式会社アライドマテリアル | 硬質合金及びその製造方法 |
US6638474B2 (en) * | 2000-03-24 | 2003-10-28 | Kennametal Inc. | method of making cemented carbide tool |
JP2001329331A (ja) * | 2000-05-19 | 2001-11-27 | Hitachi Tool Engineering Ltd | 高硬度高靱性超硬合金及びその製法 |
JP3872653B2 (ja) * | 2001-02-26 | 2007-01-24 | 本田技研工業株式会社 | 複合材料の製造方法 |
JP4313587B2 (ja) * | 2003-03-03 | 2009-08-12 | 株式会社タンガロイ | 超硬合金及び被覆超硬合金部材並びにそれらの製造方法 |
-
2003
- 2003-10-28 SE SE0302835A patent/SE527173C2/sv not_active IP Right Cessation
-
2004
- 2004-06-21 AT AT04014482T patent/ATE370257T1/de active
- 2004-06-21 EP EP04014482A patent/EP1500713B1/en not_active Expired - Lifetime
- 2004-06-21 DE DE602004008166T patent/DE602004008166T2/de not_active Expired - Lifetime
- 2004-06-22 IL IL162686A patent/IL162686A/en not_active IP Right Cessation
- 2004-06-23 US US10/873,234 patent/US20050025657A1/en not_active Abandoned
- 2004-07-13 KR KR1020040054227A patent/KR101202225B1/ko active IP Right Grant
- 2004-07-26 JP JP2004217547A patent/JP2005042201A/ja active Pending
-
2005
- 2005-10-13 US US11/248,180 patent/US20060029511A1/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
DE602004008166D1 (de) | 2007-09-27 |
SE0302835L (sv) | 2005-01-26 |
IL162686A0 (en) | 2005-11-20 |
US20060029511A1 (en) | 2006-02-09 |
KR20050013077A (ko) | 2005-02-02 |
IL162686A (en) | 2007-10-31 |
SE0302835D0 (sv) | 2003-10-28 |
EP1500713B1 (en) | 2007-08-15 |
ATE370257T1 (de) | 2007-09-15 |
EP1500713A1 (en) | 2005-01-26 |
JP2005042201A (ja) | 2005-02-17 |
US20050025657A1 (en) | 2005-02-03 |
KR101202225B1 (ko) | 2012-11-16 |
SE527173C2 (sv) | 2006-01-17 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
8364 | No opposition during term of opposition |