DE60122790T2 - Hochtemperaturfeste und korrosionsbeständige ni-co-cr legierung - Google Patents
Hochtemperaturfeste und korrosionsbeständige ni-co-cr legierung Download PDFInfo
- Publication number
- DE60122790T2 DE60122790T2 DE60122790T DE60122790T DE60122790T2 DE 60122790 T2 DE60122790 T2 DE 60122790T2 DE 60122790 T DE60122790 T DE 60122790T DE 60122790 T DE60122790 T DE 60122790T DE 60122790 T2 DE60122790 T2 DE 60122790T2
- Authority
- DE
- Germany
- Prior art keywords
- alloy
- strength
- balance
- plus
- impurities
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 72
- 239000000956 alloy Substances 0.000 claims abstract description 72
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 27
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 26
- 229910052758 niobium Inorganic materials 0.000 claims abstract description 25
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 24
- 238000005260 corrosion Methods 0.000 claims abstract description 23
- 230000007797 corrosion Effects 0.000 claims abstract description 23
- 229910052742 iron Inorganic materials 0.000 claims abstract description 13
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 12
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 9
- 229910052796 boron Inorganic materials 0.000 claims abstract description 8
- 239000012535 impurity Substances 0.000 claims abstract description 8
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 8
- 229910052715 tantalum Inorganic materials 0.000 claims abstract description 8
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 7
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 7
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 7
- 229910052721 tungsten Inorganic materials 0.000 claims abstract description 7
- 229910052726 zirconium Inorganic materials 0.000 claims abstract description 7
- 229910001122 Mischmetal Inorganic materials 0.000 claims abstract description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000011593 sulfur Substances 0.000 claims abstract description 6
- 229910052761 rare earth metal Inorganic materials 0.000 claims abstract 3
- 150000002910 rare earth metals Chemical class 0.000 claims abstract 3
- 239000011651 chromium Substances 0.000 claims description 35
- 239000007789 gas Substances 0.000 claims description 12
- 239000011159 matrix material Substances 0.000 claims description 6
- 230000001590 oxidative effect Effects 0.000 claims description 5
- 229910052727 yttrium Inorganic materials 0.000 claims description 4
- 239000011241 protective layer Substances 0.000 claims 4
- 238000005486 sulfidation Methods 0.000 abstract description 15
- 230000003647 oxidation Effects 0.000 abstract description 8
- 238000007254 oxidation reaction Methods 0.000 abstract description 8
- 238000007792 addition Methods 0.000 abstract description 4
- 229910020630 Co Ni Inorganic materials 0.000 abstract description 2
- 229910002440 Co–Ni Inorganic materials 0.000 abstract description 2
- 229910052760 oxygen Inorganic materials 0.000 abstract description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 239000010955 niobium Substances 0.000 description 26
- 239000010936 titanium Substances 0.000 description 23
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 15
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 11
- 239000010883 coal ash Substances 0.000 description 11
- 239000000203 mixture Substances 0.000 description 10
- 239000011248 coating agent Substances 0.000 description 8
- 238000000576 coating method Methods 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 8
- 239000002184 metal Substances 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 229910004298 SiO 2 Inorganic materials 0.000 description 5
- 238000005275 alloying Methods 0.000 description 5
- 239000011575 calcium Substances 0.000 description 5
- 229910002091 carbon monoxide Inorganic materials 0.000 description 5
- 239000011777 magnesium Substances 0.000 description 5
- 239000011572 manganese Substances 0.000 description 5
- 150000001247 metal acetylides Chemical class 0.000 description 5
- 229910052759 nickel Inorganic materials 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 4
- 238000005728 strengthening Methods 0.000 description 4
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 239000010941 cobalt Substances 0.000 description 3
- 229910017052 cobalt Inorganic materials 0.000 description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 3
- 238000001723 curing Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000006870 function Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000011253 protective coating Substances 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 239000002956 ash Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 238000012423 maintenance Methods 0.000 description 2
- 238000005088 metallography Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000011733 molybdenum Substances 0.000 description 2
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 238000010791 quenching Methods 0.000 description 2
- 230000000630 rising effect Effects 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 239000006104 solid solution Substances 0.000 description 2
- 229910052596 spinel Inorganic materials 0.000 description 2
- 239000011029 spinel Substances 0.000 description 2
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 2
- 229920001187 thermosetting polymer Polymers 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 229910000604 Ferrochrome Inorganic materials 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 230000000254 damaging effect Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 238000013007 heat curing Methods 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000011089 mechanical engineering Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000010309 melting process Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 230000001473 noxious effect Effects 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000009993 protective function Effects 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000003303 reheating Methods 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- VSZWPYCFIRKVQL-UHFFFAOYSA-N selanylidenegallium;selenium Chemical compound [Se].[Se]=[Ga].[Se]=[Ga] VSZWPYCFIRKVQL-UHFFFAOYSA-N 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000005482 strain hardening Methods 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C19/00—Alloys based on nickel or cobalt
- C22C19/03—Alloys based on nickel or cobalt based on nickel
- C22C19/05—Alloys based on nickel or cobalt based on nickel with chromium
- C22C19/051—Alloys based on nickel or cobalt based on nickel with chromium and Mo or W
- C22C19/055—Alloys based on nickel or cobalt based on nickel with chromium and Mo or W with the maximum Cr content being at least 20% but less than 30%
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C19/00—Alloys based on nickel or cobalt
- C22C19/03—Alloys based on nickel or cobalt based on nickel
- C22C19/05—Alloys based on nickel or cobalt based on nickel with chromium
- C22C19/058—Alloys based on nickel or cobalt based on nickel with chromium without Mo and W
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Heat Treatment Of Articles (AREA)
- Exhaust Silencers (AREA)
- Chemically Coating (AREA)
- Secondary Cells (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
- Heat Treatment Of Steel (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US17786200P | 2000-01-24 | 2000-01-24 | |
| US177862P | 2000-01-24 | ||
| PCT/US2001/002247 WO2001053548A2 (en) | 2000-01-24 | 2001-01-24 | Ni-Co-Cr HIGH TEMPERATURE STRENGTH AND CORROSION RESISTANT ALLOY |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE60122790D1 DE60122790D1 (de) | 2006-10-12 |
| DE60122790T2 true DE60122790T2 (de) | 2007-09-13 |
Family
ID=22650239
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE60122790T Expired - Lifetime DE60122790T2 (de) | 2000-01-24 | 2001-01-24 | Hochtemperaturfeste und korrosionsbeständige ni-co-cr legierung |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US6491769B1 (enExample) |
| EP (1) | EP1466027B1 (enExample) |
| JP (1) | JP5052724B2 (enExample) |
| AT (1) | ATE338148T1 (enExample) |
| DE (1) | DE60122790T2 (enExample) |
| WO (1) | WO2001053548A2 (enExample) |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10202770B4 (de) * | 2002-01-25 | 2006-06-14 | Stahlwerk Ergste Westig Gmbh | Bimetall-Sägeband |
| DE60222681T2 (de) * | 2002-12-12 | 2008-06-19 | Federal-Mogul Sealing Systems Gmbh | Dichtung für Abgas- Flansch |
| US7592051B2 (en) * | 2005-02-09 | 2009-09-22 | Southwest Research Institute | Nanostructured low-Cr Cu-Cr coatings for high temperature oxidation resistance |
| US20060191603A1 (en) * | 2005-02-25 | 2006-08-31 | Popielas Frank W | Lower strength material for MLS active layers |
| US20070104974A1 (en) * | 2005-06-01 | 2007-05-10 | University Of Chicago | Nickel based alloys to prevent metal dusting degradation |
| US20090139510A1 (en) * | 2007-11-30 | 2009-06-04 | Eric Adair | Biofuel appliance venting system |
| US10041153B2 (en) * | 2008-04-10 | 2018-08-07 | Huntington Alloys Corporation | Ultra supercritical boiler header alloy and method of preparation |
| US20090321405A1 (en) * | 2008-06-26 | 2009-12-31 | Huntington Alloys Corporation | Ni-Co-Cr High Strength and Corrosion Resistant Welding Product and Method of Preparation |
| CH699716A1 (de) * | 2008-10-13 | 2010-04-15 | Alstom Technology Ltd | Bauteil für eine hochtemperaturdampfturbine sowie hochtemperaturdampfturbine. |
| FR2949234B1 (fr) * | 2009-08-20 | 2011-09-09 | Aubert & Duval Sa | Superalliage base nickel et pieces realisees en ce suparalliage |
| ITMI20110830A1 (it) | 2011-05-12 | 2012-11-13 | Alstom Technology Ltd | Valvola per una turbina a vapore 700 c |
| KR101476145B1 (ko) * | 2012-12-21 | 2014-12-24 | 한국기계연구원 | 도재 금속간 접합 특성과 기계적 특성이 우수한 니켈-크롬-코발트계 도재소부용 합금 |
| GB2513852B (en) * | 2013-05-03 | 2015-04-01 | Goodwin Plc | Alloy composition |
| US9587302B2 (en) * | 2014-01-14 | 2017-03-07 | Praxair S.T. Technology, Inc. | Methods of applying chromium diffusion coatings onto selective regions of a component |
| DE102014001330B4 (de) | 2014-02-04 | 2016-05-12 | VDM Metals GmbH | Aushärtende Nickel-Chrom-Kobalt-Titan-Aluminium-Legierung mit guter Verschleißbeständigkeit, Kriechfestigkeit, Korrosionsbeständigkeit und Verarbeitbarkeit |
| DE102014001329B4 (de) | 2014-02-04 | 2016-04-28 | VDM Metals GmbH | Verwendung einer aushärtenden Nickel-Chrom-Titan-Aluminium-Legierung mit guter Verschleißbeständigkeit, Kriechfestigkeit, Korrosionsbeständigkeit und Verarbeitbarkeit |
| CN103993202B (zh) * | 2014-05-20 | 2016-03-30 | 太原钢铁(集团)有限公司 | 一种超超临界电站锅炉管材用镍基合金及制备方法 |
| US10557388B2 (en) * | 2015-01-26 | 2020-02-11 | Daido Steel Co., Ltd. | Engine exhaust valve for large ship and method for manufacturing the same |
| US20160326613A1 (en) * | 2015-05-07 | 2016-11-10 | General Electric Company | Article and method for forming an article |
| EP3249063B1 (en) | 2016-05-27 | 2018-10-17 | The Japan Steel Works, Ltd. | High strength ni-based superalloy |
| JP6772735B2 (ja) * | 2016-10-03 | 2020-10-21 | 日本製鉄株式会社 | Ｎｉ基耐熱合金部材およびその製造方法 |
| DE102017007106B4 (de) * | 2017-07-28 | 2020-03-26 | Vdm Metals International Gmbh | Hochtemperatur-Nickelbasislegierung |
| CN110423960A (zh) * | 2019-08-06 | 2019-11-08 | 北京科技大学 | 一种高钨高钴的镍合金铸锭均匀化工艺 |
| AU2022308365A1 (en) | 2021-07-09 | 2024-01-25 | Ati Properties Llc | Nickel-base alloys |
| AU2024243895A1 (en) | 2023-04-06 | 2025-11-20 | Ati Properties Llc | Nickel-base alloys |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4110110A (en) * | 1975-08-27 | 1978-08-29 | Mitsubishi Kinzoku Kabushiki Kaisha | Nickel-base alloy excellent in corrosion resistance at high temperatures |
| US4379120B1 (en) | 1980-07-28 | 1999-08-24 | Crs Holdings Inc | Sulfidation resistant nickel-iron base alloy |
| JPS6070155A (ja) | 1983-09-28 | 1985-04-20 | Hitachi Metals Ltd | 排気弁用Νｉ基合金 |
| JPS60211028A (ja) | 1984-04-03 | 1985-10-23 | Daido Steel Co Ltd | 排気バルブ用合金 |
| JPS61119640A (ja) | 1984-11-16 | 1986-06-06 | Honda Motor Co Ltd | 排気バルブ用合金 |
| US4761190A (en) * | 1985-12-11 | 1988-08-02 | Inco Alloys International, Inc. | Method of manufacture of a heat resistant alloy useful in heat recuperator applications and product |
| US4844864A (en) | 1988-04-27 | 1989-07-04 | Carpenter Technology Corporation | Precipitation hardenable, nickel-base alloy |
| US5017249A (en) * | 1988-09-09 | 1991-05-21 | Inco Alloys International, Inc. | Nickel-base alloy |
| JPH09268337A (ja) * | 1996-04-03 | 1997-10-14 | Hitachi Metals Ltd | 鍛造製高耐食超耐熱合金 |
| US6258317B1 (en) * | 1998-06-19 | 2001-07-10 | Inco Alloys International, Inc. | Advanced ultra-supercritical boiler tubing alloy |
| US6287398B1 (en) * | 1998-12-09 | 2001-09-11 | Inco Alloys International, Inc. | High strength alloy tailored for high temperature mixed-oxidant environments |
| JP2003535214A (ja) * | 2000-01-24 | 2003-11-25 | ハンチントン、アロイス、コーポレーション | 高温熱処理合金 |
-
2001
- 2001-01-24 US US09/914,504 patent/US6491769B1/en not_active Expired - Lifetime
- 2001-01-24 WO PCT/US2001/002247 patent/WO2001053548A2/en not_active Ceased
- 2001-01-24 EP EP01908669A patent/EP1466027B1/en not_active Expired - Lifetime
- 2001-01-24 DE DE60122790T patent/DE60122790T2/de not_active Expired - Lifetime
- 2001-01-24 AT AT01908669T patent/ATE338148T1/de active
- 2001-01-24 JP JP2001553406A patent/JP5052724B2/ja not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JP2004500485A (ja) | 2004-01-08 |
| EP1466027A4 (en) | 2004-10-13 |
| ATE338148T1 (de) | 2006-09-15 |
| DE60122790D1 (de) | 2006-10-12 |
| JP5052724B2 (ja) | 2012-10-17 |
| US6491769B1 (en) | 2002-12-10 |
| WO2001053548A3 (en) | 2004-08-05 |
| EP1466027B1 (en) | 2006-08-30 |
| WO2001053548A2 (en) | 2001-07-26 |
| EP1466027A2 (en) | 2004-10-13 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8363 | Opposition against the patent |