DE60105183T2 - Zusammensetzung, enthaltend ein nitroxid, einen promotor und eventuell einen radikalischen initiator - Google Patents
Zusammensetzung, enthaltend ein nitroxid, einen promotor und eventuell einen radikalischen initiator Download PDFInfo
- Publication number
- DE60105183T2 DE60105183T2 DE60105183T DE60105183T DE60105183T2 DE 60105183 T2 DE60105183 T2 DE 60105183T2 DE 60105183 T DE60105183 T DE 60105183T DE 60105183 T DE60105183 T DE 60105183T DE 60105183 T2 DE60105183 T2 DE 60105183T2
- Authority
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- Germany
- Prior art keywords
- composition according
- radical
- moiety
- nitroxide
- promoter
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- LYCKDYZIIOVFCX-UHFFFAOYSA-N 1-[[3-[(2,5-dioxopyrrol-1-yl)methyl]phenyl]methyl]pyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1CC1=CC=CC(CN2C(C=CC2=O)=O)=C1 LYCKDYZIIOVFCX-UHFFFAOYSA-N 0.000 description 1
- XFRPTDABLAIJMY-UHFFFAOYSA-N 1-[[4-[(2,5-dioxopyrrol-1-yl)methyl]phenyl]methyl]pyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1CC(C=C1)=CC=C1CN1C(=O)C=CC1=O XFRPTDABLAIJMY-UHFFFAOYSA-N 0.000 description 1
- ODBCKCWTWALFKM-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhex-3-yne Chemical compound CC(C)(C)OOC(C)(C)C#CC(C)(C)OOC(C)(C)C ODBCKCWTWALFKM-UHFFFAOYSA-N 0.000 description 1
- DMWVYCCGCQPJEA-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhexane Chemical compound CC(C)(C)OOC(C)(C)CCC(C)(C)OOC(C)(C)C DMWVYCCGCQPJEA-UHFFFAOYSA-N 0.000 description 1
- PZILQNGWHUGDLZ-UHFFFAOYSA-N 2-(2-acetyloxypropan-2-yldiazenyl)propan-2-yl acetate Chemical compound CC(=O)OC(C)(C)N=NC(C)(C)OC(C)=O PZILQNGWHUGDLZ-UHFFFAOYSA-N 0.000 description 1
- JJRDRFZYKKFYMO-UHFFFAOYSA-N 2-methyl-2-(2-methylbutan-2-ylperoxy)butane Chemical compound CCC(C)(C)OOC(C)(C)CC JJRDRFZYKKFYMO-UHFFFAOYSA-N 0.000 description 1
- PHIGUQOUWMSXFV-UHFFFAOYSA-N 2-methyl-2-[2-(2-methylbutan-2-ylperoxy)propan-2-ylperoxy]butane Chemical compound CCC(C)(C)OOC(C)(C)OOC(C)(C)CC PHIGUQOUWMSXFV-UHFFFAOYSA-N 0.000 description 1
- OCVLSHAVSIYKLI-UHFFFAOYSA-N 3h-1,3-thiazole-2-thione Chemical class SC1=NC=CS1 OCVLSHAVSIYKLI-UHFFFAOYSA-N 0.000 description 1
- CCOJJJCQUHWYAT-UHFFFAOYSA-N 4-methyl-4-(2-methylbutan-2-ylperoxy)pentan-2-ol Chemical compound CCC(C)(C)OOC(C)(C)CC(C)O CCOJJJCQUHWYAT-UHFFFAOYSA-N 0.000 description 1
- 125000000339 4-pyridyl group Chemical group N1=C([H])C([H])=C([*])C([H])=C1[H] 0.000 description 1
- JNSWFNBIZLIBPH-UHFFFAOYSA-N 4-tert-butylperoxy-4-methylpentan-2-ol Chemical compound CC(O)CC(C)(C)OOC(C)(C)C JNSWFNBIZLIBPH-UHFFFAOYSA-N 0.000 description 1
- 125000004939 6-pyridyl group Chemical group N1=CC=CC=C1* 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 241001441571 Hiodontidae Species 0.000 description 1
- RSPISYXLHRIGJD-UHFFFAOYSA-N OOOO Chemical class OOOO RSPISYXLHRIGJD-UHFFFAOYSA-N 0.000 description 1
- 239000002174 Styrene-butadiene Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 150000004982 aromatic amines Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- XOZUGNYVDXMRKW-AATRIKPKSA-N azodicarbonamide Chemical compound NC(=O)\N=N\C(N)=O XOZUGNYVDXMRKW-AATRIKPKSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- DKVNPHBNOWQYFE-UHFFFAOYSA-N carbamodithioic acid Chemical compound NC(S)=S DKVNPHBNOWQYFE-UHFFFAOYSA-N 0.000 description 1
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- 230000001143 conditioned effect Effects 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- 239000012990 dithiocarbamate Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- MKGMCCVHOVSDTI-UHFFFAOYSA-N ethyl 2-(3,6,6,9,9-pentamethyl-1,2,4,5-tetraoxonan-3-yl)acetate Chemical compound CCOC(=O)CC1(C)OOC(C)(C)CCC(C)(C)OO1 MKGMCCVHOVSDTI-UHFFFAOYSA-N 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 150000003949 imides Chemical class 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 150000002826 nitrites Chemical class 0.000 description 1
- 230000010355 oscillation Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000010412 perfusion Effects 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- 229940116351 sebacate Drugs 0.000 description 1
- CXMXRPHRNRROMY-UHFFFAOYSA-L sebacate(2-) Chemical compound [O-]C(=O)CCCCCCCCC([O-])=O CXMXRPHRNRROMY-UHFFFAOYSA-L 0.000 description 1
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- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
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- 230000009466 transformation Effects 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/14—Peroxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0025—Crosslinking or vulcanising agents; including accelerators
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/01—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/32—Compounds containing nitrogen bound to oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3415—Five-membered rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3432—Six-membered rings
- C08K5/3435—Piperidines
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Dental Preparations (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Graft Or Block Polymers (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Polymerization Catalysts (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0012580A FR2819517B1 (fr) | 2000-10-03 | 2000-10-03 | Composition comprenant un nitroxyde, un promoteur et eventuellement un initiateur de radicaux libres |
| FR0012580 | 2000-10-03 | ||
| PCT/FR2001/003011 WO2002028946A1 (fr) | 2000-10-03 | 2001-09-28 | Composition comprenant un nitroxyde, un promoteur et eventuellement un initiateur de radicaux libres |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE60105183D1 DE60105183D1 (de) | 2004-09-30 |
| DE60105183T2 true DE60105183T2 (de) | 2005-10-20 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE60105183T Expired - Lifetime DE60105183T2 (de) | 2000-10-03 | 2001-09-28 | Zusammensetzung, enthaltend ein nitroxid, einen promotor und eventuell einen radikalischen initiator |
Country Status (12)
| Country | Link |
|---|---|
| EP (1) | EP1322696B1 (https=) |
| JP (2) | JP4086144B2 (https=) |
| KR (1) | KR100735589B1 (https=) |
| CN (1) | CN100564430C (https=) |
| AT (1) | ATE274545T1 (https=) |
| AU (1) | AU2001293932A1 (https=) |
| CA (1) | CA2424912C (https=) |
| DE (1) | DE60105183T2 (https=) |
| ES (1) | ES2227278T3 (https=) |
| FR (1) | FR2819517B1 (https=) |
| PT (1) | PT1322696E (https=) |
| WO (1) | WO2002028946A1 (https=) |
Families Citing this family (36)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2814749B1 (fr) * | 2000-10-03 | 2003-06-13 | Atofina | Composition retardant le grillage |
| TW200535182A (en) * | 2003-12-24 | 2005-11-01 | Dow Global Technologies Inc | Free-radical crosslinkable polymers: improved process for crosslinking and compositions |
| FR2875502B1 (fr) * | 2004-09-22 | 2007-01-05 | Arkema Sa | Composition retardant le grillage |
| US7465769B2 (en) * | 2006-10-09 | 2008-12-16 | Dow Global Technologies Inc. | Nitroxide compounds for minimizing scorch in crosslinkable compositions |
| WO2008097732A1 (en) * | 2007-02-05 | 2008-08-14 | Dow Global Technologies Inc. | A crosslinkable polyethylene composition, method of making the same, and articles made therefrom |
| JP5133983B2 (ja) * | 2007-04-25 | 2013-01-30 | 日本ケミコン株式会社 | 電解コンデンサの封口体とその封口体を用いた電解コンデンサ |
| EP2014707B1 (en) * | 2007-07-12 | 2014-04-23 | Borealis Technology Oy | Modified polymer compositions, modification process and free radical generating agents for i.a. wire and cable applications |
| US9234093B2 (en) | 2008-03-31 | 2016-01-12 | Exxonmobil Chemical Patents Inc. | Thermoplastic vulcanizates |
| US8644470B2 (en) | 2008-04-15 | 2014-02-04 | Cequint, Inc. | Methods and systems for improved caller name identification on a telephone network |
| US8983540B2 (en) | 2008-09-22 | 2015-03-17 | Cequint, Inc. | Delivery of caller identification data to a mobile device using application directed short messaging service |
| US8877867B2 (en) | 2008-11-06 | 2014-11-04 | Exxonmobil Chemical Patents Inc. | Process for forming thermoplastic vulcanizates and extruded articles therefrom |
| US8160556B2 (en) | 2009-04-13 | 2012-04-17 | Cequint, Inc. | System and method for local handset check of the NXX local exchange to determine carrier |
| US8160555B2 (en) | 2009-04-13 | 2012-04-17 | Cequint, Inc. | System and method for determination of network and conditional execution of applications and promotions |
| US8160554B2 (en) | 2009-04-13 | 2012-04-17 | Cequint, Inc. | System and method for enhanced display of in-network caller information on a mobile device |
| US8620281B2 (en) | 2009-04-13 | 2013-12-31 | Cequint, Inc. | System and method for determination and display of “in-network caller” notification on a mobile device |
| CN101820001B (zh) * | 2010-04-30 | 2011-08-31 | 南京红宝丽新材料有限公司 | 太阳能电池封装胶膜 |
| JP5533208B2 (ja) * | 2010-05-06 | 2014-06-25 | 横浜ゴム株式会社 | ゴム組成物およびホース |
| WO2013157643A1 (ja) * | 2012-04-20 | 2013-10-24 | 旭化成イーマテリアルズ株式会社 | ラジカル架橋性基を有するポリシロキサン組成物 |
| WO2013156358A1 (de) * | 2012-04-20 | 2013-10-24 | Hilti Aktiengesellschaft | Indolin-nitroxidradikal als stabilisator und inhibitor für reaktionsharze, diese enthaltende reaktionsharze und deren verwendung |
| FR2995313B1 (fr) * | 2012-09-12 | 2015-08-21 | Arkema France | Melange primaire d'initiateur et de promoteur de reticulation |
| CN103206541B (zh) * | 2013-04-23 | 2015-07-15 | 广州机械科学研究院有限公司 | 一种夹布油封及其制备方法与应用 |
| US10400096B2 (en) * | 2014-03-14 | 2019-09-03 | Milliken & Company | Modified heterophasic polyolefin composition |
| JP6355375B2 (ja) * | 2014-03-18 | 2018-07-11 | 日本バルカー工業株式会社 | パーフルオロエラストマー組成物及びシール材 |
| EP2995631A1 (en) | 2014-09-12 | 2016-03-16 | Borealis AG | Process for producing graft copolymers on polyolefin backbone |
| CN107001724B (zh) * | 2014-12-09 | 2019-11-19 | 阿科玛股份有限公司 | 液体和可熔固体等级的焦烧保护的过氧化物 |
| US10316154B2 (en) * | 2014-12-09 | 2019-06-11 | Arkema Inc. | Compositions and methods for crosslinking polymers in the presence of atmospheric oxygen |
| US20190106557A1 (en) * | 2016-03-30 | 2019-04-11 | Dow Global Technologies Llc | Crosslinkable polymeric compositions with methyl-radical scavengers and articles made therefrom |
| US10508179B2 (en) | 2017-02-28 | 2019-12-17 | Exxonmobil Chemical Patents Inc. | Thermoplastic vulcanizate prepared with oil-extended, bimodal metallocene-synthesized EPDM |
| KR20200023636A (ko) | 2017-06-28 | 2020-03-05 | 에누오케 가부시키가이샤 | 고무 조성물 및 연료전지 세퍼레이터용 시일재 |
| KR102551057B1 (ko) * | 2017-11-08 | 2023-07-05 | 다우 글로벌 테크놀로지스 엘엘씨 | 공기 경화성 에틸렌/알파-올레핀/디엔 혼성중합체 조성물 |
| WO2020023193A1 (en) | 2018-07-23 | 2020-01-30 | Exxonmobil Chemical Patents Inc. | Preparation of bimodal rubber, thermoplastic vulcanizates, and articles made therefrom |
| JP2023527792A (ja) | 2020-05-27 | 2023-06-30 | アキシャル セラピューティクス，インク． | Ｔｌｒ２調節剤化合物、医薬組成物、及びそれらの使用 |
| US11674024B2 (en) | 2020-05-29 | 2023-06-13 | Exxonmobil Chemical Patents Inc. | Sequential, double elastomer vulcanization system, method and composition |
| US20230295407A1 (en) | 2020-07-02 | 2023-09-21 | Exxonmobil Chemical Patents | Thermoplastic Vulcanizate Compositions Containing Metallocene Multimodal Copolymer Rubber and Processes for Making Same |
| FR3139825A1 (fr) | 2022-09-21 | 2024-03-22 | Arkema France | Composition comprenant au moins un peroxyde de dialkyle ou de peroxycétal et au moins un peroxyde organique insaturé |
| EP4715006A2 (en) | 2024-09-19 | 2026-03-25 | Nouryon Chemicals International B.V. | Unsaturated scorch retarders |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0499581B1 (de) * | 1991-02-13 | 1997-07-09 | Ciba SC Holding AG | Stabilisierte Polymermischung |
| US6084015A (en) * | 1996-10-25 | 2000-07-04 | The Yokohama Rubber Co., Ltd. | Rubber composition |
| JPH1149865A (ja) * | 1997-07-31 | 1999-02-23 | Nof Corp | エチレン系ポリマーの架橋用組成物、架橋方法及びポリマー組成物 |
| FR2768739B1 (fr) * | 1997-09-19 | 2004-08-06 | Atochem Elf Sa | Polymere vinylaromatique choc obtenu a partir d'un caoutchouc porteur d'un groupement generateur d'un radical libre stable |
| SE9802386D0 (sv) * | 1998-07-03 | 1998-07-03 | Borealis As | Composition for elektric cables |
| FR2791060A1 (fr) * | 1999-03-18 | 2000-09-22 | Atochem Elf Sa | Procede de preparation d'un caoutchouc porteur de radical libre stable et utilisation dudit caoutchouc porteur pour la preparation d'un polymere vinylaromatique choc |
-
2000
- 2000-10-03 FR FR0012580A patent/FR2819517B1/fr not_active Expired - Fee Related
-
2001
- 2001-09-28 AU AU2001293932A patent/AU2001293932A1/en not_active Abandoned
- 2001-09-28 KR KR1020037004684A patent/KR100735589B1/ko not_active Expired - Lifetime
- 2001-09-28 CN CNB018200095A patent/CN100564430C/zh not_active Expired - Lifetime
- 2001-09-28 JP JP2002532523A patent/JP4086144B2/ja not_active Expired - Lifetime
- 2001-09-28 DE DE60105183T patent/DE60105183T2/de not_active Expired - Lifetime
- 2001-09-28 WO PCT/FR2001/003011 patent/WO2002028946A1/fr not_active Ceased
- 2001-09-28 ES ES01974408T patent/ES2227278T3/es not_active Expired - Lifetime
- 2001-09-28 PT PT01974408T patent/PT1322696E/pt unknown
- 2001-09-28 AT AT01974408T patent/ATE274545T1/de active
- 2001-09-28 EP EP01974408A patent/EP1322696B1/fr not_active Expired - Lifetime
- 2001-09-28 CA CA002424912A patent/CA2424912C/fr not_active Expired - Lifetime
-
2007
- 2007-07-02 JP JP2007174536A patent/JP2007327063A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| JP4086144B2 (ja) | 2008-05-14 |
| FR2819517A1 (fr) | 2002-07-19 |
| KR20030060902A (ko) | 2003-07-16 |
| PT1322696E (pt) | 2004-12-31 |
| CA2424912C (fr) | 2009-05-12 |
| DE60105183D1 (de) | 2004-09-30 |
| FR2819517B1 (fr) | 2003-03-21 |
| EP1322696B1 (fr) | 2004-08-25 |
| EP1322696A1 (fr) | 2003-07-02 |
| CA2424912A1 (fr) | 2002-04-11 |
| AU2001293932A1 (en) | 2002-04-15 |
| KR100735589B1 (ko) | 2007-07-04 |
| JP2004510858A (ja) | 2004-04-08 |
| ATE274545T1 (de) | 2004-09-15 |
| CN100564430C (zh) | 2009-12-02 |
| JP2007327063A (ja) | 2007-12-20 |
| CN1478118A (zh) | 2004-02-25 |
| WO2002028946A1 (fr) | 2002-04-11 |
| ES2227278T3 (es) | 2005-04-01 |
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