DE60104509T2 - Propylenpolymerzusammensetzung mit verbesserter schlagzähigkeit und sehr guten optischen eigenschaften - Google Patents
Propylenpolymerzusammensetzung mit verbesserter schlagzähigkeit und sehr guten optischen eigenschaften Download PDFInfo
- Publication number
- DE60104509T2 DE60104509T2 DE60104509T DE60104509T DE60104509T2 DE 60104509 T2 DE60104509 T2 DE 60104509T2 DE 60104509 T DE60104509 T DE 60104509T DE 60104509 T DE60104509 T DE 60104509T DE 60104509 T2 DE60104509 T2 DE 60104509T2
- Authority
- DE
- Germany
- Prior art keywords
- propylene
- ethylene
- weight
- bottles
- polymer compositions
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title claims description 31
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 title claims description 21
- 230000003287 optical effect Effects 0.000 title description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 24
- 239000005977 Ethylene Substances 0.000 claims description 20
- 238000006116 polymerization reaction Methods 0.000 claims description 19
- 239000003054 catalyst Substances 0.000 claims description 17
- 229920001155 polypropylene Polymers 0.000 claims description 17
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 14
- 229920000642 polymer Polymers 0.000 claims description 13
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 11
- 239000008096 xylene Substances 0.000 claims description 7
- 229920005604 random copolymer Polymers 0.000 claims description 5
- 238000010101 extrusion blow moulding Methods 0.000 claims description 4
- 229920005606 polypropylene copolymer Polymers 0.000 claims description 2
- -1 Polypropylene Polymers 0.000 description 29
- 238000000034 method Methods 0.000 description 25
- 238000012360 testing method Methods 0.000 description 15
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 13
- 239000011949 solid catalyst Substances 0.000 description 12
- 229910052782 aluminium Inorganic materials 0.000 description 10
- 150000001875 compounds Chemical class 0.000 description 10
- 238000005259 measurement Methods 0.000 description 10
- 239000004743 Polypropylene Substances 0.000 description 9
- 239000007789 gas Substances 0.000 description 9
- 239000011777 magnesium Substances 0.000 description 8
- 229910052749 magnesium Inorganic materials 0.000 description 8
- 238000002156 mixing Methods 0.000 description 7
- 239000012071 phase Substances 0.000 description 7
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 229920001577 copolymer Polymers 0.000 description 6
- FMZUHGYZWYNSOA-VVBFYGJXSA-N (1r)-1-[(4r,4ar,8as)-2,6-diphenyl-4,4a,8,8a-tetrahydro-[1,3]dioxino[5,4-d][1,3]dioxin-4-yl]ethane-1,2-diol Chemical compound C([C@@H]1OC(O[C@@H]([C@@H]1O1)[C@H](O)CO)C=2C=CC=CC=2)OC1C1=CC=CC=C1 FMZUHGYZWYNSOA-VVBFYGJXSA-N 0.000 description 5
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 5
- 238000007334 copolymerization reaction Methods 0.000 description 5
- 125000004122 cyclic group Chemical group 0.000 description 5
- 229940087101 dibenzylidene sorbitol Drugs 0.000 description 5
- 238000002347 injection Methods 0.000 description 5
- 239000007924 injection Substances 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 239000010936 titanium Substances 0.000 description 5
- 239000004711 α-olefin Substances 0.000 description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 238000000113 differential scanning calorimetry Methods 0.000 description 4
- 229920001198 elastomeric copolymer Polymers 0.000 description 4
- 239000011888 foil Substances 0.000 description 4
- 229920001519 homopolymer Polymers 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 239000010410 layer Substances 0.000 description 4
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 239000002667 nucleating agent Substances 0.000 description 4
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- ZWINORFLMHROGF-UHFFFAOYSA-N 9,9-bis(methoxymethyl)fluorene Chemical compound C1=CC=C2C(COC)(COC)C3=CC=CC=C3C2=C1 ZWINORFLMHROGF-UHFFFAOYSA-N 0.000 description 3
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 3
- 238000002083 X-ray spectrum Methods 0.000 description 3
- 125000000753 cycloalkyl group Chemical group 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 150000004820 halides Chemical class 0.000 description 3
- 125000005843 halogen group Chemical group 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 238000001746 injection moulding Methods 0.000 description 3
- 239000007791 liquid phase Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 229920001384 propylene homopolymer Polymers 0.000 description 3
- 230000011514 reflex Effects 0.000 description 3
- 239000000523 sample Substances 0.000 description 3
- 238000001228 spectrum Methods 0.000 description 3
- 150000003609 titanium compounds Chemical class 0.000 description 3
- CJYDNDLQIIGSTH-UHFFFAOYSA-N 1-(3,5,7-trinitro-1,3,5,7-tetrazocan-1-yl)ethanone Chemical compound CC(=O)N1CN([N+]([O-])=O)CN([N+]([O-])=O)CN([N+]([O-])=O)C1 CJYDNDLQIIGSTH-UHFFFAOYSA-N 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- UWNADWZGEHDQAB-UHFFFAOYSA-N 2,5-dimethylhexane Chemical group CC(C)CCC(C)C UWNADWZGEHDQAB-UHFFFAOYSA-N 0.000 description 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
- IRIAEXORFWYRCZ-UHFFFAOYSA-N Butylbenzyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCC1=CC=CC=C1 IRIAEXORFWYRCZ-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 125000003710 aryl alkyl group Chemical group 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 150000005840 aryl radicals Chemical class 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 230000001143 conditioned effect Effects 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 125000005842 heteroatom Chemical group 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 2
- 229910001629 magnesium chloride Inorganic materials 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 125000004433 nitrogen atom Chemical group N* 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 229920005653 propylene-ethylene copolymer Polymers 0.000 description 2
- 150000003377 silicon compounds Chemical class 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 230000000707 stereoselective effect Effects 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 125000001424 substituent group Chemical group 0.000 description 2
- 239000006228 supernatant Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- NWXADGGHXYSLSP-IYWMVGAKSA-N (3s,4s,5s,6r)-1,8-diphenylocta-1,7-diene-2,3,4,5,6,7-hexol Chemical compound OC([C@H](O)[C@@H](O)[C@H](O)[C@H](O)C(O)=CC=1C=CC=CC=1)=CC1=CC=CC=C1 NWXADGGHXYSLSP-IYWMVGAKSA-N 0.000 description 1
- OUPPKRIDJAMCCA-UHFFFAOYSA-N 1-methoxy-2-(methoxymethyl)-2,3-dimethylbutane Chemical compound COCC(C)(C(C)C)COC OUPPKRIDJAMCCA-UHFFFAOYSA-N 0.000 description 1
- BHPDSAAGSUWVMP-UHFFFAOYSA-N 3,3-bis(methoxymethyl)-2,6-dimethylheptane Chemical compound COCC(C(C)C)(COC)CCC(C)C BHPDSAAGSUWVMP-UHFFFAOYSA-N 0.000 description 1
- PVWCLOAAEFMTLH-UHFFFAOYSA-N 4,4-bis(methoxymethyl)-2,6-dimethylheptane Chemical compound COCC(COC)(CC(C)C)CC(C)C PVWCLOAAEFMTLH-UHFFFAOYSA-N 0.000 description 1
- 241000251468 Actinopterygii Species 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241000282693 Cercopithecidae Species 0.000 description 1
- 238000004566 IR spectroscopy Methods 0.000 description 1
- 241000170793 Phalaris canariensis Species 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000011954 Ziegler–Natta catalyst Substances 0.000 description 1
- XMYDKOZNENQEHO-UHFFFAOYSA-N [1-methoxy-2-(methoxymethyl)-3-methylbutan-2-yl]cyclopentane Chemical compound COCC(COC)(C(C)C)C1CCCC1 XMYDKOZNENQEHO-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 159000000032 aromatic acids Chemical class 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 125000006267 biphenyl group Chemical group 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- DLAHAXOYRFRPFQ-UHFFFAOYSA-N dodecyl benzoate Chemical compound CCCCCCCCCCCCOC(=O)C1=CC=CC=C1 DLAHAXOYRFRPFQ-UHFFFAOYSA-N 0.000 description 1
- 239000003651 drinking water Substances 0.000 description 1
- 235000020188 drinking water Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229920001903 high density polyethylene Polymers 0.000 description 1
- 239000004700 high-density polyethylene Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 239000003701 inert diluent Substances 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 230000002262 irrigation Effects 0.000 description 1
- 238000003973 irrigation Methods 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 150000002596 lactones Chemical class 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 229920000092 linear low density polyethylene Polymers 0.000 description 1
- 239000004707 linear low-density polyethylene Substances 0.000 description 1
- 235000021056 liquid food Nutrition 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 239000004702 low-density polyethylene Substances 0.000 description 1
- 150000002681 magnesium compounds Chemical class 0.000 description 1
- 239000000320 mechanical mixture Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000007431 microscopic evaluation Methods 0.000 description 1
- 239000002557 mineral fiber Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 150000002763 monocarboxylic acids Chemical class 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 238000009527 percussion Methods 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- 125000004437 phosphorous atom Chemical group 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 150000003021 phthalic acid derivatives Chemical class 0.000 description 1
- 125000003367 polycyclic group Chemical group 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920005672 polyolefin resin Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 230000000284 resting effect Effects 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical group [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 235000010356 sorbitol Nutrition 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- LYDRKKWPKKEMNZ-UHFFFAOYSA-N tert-butyl benzoate Chemical compound CC(C)(C)OC(=O)C1=CC=CC=C1 LYDRKKWPKKEMNZ-UHFFFAOYSA-N 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
- C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
- C08F297/083—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins the monomers being ethylene or propylene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/0005—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor characterised by the material
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2308/00—Chemical blending or stepwise polymerisation process with the same catalyst
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
- C08L2666/04—Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
- Y10T428/1397—Single layer [continuous layer]
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Graft Or Block Polymers (AREA)
- Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
- Containers Having Bodies Formed In One Piece (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP00201931 | 2000-05-31 | ||
| EP00201931 | 2000-05-31 | ||
| PCT/EP2001/005707 WO2001092406A1 (en) | 2000-05-31 | 2001-05-18 | Propylene polymer compositions having improved impact strength and excellent optical properties |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE60104509D1 DE60104509D1 (de) | 2004-09-02 |
| DE60104509T2 true DE60104509T2 (de) | 2005-08-11 |
Family
ID=8171582
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE60104509T Expired - Lifetime DE60104509T2 (de) | 2000-05-31 | 2001-05-18 | Propylenpolymerzusammensetzung mit verbesserter schlagzähigkeit und sehr guten optischen eigenschaften |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US6599986B2 (enExample) |
| EP (1) | EP1206499B1 (enExample) |
| JP (1) | JP2003535178A (enExample) |
| KR (1) | KR100758159B1 (enExample) |
| CN (1) | CN1227288C (enExample) |
| AR (1) | AR029106A1 (enExample) |
| AT (1) | ATE272093T1 (enExample) |
| AU (1) | AU781625B2 (enExample) |
| BR (1) | BR0106714B1 (enExample) |
| CA (1) | CA2379057A1 (enExample) |
| DE (1) | DE60104509T2 (enExample) |
| ES (1) | ES2225544T3 (enExample) |
| PL (1) | PL200539B1 (enExample) |
| RU (1) | RU2255948C2 (enExample) |
| TR (1) | TR200401981T4 (enExample) |
| WO (1) | WO2001092406A1 (enExample) |
Families Citing this family (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AT411903B (de) * | 2002-04-05 | 2004-07-26 | Ke Kelit Kunststoffwerk Gmbh | Verfahren zum herstellen eines hohlen formlings, insbesondere für eine wasserleitungsinstallation |
| EP1484345A1 (en) * | 2003-06-06 | 2004-12-08 | Borealis Technology Oy | Process for the production of polypropylene using a Ziegler-Natta catalyst |
| WO2006018777A1 (en) * | 2004-08-18 | 2006-02-23 | Basell Poliolefine Italia S.R.L. | Process for producing clear polypropylene based stretch blow molded containers with improved infrared heat-up rates |
| US20070202285A1 (en) * | 2004-12-15 | 2007-08-30 | Fina Technology, Inc. | Articles having improved clarity, prepared from propylene-ethylene copolymers |
| ATE446987T1 (de) | 2005-02-03 | 2009-11-15 | Basell Poliolefine Srl | Propylen-polymer-zusammensetzung zum spritzgiessen |
| JP4710385B2 (ja) * | 2005-04-04 | 2011-06-29 | 凸版印刷株式会社 | 金属化粧板用化粧シート |
| CN101163727B (zh) * | 2005-04-28 | 2012-11-28 | 巴塞尔聚烯烃意大利有限责任公司 | 热成形用的丙烯聚合物组合物 |
| EP1874530A2 (en) * | 2005-04-28 | 2008-01-09 | Basell Poliolefine Italia S.r.l. | Reinforced polypropylene pipe |
| CN101175778B (zh) | 2005-05-12 | 2011-12-07 | 巴塞尔聚烯烃意大利有限责任公司 | 丙烯-乙烯共聚物和它们的制备方法 |
| ES2269021T5 (es) † | 2005-05-12 | 2012-06-27 | Borealis Technology Oy | Elemento laminar transparente y fácilmente rompible |
| EP1726285A1 (de) * | 2005-05-24 | 2006-11-29 | Vifor (International) Ag | Behälter für die Abgabe eines Medikaments und zugehörige Verabreichungsvorrichtung |
| AU2006265203A1 (en) | 2005-07-01 | 2007-01-11 | Basell Poliolefine Italia S.R.L. | Propylene polymers having broad molecular weight distribution |
| US8178632B2 (en) * | 2006-07-28 | 2012-05-15 | Basell Poliolefine Italia, s.r.l. | Propylene polymers |
| US8507717B2 (en) * | 2008-12-31 | 2013-08-13 | Dow Global Technologies Llc | Production of substituted phenylene aromatic diesters |
| US8076429B2 (en) | 2009-03-11 | 2011-12-13 | Lummus Novolen Technology Gmbh | Supertransparent high impact strength random block copolymer |
| EP2264099A1 (en) | 2009-05-21 | 2010-12-22 | Basell Poliolefine Italia S.R.L. | Propylene polymer compositions |
| KR101538910B1 (ko) | 2009-05-21 | 2015-07-23 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 프로필렌 중합체 조성물 |
| US8907019B2 (en) | 2010-12-21 | 2014-12-09 | Basell Polyolefine Gmbh | Polypropylene composition with high elasticity and transparency |
| EP2578628A1 (en) | 2011-10-07 | 2013-04-10 | Basell Poliolefine Italia S.r.l. | Propylene Polymer Compositions |
| EP2639268A1 (en) | 2012-03-13 | 2013-09-18 | Basell Poliolefine Italia S.r.l. | Propylene polymer compositions |
| EP2639267A1 (en) | 2012-03-13 | 2013-09-18 | Basell Poliolefine Italia S.r.l. | Propylene polymer compositions |
| CN104736627B (zh) * | 2012-10-03 | 2018-04-17 | 胜亚诺盟股份有限公司 | 蒸煮膜用丙烯树脂组合物 |
| CN104558811A (zh) * | 2013-10-10 | 2015-04-29 | 中国石油化工股份有限公司 | 一种聚丙烯组合物及其制备方法和应用 |
| US20170327606A1 (en) * | 2014-12-12 | 2017-11-16 | Sabic Global Technologies B.V. | Polyethylene composition and pipe comprising such composition |
| EP3184587B1 (en) * | 2015-12-21 | 2020-03-18 | Borealis AG | Extruded articles with improved optical properties |
| CN107629332B (zh) * | 2016-07-18 | 2022-07-05 | Sabic环球技术有限责任公司 | 聚烯烃组合物 |
| CN110352203B (zh) | 2017-03-27 | 2022-04-19 | 巴塞尔聚烯烃意大利有限公司 | 丙烯乙烯无规共聚物 |
| US11084920B2 (en) | 2017-12-20 | 2021-08-10 | Borealis Ag | Heterophasic polypropylene composition |
| EP3781604B1 (en) * | 2018-04-18 | 2024-12-11 | W. R. Grace & Co.-Conn | Transparent polypropylene copolymer composition having impact resistance |
| EP3790929B1 (en) | 2018-05-09 | 2023-04-12 | Borealis AG | Heterophasic polypropylene with propylene hexene random copolymer as matrix |
| EP3567079B1 (en) | 2018-05-09 | 2021-12-01 | Borealis AG | Heterophasic polypropylene with propylene hexene random copolymer as matrix |
| US11834534B2 (en) * | 2018-08-22 | 2023-12-05 | Basell Poliolefine Italia S.R.L. | Random propylene-ethylene copolymers |
| US20250340726A1 (en) * | 2022-04-12 | 2025-11-06 | Basell Poliolefine Italia S.R.L. | Propylene-based copolymer composition |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1098272B (it) | 1978-08-22 | 1985-09-07 | Montedison Spa | Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine |
| IT1209255B (it) | 1980-08-13 | 1989-07-16 | Montedison Spa | Catalizzatori per la polimerizzazione di olefine. |
| IT1190681B (it) | 1982-02-12 | 1988-02-24 | Montedison Spa | Componenti e catalizzatori per la polimerizzazione di olefine |
| JPS60212443A (ja) | 1984-04-09 | 1985-10-24 | Toa Nenryo Kogyo Kk | ポリプロピレン組成物 |
| IT1227893B (it) | 1988-12-14 | 1991-05-14 | Himont Inc Centerville Road Ne | Composizioni polipropileniche aventi buona trasparenza e migliorata resistenza all'urto |
| JPH0694155B2 (ja) | 1991-03-01 | 1994-11-24 | チッソ株式会社 | ポリオレフィン系樹脂製中空容器 |
| TW248565B (enExample) * | 1991-08-14 | 1995-06-01 | Mitsui Petroleum Chemicals Industry Co | |
| AU662202B2 (en) * | 1992-02-24 | 1995-08-24 | Montell North America Inc. | Polyolefin compositions having good transparency and impact resistance |
| IT1269914B (it) * | 1994-03-24 | 1997-04-16 | Himonty Inc | Composizioni verniciabili di copolimeri cristallini del propilene aventi bassa temperatura di saldabilita' |
| US5994482A (en) | 1997-03-04 | 1999-11-30 | Exxon Chemical Patents, Inc. | Polypropylene copolymer alloys and process for making |
| TW400341B (en) * | 1997-05-22 | 2000-08-01 | Chisso Corp | Propyene polymer blends, processes of producing the same, and polypropylene resin compositions |
| WO1999002604A1 (de) * | 1997-07-11 | 1999-01-21 | Pcd Polymere Aktiengesellschaft | Verwendung von olefin-copolymeren mit verbesserter stabilität gegenüber ionisierender strahlung |
-
2001
- 2001-05-18 KR KR1020027001076A patent/KR100758159B1/ko not_active Expired - Fee Related
- 2001-05-18 US US10/031,584 patent/US6599986B2/en not_active Expired - Lifetime
- 2001-05-18 AU AU60315/01A patent/AU781625B2/en not_active Ceased
- 2001-05-18 EP EP01933987A patent/EP1206499B1/en not_active Expired - Lifetime
- 2001-05-18 CN CNB018015352A patent/CN1227288C/zh not_active Expired - Fee Related
- 2001-05-18 PL PL352073A patent/PL200539B1/pl unknown
- 2001-05-18 JP JP2002500609A patent/JP2003535178A/ja not_active Withdrawn
- 2001-05-18 TR TR2004/01981T patent/TR200401981T4/xx unknown
- 2001-05-18 BR BRPI0106714-1A patent/BR0106714B1/pt not_active IP Right Cessation
- 2001-05-18 AT AT01933987T patent/ATE272093T1/de not_active IP Right Cessation
- 2001-05-18 ES ES01933987T patent/ES2225544T3/es not_active Expired - Lifetime
- 2001-05-18 RU RU2002105010/04A patent/RU2255948C2/ru not_active IP Right Cessation
- 2001-05-18 DE DE60104509T patent/DE60104509T2/de not_active Expired - Lifetime
- 2001-05-18 CA CA002379057A patent/CA2379057A1/en not_active Abandoned
- 2001-05-18 WO PCT/EP2001/005707 patent/WO2001092406A1/en not_active Ceased
- 2001-05-31 AR ARP010102599A patent/AR029106A1/es not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| DE60104509D1 (de) | 2004-09-02 |
| ATE272093T1 (de) | 2004-08-15 |
| JP2003535178A (ja) | 2003-11-25 |
| KR20020016916A (ko) | 2002-03-06 |
| BR0106714B1 (pt) | 2011-02-22 |
| AR029106A1 (es) | 2003-06-04 |
| PL352073A1 (en) | 2003-07-28 |
| AU6031501A (en) | 2001-12-11 |
| PL200539B1 (pl) | 2009-01-30 |
| TR200401981T4 (tr) | 2004-10-21 |
| AU781625B2 (en) | 2005-06-02 |
| CN1380893A (zh) | 2002-11-20 |
| KR100758159B1 (ko) | 2007-09-12 |
| US6599986B2 (en) | 2003-07-29 |
| ES2225544T3 (es) | 2005-03-16 |
| US20020156194A1 (en) | 2002-10-24 |
| RU2255948C2 (ru) | 2005-07-10 |
| WO2001092406A1 (en) | 2001-12-06 |
| EP1206499A1 (en) | 2002-05-22 |
| BR0106714A (pt) | 2002-04-16 |
| EP1206499B1 (en) | 2004-07-28 |
| CA2379057A1 (en) | 2001-12-06 |
| CN1227288C (zh) | 2005-11-16 |
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| 8363 | Opposition against the patent |