DE60044540D1 - Selektive oxidation von alkoholen oder ketonen mit einem gold-katalysator - Google Patents

Selektive oxidation von alkoholen oder ketonen mit einem gold-katalysator

Info

Publication number
DE60044540D1
DE60044540D1 DE60044540T DE60044540T DE60044540D1 DE 60044540 D1 DE60044540 D1 DE 60044540D1 DE 60044540 T DE60044540 T DE 60044540T DE 60044540 T DE60044540 T DE 60044540T DE 60044540 D1 DE60044540 D1 DE 60044540D1
Authority
DE
Germany
Prior art keywords
ketons
alcohols
selective oxidation
gold catalyst
gold
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE60044540T
Other languages
English (en)
Inventor
Norman Herron
Stephan Schwarz
Joe Douglas Druliner
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Invista Technologies SARL Switzerland
Original Assignee
Invista Technologies SARL Switzerland
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Invista Technologies SARL Switzerland filed Critical Invista Technologies SARL Switzerland
Application granted granted Critical
Publication of DE60044540D1 publication Critical patent/DE60044540D1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/285—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with peroxy-compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
    • C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/52—Gold
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
    • C07C29/50—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/29—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/30—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with halogen containing compounds, e.g. hypohalogenation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/37—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
    • C07C45/39—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups being a secondary hydroxyl group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
    • C07C51/245—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of keto groups or secondary alcohol groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/29—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with halogen-containing compounds which may be formed in situ
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/31—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting
    • C07C51/313—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting with molecular oxygen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
DE60044540T 2000-08-18 2000-08-18 Selektive oxidation von alkoholen oder ketonen mit einem gold-katalysator Expired - Lifetime DE60044540D1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/US2000/022865 WO2002016298A1 (en) 2000-08-18 2000-08-18 Gold catalyst for selective oxidation

Publications (1)

Publication Number Publication Date
DE60044540D1 true DE60044540D1 (de) 2010-07-22

Family

ID=21741695

Family Applications (1)

Application Number Title Priority Date Filing Date
DE60044540T Expired - Lifetime DE60044540D1 (de) 2000-08-18 2000-08-18 Selektive oxidation von alkoholen oder ketonen mit einem gold-katalysator

Country Status (7)

Country Link
EP (1) EP1309536B1 (de)
JP (1) JP2004506705A (de)
KR (1) KR20030066599A (de)
CN (1) CN100393683C (de)
AU (1) AU2000267914A1 (de)
DE (1) DE60044540D1 (de)
WO (1) WO2002016298A1 (de)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005104941A (ja) * 2003-10-02 2005-04-21 Nippon Shokubai Co Ltd 芳香族カルボニル化合物の製造方法及び芳香族カルボニル化合物製造用触媒
JP2007223992A (ja) 2006-02-27 2007-09-06 Sumitomo Chemical Co Ltd シクロアルカノール及び／又はシクロアルカノンの製造方法
DE102006037447A1 (de) * 2006-08-10 2008-02-14 Clariant Specialty Fine Chemicals (Deutschland) Gmbh Katalytische Oxidation von Terpenen mit Edelmetallkatalysatoren
DE102007017179A1 (de) * 2007-04-12 2008-10-23 Clariant International Ltd. Verfahren zur Herstellung von Alkylpolyglykolcarbonsäuren und Polyglykoldicarbonsäuren mittels Direktoxidation
JP4978864B2 (ja) * 2008-03-11 2012-07-18 独立行政法人科学技術振興機構 キャピラリーとキャピラリーへの触媒固定化方法、並びにマイクロリアクターとこれを用いた固相−液相−気相反応方法
DE102008037065A1 (de) * 2008-08-08 2010-02-11 Clariant International Ltd. Verfahren zur Herstellung von Arylpolyglykolcarbonsäuren mittels Direktoxidation
JP5787206B2 (ja) * 2010-03-23 2015-09-30 公立大学法人首都大学東京 エタノール酸化用金触媒およびそれを用いたアセトアルデヒド、酢酸の製造方法
CN102452918B (zh) * 2010-10-29 2014-03-26 中国石油化工股份有限公司 一种催化氧化羟基酸制备相应二元羧酸的方法
EP2858748B1 (de) * 2012-06-11 2018-04-11 Rennovia Inc. Verfahren zur herstellung von adipinsäure aus 1,6-hexandiol
WO2015155784A1 (en) * 2014-04-09 2015-10-15 Natco Pharma Limited Process for the preparation of 2,5-furandicarboxylic acid and its ester derivative
CN105017001A (zh) * 2014-04-29 2015-11-04 中国科学院大连化学物理研究所 一种脂肪醇氧化制备脂肪酸的催化剂及其应用
WO2016026132A1 (en) * 2014-08-22 2016-02-25 Rhodia Operations Process for oxidation of alcohols
CN105237343B (zh) * 2015-09-29 2017-05-31 江西科苑生物药业有限公司 一种联产甲基苯甲醇、甲基苯甲醛及甲基苯甲酸的方法

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3149166A (en) * 1959-12-28 1964-09-15 Basf Ag Process for the production of pure cyclohexanone
DE1262264B (de) * 1964-04-10 1968-03-07 Dynamit Nobel Ag Verfahren zur Herstellung von Alkalisalzen der Acrylsaeure durch Oxydation von Allylalkohol
CH592594A5 (de) * 1973-05-30 1977-10-31 Givaudan & Cie Sa
US4816606A (en) * 1987-09-30 1989-03-28 Basf Aktiengesellschaft Continuous preparation of aldehydes and ketones
US5689000A (en) * 1994-07-01 1997-11-18 Monsanto Company Process for preparing carboxylic acid salts and catalysts useful in such process
JP2615432B2 (ja) * 1994-10-28 1997-05-28 工業技術院長 金−酸化チタン含有触媒による炭化水素の部分酸化方法
JPH08225470A (ja) * 1994-12-19 1996-09-03 Mitsubishi Chem Corp シクロオレフィンの製造方法
JPH1053545A (ja) * 1996-05-17 1998-02-24 Toray Ind Inc 芳香族カルボン酸、芳香族アルデヒドおよび／または芳香族アルコールの製造法
JP4016121B2 (ja) * 1997-09-05 2007-12-05 独立行政法人産業技術総合研究所 炭化水素部分酸化用触媒及び含酸素有機化合物の製造方法
JP2000070718A (ja) * 1998-06-17 2000-03-07 Nippon Shokubai Co Ltd ベンジルエステルの製造方法

Also Published As

Publication number Publication date
KR20030066599A (ko) 2003-08-09
EP1309536A1 (de) 2003-05-14
CN100393683C (zh) 2008-06-11
WO2002016298A1 (en) 2002-02-28
AU2000267914A1 (en) 2002-03-04
CN1454201A (zh) 2003-11-05
JP2004506705A (ja) 2004-03-04
EP1309536B1 (de) 2010-06-09

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