DE60016390T2 - Verfahren zur behandlung von metallen mit einer mischung von ureido-silanen und multisilylierten funktionellen silanen - Google Patents
Verfahren zur behandlung von metallen mit einer mischung von ureido-silanen und multisilylierten funktionellen silanen Download PDFInfo
- Publication number
- DE60016390T2 DE60016390T2 DE60016390T DE60016390T DE60016390T2 DE 60016390 T2 DE60016390 T2 DE 60016390T2 DE 60016390 T DE60016390 T DE 60016390T DE 60016390 T DE60016390 T DE 60016390T DE 60016390 T2 DE60016390 T2 DE 60016390T2
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- Germany
- Prior art keywords
- use according
- group
- coating
- butyl
- hydrolyzed
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- Expired - Lifetime
Links
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 83
- 239000002184 metal Substances 0.000 title claims abstract description 83
- 150000004756 silanes Chemical class 0.000 title claims abstract description 38
- 239000000203 mixture Substances 0.000 title claims description 16
- 238000000034 method Methods 0.000 title abstract description 35
- 150000002739 metals Chemical class 0.000 title description 6
- 238000011282 treatment Methods 0.000 claims abstract description 51
- 238000005260 corrosion Methods 0.000 claims abstract description 40
- 230000007797 corrosion Effects 0.000 claims abstract description 40
- 239000000758 substrate Substances 0.000 claims abstract description 36
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 23
- IYMSIPPWHNIMGE-UHFFFAOYSA-N silylurea Chemical class NC(=O)N[SiH3] IYMSIPPWHNIMGE-UHFFFAOYSA-N 0.000 claims abstract description 23
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000011701 zinc Substances 0.000 claims abstract description 17
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 17
- 229910000838 Al alloy Inorganic materials 0.000 claims abstract description 16
- 239000010960 cold rolled steel Substances 0.000 claims abstract description 8
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 48
- 229910000077 silane Inorganic materials 0.000 claims description 48
- 238000000576 coating method Methods 0.000 claims description 46
- 239000011248 coating agent Substances 0.000 claims description 43
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 32
- 239000003973 paint Substances 0.000 claims description 26
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 16
- 125000003277 amino group Chemical group 0.000 claims description 15
- 229910052739 hydrogen Inorganic materials 0.000 claims description 15
- 239000001257 hydrogen Substances 0.000 claims description 15
- 229910000831 Steel Inorganic materials 0.000 claims description 14
- 229920001971 elastomer Polymers 0.000 claims description 14
- 239000005060 rubber Substances 0.000 claims description 14
- 239000010959 steel Substances 0.000 claims description 14
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 13
- 229920000642 polymer Polymers 0.000 claims description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 12
- 125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 claims description 12
- 125000003161 (C1-C6) alkylene group Chemical group 0.000 claims description 10
- 239000002904 solvent Substances 0.000 claims description 10
- -1 C 2 -C 6 -alkenylene Chemical group 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 7
- 125000000732 arylene group Chemical group 0.000 claims description 7
- 239000000853 adhesive Substances 0.000 claims description 6
- 230000001070 adhesive effect Effects 0.000 claims description 6
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 6
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 6
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims description 6
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 6
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 6
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 6
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 6
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 6
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 5
- 229910001297 Zn alloy Inorganic materials 0.000 claims description 5
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims description 4
- 238000007598 dipping method Methods 0.000 claims description 3
- LVNLBBGBASVLLI-UHFFFAOYSA-N 3-triethoxysilylpropylurea Chemical compound CCO[Si](OCC)(OCC)CCCNC(N)=O LVNLBBGBASVLLI-UHFFFAOYSA-N 0.000 claims description 2
- 235000019260 propionic acid Nutrition 0.000 claims description 2
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 claims description 2
- 125000000882 C2-C6 alkenyl group Chemical group 0.000 claims 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N formic acid Substances OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims 1
- 229910000897 Babbitt (metal) Inorganic materials 0.000 claims 1
- 235000019253 formic acid Nutrition 0.000 claims 1
- 239000003960 organic solvent Substances 0.000 claims 1
- 235000006408 oxalic acid Nutrition 0.000 claims 1
- IZRJPHXTEXTLHY-UHFFFAOYSA-N triethoxy(2-triethoxysilylethyl)silane Chemical group CCO[Si](OCC)(OCC)CC[Si](OCC)(OCC)OCC IZRJPHXTEXTLHY-UHFFFAOYSA-N 0.000 claims 1
- 229910052782 aluminium Inorganic materials 0.000 abstract description 21
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract description 9
- 229910052742 iron Inorganic materials 0.000 abstract description 5
- 239000004411 aluminium Substances 0.000 abstract description 3
- 239000000243 solution Substances 0.000 description 67
- 238000012360 testing method Methods 0.000 description 29
- 239000010408 film Substances 0.000 description 17
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 15
- 229910001335 Galvanized steel Inorganic materials 0.000 description 12
- 239000008397 galvanized steel Substances 0.000 description 12
- 239000007921 spray Substances 0.000 description 12
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 10
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 9
- 241001163841 Albugo ipomoeae-panduratae Species 0.000 description 8
- 230000008901 benefit Effects 0.000 description 8
- BBEAQIROQSPTKN-UHFFFAOYSA-N pyrene Chemical compound C1=CC=C2C=CC3=CC=CC4=CC=C1C2=C43 BBEAQIROQSPTKN-UHFFFAOYSA-N 0.000 description 8
- 125000003808 silyl group Chemical group [H][Si]([H])([H])[*] 0.000 description 8
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 7
- 150000003839 salts Chemical class 0.000 description 7
- 150000001298 alcohols Chemical class 0.000 description 6
- 239000011651 chromium Substances 0.000 description 6
- 230000007062 hydrolysis Effects 0.000 description 6
- 238000006460 hydrolysis reaction Methods 0.000 description 6
- 239000000843 powder Substances 0.000 description 6
- 239000002966 varnish Substances 0.000 description 6
- 229910019142 PO4 Inorganic materials 0.000 description 5
- 125000004423 acyloxy group Chemical group 0.000 description 5
- 125000003545 alkoxy group Chemical group 0.000 description 5
- 125000000217 alkyl group Chemical group 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 229910052804 chromium Inorganic materials 0.000 description 5
- 238000002329 infrared spectrum Methods 0.000 description 5
- 230000007774 longterm Effects 0.000 description 5
- 235000021317 phosphate Nutrition 0.000 description 5
- 125000001424 substituent group Chemical group 0.000 description 5
- 125000002252 acyl group Chemical group 0.000 description 4
- 125000001931 aliphatic group Chemical group 0.000 description 4
- 239000012670 alkaline solution Substances 0.000 description 4
- 125000003118 aryl group Chemical group 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 4
- GVEPBJHOBDJJJI-UHFFFAOYSA-N fluoranthrene Natural products C1=CC(C2=CC=CC=C22)=C3C2=CC=CC3=C1 GVEPBJHOBDJJJI-UHFFFAOYSA-N 0.000 description 4
- 238000007654 immersion Methods 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 4
- 239000010452 phosphate Substances 0.000 description 4
- 229920000728 polyester Polymers 0.000 description 4
- 238000002203 pretreatment Methods 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 description 4
- 229910000165 zinc phosphate Inorganic materials 0.000 description 4
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 239000003431 cross linking reagent Substances 0.000 description 3
- 125000004122 cyclic group Chemical group 0.000 description 3
- 239000003599 detergent Substances 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 238000009661 fatigue test Methods 0.000 description 3
- 125000005842 heteroatom Chemical group 0.000 description 3
- 238000010422 painting Methods 0.000 description 3
- 238000002161 passivation Methods 0.000 description 3
- 125000006727 (C1-C6) alkenyl group Chemical group 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 239000004971 Cross linker Substances 0.000 description 2
- 229920001967 Metal rubber Polymers 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 239000002390 adhesive tape Substances 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 150000004645 aluminates Chemical class 0.000 description 2
- 125000004104 aryloxy group Chemical group 0.000 description 2
- 125000001951 carbamoylamino group Chemical group C(N)(=O)N* 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 230000009189 diving Effects 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical class CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- 230000009972 noncorrosive effect Effects 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 125000005373 siloxane group Chemical group [SiH2](O*)* 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- UKRDPEFKFJNXQM-UHFFFAOYSA-N vinylsilane Chemical class [SiH3]C=C UKRDPEFKFJNXQM-UHFFFAOYSA-N 0.000 description 2
- IFIOCROSOWHDOL-UHFFFAOYSA-N 3-cyanato-2-methyl-3-sulfanylprop-2-enoic acid Chemical compound SC(=C(C(=O)O)C)OC#N IFIOCROSOWHDOL-UHFFFAOYSA-N 0.000 description 1
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 206010013786 Dry skin Diseases 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 238000004566 IR spectroscopy Methods 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 239000004972 Polyurethane varnish Substances 0.000 description 1
- 239000006087 Silane Coupling Agent Substances 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229910000611 Zinc aluminium Inorganic materials 0.000 description 1
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 229940069428 antacid Drugs 0.000 description 1
- 239000003159 antacid agent Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 238000010420 art technique Methods 0.000 description 1
- 239000010953 base metal Substances 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 238000004532 chromating Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 238000001962 electrophoresis Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 208000028626 extracranial carotid artery aneurysm Diseases 0.000 description 1
- 229910052909 inorganic silicate Inorganic materials 0.000 description 1
- 229910000398 iron phosphate Inorganic materials 0.000 description 1
- WBJZTOZJJYAKHQ-UHFFFAOYSA-K iron(3+) phosphate Chemical compound [Fe+3].[O-]P([O-])([O-])=O WBJZTOZJJYAKHQ-UHFFFAOYSA-K 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 125000005372 silanol group Chemical group 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 125000005369 trialkoxysilyl group Chemical group 0.000 description 1
- FOQJQXVUMYLJSU-UHFFFAOYSA-N triethoxy(1-triethoxysilylethyl)silane Chemical group CCO[Si](OCC)(OCC)C(C)[Si](OCC)(OCC)OCC FOQJQXVUMYLJSU-UHFFFAOYSA-N 0.000 description 1
- BTLPDSCJUZOEJB-BUHFOSPRSA-N triethoxy-[(e)-2-triethoxysilylethenyl]silane Chemical group CCO[Si](OCC)(OCC)\C=C\[Si](OCC)(OCC)OCC BTLPDSCJUZOEJB-BUHFOSPRSA-N 0.000 description 1
- JCGDCINCKDQXDX-UHFFFAOYSA-N trimethoxy(2-trimethoxysilylethyl)silane Chemical compound CO[Si](OC)(OC)CC[Si](OC)(OC)OC JCGDCINCKDQXDX-UHFFFAOYSA-N 0.000 description 1
- GFKCWAROGHMSTC-UHFFFAOYSA-N trimethoxy(6-trimethoxysilylhexyl)silane Chemical class CO[Si](OC)(OC)CCCCCC[Si](OC)(OC)OC GFKCWAROGHMSTC-UHFFFAOYSA-N 0.000 description 1
- MAFQBSQRZKWGGE-UHFFFAOYSA-N trimethoxy-[2-[4-(2-trimethoxysilylethyl)phenyl]ethyl]silane Chemical compound CO[Si](OC)(OC)CCC1=CC=C(CC[Si](OC)(OC)OC)C=C1 MAFQBSQRZKWGGE-UHFFFAOYSA-N 0.000 description 1
- 231100000925 very toxic Toxicity 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/48—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 not containing phosphates, hexavalent chromium compounds, fluorides or complex fluorides, molybdates, tungstates, vanadates or oxalates
- C23C22/56—Treatment of aluminium or alloys based thereon
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/14—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/48—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 not containing phosphates, hexavalent chromium compounds, fluorides or complex fluorides, molybdates, tungstates, vanadates or oxalates
- C23C22/50—Treatment of iron or alloys based thereon
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/48—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 not containing phosphates, hexavalent chromium compounds, fluorides or complex fluorides, molybdates, tungstates, vanadates or oxalates
- C23C22/53—Treatment of zinc or alloys based thereon
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2222/00—Aspects relating to chemical surface treatment of metallic material by reaction of the surface with a reactive medium
- C23C2222/20—Use of solutions containing silanes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Paints Or Removers (AREA)
- Chemical Treatment Of Metals (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US245602 | 1999-02-05 | ||
| US09/245,602 US6106901A (en) | 1999-02-05 | 1999-02-05 | Method of treating metals using ureido silanes and multi-silyl-functional silanes in admixture |
| PCT/GB2000/000350 WO2000046311A1 (en) | 1999-02-05 | 2000-02-04 | Method of treating metals using ureido silanes and multi-silyl-functional silanes in admixture |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE60016390D1 DE60016390D1 (de) | 2005-01-05 |
| DE60016390T2 true DE60016390T2 (de) | 2005-10-27 |
Family
ID=22927358
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE60016390T Expired - Lifetime DE60016390T2 (de) | 1999-02-05 | 2000-02-04 | Verfahren zur behandlung von metallen mit einer mischung von ureido-silanen und multisilylierten funktionellen silanen |
Country Status (11)
| Country | Link |
|---|---|
| US (2) | US6106901A (enExample) |
| EP (1) | EP1163296B1 (enExample) |
| JP (1) | JP4138253B2 (enExample) |
| CN (1) | CN1164690C (enExample) |
| AT (1) | ATE283900T1 (enExample) |
| AU (1) | AU2309300A (enExample) |
| CA (1) | CA2360637A1 (enExample) |
| DE (1) | DE60016390T2 (enExample) |
| DK (1) | DK1163296T3 (enExample) |
| ES (1) | ES2231155T3 (enExample) |
| WO (1) | WO2000046311A1 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102005010568A1 (de) * | 2005-03-04 | 2006-09-07 | Braun Gmbh | Haarformgerät |
Families Citing this family (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6358349B1 (en) * | 1999-07-01 | 2002-03-19 | Eagle-Picher Industries, Inc. | Method to improve adhesion between pre-cured elastomer and metal surface |
| US6413646B1 (en) * | 1999-07-29 | 2002-07-02 | Crompton Corporation | Blocked phenolic silanes |
| DE60235927D1 (de) * | 2001-06-28 | 2010-05-20 | Alonim Holding Agricultural Co | Oberflächebehandlung zur Verbesserung der Korrosionsbeständigkeit von Magnesium |
| US7244498B2 (en) * | 2002-06-12 | 2007-07-17 | Tda Research, Inc. | Nanoparticles modified with multiple organic acids |
| US6933046B1 (en) * | 2002-06-12 | 2005-08-23 | Tda Research, Inc. | Releasable corrosion inhibitor compositions |
| MXPA05000879A (es) | 2002-07-24 | 2005-10-19 | Univ Cincinnati | Superimprimador. |
| US6887308B2 (en) * | 2003-01-21 | 2005-05-03 | Johnsondiversey, Inc. | Metal coating coupling composition |
| US20050079364A1 (en) * | 2003-10-08 | 2005-04-14 | University Of Cincinnati | Silane compositions and methods for bonding rubber to metals |
| JP4304510B2 (ja) * | 2004-02-16 | 2009-07-29 | 信越化学工業株式会社 | 難燃性添加剤、並びにエマルション型コーティング剤及び難燃性組成物 |
| ES2370411T3 (es) * | 2005-01-25 | 2011-12-15 | Sigma Coatings B.V. | Composición aglutinante. |
| US10041176B2 (en) * | 2005-04-07 | 2018-08-07 | Momentive Performance Materials Inc. | No-rinse pretreatment methods and compositions |
| US7534472B2 (en) * | 2005-08-09 | 2009-05-19 | Century Industrial Coatings Incorporated | Treating metal surfaces with coating material |
| US7527872B2 (en) * | 2005-10-25 | 2009-05-05 | Goodrich Corporation | Treated aluminum article and method for making same |
| US20080026151A1 (en) * | 2006-07-31 | 2008-01-31 | Danqing Zhu | Addition of silanes to coating compositions |
| BRPI0622060B1 (pt) * | 2006-09-29 | 2019-06-25 | Momentive Performance Materials Inc. | Composição estável para tratamento de uma superfície de metal para formar um revestimento de conversão ou passivação sobre a mesma e processo para tratamento de uma superfície de metal para formar um revestimento de conversão ou passivação sobre a mesma |
| US7875318B2 (en) * | 2007-04-24 | 2011-01-25 | Momentive Performance Materials Inc. | Method of applying an anti-corrosion and/or adhesion promoting coating to a metal and resulting coated metal |
| US8575292B2 (en) * | 2007-04-24 | 2013-11-05 | Momentive Performance Materials Inc. | Hydroxyl-functional carbamoyl organosilicon compounds of low VOC and HAP generating potential, anti-corrosion and/or adhesion promoting coating composition containing same, environmentally benign method of coating metal therewith and resulting coated metal |
| US11066750B2 (en) * | 2007-08-27 | 2021-07-20 | Momentive Performance Materials Inc. | Metal corrosion inhibition |
| US7972659B2 (en) * | 2008-03-14 | 2011-07-05 | Ecosil Technologies Llc | Method of applying silanes to metal in an oil bath containing a controlled amount of water |
| TW201038684A (en) | 2009-01-09 | 2010-11-01 | Momentive Performance Mat Inc | Silane coating compositions containing silicon-based polyether copolymers, methods for coating metal surfaces and articles made therefrom |
| DE102011084183A1 (de) | 2011-03-25 | 2012-09-27 | Evonik Degussa Gmbh | Wässrige Korrosionsschutzformulierung auf Silanebasis |
| JP2013221210A (ja) * | 2012-04-19 | 2013-10-28 | Hitachi Ltd | 防食処理アルミニウム材及びその製造方法 |
| JP5860830B2 (ja) * | 2013-03-27 | 2016-02-16 | モメンティブ パフォーマンス マテリアルズ インコーポレイテッド | 加水分解性有機官能性シランの部分および／または完全縮合物の貯蔵に安定な組成物 |
| KR102221109B1 (ko) * | 2014-04-22 | 2021-02-25 | 동우 화인켐 주식회사 | 점착제 조성물 |
| BR102016008523A2 (pt) * | 2016-04-15 | 2018-02-20 | Instituto Nacional De Tecnologia | Bronzina com cobertura polimérica para redução de atrito em motores de combustão interna e processo para a produção da mesma |
| EP3398998A1 (de) | 2017-05-03 | 2018-11-07 | Evonik Degussa GmbH | Wässrige sol-gel-zusammensetzung als lagerstabile vorstufe für zinkstaubfarben |
| CN115725966B (zh) * | 2022-11-18 | 2025-07-22 | 诺泰生物科技(合肥)有限公司 | 一种葫芦脲改性的有机硅类金属防锈水及其制备方法和应用 |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US34675A (en) * | 1862-03-18 | Improvement in machines for cutting chair-backs | ||
| JPS59193175A (ja) * | 1983-04-19 | 1984-11-01 | Toa Nenryo Kogyo Kk | 積層物 |
| JPS59193174A (ja) * | 1983-04-19 | 1984-11-01 | Toa Nenryo Kogyo Kk | 金属表面の処理法 |
| US4689085A (en) | 1986-06-30 | 1987-08-25 | Dow Corning Corporation | Coupling agent compositions |
| US5073456A (en) * | 1989-12-05 | 1991-12-17 | E. I. Du Pont De Nemours And Company | Multilayer printed circuit board formation |
| US5108793A (en) * | 1990-12-24 | 1992-04-28 | Armco Steel Company, L.P. | Steel sheet with enhanced corrosion resistance having a silane treated silicate coating |
| US5292549A (en) * | 1992-10-23 | 1994-03-08 | Armco Inc. | Metallic coated steel having a siloxane film providing temporary corrosion protection and method therefor |
| US5326594A (en) * | 1992-12-02 | 1994-07-05 | Armco Inc. | Metal pretreated with an inorganic/organic composite coating with enhanced paint adhesion |
| US5433976A (en) * | 1994-03-07 | 1995-07-18 | Armco, Inc. | Metal pretreated with an aqueous solution containing a dissolved inorganic silicate or aluminate, an organofuctional silane and a non-functional silane for enhanced corrosion resistance |
| US5578347A (en) * | 1994-05-24 | 1996-11-26 | E. I. Du Pont De Nemours And Company | Process for applying a finish to a metal substrate |
| US5759629A (en) * | 1996-11-05 | 1998-06-02 | University Of Cincinnati | Method of preventing corrosion of metal sheet using vinyl silanes |
| US5750197A (en) * | 1997-01-09 | 1998-05-12 | The University Of Cincinnati | Method of preventing corrosion of metals using silanes |
| AU1198799A (en) * | 1997-10-23 | 1999-05-10 | Cornelis P. J. Van Der Aar | Rubber to metal bonding by silane coupling agents |
-
1999
- 1999-02-05 US US09/245,602 patent/US6106901A/en not_active Expired - Lifetime
-
2000
- 2000-02-04 AU AU23093/00A patent/AU2309300A/en not_active Abandoned
- 2000-02-04 ES ES00901796T patent/ES2231155T3/es not_active Expired - Lifetime
- 2000-02-04 CN CNB00805195XA patent/CN1164690C/zh not_active Expired - Lifetime
- 2000-02-04 WO PCT/GB2000/000350 patent/WO2000046311A1/en not_active Ceased
- 2000-02-04 JP JP2000597374A patent/JP4138253B2/ja not_active Expired - Lifetime
- 2000-02-04 DK DK00901796T patent/DK1163296T3/da active
- 2000-02-04 DE DE60016390T patent/DE60016390T2/de not_active Expired - Lifetime
- 2000-02-04 EP EP00901796A patent/EP1163296B1/en not_active Expired - Lifetime
- 2000-02-04 CA CA002360637A patent/CA2360637A1/en not_active Abandoned
- 2000-02-04 AT AT00901796T patent/ATE283900T1/de not_active IP Right Cessation
- 2000-08-16 US US09/640,143 patent/US6361592B1/en not_active Expired - Lifetime
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102005010568A1 (de) * | 2005-03-04 | 2006-09-07 | Braun Gmbh | Haarformgerät |
| US8066016B2 (en) | 2005-03-04 | 2011-11-29 | Braun Gmbh | Hair styling device |
Also Published As
| Publication number | Publication date |
|---|---|
| EP1163296B1 (en) | 2004-12-01 |
| ES2231155T3 (es) | 2005-05-16 |
| ATE283900T1 (de) | 2004-12-15 |
| CN1164690C (zh) | 2004-09-01 |
| DE60016390D1 (de) | 2005-01-05 |
| US6361592B1 (en) | 2002-03-26 |
| CA2360637A1 (en) | 2000-08-10 |
| AU2309300A (en) | 2000-08-25 |
| DK1163296T3 (da) | 2005-03-21 |
| CN1353744A (zh) | 2002-06-12 |
| EP1163296A1 (en) | 2001-12-19 |
| WO2000046311A1 (en) | 2000-08-10 |
| JP4138253B2 (ja) | 2008-08-27 |
| US6106901A (en) | 2000-08-22 |
| JP2002536159A (ja) | 2002-10-29 |
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Legal Events
| Date | Code | Title | Description |
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| 8364 | No opposition during term of opposition |