DE60011453D1 - Katalysatorzusammensetzungen für die polymerisation von olefinen zu polymeren mit multimodaler molekulargewichtsverteilung, verfahren zur herstellung und verwendung des katalysators - Google Patents

Katalysatorzusammensetzungen für die polymerisation von olefinen zu polymeren mit multimodaler molekulargewichtsverteilung, verfahren zur herstellung und verwendung des katalysators

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Publication number
DE60011453D1
DE60011453D1 DE60011453T DE60011453T DE60011453D1 DE 60011453 D1 DE60011453 D1 DE 60011453D1 DE 60011453 T DE60011453 T DE 60011453T DE 60011453 T DE60011453 T DE 60011453T DE 60011453 D1 DE60011453 D1 DE 60011453D1
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DE
Germany
Prior art keywords
compound
catalyst
transition metal
polymerization
catalyst component
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE60011453T
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English (en)
Other versions
DE60011453T2 (de
Inventor
Orass Hamed
Akhlaq Moman
Atieh Abu-Raqabah
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Saudi Basic Industries Corp
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Saudi Basic Industries Corp
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Filing date
Publication date
Application filed by Saudi Basic Industries Corp filed Critical Saudi Basic Industries Corp
Publication of DE60011453D1 publication Critical patent/DE60011453D1/de
Application granted granted Critical
Publication of DE60011453T2 publication Critical patent/DE60011453T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
DE60011453T 1999-09-17 2000-09-11 Katalysatorzusammensetzungen für die polymerisation von olefinen zu polymeren mit multimodaler molekulargewichtsverteilung, verfahren zur herstellung und verwendung des katalysators Expired - Lifetime DE60011453T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US399305 1999-09-17
US09/399,305 US6403520B1 (en) 1999-09-17 1999-09-17 Catalyst compositions for polymerizing olefins to multimodal molecular weight distribution polymer, processes for production and use of the catalyst
PCT/EP2000/008888 WO2001021673A1 (en) 1999-09-17 2000-09-11 Catalyst compositions for polymerizing olefins to multimodal molecular weight distribution polymer, processes for production and use of the catalyst

Publications (2)

Publication Number Publication Date
DE60011453D1 true DE60011453D1 (de) 2004-07-15
DE60011453T2 DE60011453T2 (de) 2005-06-30

Family

ID=23579024

Family Applications (1)

Application Number Title Priority Date Filing Date
DE60011453T Expired - Lifetime DE60011453T2 (de) 1999-09-17 2000-09-11 Katalysatorzusammensetzungen für die polymerisation von olefinen zu polymeren mit multimodaler molekulargewichtsverteilung, verfahren zur herstellung und verwendung des katalysators

Country Status (6)

Country Link
US (2) US6403520B1 (de)
EP (1) EP1216261B1 (de)
JP (1) JP2003523415A (de)
AT (1) ATE268785T1 (de)
DE (1) DE60011453T2 (de)
WO (1) WO2001021673A1 (de)

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Publication number Priority date Publication date Assignee Title
US6143854A (en) * 1993-08-06 2000-11-07 Exxon Chemical Patents, Inc. Polymerization catalysts, their production and use
US6653254B1 (en) * 1999-02-22 2003-11-25 Fina Technology, Inc Ziegler-Natta catalyst with metallocene for olefin polymerization
US6992152B2 (en) * 1999-10-19 2006-01-31 Texas Petrochemicals Lp Apparatus and method for controlling olefin polymerization process
GB0023662D0 (en) 2000-09-27 2000-11-08 Borealis Tech Oy Supported catalyst
GC0000293A (en) * 2000-10-10 2006-11-01 Saudi Basic Ind Corp Catalyst composition and process for olfin polymerization and copolymerization using supported metallocene catalyst systems
DE60104809T2 (de) * 2001-02-07 2005-01-05 Saudi Basic Industries Corp. Katalysatorzusammensetzung für die Olefinpolymerisation und Verfahren zu ihrer Herstellung
EP1231223B1 (de) * 2001-02-07 2004-04-28 Saudi Basic Industries Corporation Verfahren zur Olefinpolymerisation
DE60101207T2 (de) * 2001-02-15 2004-08-26 Saudi Basic Industries Corp. Geträgerte Katalysatorzusammensetzung für die Olefinpolymerisation; Verfahren zu deren Herstellung und Polymerisationsverfahren unter deren Verwendung
EP1302480B1 (de) * 2001-10-15 2004-08-11 Saudi Basic Industries Corporation (Sabic) Geträter Polymerisationskatalysator enthaltend Magnesium und einen Metallocen
EP1461151A4 (de) * 2001-11-30 2010-03-24 Univation Tech Llc Verfahren zur herstellung von gemischten ziegler-natta-/metallocen-katalysatoren
WO2003048213A1 (en) * 2001-11-30 2003-06-12 Exxonmobil Chemical Patents, Inc. Ethylene/alpha-olefin copolymer made with a non-single-site/single-site catalyst combination, its preparation and use
ES2240613T3 (es) * 2002-07-12 2005-10-16 Saudi Basic Industries Corporation Composicion catalizadora ziegler-metaloceno soportada y procedimiento de polimerizacion y copolimerizacion de olefinas con alfa-olefinas usando sistemas catalizadores novedosos.
US6861487B2 (en) * 2003-04-15 2005-03-01 Saudi Basic Industries Corporation Catalyst precursor for the polymerization of olefins and polymerization process using the same
US7662894B2 (en) * 2006-12-19 2010-02-16 Saudi Bosic Industries Corporation Polymer supported metallocene catalyst composition for polymerizing olefins
CN101274968B (zh) * 2007-03-28 2012-11-21 中国石油化工股份有限公司 一种用于生产宽分子量分布的聚乙烯的复合催化剂
KR101585204B1 (ko) 2013-06-28 2016-01-13 주식회사 엘지화학 디엔을 포함하는 3원계 탄성 공중합체 및 이의 제조 방법
WO2014209085A1 (ko) 2013-06-28 2014-12-31 주식회사 엘지화학 디엔을 포함하는 3원계 탄성 공중합체 및 이의 제조 방법
US9650460B2 (en) 2013-06-28 2017-05-16 Lg Chem, Ltd. Elastic diene terpolymer and preparation method thereof

Family Cites Families (15)

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Publication number Priority date Publication date Assignee Title
US4107415A (en) 1972-09-26 1978-08-15 Montecatini Edison S.P.A. Process for the stereospecific polymerization of alpha-olefins
US4414369A (en) 1977-08-17 1983-11-08 Nippon Oil Company, Limited Continuous process for the preparation of polyolefins having widely distributed molecular weights
JPS6045645B2 (ja) 1980-10-09 1985-10-11 三井化学株式会社 オレフイン類の気相重合方法
US4530914A (en) 1983-06-06 1985-07-23 Exxon Research & Engineering Co. Process and catalyst for producing polyethylene having a broad molecular weight distribution
US4937299A (en) 1983-06-06 1990-06-26 Exxon Research & Engineering Company Process and catalyst for producing reactor blend polyolefins
US4522982A (en) 1983-06-06 1985-06-11 Exxon Research & Engineering Co. Isotactic-stereoblock polymers of alpha-olefins and process for producing the same
KR900008459B1 (ko) 1984-12-14 1990-11-22 엑손 리서치 앤드 엔지니어링 컴패니 튜브 반응기내에서의 분자량 분포 조절 다중 모드
FR2577558B1 (fr) 1985-02-19 1987-03-06 Bp Chimie Sa Polymerisation en plusieurs etapes d'alpha-olefines en phase gazeuse
US5077255A (en) 1986-09-09 1991-12-31 Exxon Chemical Patents Inc. New supported polymerization catalyst
US5070055A (en) 1990-06-29 1991-12-03 Union Carbide Chemicals And Plastics Technology Corporation Novel coimpregnated vanadium-zirconium catalyst for making polyethylene with broad or bimodal MW distribution
CA2082678C (en) 1991-11-12 1996-07-30 Naoki Kataoka Catalyst components for polymerization of olefins
BE1007040A3 (fr) 1993-05-25 1995-02-28 Solvay Support de catalyseur et catalyseur de polymerisation des alpha-olefines; procedes pour leur obtention et polymerisation des alpha-olefines en presence du catalyseur.
KR100359370B1 (ko) 1995-02-07 2003-02-11 미쓰이 가가쿠 가부시키가이샤 올레핀중합체의제조방법
US5885924A (en) 1995-06-07 1999-03-23 W. R. Grace & Co.-Conn. Halogenated supports and supported activators
US5882750A (en) 1995-07-03 1999-03-16 Mobil Oil Corporation Single reactor bimodal HMW-HDPE film resin with improved bubble stability

Also Published As

Publication number Publication date
US20020165085A1 (en) 2002-11-07
EP1216261A1 (de) 2002-06-26
US6784263B2 (en) 2004-08-31
EP1216261B1 (de) 2004-06-09
US6403520B1 (en) 2002-06-11
WO2001021673A1 (en) 2001-03-29
JP2003523415A (ja) 2003-08-05
ATE268785T1 (de) 2004-06-15
DE60011453T2 (de) 2005-06-30

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