DE3782120D1 - Asymmetrische gastrennungsmembranen, deren haut einen dichtegradienten aufweisen. - Google Patents
Asymmetrische gastrennungsmembranen, deren haut einen dichtegradienten aufweisen.Info
- Publication number
- DE3782120D1 DE3782120D1 DE8787870113T DE3782120T DE3782120D1 DE 3782120 D1 DE3782120 D1 DE 3782120D1 DE 8787870113 T DE8787870113 T DE 8787870113T DE 3782120 T DE3782120 T DE 3782120T DE 3782120 D1 DE3782120 D1 DE 3782120D1
- Authority
- DE
- Germany
- Prior art keywords
- radient
- skin
- density
- gas separation
- separation membranes
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000012528 membrane Substances 0.000 title 1
- 238000000926 separation method Methods 0.000 title 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/14—Ultrafiltration; Microfiltration
- B01D61/145—Ultrafiltration
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/02—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor characterised by their properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/08—Hollow fibre membranes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/12—Composite membranes; Ultra-thin membranes
- B01D69/1212—Coextruded layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/12—Composite membranes; Ultra-thin membranes
- B01D69/1213—Laminated layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/12—Composite membranes; Ultra-thin membranes
- B01D69/1216—Three or more layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/66—Polymers having sulfur in the main chain, with or without nitrogen, oxygen or carbon only
- B01D71/68—Polysulfones; Polyethersulfones
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/02—Details relating to pores or porosity of the membranes
- B01D2325/022—Asymmetric membranes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/40—Capture or disposal of greenhouse gases of CO2
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Water Supply & Treatment (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US89699086A | 1986-08-15 | 1986-08-15 | |
US6675287A | 1987-06-25 | 1987-06-25 |
Publications (2)
Publication Number | Publication Date |
---|---|
DE3782120D1 true DE3782120D1 (de) | 1992-11-12 |
DE3782120T2 DE3782120T2 (de) | 1993-02-11 |
Family
ID=26747124
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE8787870113T Expired - Lifetime DE3782120T2 (de) | 1986-08-15 | 1987-08-12 | Asymmetrische gastrennungsmembranen, deren haut einen dichtegradienten aufweisen. |
Country Status (16)
Country | Link |
---|---|
US (1) | US4880441A (de) |
EP (1) | EP0257012B1 (de) |
JP (1) | JP2635051B2 (de) |
KR (1) | KR900008712B1 (de) |
CN (1) | CN1009430B (de) |
AR (1) | AR244564A1 (de) |
AU (1) | AU596859B2 (de) |
BR (1) | BR8704235A (de) |
CA (1) | CA1321686C (de) |
DE (1) | DE3782120T2 (de) |
ES (1) | ES2052605T3 (de) |
GR (1) | GR3006559T3 (de) |
IL (1) | IL83542A (de) |
MX (1) | MX169433B (de) |
NO (1) | NO173003C (de) |
TR (1) | TR23207A (de) |
Families Citing this family (58)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4793830A (en) * | 1987-12-28 | 1988-12-27 | Murphy Milton K | Process for producing high quality gas for instrumentation application using gas separation membranes |
US4783201A (en) * | 1987-12-28 | 1988-11-08 | Rice Arthur W | Gas dehydration membrane apparatus |
US4902422A (en) * | 1988-12-06 | 1990-02-20 | Board Regents The University Of Texas System | Defect-free ultrahigh flux asymmetric membranes |
US5013767A (en) * | 1989-09-27 | 1991-05-07 | Permea, Inc. | Asymmetric gas separation membranes having improved strength |
US4992221A (en) * | 1989-09-27 | 1991-02-12 | Permea, Inc. | Asymmetric gas separation membranes having improved strength |
US5009678A (en) * | 1989-10-31 | 1991-04-23 | Union Carbide Industrial Gases Technology Corporation | Process for recovery of ammonia from an ammonia-containing gas mixture |
US5332547A (en) * | 1991-04-16 | 1994-07-26 | Prolong Systems, Inc. | Controlled atmosphere storage container |
FR2676007B1 (fr) * | 1991-04-30 | 1994-04-08 | Tech Sep | Membrane composite de nanofiltration. |
US5147549A (en) * | 1991-07-22 | 1992-09-15 | Texaco Inc. | Membrane separation process |
US5355781A (en) * | 1992-02-28 | 1994-10-18 | Prolong Systems, Inc. | Controlled atmosphere storage system |
US5244363A (en) * | 1992-05-08 | 1993-09-14 | Prolong Systems, Inc. | Low blow-by compressor |
US5788862A (en) * | 1992-05-13 | 1998-08-04 | Pall Corporation | Filtration medium |
US5480554A (en) * | 1992-05-13 | 1996-01-02 | Pall Corporation | Integrity-testable wet-dry-reversible ultrafiltration membranes and method for testing same |
US5623105A (en) * | 1992-10-21 | 1997-04-22 | Prolong Systems, Inc. | Oxygen/carbon dioxide sensor and controller for a refrigerated controlled atmosphere shipping container |
DK0703819T3 (da) * | 1993-06-15 | 1998-06-02 | Uop Inc | Fremgangsmåde til fremstilling af gasseparationskompositmembraner |
US5482539A (en) † | 1993-09-22 | 1996-01-09 | Enerfex, Inc. | Multiple stage semi-permeable membrane process and apparatus for gas separation |
FR2710549B1 (fr) * | 1993-09-27 | 1996-06-21 | Inst Francais Du Petrole | Membranes asymétriques de haute sélectivité pour la séparation des gaz et un procédé pour leur fabrication. |
US5468430A (en) * | 1994-05-19 | 1995-11-21 | L'air Liquide S.A. | Process of making multicomponent or asymmetric gas separation membranes |
US5702503A (en) * | 1994-06-03 | 1997-12-30 | Uop | Composite gas separation membranes and making thereof |
US5817165A (en) * | 1995-06-15 | 1998-10-06 | Nitto Denko Corporation | Fluorine-containing polyimide gas separation membrane and method of manufacturing the same |
US5785741A (en) * | 1995-07-17 | 1998-07-28 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges, Claude | Process and system for separation and recovery of perfluorocompound gases |
US5858065A (en) * | 1995-07-17 | 1999-01-12 | American Air Liquide | Process and system for separation and recovery of perfluorocompound gases |
US5795920A (en) * | 1995-08-21 | 1998-08-18 | Korea Institute Of Science And Technology | Polymeric dope solution for use in the preparation of an integrally skinned asymmetric membrane |
JPH09122463A (ja) * | 1995-10-31 | 1997-05-13 | Nitto Denko Corp | ポリスルホン系半透膜及びその製造方法 |
JPH09122461A (ja) * | 1995-10-31 | 1997-05-13 | Nitto Denko Corp | ポリイミド系半透膜 |
JPH09225273A (ja) * | 1996-02-23 | 1997-09-02 | Nitto Denko Corp | 積層非対称膜及びその製造方法 |
US5753009A (en) * | 1996-05-14 | 1998-05-19 | New Jersey Institute Of Technology | Method and apparatus for selectively removing a component from a multicomponent gas/vapor mixture |
US5993515A (en) * | 1996-05-14 | 1999-11-30 | New Jersey Institute Of Technology | Apparatus and process for selectively removing a component from a multicomponent aqueous solution by pervaporation |
IE80909B1 (en) * | 1996-06-14 | 1999-06-16 | Air Liquide | An improved process and system for separation and recovery of perfluorocompound gases |
US6118021A (en) * | 1997-07-10 | 2000-09-12 | Membrane Technology And Research, Inc. | Membrane process for argon purging from vinyl acetate reactors |
US5843208A (en) * | 1997-07-24 | 1998-12-01 | Alliedsignal Inc. | Process for recovering sulfur hexafluoride |
US6602418B2 (en) | 2001-01-22 | 2003-08-05 | Bechtel Bwxt Idaho, Llc | Solution dewatering with concomitant ion removal |
US6913736B2 (en) * | 2001-03-30 | 2005-07-05 | Siemens Westinghouse Power Corporation | Metal gas separation membrane module design |
US6916454B2 (en) | 2001-03-30 | 2005-07-12 | Siemens Westinghouse Power Corporation | Metal gas separation membrane |
US7018446B2 (en) * | 2003-09-24 | 2006-03-28 | Siemens Westinghouse Power Corporation | Metal gas separation membrane |
US8096424B2 (en) * | 2006-11-14 | 2012-01-17 | The United States Of America As Represented By The Environmental Protection Agency | Method for fabrication of elastomeric asymmetric membranes from hydrophobic polymers |
KR20100061731A (ko) * | 2007-09-14 | 2010-06-08 | 퀄컴 엠이엠스 테크놀로지스, 인크. | Mems 제조에 이용되는 에칭 방법 |
DE102008041477A1 (de) * | 2008-08-22 | 2010-02-25 | Wacker Chemie Ag | Poröse Membranen aus Organopolysiloxan Copolymeren |
US9630141B2 (en) * | 2009-02-20 | 2017-04-25 | Cameron Solutions, Inc. | Membrane filter element with multiple fiber types |
JP5319380B2 (ja) * | 2009-04-24 | 2013-10-16 | 北越紀州製紙株式会社 | 低坪量エアフィルタ用濾材 |
WO2012151482A2 (en) | 2011-05-04 | 2012-11-08 | Cornell University | Multiblock copolymer films, methods of making same, and uses thereof |
KR101514801B1 (ko) * | 2013-06-25 | 2015-04-24 | (주)파인텍 | 과불화화합물의 분리 및 재활용시스템 |
US11072565B2 (en) | 2015-02-27 | 2021-07-27 | General Electric Company | Ceramic matrix composite structures with controlled microstructures fabricated using chemical vapor infiltration (CVI) |
CN105217729B (zh) * | 2015-09-08 | 2017-07-28 | 浙江浙能技术研究院有限公司 | 补给水氧气及二氧化碳去除装置 |
CN105233707A (zh) * | 2015-09-17 | 2016-01-13 | 重庆润泽医药有限公司 | 一种聚四氟乙烯膜的制备方法 |
WO2017070640A1 (en) * | 2015-10-23 | 2017-04-27 | Eccrine Systems, Inc. | Devices capable of sample concentration for extended sensing of sweat analytes |
SG10202010709UA (en) | 2016-04-28 | 2020-11-27 | Terapore Tech Inc | Charged isoporous materials for electrostatic separations |
MX2019005774A (es) | 2016-11-17 | 2020-02-07 | Terapore Tech Inc | Películas isoporosas de copolímero de bloques autoensamblados que contienen aditivos hidrofílicos de alto peso molecular y métodos para hacer las mismas. |
MX2019010056A (es) | 2017-02-22 | 2019-10-09 | Terapore Tech Inc | Membranas de mbp unido por ligando, usos y metodo de elaboracion. |
CA3062637A1 (en) | 2017-05-12 | 2018-11-15 | Terapore Technologies, Inc. | Chemically resistant fluorinated multiblock polymer structures, methods of manufacturing and use |
US10682606B2 (en) * | 2017-07-07 | 2020-06-16 | Saudi Arabian Oil Company | Multilayer aromatic polyamide thin-film composite membranes for separation of gas mixtures |
WO2019060390A1 (en) | 2017-09-19 | 2019-03-28 | Terapore Technologies, Inc. | CHEMICALLY RESISTANT ISOPOROUS CROSSLINKED CROSSLINK COPOLYMER STRUCTURE |
KR101984893B1 (ko) | 2017-10-27 | 2019-05-31 | (주)에어레인 | 바이오가스 고질화용 중공사 복합막, 이를 포함하는 막모듈 및 그 제조방법 |
CN111936226A (zh) * | 2018-02-22 | 2020-11-13 | 博里利斯股份公司 | 方法 |
MX2020009506A (es) * | 2018-03-12 | 2021-01-15 | Terapore Tech Inc | Materiales de copolímero de bloques asimétricos mesoporosos isoporosos con macrohuecos y método para fabricarlo. |
BR112021005265A2 (pt) * | 2018-10-04 | 2021-06-15 | Ngk Insulators, Ltd. | método de separação de gás e separador de gás |
US12116326B2 (en) | 2021-11-22 | 2024-10-15 | Saudi Arabian Oil Company | Conversion of hydrogen sulfide and carbon dioxide into hydrocarbons using non-thermal plasma and a catalyst |
CN114534526B (zh) * | 2022-03-23 | 2023-03-28 | 烟台大学 | 一种非对称结构聚醚醚酮中空纤维膜 |
Family Cites Families (29)
Publication number | Priority date | Publication date | Assignee | Title |
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NL271831A (de) * | 1960-11-29 | |||
US3615024A (en) * | 1968-08-26 | 1971-10-26 | Amicon Corp | High flow membrane |
US3551331A (en) * | 1969-09-22 | 1970-12-29 | Du Pont | Reverse osmosis separations using a treated polyamide membrane |
US3709774A (en) * | 1970-05-13 | 1973-01-09 | Gen Electric | Preparation of asymmetric polymer membranes |
US3752784A (en) * | 1970-12-23 | 1973-08-14 | Du Pont | Process for preparing microporous opencelled cellular polymeric structures |
US3792135A (en) * | 1972-01-06 | 1974-02-12 | Eastman Kodak Co | Process for manufacturing cellulosic reverse osmosis membranes using a very high temperature initial aqueous quench |
GB1417396A (en) * | 1972-01-12 | 1975-12-10 | Ici Ltd | Asymmetric membranous articles and methods for their manufacture |
US3917777A (en) * | 1972-12-13 | 1975-11-04 | Kobe Steel Ltd | Process for the preparation of dry semipermeable |
JPS5331105B2 (de) * | 1973-03-27 | 1978-08-31 | ||
JPS518179A (en) * | 1974-07-11 | 1976-01-22 | Daicel Ltd | Sentakutokaseikobunshimakuoyobisono seizoho |
US3980456A (en) * | 1975-03-31 | 1976-09-14 | General Electric Company | Method for sealing breaches in multi-layer ultrathin membrane composites |
ZA762209B (en) * | 1975-04-23 | 1977-04-27 | Envirogenics Syst | Gas separation membrane |
US4230463A (en) * | 1977-09-13 | 1980-10-28 | Monsanto Company | Multicomponent membranes for gas separations |
US4157960A (en) * | 1977-11-30 | 1979-06-12 | Monsanto Company | Method for enhancing membrane separation |
JPS54145379A (en) * | 1978-05-02 | 1979-11-13 | Asahi Chem Ind Co Ltd | Aromatic polysulfone hollow fiber semipermeable membrane |
IL59581A0 (en) * | 1979-03-28 | 1980-06-30 | Monsanto Co | Methods for preparing anisotropic membranes and membranes prepared therefrom |
US4364759A (en) * | 1979-03-28 | 1982-12-21 | Monsanto Company | Methods for preparing anisotropic hollow fiber membranes comprising polymer of acrylonitrile and styrene and hollow fiber membranes produced therefrom |
US4629563B1 (en) * | 1980-03-14 | 1997-06-03 | Memtec North America | Asymmetric membranes |
DE3028213C2 (de) * | 1980-07-25 | 1990-12-06 | Akzo Gmbh, 5600 Wuppertal | Verfahren zur Herstellung einer Ultrafiltrationsmembran aus Polyamid und daraus hergestellte Membran |
JPS5824305A (ja) * | 1981-07-31 | 1983-02-14 | Daicel Chem Ind Ltd | ポリスルホン樹脂半透膜の製造法 |
JPS59189903A (ja) * | 1983-04-09 | 1984-10-27 | Kanegafuchi Chem Ind Co Ltd | 中空糸状フイルタ−およびその製法 |
US4544484A (en) * | 1983-06-24 | 1985-10-01 | E. I. Du Pont De Nemours And Company | Reverse osmosis membrane quenching |
US4472175A (en) * | 1983-06-30 | 1984-09-18 | Monsanto Company | Asymmetric gas separation membranes |
ATE31146T1 (de) * | 1983-06-30 | 1987-12-15 | Monsanto Co | Membranen auf der basis von amorphen polyarylaethern,welche an die arylgruppen substituiert sind. |
US4568579A (en) * | 1983-11-03 | 1986-02-04 | Owens-Illinois, Inc. | Asymmetrical layered structures of polyalkylene sulfone resins |
JPS60172312A (ja) * | 1984-02-17 | 1985-09-05 | Toyobo Co Ltd | ポリスルホン中空糸膜の製造法 |
US4527999A (en) * | 1984-03-23 | 1985-07-09 | Abcor, Inc. | Separation membrane and method of preparing and using same |
DE3420373C2 (de) * | 1984-06-01 | 1986-09-18 | Gkss - Forschungszentrum Geesthacht Gmbh, 2054 Geesthacht | Verfahren zur Herstellung einer integralasymmetrischen Membran zur Trennung von Gasen |
JPS61141907A (ja) * | 1984-12-14 | 1986-06-28 | Sumitomo Bakelite Co Ltd | 中空繊維状分離膜の製造方法 |
-
1987
- 1987-08-12 DE DE8787870113T patent/DE3782120T2/de not_active Expired - Lifetime
- 1987-08-12 EP EP87870113A patent/EP0257012B1/de not_active Expired - Lifetime
- 1987-08-12 ES ES87870113T patent/ES2052605T3/es not_active Expired - Lifetime
- 1987-08-14 IL IL8783542A patent/IL83542A/xx unknown
- 1987-08-14 AU AU76871/87A patent/AU596859B2/en not_active Ceased
- 1987-08-14 AR AR87308436A patent/AR244564A1/es active
- 1987-08-14 NO NO873424A patent/NO173003C/no unknown
- 1987-08-14 TR TR573/87A patent/TR23207A/xx unknown
- 1987-08-14 KR KR1019870008966A patent/KR900008712B1/ko not_active IP Right Cessation
- 1987-08-14 CN CN87106272A patent/CN1009430B/zh not_active Expired
- 1987-08-14 MX MX007745A patent/MX169433B/es unknown
- 1987-08-14 CA CA000544614A patent/CA1321686C/en not_active Expired - Fee Related
- 1987-08-14 BR BR878704235A patent/BR8704235A/pt not_active Application Discontinuation
- 1987-08-15 JP JP62203355A patent/JP2635051B2/ja not_active Expired - Lifetime
-
1989
- 1989-01-12 US US07/296,843 patent/US4880441A/en not_active Expired - Lifetime
-
1992
- 1992-12-16 GR GR920402933T patent/GR3006559T3/el unknown
Also Published As
Publication number | Publication date |
---|---|
NO173003B (no) | 1993-07-05 |
IL83542A0 (en) | 1988-01-31 |
CN87106272A (zh) | 1988-03-02 |
AU596859B2 (en) | 1990-05-17 |
US4880441A (en) | 1989-11-14 |
NO873424L (no) | 1988-02-16 |
MX169433B (es) | 1993-07-05 |
GR3006559T3 (de) | 1993-06-30 |
AU7687187A (en) | 1988-02-18 |
KR890001614A (ko) | 1989-03-28 |
IL83542A (en) | 1990-12-23 |
NO173003C (no) | 1993-10-13 |
TR23207A (tr) | 1989-06-19 |
JPS63107723A (ja) | 1988-05-12 |
CN1009430B (zh) | 1990-09-05 |
EP0257012B1 (de) | 1992-10-07 |
AR244564A1 (es) | 1993-11-30 |
BR8704235A (pt) | 1988-04-12 |
ES2052605T3 (es) | 1994-07-16 |
CA1321686C (en) | 1993-08-31 |
KR900008712B1 (ko) | 1990-11-27 |
JP2635051B2 (ja) | 1997-07-30 |
EP0257012A3 (en) | 1989-03-22 |
DE3782120T2 (de) | 1993-02-11 |
NO873424D0 (no) | 1987-08-14 |
EP0257012A2 (de) | 1988-02-24 |
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