DE3773890D1 - Durch uebergangsmetallkomplexe katalysierte hydroformylierung. - Google Patents
Durch uebergangsmetallkomplexe katalysierte hydroformylierung.Info
- Publication number
- DE3773890D1 DE3773890D1 DE8787903774T DE3773890T DE3773890D1 DE 3773890 D1 DE3773890 D1 DE 3773890D1 DE 8787903774 T DE8787903774 T DE 8787903774T DE 3773890 T DE3773890 T DE 3773890T DE 3773890 D1 DE3773890 D1 DE 3773890D1
- Authority
- DE
- Germany
- Prior art keywords
- transition metal
- metal complex
- hydroformylation catalyzed
- hydroformylation
- catalyzed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000007037 hydroformylation reaction Methods 0.000 title 1
- 229910052723 transition metal Inorganic materials 0.000 title 1
- 150000003624 transition metals Chemical class 0.000 title 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/78—Separation; Purification; Stabilisation; Use of additives
- C07C45/81—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
- C07C45/82—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Crystallography & Structural Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US06/865,061 US4717775A (en) | 1984-12-28 | 1986-05-20 | Transition metal complex catalyzed reactions |
US07/046,821 US4774361A (en) | 1986-05-20 | 1987-05-11 | Transition metal complex catalyzed reactions |
PCT/US1987/001124 WO1987007261A2 (en) | 1986-05-20 | 1987-05-19 | Transition metal complex catalyzed hydroformulation |
Publications (1)
Publication Number | Publication Date |
---|---|
DE3773890D1 true DE3773890D1 (de) | 1991-11-21 |
Family
ID=26724327
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE8787903774T Expired - Lifetime DE3773890D1 (de) | 1986-05-20 | 1987-05-19 | Durch uebergangsmetallkomplexe katalysierte hydroformylierung. |
Country Status (12)
Country | Link |
---|---|
US (1) | US4774361A (forum.php) |
EP (1) | EP0276231B1 (forum.php) |
JP (1) | JPS63503385A (forum.php) |
CN (1) | CN1010011B (forum.php) |
AU (1) | AU613312B2 (forum.php) |
CA (1) | CA1312094C (forum.php) |
DE (1) | DE3773890D1 (forum.php) |
ES (1) | ES2004935A6 (forum.php) |
IN (1) | IN169727B (forum.php) |
MX (1) | MX166107B (forum.php) |
NO (1) | NO166583C (forum.php) |
WO (1) | WO1987007261A2 (forum.php) |
Families Citing this family (85)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4835299A (en) * | 1987-03-31 | 1989-05-30 | Union Carbide Corporation | Process for purifying tertiary organophosphites |
IT1237530B (it) * | 1989-12-12 | 1993-06-08 | Eniricerche Spa | Procedimento per la sintesi diretta di alcoli da olefine,ossidi di carbonio e idrogeno,promossa da un catalizzatore di rodio supportato |
US5210318A (en) * | 1990-05-04 | 1993-05-11 | Union Carbide Chemicals & Plastics Technology Corporation | Catalysts and processes useful in producing 1,3-diols and/or 3-hydroxyldehydes |
US5087763A (en) * | 1990-11-09 | 1992-02-11 | Union Carbide Chemicals & Plastics Technology Corporation | Hydroformylation process |
JP2946790B2 (ja) * | 1991-03-14 | 1999-09-06 | 三菱化学株式会社 | アルデヒド類の製造法 |
US5360938A (en) * | 1991-08-21 | 1994-11-01 | Union Carbide Chemicals & Plastics Technology Corporation | Asymmetric syntheses |
GB9119955D0 (en) * | 1991-09-18 | 1991-10-30 | Imperial College | Treatment of aqueous supplies containing organic material |
US5243099A (en) * | 1991-12-06 | 1993-09-07 | Union Carbide Chemicals & Plastics Technology Corporation | Synthesis of alpha-substituted alkadienes |
US5169981A (en) * | 1991-12-06 | 1992-12-08 | Union Carbide Chemicals & Plastics Technology Corporation | Synthesis of alpha-substituted alkadienes |
US5756855A (en) | 1994-08-19 | 1998-05-26 | Union Carbide Chemicals & Plastics Technology Corporation | Stabilization of phosphite ligands in hydroformylation process |
US5672766A (en) * | 1994-12-12 | 1997-09-30 | Mitsubishi Chemical Corporation | Method for producing aldehydes |
KR970703805A (ko) * | 1995-05-01 | 1997-08-09 | 유니온 카바이드 케미칼즈 앤드 플라스틱스 테크놀러지 코포레이션 | 막 분리방법(Membrane Separation) |
US5739352A (en) * | 1995-10-19 | 1998-04-14 | United Carbide Chemicals & Plastics Technology Corporation | Process for preparing carboxylic acids |
DE19605435A1 (de) * | 1996-02-14 | 1997-08-21 | Basf Ag | Verfahren zur Herstellung von Aldehyden durch Hydroformylierung mit einem Rhodiumkatalysator und Wiedergewinnung des Rhodiumkatalysators durch Extraktion |
US6090987A (en) * | 1998-07-06 | 2000-07-18 | Union Carbide Chemicals & Plastics Technology Corporation | Metal-ligand complex catalyzed processes |
CN1163463C (zh) * | 1998-12-10 | 2004-08-25 | 三菱化学株式会社 | 醛的制备方法 |
JP3921853B2 (ja) * | 1998-12-10 | 2007-05-30 | 三菱化学株式会社 | アルデヒド類及びアルコール類の製造方法 |
GB9918229D0 (en) † | 1999-08-04 | 1999-10-06 | Ici Plc | Improvements relating to metal-compound catalysed processes |
DE19954510A1 (de) | 1999-11-12 | 2001-05-17 | Oxeno Olefinchemie Gmbh | Verfahren zur katalytischen Herstellung von Aldehyden aus Olefinen unter Einsatz von Ligandenmischungen |
EP2453320B1 (en) | 2000-06-27 | 2016-06-29 | Dai Nippon Printing Co., Ltd. | Multilayer volume hologram, and label for multilayer volume hologram fabrication |
EP1249441A1 (en) | 2001-04-13 | 2002-10-16 | Dsm N.V. | Continuous hydroformylation process |
DE10220801A1 (de) * | 2002-05-10 | 2003-11-20 | Oxeno Olefinchemie Gmbh | Verfahren zur Rhodium-katalysierten Hydroformylierung von Olefinen unter Reduzierung der Rhodiumverluste |
JP2005537330A (ja) | 2002-08-31 | 2005-12-08 | オクセノ オレフィンヒェミー ゲゼルシャフト ミット ベシュレンクテル ハフツング | 環状カルボン酸エステルの存在で非変性金属錯体により触媒活性されるオレフィン不飽和化合物のヒドロホルミル化によりアルデヒドを製造する方法 |
PL206145B1 (pl) * | 2002-08-31 | 2010-07-30 | Oxeno Olefinchemie Gmbhoxeno Olefinchemie Gmbh | Sposób hydroformylowania związków nienasyconych olefinowo, w szczególności olefin, w obecności cyklicznych estrów kwasów karboksylowych |
CA2513348A1 (en) * | 2003-01-16 | 2004-07-29 | Teijin Fibers Limited | Differential-shrinkage polyester combined filament yarn |
EP2308817B1 (en) | 2003-07-03 | 2016-10-05 | Dow Technology Investments LLC | Minimization of ligand degradation products, or reversion of same to useful phosphine ligands |
DE10349343A1 (de) * | 2003-10-23 | 2005-06-02 | Basf Ag | Stabilisierung von Hydroformylierungskatalysatoren auf Basis von Phosphoramiditliganden |
WO2006020287A1 (en) | 2004-08-02 | 2006-02-23 | Union Carbide Chemicals & Plastics Technology Corporation | Stabilization of a hydroformylation process |
CN101657407B (zh) * | 2007-03-20 | 2014-02-12 | 陶氏技术投资有限公司 | 改善对产物同分异构体的控制的加氢甲酰基化方法 |
KR100964098B1 (ko) * | 2007-04-09 | 2010-06-16 | 주식회사 엘지화학 | 포스파이트 리간드를 포함하는 촉매 조성물 및 이를 이용한히드로포르밀화 방법 |
PL2297077T3 (pl) | 2008-07-03 | 2014-11-28 | Dow Technology Investments Llc | Sposób regulowania ilości substancji ciężkich w strumieniu powrotnym katalizatora |
CN102281948B (zh) | 2008-11-14 | 2015-11-25 | 堪萨斯大学 | 聚合物负载的过渡金属催化剂络合物及使用方法 |
US8513469B2 (en) | 2009-03-31 | 2013-08-20 | Dow Technology Investments Llc | Hydroformylation process with doubly open-ended bisphosphite ligand |
US7928267B1 (en) * | 2009-06-22 | 2011-04-19 | Eastman Chemical Company | Phosphite containing catalysts for hydroformylation processes |
CN102574878A (zh) | 2009-10-16 | 2012-07-11 | 陶氏技术投资有限责任公司 | 气相加氢甲酰化方法 |
KR101815328B1 (ko) | 2009-12-22 | 2018-01-04 | 다우 테크놀로지 인베스트먼츠 엘엘씨. | 합성가스 분압의 조절에 의한 혼합된 리간드 하이드로폼일화 공정에서의 노말:아이소 알데하이드 비의 조절 방법 |
PL2942343T3 (pl) | 2009-12-22 | 2020-02-28 | Dow Technology Investments Llc | Kontrolowanie stosunku aldehydu normalnego : aldehydu izo w procesie hydroformylowania z ligandami mieszanymi |
WO2011087696A1 (en) | 2009-12-22 | 2011-07-21 | Dow Technology Investments Llc | Controlling the normal:iso aldehyde ratio in a mixed ligand hydroformylation process by controlling the olefin partial pressure |
JP2014502254A (ja) | 2010-10-05 | 2014-01-30 | ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー | ヒドロホルミル化の方法 |
MX346922B (es) | 2010-11-12 | 2017-04-05 | Dow Technology Investments Llc | Moderación de suciedad en procesos de hidroformilación mediante adición de agua. |
SA112330271B1 (ar) | 2011-04-18 | 2015-02-09 | داو تكنولوجى انفستمنتس ال ال سى | تخفيف التلوث في عمليات هيدروفورملة عن طريق إضافة الماء |
SG10201607488XA (en) | 2012-03-07 | 2016-10-28 | Basf Se | Method for thermal integration in the hydrogenation and distillation of c3-c20 aldehydes |
SG11201405863QA (en) | 2012-04-12 | 2014-11-27 | Basf Se | Method for replenishing the catalyst in continuous hydroformylation |
US8889917B2 (en) | 2012-04-12 | 2014-11-18 | Basf Se | Method of supplementing the catalyst in continuous hydroformylation |
MX358981B (es) | 2012-06-04 | 2018-09-11 | Dow Technology Investments Llc | Proceso de hidroformilacion. |
RU2639874C2 (ru) * | 2012-08-29 | 2017-12-25 | Дау Текнолоджи Инвестментс Ллс | Способ получения катализатора |
IN2015DN02639A (forum.php) | 2012-09-25 | 2015-09-18 | Dow Technology Investments Llc | |
EP2740535A1 (en) | 2012-12-04 | 2014-06-11 | Dow Technology Investments LLC | Bidentate ligands for hydroformylation of ethylene |
KR102098429B1 (ko) | 2012-12-06 | 2020-04-07 | 다우 테크놀로지 인베스트먼츠 엘엘씨. | 하이드로포밀화 방법 |
CN104045532B (zh) | 2013-03-15 | 2018-05-25 | 陶氏技术投资有限责任公司 | 加氢甲酰化方法 |
EP3083542A1 (en) | 2013-12-19 | 2016-10-26 | Dow Technology Investments LLC | Hydroformylation process |
CN104725170B (zh) | 2013-12-19 | 2019-08-23 | 陶氏技术投资有限责任公司 | 加氢甲酰化方法 |
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JP6908602B2 (ja) | 2015-11-10 | 2021-07-28 | ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー | アルデヒドの生成プロセス |
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TW201840362A (zh) | 2016-11-08 | 2018-11-16 | 美商陶氏科技投資有限公司 | 使去活化的氫甲醯化催化劑溶液再生的方法 |
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RU2020117417A (ru) | 2017-11-13 | 2021-11-29 | Дау Текнолоджи Инвестментс Ллк | Способы извлечения родия из процесса гидроформилирования |
TWI793216B (zh) | 2017-12-07 | 2023-02-21 | 美商陶氏科技投資公司 | 氫甲醯化方法 |
US12090473B2 (en) | 2018-05-30 | 2024-09-17 | Dow Technology Investments Llc | Catalyst compositions and hydroformylation processes |
MX2020011380A (es) | 2018-05-30 | 2020-11-24 | Dow Technology Investments Llc | Metodos de control de procesos de hidroformilacion. |
CN112074347A (zh) | 2018-05-30 | 2020-12-11 | 陶氏技术投资有限责任公司 | 在加氢甲酰化过程中减缓催化剂失活和/或减缓四膦配位体使用的方法 |
CN113179638B (zh) * | 2018-11-29 | 2023-11-28 | 陶氏技术投资有限责任公司 | 加氢甲酰化工艺 |
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CN116635362A (zh) | 2020-12-14 | 2023-08-22 | 陶氏技术投资有限责任公司 | 改进加氢甲酰化方法中的催化金属可计量性的方法 |
MX2024005136A (es) | 2021-11-11 | 2024-05-16 | Dow Technology Investments Llc | Procesos para recuperar rodio a partir de procesos de hidroformilacion. |
CN118317834A (zh) | 2021-12-16 | 2024-07-09 | 陶氏技术投资有限责任公司 | 化合物、包含此类化合物的过渡金属络合物加氢甲酰化催化剂前体组合物和加氢甲酰化方法 |
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WO2025029349A1 (en) | 2023-08-03 | 2025-02-06 | Dow Technology Investments Llc | Hydroformylation process |
WO2025029369A1 (en) | 2023-08-03 | 2025-02-06 | Dow Technology Investments Llc | Process for improving rhodium/phosphite- based homogenous hydroformylation catalyst activity |
GB202404300D0 (en) | 2024-03-26 | 2024-05-08 | Johnson Matthey Davy Technologies Ltd | Process for the production of 2-alkylalkanol |
Family Cites Families (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE156528C (forum.php) * | ||||
US4482748A (en) * | 1967-05-29 | 1984-11-13 | Celanese Corporation | Hydrocarbonylation |
DE2145532C3 (de) * | 1971-09-11 | 1975-02-20 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Aufarbeitung von Hydroformylierungsgemischen |
DE2326489A1 (de) * | 1973-05-24 | 1974-12-12 | Ernst Prof Dr Bayer | Verfahren zur katalyse unter verwendung von loeslichen metallverbindungen synthetischer polymerer |
JPS5638576B2 (forum.php) * | 1974-07-25 | 1981-09-08 | ||
US4148830A (en) * | 1975-03-07 | 1979-04-10 | Union Carbide Corporation | Hydroformylation of olefins |
JPS6022688B2 (ja) * | 1976-12-29 | 1985-06-03 | 和光純薬工業株式会社 | アルデヒド化合物の蒸留方法 |
EP0008407B1 (de) * | 1978-08-17 | 1983-10-26 | Heyl Chemisch-pharmazeutische Fabrik GmbH & Co. KG | Polymere Hydrierkatalysatoren, Verfahren zur Herstellung dieser Katalysatoren und ihre Verwendung für katalytische Hydrierungen |
US4235744A (en) * | 1978-10-30 | 1980-11-25 | Standard Oil Company (Ohio) | Carbonylation of olefinically unsaturated compounds |
US4504684A (en) * | 1982-01-06 | 1985-03-12 | The Standard Oil Company | Metal coordination polymers as hydroformylation and hydrogenation catalysts |
ATE28183T1 (de) * | 1982-06-11 | 1987-07-15 | Davy Mckee London | Hydroformylierungsverfahren. |
US4528403A (en) * | 1982-10-21 | 1985-07-09 | Mitsubishi Chemical Industries Ltd. | Hydroformylation process for preparation of aldehydes and alcohols |
US4528404A (en) * | 1983-03-16 | 1985-07-09 | Exxon Research And Engineering Co. | High temperature hydroformylation in the presence of triarylphosphine rhodium carbonyl hydride complex catalyst systems |
GB8334359D0 (en) * | 1983-12-23 | 1984-02-01 | Davy Mckee Ltd | Process |
US4599206A (en) * | 1984-02-17 | 1986-07-08 | Union Carbide Corporation | Transition metal complex catalyzed reactions |
US4599456A (en) * | 1984-12-20 | 1986-07-08 | Phillips Petroleum Company | Novel aldehyde-phosphine compositions and uses therefor |
US4668651A (en) * | 1985-09-05 | 1987-05-26 | Union Carbide Corporation | Transition metal complex catalyzed processes |
US4613701A (en) * | 1985-09-19 | 1986-09-23 | Celanese Corporation | Recovery of rhodium from hydroformylation reaction product |
-
1987
- 1987-05-11 US US07/046,821 patent/US4774361A/en not_active Expired - Lifetime
- 1987-05-19 AU AU74898/87A patent/AU613312B2/en not_active Ceased
- 1987-05-19 WO PCT/US1987/001124 patent/WO1987007261A2/en active IP Right Grant
- 1987-05-19 JP JP62503400A patent/JPS63503385A/ja active Granted
- 1987-05-19 EP EP87903774A patent/EP0276231B1/en not_active Expired - Lifetime
- 1987-05-19 DE DE8787903774T patent/DE3773890D1/de not_active Expired - Lifetime
- 1987-05-20 IN IN373/MAS/87A patent/IN169727B/en unknown
- 1987-05-20 CN CN87104311A patent/CN1010011B/zh not_active Expired
- 1987-05-20 ES ES8701486A patent/ES2004935A6/es not_active Expired
- 1987-05-20 MX MX006566A patent/MX166107B/es unknown
- 1987-05-20 CA CA000537549A patent/CA1312094C/en not_active Expired - Lifetime
-
1988
- 1988-01-19 NO NO880207A patent/NO166583C/no unknown
Also Published As
Publication number | Publication date |
---|---|
NO880207L (no) | 1988-01-19 |
US4774361A (en) | 1988-09-27 |
CA1312094C (en) | 1992-12-29 |
IN169727B (forum.php) | 1991-12-14 |
AU7489887A (en) | 1987-12-22 |
NO166583B (no) | 1991-05-06 |
JPS63503385A (ja) | 1988-12-08 |
EP0276231B1 (en) | 1991-10-16 |
WO1987007261A3 (en) | 1988-04-07 |
EP0276231A1 (en) | 1988-08-03 |
NO880207D0 (no) | 1988-01-19 |
NO166583C (no) | 1991-08-14 |
ES2004935A6 (es) | 1989-02-16 |
CN87104311A (zh) | 1988-06-08 |
WO1987007261A2 (en) | 1987-12-03 |
AU613312B2 (en) | 1991-08-01 |
MX166107B (es) | 1992-12-21 |
JPH0548215B2 (forum.php) | 1993-07-20 |
CN1010011B (zh) | 1990-10-17 |
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