DE3540973A1 - Simultane so(pfeil abwaerts)2(pfeil abwaerts)- und no(pfeil abwaerts)x(pfeil abwaerts)-abscheidung bei rauchgasen, die mit hohem no(pfeil abwaerts)x(pfeil abwaerts) und hcl belastet sind - Google Patents
Simultane so(pfeil abwaerts)2(pfeil abwaerts)- und no(pfeil abwaerts)x(pfeil abwaerts)-abscheidung bei rauchgasen, die mit hohem no(pfeil abwaerts)x(pfeil abwaerts) und hcl belastet sindInfo
- Publication number
- DE3540973A1 DE3540973A1 DE19853540973 DE3540973A DE3540973A1 DE 3540973 A1 DE3540973 A1 DE 3540973A1 DE 19853540973 DE19853540973 DE 19853540973 DE 3540973 A DE3540973 A DE 3540973A DE 3540973 A1 DE3540973 A1 DE 3540973A1
- Authority
- DE
- Germany
- Prior art keywords
- iron
- nox
- hcl
- flue gases
- scrubbing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003546 flue gas Substances 0.000 title claims abstract description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229910052742 iron Inorganic materials 0.000 claims abstract description 10
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 claims abstract description 6
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims abstract description 4
- 238000005868 electrolysis reaction Methods 0.000 claims abstract description 4
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims abstract description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract 6
- -1 iron chelate complex salts Chemical class 0.000 claims abstract 4
- 238000010521 absorption reaction Methods 0.000 claims abstract 2
- 238000005406 washing Methods 0.000 claims description 9
- 239000003513 alkali Substances 0.000 claims description 3
- 239000007789 gas Substances 0.000 claims description 3
- 229910052801 chlorine Inorganic materials 0.000 claims description 2
- 239000000460 chlorine Substances 0.000 claims description 2
- 150000001805 chlorine compounds Chemical class 0.000 claims description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 1
- 238000004140 cleaning Methods 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract description 5
- 239000013522 chelant Substances 0.000 abstract description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract description 3
- 230000002378 acidificating effect Effects 0.000 abstract description 3
- 238000001704 evaporation Methods 0.000 abstract description 3
- 230000008020 evaporation Effects 0.000 abstract description 3
- 229910001514 alkali metal chloride Inorganic materials 0.000 abstract description 2
- 238000011144 upstream manufacturing Methods 0.000 abstract description 2
- 238000005201 scrubbing Methods 0.000 abstract 5
- 238000002485 combustion reaction Methods 0.000 abstract 1
- 239000007788 liquid Substances 0.000 description 3
- 229910001854 alkali hydroxide Inorganic materials 0.000 description 2
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000009938 salting Methods 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/60—Simultaneously removing sulfur oxides and nitrogen oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/68—Halogens or halogen compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/18—Nature of the water, waste water, sewage or sludge to be treated from the purification of gaseous effluents
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Environmental & Geological Engineering (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treating Waste Gases (AREA)
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19853540973 DE3540973A1 (de) | 1984-12-24 | 1985-11-19 | Simultane so(pfeil abwaerts)2(pfeil abwaerts)- und no(pfeil abwaerts)x(pfeil abwaerts)-abscheidung bei rauchgasen, die mit hohem no(pfeil abwaerts)x(pfeil abwaerts) und hcl belastet sind |
PCT/EP1986/000572 WO1987002269A1 (en) | 1985-10-11 | 1986-10-08 | Process for simultaneous extraction of so2 and nox contained in waste gases |
EP86905803A EP0241496A1 (de) | 1985-10-11 | 1986-10-08 | Verfahren zur simultanen so2- und nox-abscheidung aus rauchgasen |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3447425A DE3447425C2 (de) | 1984-12-24 | 1984-12-24 | Verfahren zur Verminderung von Stickstoffoxiden in Rauchgasen |
DE19853540973 DE3540973A1 (de) | 1984-12-24 | 1985-11-19 | Simultane so(pfeil abwaerts)2(pfeil abwaerts)- und no(pfeil abwaerts)x(pfeil abwaerts)-abscheidung bei rauchgasen, die mit hohem no(pfeil abwaerts)x(pfeil abwaerts) und hcl belastet sind |
Publications (2)
Publication Number | Publication Date |
---|---|
DE3540973A1 true DE3540973A1 (de) | 1987-05-21 |
DE3540973C2 DE3540973C2 (enrdf_load_stackoverflow) | 1988-06-30 |
Family
ID=25827789
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE19853540973 Granted DE3540973A1 (de) | 1984-12-24 | 1985-11-19 | Simultane so(pfeil abwaerts)2(pfeil abwaerts)- und no(pfeil abwaerts)x(pfeil abwaerts)-abscheidung bei rauchgasen, die mit hohem no(pfeil abwaerts)x(pfeil abwaerts) und hcl belastet sind |
Country Status (1)
Country | Link |
---|---|
DE (1) | DE3540973A1 (enrdf_load_stackoverflow) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0667179A1 (en) * | 1990-06-25 | 1995-08-16 | Mitsubishi Jukogyo Kabushiki Kaisha | Method for desulfurizing exhaust smoke |
CN107522297A (zh) * | 2017-09-15 | 2017-12-29 | 北京高能时代环境技术股份有限公司 | 一种利用烟道气进行脱硫废水软化的系统 |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3921180A1 (de) * | 1989-06-28 | 1991-01-03 | Gsb Ges Zur Beseitigung Von So | Verfahren und anlage zur reinigung von schadstoffhaltigen abgasen unter vermeidung von salzrueckstaenden |
DE4033489A1 (de) * | 1990-10-20 | 1992-04-23 | Kernforschungsz Karlsruhe | Verfahren zur reinigung von rauchgas |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2353528A1 (de) * | 1972-10-25 | 1974-05-16 | Hitachi Ltd | Verfahren zur behandlung von abgasen |
US3941667A (en) * | 1975-03-21 | 1976-03-02 | Friedrich Uhde Gmbh | Method for the reprocessing of cell liquor from diaphragm cell electrolysis plants |
DE2604371A1 (de) * | 1975-02-07 | 1976-08-26 | Andco Inc | Verfahren zum elektrochemischen entfernen verunreinigender ionen aus einem ionisierenden medium sowie elektrochemische zelle zur durchfuehrung des verfahrens |
CH585582A5 (enrdf_load_stackoverflow) * | 1972-09-15 | 1977-03-15 | Dart Ind Inc | |
DE2710328A1 (de) * | 1976-03-09 | 1977-09-15 | Solex Res Corp Japan | Verfahren zur wiedergewinnung von verbrauchter schwefelsaeure und salzsaeure |
DD131041A1 (de) * | 1977-01-31 | 1978-05-24 | Elisabeth Gerber | Verfahren zur aufbereitung von eisenchlorid-salzsaeureloesung |
DE3110320A1 (de) * | 1980-03-17 | 1982-01-07 | National Research Development Corp., London | Anoden-unterstuetzte kationenreduktion |
-
1985
- 1985-11-19 DE DE19853540973 patent/DE3540973A1/de active Granted
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CH585582A5 (enrdf_load_stackoverflow) * | 1972-09-15 | 1977-03-15 | Dart Ind Inc | |
DE2353528A1 (de) * | 1972-10-25 | 1974-05-16 | Hitachi Ltd | Verfahren zur behandlung von abgasen |
DE2604371A1 (de) * | 1975-02-07 | 1976-08-26 | Andco Inc | Verfahren zum elektrochemischen entfernen verunreinigender ionen aus einem ionisierenden medium sowie elektrochemische zelle zur durchfuehrung des verfahrens |
US3941667A (en) * | 1975-03-21 | 1976-03-02 | Friedrich Uhde Gmbh | Method for the reprocessing of cell liquor from diaphragm cell electrolysis plants |
DE2710328A1 (de) * | 1976-03-09 | 1977-09-15 | Solex Res Corp Japan | Verfahren zur wiedergewinnung von verbrauchter schwefelsaeure und salzsaeure |
DD131041A1 (de) * | 1977-01-31 | 1978-05-24 | Elisabeth Gerber | Verfahren zur aufbereitung von eisenchlorid-salzsaeureloesung |
DE3110320A1 (de) * | 1980-03-17 | 1982-01-07 | National Research Development Corp., London | Anoden-unterstuetzte kationenreduktion |
Non-Patent Citations (1)
Title |
---|
DE-Z: Chem.-Ing.Techn., 57, 1985, Nr.9, S.717-727 * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0667179A1 (en) * | 1990-06-25 | 1995-08-16 | Mitsubishi Jukogyo Kabushiki Kaisha | Method for desulfurizing exhaust smoke |
CN107522297A (zh) * | 2017-09-15 | 2017-12-29 | 北京高能时代环境技术股份有限公司 | 一种利用烟道气进行脱硫废水软化的系统 |
Also Published As
Publication number | Publication date |
---|---|
DE3540973C2 (enrdf_load_stackoverflow) | 1988-06-30 |
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