DE3512917A1 - Makroemulsionen - Google Patents
MakroemulsionenInfo
- Publication number
- DE3512917A1 DE3512917A1 DE19853512917 DE3512917A DE3512917A1 DE 3512917 A1 DE3512917 A1 DE 3512917A1 DE 19853512917 DE19853512917 DE 19853512917 DE 3512917 A DE3512917 A DE 3512917A DE 3512917 A1 DE3512917 A1 DE 3512917A1
- Authority
- DE
- Germany
- Prior art keywords
- macroemulsions
- weight
- polyvinyl alcohol
- percent
- group content
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000004907 Macro-emulsion Substances 0.000 title claims abstract description 46
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 32
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 31
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000000654 additive Substances 0.000 claims abstract description 13
- 239000002253 acid Substances 0.000 claims abstract description 9
- 125000003118 aryl group Chemical group 0.000 claims abstract description 9
- 239000003085 diluting agent Substances 0.000 claims abstract description 8
- 238000000034 method Methods 0.000 claims abstract description 8
- 239000002245 particle Substances 0.000 claims abstract description 7
- 239000002728 pyrethroid Substances 0.000 claims abstract description 7
- 239000007787 solid Substances 0.000 claims abstract description 7
- 241000607479 Yersinia pestis Species 0.000 claims abstract description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical group CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 24
- 239000000839 emulsion Substances 0.000 claims description 17
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 15
- 239000003921 oil Substances 0.000 claims description 10
- 239000012071 phase Substances 0.000 claims description 10
- 239000007864 aqueous solution Substances 0.000 claims description 9
- 239000008346 aqueous phase Substances 0.000 claims description 8
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 6
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 6
- 239000000243 solution Substances 0.000 claims description 5
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 claims description 4
- 238000002425 crystallisation Methods 0.000 claims description 4
- 239000003755 preservative agent Substances 0.000 claims description 4
- YATDSXRLIUJOQN-SVRRBLITSA-N (2,3,4,5,6-pentafluorophenyl)methyl (1r,3s)-3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropane-1-carboxylate Chemical compound CC1(C)[C@H](C=C(Cl)Cl)[C@H]1C(=O)OCC1=C(F)C(F)=C(F)C(F)=C1F YATDSXRLIUJOQN-SVRRBLITSA-N 0.000 claims description 3
- 239000005711 Benzoic acid Substances 0.000 claims description 3
- 150000007513 acids Chemical class 0.000 claims description 3
- 239000007798 antifreeze agent Substances 0.000 claims description 3
- 235000010233 benzoic acid Nutrition 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- UFWIBTONFRDIAS-UHFFFAOYSA-N naphthalene-acid Natural products C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 2
- VEMKTZHHVJILDY-UXHICEINSA-N bioresmethrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCC1=COC(CC=2C=CC=CC=2)=C1 VEMKTZHHVJILDY-UXHICEINSA-N 0.000 claims description 2
- -1 defoamers Substances 0.000 claims description 2
- 239000000975 dye Substances 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- 239000008096 xylene Substances 0.000 claims description 2
- 150000003738 xylenes Chemical class 0.000 claims description 2
- 150000001555 benzenes Chemical class 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 125000001624 naphthyl group Chemical group 0.000 claims 1
- 238000002360 preparation method Methods 0.000 abstract description 7
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 25
- 239000004480 active ingredient Substances 0.000 description 7
- 239000003995 emulsifying agent Substances 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 239000003960 organic solvent Substances 0.000 description 5
- 239000012141 concentrate Substances 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 239000012868 active agrochemical ingredient Substances 0.000 description 3
- 230000008025 crystallization Effects 0.000 description 3
- 230000002349 favourable effect Effects 0.000 description 3
- 239000004530 micro-emulsion Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 239000002562 thickening agent Substances 0.000 description 3
- 230000002110 toxicologic effect Effects 0.000 description 3
- 231100000723 toxicological property Toxicity 0.000 description 3
- RGHHSNMVTDWUBI-UHFFFAOYSA-N 4-hydroxybenzaldehyde Chemical compound OC1=CC=C(C=O)C=C1 RGHHSNMVTDWUBI-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 239000003849 aromatic solvent Substances 0.000 description 2
- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 description 2
- LLEMOWNGBBNAJR-UHFFFAOYSA-N biphenyl-2-ol Chemical group OC1=CC=CC=C1C1=CC=CC=C1 LLEMOWNGBBNAJR-UHFFFAOYSA-N 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 230000000622 irritating effect Effects 0.000 description 2
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 2
- 210000004400 mucous membrane Anatomy 0.000 description 2
- QELSKZZBTMNZEB-UHFFFAOYSA-N propylparaben Chemical compound CCCOC(=O)C1=CC=C(O)C=C1 QELSKZZBTMNZEB-UHFFFAOYSA-N 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- BTJIUGUIPKRLHP-UHFFFAOYSA-N 4-nitrophenol Chemical compound OC1=CC=C([N+]([O-])=O)C=C1 BTJIUGUIPKRLHP-UHFFFAOYSA-N 0.000 description 1
- 241000239223 Arachnida Species 0.000 description 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical class C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 230000000895 acaricidal effect Effects 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 1
- 239000001000 anthraquinone dye Substances 0.000 description 1
- 150000004056 anthraquinones Chemical class 0.000 description 1
- 239000000987 azo dye Substances 0.000 description 1
- 125000000751 azo group Chemical group [*]N=N[*] 0.000 description 1
- 229940095076 benzaldehyde Drugs 0.000 description 1
- 229960004365 benzoic acid Drugs 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 238000003898 horticulture Methods 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 230000000749 insecticidal effect Effects 0.000 description 1
- 229960002216 methylparaben Drugs 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 235000010292 orthophenyl phenol Nutrition 0.000 description 1
- QNGNSVIICDLXHT-UHFFFAOYSA-N para-ethylbenzaldehyde Natural products CCC1=CC=C(C=O)C=C1 QNGNSVIICDLXHT-UHFFFAOYSA-N 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 239000001007 phthalocyanine dye Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 238000005204 segregation Methods 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 235000010199 sorbic acid Nutrition 0.000 description 1
- 239000004334 sorbic acid Substances 0.000 description 1
- 229940075582 sorbic acid Drugs 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
Landscapes
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Dispersion Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Priority Applications (23)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19853512917 DE3512917A1 (de) | 1985-04-11 | 1985-04-11 | Makroemulsionen |
| ZW34/86A ZW3486A1 (en) | 1985-03-12 | 1986-02-14 | Macroemulsions |
| AU54014/86A AU573962B2 (en) | 1985-03-12 | 1986-02-24 | Macroemulsions comprising pyrethroids, polyvinyl alcohol and an aromatic diluent |
| DE8686102761T DE3661458D1 (de) | 1985-03-12 | 1986-03-03 | Macroemulsions |
| PT82129A PT82129B (en) | 1985-03-12 | 1986-03-03 | Process for the preparation of macroemulsions containing at least one solid pyrethroid as active ingredient |
| EP86102761A EP0197293B1 (de) | 1985-03-12 | 1986-03-03 | Makroemulsionen |
| AT86102761T ATE39319T1 (de) | 1985-03-12 | 1986-03-03 | Makroemulsionen. |
| NZ215407A NZ215407A (en) | 1985-03-12 | 1986-03-07 | Microemulsions containing pyrethroid biocides |
| US06/837,466 US4814167A (en) | 1985-03-12 | 1986-03-07 | Pyrettroid macroemulsions containing polyvinyl alcohol |
| CA000503673A CA1271646A (en) | 1985-03-12 | 1986-03-10 | Macroemulsions |
| DK108886A DK108886A (da) | 1985-03-12 | 1986-03-10 | Makroemulsioner |
| GR860650A GR860650B (en) | 1985-03-12 | 1986-03-10 | Macroemulsions |
| TR129/86A TR22758A (tr) | 1985-03-12 | 1986-03-10 | Yeni makroemuelsiyonlar bunlarin hazirlanisi icin usul ve zararhlarla muecadele de kullanimlari |
| IL78081A IL78081A (en) | 1985-03-12 | 1986-03-10 | Pesticidal pyrethroid macroemulsions and their preparation |
| JP61050715A JPS61212325A (ja) | 1985-03-12 | 1986-03-10 | マクロ乳化液 |
| KR1019860001715A KR860006923A (ko) | 1985-03-12 | 1986-03-11 | 마크로에멀젼 및 이의 제조방법 |
| BR8601035A BR8601035A (pt) | 1985-03-12 | 1986-03-11 | Macroemulsoes,processo para sua preparacao e emprego |
| MA20868A MA20643A1 (fr) | 1985-03-12 | 1986-03-11 | Macroemulsions, leur procede de production et leur utilisation comme pesticides |
| PH33509A PH21745A (en) | 1985-03-12 | 1986-03-11 | Macroemulsions |
| PL25836386A PL147429B1 (en) | 1985-04-11 | 1986-03-11 | Agrochemical macroemulsion |
| CS166286A CS259535B2 (en) | 1985-04-11 | 1986-03-11 | Macroemulsion and method of its production |
| ES552891A ES8800578A1 (es) | 1985-03-12 | 1986-03-11 | Procedimiento para la obtencion macroemulsiones de productos activos piretroides agroquimicos. |
| HU861041A HUT41198A (en) | 1985-03-12 | 1986-03-12 | Pesticide emulsions |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19853512917 DE3512917A1 (de) | 1985-04-11 | 1985-04-11 | Makroemulsionen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE3512917A1 true DE3512917A1 (de) | 1986-10-16 |
Family
ID=6267680
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19853512917 Withdrawn DE3512917A1 (de) | 1985-03-12 | 1985-04-11 | Makroemulsionen |
Country Status (3)
| Country | Link |
|---|---|
| CS (1) | CS259535B2 (cs) |
| DE (1) | DE3512917A1 (cs) |
| PL (1) | PL147429B1 (cs) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1988008248A1 (en) * | 1987-04-30 | 1988-11-03 | A/S Cheminova | An oil-in-water preparation for use as a pesticidal composition, and a method for combating pests therewith |
-
1985
- 1985-04-11 DE DE19853512917 patent/DE3512917A1/de not_active Withdrawn
-
1986
- 1986-03-11 CS CS166286A patent/CS259535B2/cs unknown
- 1986-03-11 PL PL25836386A patent/PL147429B1/pl unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1988008248A1 (en) * | 1987-04-30 | 1988-11-03 | A/S Cheminova | An oil-in-water preparation for use as a pesticidal composition, and a method for combating pests therewith |
Also Published As
| Publication number | Publication date |
|---|---|
| CS259535B2 (en) | 1988-10-14 |
| PL147429B1 (en) | 1989-06-30 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8130 | Withdrawal |